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    • 95. 发明授权
    • Method for producing difluorophosphate
    • 二氟磷酸盐生产方法
    • US09567217B2
    • 2017-02-14
    • US14419071
    • 2014-06-06
    • STELLA CHEMIFA CORPORATION
    • Sojiro KonTetsuo Nishida
    • C01B25/455
    • C01B25/455
    • Provided is a method for producing a difluorophosphate, which can simply and easily produce a high-purity difluorophosphate in an industrially advantageous manner. The method includes steps of: reacting an aqueous hydrofluoric acid solution with an oxyhalide of phosphorous (except phosphoric trifluoride) to produce a crude difluorophosphoric acid; reacting the crude difluorophosphoric acid with a halide of an alkali metal, an alkaline earth metal, aluminum or an onium to produce a difluorophosphate in the crude difluorophosphoric acid; and heating and drying the crude difluorophosphoric acid containing the difluorophosphate to distill away the crude difluorophosphoric acid, or precipitating the difluorophosphate in the crude difluorophosphoric acid by crystallization, subsequently separating the difluorophosphate by solid-liquid separation, and further distilling away the crude difluorophosphoric acid contained in the difluorophosphate after solid-liquid separation.
    • 本发明提供可以简单且容易地以工业上有利的方式制备高纯度二氟磷酸盐的二氟磷酸盐的制造方法。 该方法包括以下步骤:使氢氟酸水溶液与磷的卤氧化物(除了三氟化磷)反应以产生粗二氟磷酸; 使粗二氟磷酸与碱金属,碱土金属,铝或鎓的卤化物反应,在粗二氟磷酸中产生二氟磷酸盐; 并加热干燥含有二氟磷酸的粗二氟磷酸,蒸出粗二氟磷酸,或通过结晶沉淀粗二氟磷酸中的二氟磷酸盐,随后通过固 - 液分离分离二氟磷酸盐,进一步蒸馏除去含二氟磷酸的粗二氟磷酸 在固液分离后的二氟磷酸盐中。
    • 99. 发明授权
    • Method for producing hollow structual body
    • 生产中空结构体的方法
    • US08366980B2
    • 2013-02-05
    • US12668950
    • 2008-07-30
    • Terunori YamaguchiShinji HashiguchiMitsuo Ueno
    • Terunori YamaguchiShinji HashiguchiMitsuo Ueno
    • C04B40/00B27N3/08F16L9/00B29C47/00
    • D01F11/04B29C67/0014D01D5/24D06M11/09D06M11/11D06M11/17D06M11/22
    • It is intended to provide a method of producing a hollow construct, which may be in various shapes such as a fiber or a film as well as in various sizes and has chemical resistance, made of a fluorinated hydrocarbon polymer, a fluorinated carbon polymer or a polymer carrying a nitrogen-containing group, a silicon-containing group, an oxygen-containing group, a phosphorus-containing group or a sulfur-containing group having been introduced into the above-described polymer; and a hollow construct obtained by this method. The method of producing a hollow construct as described above is characterized by comprising the fluorination step wherein a construct made of a hydrocarbon polymer or a polymer carrying a nitrogen-containing group, a silicon-containing group, an oxygen-containing group, a phosphorus-containing group or a sulfur-containing group having been introduced into the above-described polymer is brought into contact with a treating gas containing fluorine under definite conditions and thus the treating gas is allowed to penetrate from the outer surface of the construct toward the inside thereof to thereby fluorinate the construct excluding the core part, and the removal step wherein the core part having been not fluorinated as described above is removed.
    • 本发明提供一种中空构造体的制造方法,该中空构造体可以是各种形状,例如纤维或膜,以及各种尺寸,并且具有耐化学性,由氟化烃聚合物,氟化碳聚合物或 携带含氮基团的聚合物,含有导入到上述聚合物中的含氮基团,含氧基团,含磷基团或含硫基团; 和通过该方法获得的中空构造。 如上所述的制造中空构造体的方法的特征在于包括氟化步骤,其中由烃聚合物或携带含氮基团的聚合物,含硅基团,含氧基团, 导入上述聚合物的含氟基团或含硫基团在一定条件下与含氟处理气体接触,从而允许处理气体从构造体的外表面向其内部渗透 除去核心部分以外的构造物氟化,除去上述未被氟化的芯部的除去工序。