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    • 91. 发明申请
    • CLEANING COMPOSITIONS INCORPORATING GREEN SOLVENTS AND METHODS FOR USE
    • 包含绿色溶剂的清洁组合物和使用方法
    • WO2009137096A1
    • 2009-11-12
    • PCT/US2009/002873
    • 2009-05-08
    • Rhodia Inc.TRIVEDI, SatyenFLUCK, DavidSEHGAL, AmitOSBORNE, AlexandraDAHANAYAKE, Manual S.TALINGTING-PABALAN, RuelaRUIZ, JoseAYMES, Charles
    • TRIVEDI, SatyenFLUCK, DavidSEHGAL, AmitOSBORNE, AlexandraDAHANAYAKE, Manual S.TALINGTING-PABALAN, RuelaRUIZ, JoseAYMES, Charles
    • C11D17/00C11D3/20C08G63/00
    • C11D3/2093C08G65/3314C08L71/02C09D9/005C11D1/72C11D3/43C11D11/0017C11D11/0023
    • An environmentally-friendly cleaning composition for industrial and consumer applications comprising (a) a blend of dibasic esters, (b) one or more surfactants (c) and, optionally, (d) water or a solvent. The dibasic esters are be derived from a blend of adipic, glutaric, and succinic diacids, and, in one particular embodiment, the blend comprises dialkyl adipate, dialkyl methylglutarate and dialkyl ethylsuccinate, wherein the alkyl groups individually comprise a C 1 -C 12 hydrocarbon group. The one or more surfactants are typically chosen from alcohol alkoxylate, an alkyl phenol ethoxylate, a terpene, a terpene alkoxylate or any derivates thereof. Optionally, additional components or additives including delaminates such as pinene and d- limonene, fragrances, whiteners, stabilizers, thickeners and the like can be added to the composition. The industrial or consumer application selected from the group consisting of a graffiti cleaner, a painted-substrate cleaner, an ink cleaner, a metal substrate cleaner, a plastic substrate cleaner, an environmentally friendly cleaner, a stain-spot cleaner, an industrial hand cleaner, a resin cleaner, a tar resin cleaner, a textile cleaner, a paint stripper and any combination thereof.
    • 一种用于工业和消费应用的环保清洁组合物,其包含(a)二元酯,(b)一种或多种表面活性剂(c)和任选的(d)水或溶剂的共混物。 二元酯衍生自己二酸,戊二酸和琥珀酸二酸的共混物,在一个具体实施方案中,共混物包括己二酸二烷基酯,甲基戊二烷基酯和乙基琥珀酸二烷基酯,其中烷基各自包含C 1 -C 12烃基。 一种或多种表面活性剂通常选自醇烷氧基化物,烷基酚乙氧基化物,萜烯,萜烯烷氧基化物或其任何衍生物。 任选地,可以向组合物中加入包括分层的附加组分或添加剂,例如蒎烯和d-柠檬烯,香料,增白剂,稳定剂,增稠剂等。 选自涂鸦清洁剂,涂漆基材清洁剂,油墨清洁剂,金属基材清洁剂,塑料基材清洁剂,环境友好的清洁剂,污点清洁剂,工业洗手液的工业或消费者应用 树脂清洁剂,焦油树脂清洁剂,纺织清洁剂,脱漆剂及其任何组合。
    • 93. 发明申请
    • SELF-SITUATING STIMULI-RESPONSIVE POLYMER COMPOSITIONS IN SOIL ADDITIVES AND METHODS FOR USE
    • 土壤添加剂中自发反应性聚合物组合物的使用方法和使用方法
    • WO2009123699A2
    • 2009-10-08
    • PCT/US2009/001979
    • 2009-03-31
    • RHODIA INC.CHEN, ZhiyunCASTAING, Jean-christopheLABEAU, Marie-pierreLIZARRAGA, Gilda
    • CHEN, ZhiyunCASTAING, Jean-christopheLABEAU, Marie-pierreLIZARRAGA, Gilda
    • C09K3/00
    • C05G3/04C05D9/02C05G3/0047C09K17/22C09K17/32C09K17/40C09K17/48C09K17/50
    • Disclosed are soil additives comprised of self-situating, stimuli-responsive polymer compositions and methods of their use. In one embodiment, the polymer composition or polymer network comprises permanent cross-links and non-permanent cross-links, wherein the non-permanent cross-links are capable of being removed upon application or exposure to a stimulus, typically located within the soil. In another embodiment, the method of increasing water retention in soils includes applying a soil additive, comprising polymer networks of the present invention admixed with an aqueous solution to form a colloidal dispersion solution or suspension, to a soil surface. The suspension or colloidal dispersion solution facilitates penetration of the polymer composition through the soil surface and into the soil, migrating typically to lower water potential areas and, more typically, along drainage channels located within the soil. After penetration of the soil surface, the polymer network is then exposed to a stimulus, typically present in the soil, whereby the non-permanent cross-links are removed and the polymer composition undergoes a volumetric change. This results in the prevention, arrest or decelerated loss of water from the targeted area, for example the plant root zone, which allows for improved water usage efficiency by plants, grasses, vegetation, etc.
    • 公开的是由自定位,刺激响应性聚合物组合物及其使用方法组成的土壤添加剂。 在一个实施方案中,聚合物组合物或聚合物网络包括永久性交联和非永久性交联,其中非永久性交联能够在施用或暴露于通常位于土壤内的刺激物时被除去。 在另一个实施方案中,增加土壤中的保水性的方法包括将包含本发明的聚合物网络的土壤添加剂与水溶液混合以形成胶体分散液或悬浮液到土壤表面。 悬浮液或胶体分散溶液有利于聚合物组合物穿过土壤表面并进入土壤,通常迁移到较低的水势区域,更典型地,沿着位于土壤内的排水通道。 在渗透土壤表面之后,聚合物网络然后暴露于通常存在于土壤中的刺激物,由此去除非永久性交联并且聚合物组合物经历体积变化。 这导致从目标区域(例如植物根区)防止,阻止或减少水分的损失,这允许植物,草,植物等改善水的使用效率。
    • 94. 发明申请
    • CROSSLINKED POLYSACCHARIDES AND METHODS OF PRODUCTION THEREOF
    • 交联多糖及其生产方法
    • WO2009099567A2
    • 2009-08-13
    • PCT/US2009/000617
    • 2009-01-30
    • RHODIA INC.MABILLE, CarolineLUCZAK, Kraig
    • MABILLE, CarolineLUCZAK, Kraig
    • A61K31/715C07H1/00
    • C07H1/00
    • A substantially boron-free method for making a cationic guar comprises reacting particles of polysaccharide with a derivatizing agent to produce derivatized polysaccharide particles, washing the derivatized polysaccharide particles, and contacting, prior to or after the washing step, the particles with a glyoxal compound in order to crosslink the derivatized polysaccharide particles. Also disclosed are methods for making crosslinked derivatized polysaccharides, comprising (a) contacting particles of a polysaccharide with a titanium compound in an aqueous medium having an alkaline pH under conditions appropriate to intra-particulately crosslink the particles; (b) reacting, prior to or after the step of contacting the particles of polysaccharide with the titanium compound, the particles of polysaccharide with a derivatizing agent under conditions appropriate to produce derivatized polysaccharide particles; (c) washing the titanium crosslinked and derivatized particles; (d) contacting, concurrently with or after the step of washing the titanium crosslinked and derivatized particles, such particles with an aqueous medium having an acidic pH under conditions appropriate to substantially de-crosslink the particles; and (e) contacting, concurrently with or after step (d), the de-crosslinked particles with a glyoxal compound under conditions appropriate to intra-particulately crosslink the particles. The crosslinked cationic guar of the present invention is especially useful in home and personal care formulations, especially formulations comprising silicone since it improves silicone deposition.
    • 用于制备阳离子瓜尔胶的基本上无硼的方法包括使多糖的颗粒与衍生化试剂反应以产生衍生化的多糖颗粒,洗涤衍生的多糖颗粒,以及在洗涤步骤之前或之后将所述颗粒与乙二醛化合物接触 以使衍生的多糖颗粒交联。 还公开了制备交联的衍生多糖的方法,其包括(a)在适于使颗粒特异性交联的条件下,在具有碱性pH的水性介质中使多糖的颗粒与钛化合物接触; (b)在使多糖颗粒与钛化合物接触的步骤之前或之后使多糖的颗粒与衍生剂在适于产生衍生化多糖颗粒的条件下反应; (c)洗涤钛交联和衍生的颗粒; (d)在使钛交联和衍生的颗粒洗涤步骤的同时或之后与具有酸性pH的水性介质在适于使颗粒基本上脱交的条件下接触; 和(e)在步骤(d)的同时或之后使脱乙烯基化合物在适于使颗粒特异性交联的条件下接触。 本发明的交联阳离子瓜尔胶在家用和个人护理制剂中尤其有用,特别是含有硅酮的制剂,因为它改善了硅氧烷沉积。
    • 95. 发明申请
    • LATEX BINDERS, AQUEOUS COATINGS AND PAINTS HAVING FREEZE-THAW STABILITY AND METHODS FOR USING SAME
    • LATEX粘合剂,具有冷冻 - 稳定性的水性涂料和油漆以及使用它们的方法
    • WO2009091592A1
    • 2009-07-23
    • PCT/US2009/000309
    • 2009-01-16
    • RHODIA INC.ZONG, ZhengangLI, Yi-zhongRUIZ, Jose
    • ZONG, ZhengangLI, Yi-zhongRUIZ, Jose
    • C08J9/00C09K8/584
    • C09D133/02C08F2/24C08K5/0008C09D133/08C08F2220/1825C08F220/14C08F220/06
    • Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.5% by weight of the polymer, in an amount greater than about 10% by weight of the polymer or in an amount greater than about 20% by weight of the polymer.
    • 公开了胶乳聚合物和具有优异的冻融稳定性,开放时间,耐污染性,低温成膜,耐泡沫性,抗粘连性,粘附性,水敏感性和低VOC含量的水性涂料组合物。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种与烷氧基化化合物共聚或共混的单体的胶乳聚合物,例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚。 还提供了包含至少一种胶乳聚合物,至少一种颜料,水和至少一种冻融添加剂的水性涂料组合物。 通常,大于约1.3重量%的聚合物的冻融添加剂,其量通常大于聚合物的约2重量%,其量大于聚合物的约4重量% 其量大于聚合物的约7.5重量%,其量大于聚合物的约10重量%,或大于聚合物重量的约20重量%。