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    • 99. 发明申请
    • METHODS OF CONTROLLING INSECTS
    • 控制方法
    • WO2014029707A1
    • 2014-02-27
    • PCT/EP2013/067183
    • 2013-08-16
    • SYNGENTA PARTICIPATIONS AG
    • EL QACEMI, MyriemCASSAYRE, Jérôme Yves
    • A01N43/36A01N43/653A01N43/80A01L7/04
    • A01N43/653A01N43/36A01N43/80
    • The present invention provides a method comprising applying to a crop of rice plants, the locus thereof, or propagation material thereof, a compound of formula (I) wherein -B 1 -Β 2 -Β 3 - is -C=N-O-, -C=N-CH 2 -, or -N-CH 2 -CH 2 -; providing that when A is A1 -B 1 -Β 2 -Β 3 - is -C=N-CH 2 - or -N-CH 2 -CH 2 -, when A is A2 -B 1 -Β 2 -Β 3 - is -C=N-O- or -N-CH 2 -CH 2 -, and when A is A3 -B 1 -B 2 -B 3 - is -C=N-O-; R 1 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl; R 2 is group (X) X 2 is C-X 6 or nitrogen; X 1 , X 3 and X 6 are independently hydrogen, halogen or trihalomethyl, wherein at least one of X 1 , X 3 and X 6 : is not hydrogen; A is selected from (A1) to (A5) Y 1 is C-R 6 , CH or nitrogen; Y 2 and Y 3 are independently CH or nitrogen; wherein no more than two of Y 1 , Y 2 and Y 3 are nitrogen and wherein Y 2 and Y 3 are not both nitrogen; R 5 is hydrogen, halogen, cyano, nitro, NH2, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 3 -C 5 cycloalkyl, C 3 -C 5 halocycloalkyl, C 1 -C 2 alkoxy, or C 1 -C 2 haloalkoxy; providing that when A is A3 or A4, R 5 is not hydrogen; R 6 when present together with R 5 forms a -CH=CH-CH=CH- bridge; R 7 is C 1 -C 4 alkyl; R 8 is C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy(C 1 -C 4 )alkyl, C 1 -C 4 alkylthio(C 1 -C 4 )alkyl, C 1 -C 4 alkylsulfmyl(C 1 -C 4 )alkyl, C 1 -C 4 alkylsulfonyl(C 1 -C 4 )alkyl, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkyl(C 1 -C 4 )alkyl-, or tetrahydrofuranyl; R 9 is C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkyl-O-CH 2 -, C 1 -C 4 haloalkyl-O-CH 2 -,C 3 -C 6 cycloalkyl, C 3 - C 6 cycloalkyl-CH 2 , C 1 -C 4 alkyl-S-CH 2 -, C 1 -C 4 alkyl-S(O)-CH 2 -, or C 1 -C 4 alkyl-S(O)-CH 2 ; each Z is independently halogen, C 1 -C 12 alkyl or C 1 -C 12 alkyl substituted by one to five R 12 , nitro, C 1 -C 12 alkoxy or C 1 -C 12 alkoxy substituted by one to five R 12 cyano, C 1 -C 12 alkylsulfinyl, C 1 -C 12 alkylsulfonyl, C 1 -C 12 haloalkylsulfinyl, C 1 -C 12 haloalkylsulfonyl, hydroxyl or thiol; each R 12 is halogen, cyano, nitro, hydroxy, C 1 -C 8 alkoxy-, C 1 -C 8 haloalkoxy-, mercapto, C 1 -C 8 alkylthio-, or C 1 -C 8 haloalkylthio; and k is 0, 1,2 or 3.
    • 本发明提供了一种方法,其包括向一系列水稻植物,其基因座或其繁殖材料施用式(I)化合物,其中-B1-β2-β3-为-C = NO-,-C = N -CH 2 - 或-N-CH 2 -CH 2 - ; 条件是当A为A 1 -B1-β2-β3-为-C = N-CH2-或-N-CH2-CH2-时,当A为A2 -B1-β2-β3-为-C = NO-或-N -CH 2 -CH 2 - ,当A为A3 -B1-B2-B3-时为-C = NO-; R1是三氟甲基,二氟甲基或氯二氟甲基; R2是基团(X)X2是C-X6或氮; X1,X3和X6独立地为氢,卤素或三卤代甲基,其中X1,X3和X6:中的至少一个不是氢; A选自(A1)至(A5),Y1为C-R6,CH或氮; Y2和Y3独立地是CH或氮; 其中Y1,Y2和Y3中不超过两个是氮,并且其中Y2和Y3不都是氮; R5是氢,卤素,氰基,硝基,NH2,C1-C4烷基,C1-C4卤代烷基,C3-C5环烷基,C3-C5卤代环烷基,C1-C2烷氧基或C1-C2卤代烷氧基; 条件是当A为A3或A4时,R5不为氢; 当与R 5一起存在时,R 6形成-CH = CH-CH = CH-桥; R7是C1-C4烷基; R8是C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基(C1-C4)烷基,C1-C4烷硫基(C1-C4)烷基,C1-C4烷基亚磺酰基(C1-C4)烷基,C1-C4烷基磺酰基(C1-C4)烷基, C 3 -C 6环烷基,C 3 -C 6环烷基(C 1 -C 4)烷基或四氢呋喃基; R9是C1-C4烷基,C1-C4卤代烷基,C1-C4烷基-O-CH2-,C1-C4卤代烷基-O-CH2-,C3-C6环烷基,C3-C6环烷基-CH2,C1-C4烷基-S-CH2-,C1-C4烷基 -S(O)-CH 2 - 或C 1 -C 4烷基-S(O)-CH 2; 每个Z独立地是卤素,被一至五个被一至五个R 12氰基,C 1 -C 12烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 1 -C 12烷基亚磺酰基取代的1至5个R 12,硝基,C 1 -C 12烷氧基或C 1 -C 12烷氧基取代的C 1 -C 12烷基或C 1 -C 12烷基 -C 12卤代烷基磺酰基,羟基或硫醇; 每个R 12是卤素,氰基,硝基,羟基,C 1 -C 8烷氧基 - ,C 1 -C 8卤代烷氧基 - ,巯基,C 1 -C 8烷硫基 - 或C 1 -C 8卤代烷硫基; 且k为0,1,2或3。
    • 100. 发明申请
    • METHODS OF SOIL PEST CONTROL
    • 土壤病虫害控制方法
    • WO2014029639A1
    • 2014-02-27
    • PCT/EP2013/066691
    • 2013-08-09
    • SYNGENTA PARTICIPATIONS AG
    • EL QACEMI, MyriemCASSAYRE, Jérôme YvesKURTZ, Benedikt
    • A01N43/80A01P7/00
    • A01N43/80G06Q30/018
    • The present invention relates to methods of controlling and/or preventing soil-dwelling pests in useful plants comprising applying to the locus of the useful plant or treating plant propagation material thereof with a compound of formula (I) wherein -B 1 -B 2 -B 3 - is -C=N-O-, -C=N-CH 2 -, -C=CH 2 -O- or -N-CH 2 -CH 2 -; L is a direct bond or methylene; A 1 and A 2 are C-H, or one of A 1 and A 2 is C-H and the other is N; X 1 is group X, formula (X) R 1 is C 1 -C 4 alkyl, C 1 -C 4 aloalkyl or C 3 -C 6 cycloalkyl; R 2 is chlorodifluoromethyl or trifluoromethyl; each R 3 is independently bromo, chloro, fluoro or trifluoromethyl; R 4 is hydrogen, halogen, methyl, halomethyl or cyano; R 5 is hydrogen; or R 4 and R 5 together form a bridging 1,3-butadiene group; p is 2 or 3. Preferably the soil-dwelling pest is selected from corn rootworm, wireworms, grubs, in particular white grubs (e.g. Phyllophaga sp., Diloboderus sp., Popillia japonica), termites (in particular for sugar cane), subterraneous stinkbugs (e.g. Scaptocoris sp.), cutworms (e.g. agrotis sp.), millipedes (e.g. Julus sp.) and broca gigante (e.g. Telchin licus).
    • 本发明涉及在有用植物中控制和/或预防土壤存在害虫的方法,其包括用式(I)化合物施用于有用植物的场所或处理植物繁殖材料,其中-B1-B2-B3- 是-C = NO - , - C = N-CH 2 - , - C = CH 2 -O-或-N-CH 2 -CH 2 - ; L是直接键或亚甲基; A1和A2是C-H,A1和A2之一是C-H,另一个是N; X 1为基团X,式(X)R 1为C 1 -C 4烷基,C 1 -C 4卤代烷基或C 3 -C 6环烷基; R2是氯二氟甲基或三氟甲基; 每个R 3独立地是溴,氯,氟或三氟甲基; R4是氢,卤素,甲基,卤代甲基或氰基; R5是氢; 或R4和R5一起形成桥连1,3-丁二烯基团; p为2或3.优选地,土壤有害生物选自玉米根虫,线虫,gr s,特别是白ub(如Phyllophaga sp。,Diloboderus sp。,Popillia japonica),白蚁(特别是甘蔗),subterraneous 臭椿(例如鳞翅目(Scaptocoris sp。)),夜蛾(例如ag is属),千足虫(例如茱萸属)和布鲁卡甘(例如,Telchin licus)。