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    • 95. 发明授权
    • Imidazole compounds and biocidal composition comprising the same for
controlling harmful organisms
    • 咪唑化合物和杀生物组合物,其组成物包含用于控制有害生物体的化合物
    • US4995898A
    • 1991-02-26
    • US168070
    • 1988-03-14
    • Rikuo NasuTerumasa KomyojiToshio NakajimaKazumi SuzukiKeiichiro ItoTakeshi OshimaHideshi Yoshimura
    • Rikuo NasuTerumasa KomyojiToshio NakajimaKazumi SuzukiKeiichiro ItoTakeshi OshimaHideshi Yoshimura
    • A01N43/50A01N31/14A01N33/00A01N37/34A01N43/08A01N43/84A01N55/00A01P3/00C07D233/84C07D233/90C07D233/92C07D401/04C07D401/12C07D405/04C07D405/14C07D409/04C07D409/12C07F7/08
    • C07D401/04A01N43/50A01N55/00C07D233/90C07D401/12C07D405/04C07D405/14C07D409/04C07F7/0814
    • Novel imidazole compounds are disclosed, which are represented by the following general formula: ##STR1## wherein: R.sub.1 represents a cyano group or a --CSNHR.sub.5 group, wherein R.sub.5 represents a hydrogen atom, a C.sub.1-4 alkyl group, or a --COR.sub.6 group, wherein R.sub.6 represents a C.sub.1-4 alkyl group, a halogenated C.sub.1-4 alkyl group, or a phenyl group;R.sub.2 and R.sub.3 each represents a hydrogen atom; a halogen atom; a nitro group; a cyano group; a trimethylsilyl group; a C.sub.3-6 cycloalkyl group; a naphthyl group; a C.sub.1-12 alkyl group which is optionally substituted with one or more halogen atoms, hydroxyl groups, acetoxy groups, C.sub.1-4 alkoxy groups, halogenated C.sub.1-4 alkoxy groups, phenyl groups, halogenated phenyl groups, or C.sub.1-4 alkylated phenyl groups; a C.sub.2-10 alkenyl group which is optionally substituted with one or more halogen atoms; a C.sub.1-6 alkoxy group which is optionally substituted with one or more halogen atoms; a phenyl group which is optionally substituted with one or more halogen atoms, C.sub.1-4 alkyl groups, halogenated C.sub.1-4 alkyl groups, C.sub.1-4 alkoxy groups, halogenated C.sub.1-4 alkoxy groups, C.sub.1-4 alkylthio groups, halogenated C.sub.1-4 alkylthio groups, nitro groups, cyano groups, or 3,4-methylenedioxy groups; a furyl group which is optionally substituted with one or more halogen atoms or C.sub.1-4 alkyl groups; a thienyl group which is optionally substituted with one or more halogen atoms or C.sub.1-4 alkyl groups; a pyridyl group which is optionally substituted with one or more halogen atoms or C.sub.1-4 alkyl groups; an --SO.sub.n R.sub.7 group, wherein R.sub.7 represents a C.sub.1-6 alkyl group, a C.sub.2-6 alkenyl group, a phenyl group which is optionally substituted with one or more halogen atoms, a benzyl group, a pyridyl group which is optionally substituted with one or more halogen atoms, C.sub.1-4 alkyl groups, or halogenated C.sub.1-4 alkyl groups; or an --NR.sub.8 R.sub.9 group, wherein R.sub.8 and R.sub.9 each represents a C.sub.1-4 alkyl group, and n is 0, 1, or 2; or a --CO(NH).sub.m R.sub.10 group, wherein R.sub.10 represents a C.sub.1-4 alkyl group which is optionally substituted with one or more halogen atoms, a C.sub.1-4 alkoxy group which is optionally substituted with one or more halogen atoms, or a phenyl group which is optionally substituted with one or more halogen atoms; and m is 0 or 1; andR.sub.4 represents a C.sub.1-6 alkyl group which is optionally substituted with one or more halogen atoms; a C.sub.3-6 cycloalkyl group; a phenyl group; a thienyl group; or an --NR.sub.11 R.sub.12 group, wherein R.sub.11 and R.sub.12 each represents a hydrogen atom, a C.sub.1-4 alkyl group which is optionally substituted with one or more halogen atoms, a C.sub.2-4 alkenyl group, or R.sub.11 and R.sub.12 are combined with each other together with a nitrogen atoms adjacent thereto to form a pyrrolidinyl group, a piperidinyl group, a morpholino group, or a thiomorpholino group, provided that R.sub.11 and R.sub.12 are not simultaneously a hydrogen atom;provided that R.sub.2 and R.sub.3 are not simultaneously a halogen atom. The compounds are effective as biocides.
    • 由通式I表示的咪唑化合物:其中:R1表示氰基或-CSNHR5基团,其中R5表示氢原子,C1-4烷基或-COR6基团,其中R6表示C1- 4烷基,卤代C 1-4烷基或苯基; R2和R3各自表示氢原子; 卤素原子; 硝基; 氰基; 三甲基甲硅烷基 C 3-6环烷基; 萘基; 任选取代的C 1-12烷基,C 2-10烯基,C 1-6烷氧基,苯基,呋喃基,亚硫酰基或吡啶基; a-SO n R 7基,其中R 7表示C 1-6烷基,C 2-6烯基,苄基,任选取代的苯基或吡啶基; NR8R9基团,其中R8和R9各自表示C1-4烷基,n为0,1或2; 或-CO(NH)m R 10 gorup,其中R 10表示任选取代的C 1-4烷基,C 1-4烷氧基或苯基,m为0或1; 并且R 4表示任选被一个或多个卤素原子取代的C 1-6烷基; C 3-6环烷基; 苯基; 噻吩基; 或-NR 11 R 12基团,其中R 11和R 12各自表示氢原子,任选被一个或多个卤素原子取代的C 1-4烷基,C 2-4链烯基或R 11和R 12一起彼此结合 与其相邻的氮原子形成吡咯烷基,哌啶基,吗啉代基或硫代吗啉基,条件是R 11和R 12不同时为氢原子; 条件是R2和R3不同时为卤素原子。 这些化合物作为杀生物剂是有效的。