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91. 发明授权

US4517277A Photosensitive recording material suitable for the production of printing plates and relief plates, and the production of these plates using this recording material 失效
标题翻译：适用于生产印版和浮雕板的感光记录材料，以及使用该记录材料生产这些印版
公开(公告)号：US4517277A
公开(公告)日：1985-05-14
申请号：US437699
申请日：1982-10-29
申请人： John Lynch , Herbert Naarmann , Gunther Schulz , Rudolf Vyvial , Gunter Wallbillich , Manfred Zurger
发明人： John Lynch , Herbert Naarmann , Gunther Schulz , Rudolf Vyvial , Gunter Wallbillich , Manfred Zurger
IPC分类号： G03F7/09 , C08F8/14 , G03F7/00 , G03F7/027 , G03F7/032 , G03F7/033 , G03F7/038 , G03C1/68 , C08F8/02
CPC分类号： G03F7/0388 , C08F8/14 , G03F7/033 , G03F7/038 , C08F2810/30 , Y10S430/11
摘要： Photosensitive recording materials which are suitable for the production of printing plates and relief plates and possess a photopolymerizable relief-forming layer which can be developed with water and is based on a polyvinylalcohol/monomer mixture contain, as a binder in the said layer, a polyvinylalcohol derivative which is obtained by reacting polyvinylalcohol with an acylating agent which has groups which are polymerizable by free radicals, the reaction being carried out in the heterogeneous phase, in an aprotic dispersant, using the acylating agent in an amount which corresponds to not less than twice the molar amount required to achieve the desired degree of acylation.
摘要翻译：适用于生产印版和浮雕板的光敏记录材料，并具有可用水显影并基于聚乙烯醇/单体混合物的可光聚合的浮雕形成层，在所述层中含有作为粘合剂的聚乙烯醇衍生物，其通过使聚乙烯醇与具有可自由基聚合的基团的酰化剂反应获得，该反应在非质子分散剂中在非均相中进行，使用酰化剂，其量相当于不少于两倍达到所需酰化度所需的摩尔量。

92. 发明授权

US4468509A Reversibly oxidizable or reducible polymers containing polyene units, their preparation and their use 失效
标题翻译：含有多烯单元的可逆的可还原的可还原的聚合物，它们的制备及其用途
公开(公告)号：US4468509A
公开(公告)日：1984-08-28
申请号：US526665
申请日：1983-08-25
申请人： Herbert Naarmann , Volker Muench , Klaus-Dieter Franz
发明人： Herbert Naarmann , Volker Muench , Klaus-Dieter Franz
IPC分类号： C09K3/16 , C08F8/00 , C08F38/00 , C08L49/00 , G02F1/15 , H01B1/12 , H01L51/30 , H01L51/42 , H01M4/60 , C08F12/32
CPC分类号： H01M4/60 , C08F38/00 , C08F8/00 , G02F1/15 , H01B1/125 , H01L51/0041 , H01L51/0052 , H01L51/0051 , H01L51/42 , Y02E10/549
摘要： Polymers which comprise polyene units possessing 5 or more conjugated aliphatic C-C double bonds and contain 1,9-disubstituted phenalenes as chemically bonded side groups are prepared by a process in which acetylene derivatives carrying 1,9-disubstituted phenalene groups are polymerized. The polymers obtained are used in the electrical industry or as reversible redox systems or for the antistatic treatment of plastics.
摘要翻译：包含具有5个或更多个共轭脂族C-C双键的多烯单元并含有作为化学键合侧基的1,9-二取代的非对映体的聚合物通过其中携带1,9-二取代的非苯烯基团的乙炔衍生物聚合的方法制备。所获得的聚合物用于电气工业或用作可逆的氧化还原体系或用于塑料的抗静电处理。

93. 发明授权

US4440693A Preparation of electrically conductive products 失效
标题翻译：导电产品的制备
公开(公告)号：US4440693A
公开(公告)日：1984-04-03
申请号：US327726
申请日：1981-12-04
申请人： Herbert Naarmann , Klaus Penzien , Volker Muench , Klaus-Dieter Franz
发明人： Herbert Naarmann , Klaus Penzien , Volker Muench , Klaus-Dieter Franz
IPC分类号： C08G79/00 , C08G79/14 , C08K5/00 , H01B1/12 , H01L51/30 , C07F1/08 , C07F15/02
CPC分类号： H01L51/0077 , C08G79/00 , C08G79/14 , C08K5/0091 , H01B1/12 , H01L51/0051 , H01L51/0052 , Y02E10/549
摘要： A process for the preparation of electrically conductive products which are stable to air and have conductivities greater than 1 .times.10.sup.-3 S/cm, by reacting a cation of a metal of group VII or VIII or of sub-group I of the periodic table with an organic chelating compound to give a metal chelate and oxidizing the latter to form a oxidized product, wherein the organic chelating compound is a 1,9-substituted phenalene of the formula I ##STR1## where X is O, NH, S, Se or Te and Y is OH, NH.sub.2 or SH. The electrically conductive products are useful for the production of solar cells, the conversion and fixing of radiation, the production of electrical and magnetic switches and the antistatic treatment of plastics.
摘要翻译：通过将元素周期表第VII族或第Ⅷ族金属或第1族元素的阳离子与阳离子的反应，通过使周期表第Ⅶ族或Ⅷ族金属的阳离子与一种有机螯合化合物，得到金属螯合物并将其氧化以形成氧化产物，其中有机螯合化合物是式I的1,9-取代的非那烯，其中X是O，NH，S，Se或 Te和Y是OH，NH2或SH。导电产品可用于生产太阳能电池，辐射的转换和固定，电气和磁性开关的生产以及塑料的抗静电处理。

94. 发明授权

US4395497A Preparation of electrically conductive soluble heteropolyphenylenes 失效
标题翻译：导电性可溶性多聚苯乙烯的制备
公开(公告)号：US4395497A
公开(公告)日：1983-07-26
申请号：US273688
申请日：1981-06-15
申请人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
发明人： Herbert Naarmann , Dieter Naegele , Klaus Penzien , Johannes Schlag
IPC分类号： C08G61/12 , C08L65/00 , H01B1/12 , H01L51/30 , C08L77/02
CPC分类号： H01B1/128 , C08G61/123 , C08L65/00 , H01B1/127 , H01L51/0035 , C08G2261/312 , Y02E10/549
摘要： A process for the preparation of electrically conductive heteropolyphenylenes, wherein from 0.5 to 5 per cent by weight of an activating additive is introduced, in the absence of moisture and of oxygen, into a heteropolyphenylene of the general formula ##STR1## where X is O, S, Se, SO or SO.sub.2 and Y has one of the meanings given for X or is NH, CH.sub.2, CO or C.sub.6 H.sub.4, and n is from 2 to 250. The activating additive is preferably one of the compounds AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, SbCl.sub.5, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid and 2,4,6-trinitrophenylcarboxylic acid, or is sodium, potassium, rubidium, cesium, calcium or barium or one of their amides, the latter being added, if appropriate, in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene. The conductive heteropolyphenylenes may be used in the electrical industry for the production of solar cells, for conversion and fixing of radiation and for the production of electrical and magnetic switches, or may be used for the antistatic treatment of plastics.
摘要翻译：一种用于制备导电杂多苯基苯的方法，其中将0.5-5重量％的活化添加剂在没有水分和氧气的情况下引入通式为“IMAGE”的杂多亚苯基，其中X为O， S，Se，SO或SO 2，Y具有对X给出的含义之一或为NH，CH 2，CO或C 6 H 4，n为2至250.活化添加剂优选为化合物AsF5，SbF5，UF6， HClO4，NO + SbF6-，NO2 + SbF6-，NO + PF6-，SbCl5，NO2 + PF6-，NO + BF4-，NO + ClO4-，（CF3）2SO4,2,4,6-三硝基苯酚，6-三硝基苯磺酸和2,4,6-三硝基苯基羧酸，或者是钠，钾，铷，铯，钙或钡或它们的酰胺之一，如果合适，将其加入四氢呋喃，二甲氧基乙二醇，蒽，萘或2-甲基苯乙烯。导电杂多亚苯基可用于电气工业中用于生产太阳能电池，用于辐射的转换和固定以及用于电气和磁性开关的生产，或可用于塑料的抗静电处理。

95. 发明授权

US4336201A Preparation of electrically conductive carotenoids 失效
标题翻译：制备导电类胡萝卜素
公开(公告)号：US4336201A
公开(公告)日：1982-06-22
申请号：US203598
申请日：1980-11-03
申请人： Franz Feichtmayr , Herbert Naarmann , Joachim Paust , Klaus Penzien
发明人： Franz Feichtmayr , Herbert Naarmann , Joachim Paust , Klaus Penzien
IPC分类号： C07C47/20 , C07C47/21 , C07C403/00 , C09K3/16 , H01B1/12 , H01L31/18 , H01L51/30 , C07C175/00 , C11C3/02
CPC分类号： H01B1/125 , C07C403/24 , C07C47/21 , C09K3/16 , H01L51/0041 , Y02E10/549
摘要： A process for the preparation of an electrically conductive polyene, wherein a polyene which contains one or more chain members of the formula where R is hydrogen or methyl, and which contains a total of not less than seven aliphatic double bonds, is treated, in the absence of moisture and of oxygen, with a strong Lewis acid having a pk.sub.a of from -10 to +4, or with an alkali metal.
摘要翻译：一种制备导电多烯的方法，其中含有一个或多个式（IMAGE）的链成员的多烯，其中R是氢或甲基，并含有总共不少于7个脂族双键的多烯被处理在没有水分和氧气的情况下，使用pka为-10至+4的强路易斯酸，或与碱金属反应。

96. 发明授权

US4205144A Preparation of graft copolymers 失效
标题翻译：接枝共聚物的制备
公开(公告)号：US4205144A
公开(公告)日：1980-05-27
申请号：US952801
申请日：1978-10-19
申请人： Herbert Naarmann , Graham E. McKee , Burghard Schmitt
发明人： Herbert Naarmann , Graham E. McKee , Burghard Schmitt
IPC分类号： C08F265/06 , C08F291/02 , C08L51/04
CPC分类号： C08F291/02 , C08F265/06
摘要： Graft copolymers comprising a crosslinked, saturated, elastomeric grafting base and a hard shell are prepared by incorporating thermolabile comonomers, as copolymerized units, into the grafting base during the preparation of the latter, in particular at a conversion of from 50 to 90%. During the subsequent grafting of the shell, the conditions used are such that the thermolabile comonomers incorporated as copolymerized units into the grafting base decompose into free radicals. This gives graft copolymers having improved mechanical properties, which copolymers also prove advantageous for the preparation of mixtures with other thermoplastics compatible with the graft copolymers.
摘要翻译：包含交联的，饱和的，弹性体接枝的基底和硬壳的接枝共聚物是通过将不溶性共聚单体作为共聚单元掺入到接枝基中制备的，特别是在50至90％的转化率下。在随后的壳接枝过程中，使用的条件是使作为共聚单元掺入接枝基质中的不耐热共聚单体分解成自由基。这提供了具有改善的机械性能的接枝共聚物，该共聚物也证明有利于制备与其它与接枝共聚物相容的热塑性塑料的混合物。

97. 发明授权

US4121027A Polymerization initiators containing thio bridges 失效
标题翻译：含有硫桥的聚合引发剂
公开(公告)号：US4121027A
公开(公告)日：1978-10-17
申请号：US792881
申请日：1977-05-02
申请人： Heinz Pohlemann , Herbert Naarmann , Dieter Seebach
发明人： Heinz Pohlemann , Herbert Naarmann , Dieter Seebach
IPC分类号： C08C19/20 , C08F2/00 , C08F4/00 , C08F4/42 , C08F8/34 , C08C19/00 , C08F4/16
CPC分类号： C08F4/00 , C08C19/20 , C08F4/42 , C08F8/34
摘要： A process for the manufacture of reactive polymers of vinyl monomers by reacting the latter, or the polymers formed therefrom, with compounds which form free radicals.The latter compounds are tetrakis-(organylthio)-methanes, 1,1,2,2-tetrakis-(organylthio)-ethanes or hexakis-(organylthio)-ethanes.The polymers obtained can readily be modified, e.g. by oxidation or quaternisation.
摘要翻译：通过使后者或由其形成的聚合物与形成自由基的化合物反应制备乙烯基单体的反应性聚合物的方法。

98. 发明授权

US4083835A Coating processes, compositions and substrates coated with maleic anhydride copolymers having the anhydride moieties reacted with hydrozine or its derivatives 失效
标题翻译：用酸酐部分与马来酸酐共聚物涂覆的涂布方法，组合物和基材与氢化锌或其衍生物反应
公开(公告)号：US4083835A
公开(公告)日：1978-04-11
申请号：US699931
申请日：1976-06-25
申请人： Heinz Pohlemann , Hermann Gausepohl , Herbert Naarmann
发明人： Heinz Pohlemann , Hermann Gausepohl , Herbert Naarmann
IPC分类号： C08F8/00 , C08F8/30 , C08F8/32 , D21H17/43 , D21H17/45 , C08F8/34
CPC分类号： D21H17/455 , C08F8/30 , C08F8/32 , D21H17/43 , Y10T428/263 , Y10T428/31699 , Y10T428/3188 , Y10T428/31935
摘要： Copolymers which have a molecular weight of from 600 to 24,500, and which contain from 0.1 to 60 per cent by weight of succinic acid hydrazide units and from 99.9 to 40% by weight of one or more ethylenically unsaturated monomers which are copolymerizable with maleic anhydride, are used as coating agents and binders.
摘要翻译：共聚物的分子量为600至24,500，并含有0.1至60重量％的琥珀酸酰肼单元和99.9至40重量％的一种或多种烯键式不饱和单体，其可与马来酸酐共聚，用作包衣剂和粘合剂。

99. 发明授权

US3933765A Polymers containing thioglycol groups 失效
标题翻译：含有巯基的聚合物
公开(公告)号：US3933765A
公开(公告)日：1976-01-20
申请号：US453376
申请日：1974-03-21
申请人： Herbert Naarmann , Heinz Pohlemann
发明人： Herbert Naarmann , Heinz Pohlemann
IPC分类号： C08F28/00 , C08F3/84
CPC分类号： C08F28/00
摘要： Polymers containing units of the general formula: ##EQU1## in which X denotes --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --, ##SPC1##or divalent C.sub.3.sup.+10 cycloalkyl,n denotes 0 or 1 andR denotes H, C.sub.1.sup.+10 alkyl or aryl.These polymers are used in the manufacture of crosslinkable coatings and for finishing papers and textiles.
摘要翻译：含有以下通式的单体的聚合物：其中X表示-CH 2 - ， - CH 2 - ， - CH 2 - 或二价C 3-10环烷基，N DENOTES 0 OR 1，R表示H，C 1-10烷基或芳基。

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