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91. 发明授权

US5258357A Carboxamides, their preparation and their use as herbicides 失效
标题翻译：羧甲酰胺，它们的制备及其作为除草剂的用途
公开(公告)号：US5258357A
公开(公告)日：1993-11-02
申请号：US947538
申请日：1992-09-21
申请人： Peter Muenster , Gerd Steiner , Wolfgang Freund , Bruno Wuerzer , Karl-Otto Westphalen
发明人： Peter Muenster , Gerd Steiner , Wolfgang Freund , Bruno Wuerzer , Karl-Otto Westphalen
IPC分类号： A01N43/08 , A01N43/10 , A01N43/28 , C07D307/68 , C07D333/38 , C07D407/12 , C07D409/12 , C07D417/12 , A01N57/08 , C07D307/38
CPC分类号： C07D407/12 , A01N43/08 , A01N43/10 , A01N43/28 , C07D307/68 , C07D333/38 , C07D409/12 , C07D417/12
摘要： Carboxamides of the formulae Ia to Ic ##STR1## where X is oxygen or sulfur;R.sup.1 is hydrogen or substituted or unsubstituted cycloalkyl or alkyl;R.sup.2 is hydroxy, alkoxy, cyanoalkyl, substituted or unsubstituted alkenyl, alkynyl, phenyl or naphthyl, a substituted or unsubstituted 5- to 6-membered heterocyclic structure or one of the groups stated for R.sup.1, orR.sup.1 and R.sup.2 together are a 4- to 7-membered chain which contains, in addition to methylene groups, one of the following groups as ring member: oxygen, sulfur, N-methyl or carbonyl;R.sup.3 and R.sup.4 are each nitro, cyano, halogen, substituted or unsubstituted amino, alkoxy, alkylthio, a substituted or unsubstituted 5- to 6 -membered heterocyclic structure, substituted or unsubstituted alkenyl, alkynyl, phenyl, phenoxy or phenylthio, or one of the groups stated for R.sup.1 ;R.sup.5 is formyl, 4,5-dihydrooxazol-2-yl or COYR.sup.6 (Y=O,S);R.sup.6 is hydrogen, cycloalkyl, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkenyl or phenyl,a 5- to 6-membered heterocyclic structure, phthalimido, tetrahydrophthalimido, succinimido, maleimido, benzotriazolyl ora group --N.dbd.CR.sup.7 R.sup.8, whereR.sup.7 and R.sup.8 are hydrogen or alkyl, and R.sup.8 may also be cycloalkyl, phenyl, furyl or R.sup.7 and R.sup.8 together form a 4- to 7 -membered alkylene chain; and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.2 is hydrogen, R.sup.3 is not hydrogen and R.sup.4 is not hydrogen or methyl, and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.4 is hydrogen, R.sup.3 is not hydrogen or R.sup.2 is not one of the following groups: hydrogen; C.sub.1 -C.sub.4 -alkyl, phenyl; 2-(3,4-dimethoxyphenyl)ethyl or 2,5 -dichlorothien-3-yl;processes for the manufacture of compounds I and herbicidal agents containing them.
摘要翻译：式Ia至Ic的酰胺酰胺其中X是氧或硫; R1是氢或取代或未取代的环烷基或烷基; R 2是羟基，烷氧基，氰基烷基，取代或未取代的烯基，炔基，苯基或萘基，取代或未取代的5至6元杂环结构或对于R1表示的基团之一，或R 1和R 2一起为4- 除了亚甲基之外，还含有以下基团之一的环元素：氧，硫，N-甲基或羰基的7-元链; R 3和R 4各自为硝基，氰基，卤素，取代或未取代的氨基，烷氧基，烷硫基，取代或未取代的5-至6-元杂环结构，取代或未取代的烯基，炔基，苯基，苯氧基或苯硫基， R1表示的组; R5是甲酰基，4,5-二氢恶唑-2-基或COYR 6（Y = O，S）; R 6是氢，环烷基，取代或未取代的烷基，烯基，炔基，环烯基或苯基，5-至6-元杂环结构，邻苯二甲酰亚氨基，四氢邻苯二甲酰亚胺基，琥珀酰亚胺基，马来酰亚胺基，苯并三唑基或基团-N = CR 7 R 8，其中R 7和R 8 R 8也可以是环烷基，苯基，呋喃基，或者R 7和R 8一起形成4-7个亚烷基链; 如果R5是羧基，甲氧基羰基或乙氧基羰基，R2是氢，R3不是氢，R4不是氢或甲基，如果R5是羧基，甲氧基羰基或乙氧基羰基，R4是氢，R3不是氢或R2不是以下组：氢; C 1 -C 4 - 烷基，苯基; 2-（3,4-二甲氧基苯基）乙基或2,5-二氯噻吩-3-基; 制备化合物I和含有它们的除草剂的方法。

92. 发明授权

US5185027A Salicylaldehyde derivatives and salicyclic acid derivatives and their sulfur analogs, and their use as herbicides and bioregulators 失效
标题翻译：水杨醛衍生物和水杨酸衍生物及其硫类似物，以及它们作为除草剂和生物调节剂的用途
公开(公告)号：US5185027A
公开(公告)日：1993-02-09
申请号：US788859
申请日：1991-11-07
申请人： Uwe J. Vogelbacher , Karl Eicken , Joachim Rheinheimer , Norbert Goetz , Albrecht Harreus , Gerhard Paul , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Uwe J. Vogelbacher , Karl Eicken , Joachim Rheinheimer , Norbert Goetz , Albrecht Harreus , Gerhard Paul , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： A01N43/54 , A01N43/56 , A01N43/653 , A01N43/66 , C07D239/52 , C07D239/60 , C07D251/16 , C07D251/30 , C07D401/12 , C07D403/12 , C07D409/12 , C07D413/12 , C07D417/12
CPC分类号： C07D401/12 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/66 , C07D239/52 , C07D239/60 , C07D251/16 , C07D251/30 , C07D403/12 , C07D409/12 , C07D413/10 , C07D417/12
摘要： Salicylaldehyde derivatives and salicylic acid derivatives of the formula I ##STR1## where A is an unsubstituted or substituted phenyl radical, an unsubstituted or substituted 5-membered heteroaromatic radical having from 2 to 4 nitrogen atoms or two nitrogen atoms and additionally one sulfur or oxygen atom or an unsubstituted or substituted thienyl, pyridyl, naphthyl, quinolyl, indazolyl or benzotriazolyl radical, X is oxygen or sulfur, and the radicals R.sup.1 to R.sup.4 have the meanings given in the specification, processes and intermediates for their production, and their use as herbicides and bioregulators.
摘要翻译：水杨醛衍生物和式I的水杨酸衍生物，其中A是未取代或取代的苯基，未取代或取代的具有2-4个氮原子或两个氮原子的5元杂芳族基团，另外一个硫或氧原子或未取代或取代的噻吩基，吡啶基，萘基，喹啉基，吲唑基或苯并三唑基，X是氧或硫，并且基团R 1至R 4具有其说明书，方法和制备中间体中给出的含义，除草剂和生物调节剂。

93. 发明授权

US5169426A Cyclohexenone derivatives, their preparation and their use for controlling undesirable plant growth 失效
标题翻译：环己烯酮衍生物，它们的制备及其用于控制不期望的植物生长的用途
公开(公告)号：US5169426A
公开(公告)日：1992-12-08
申请号：US576197
申请日：1990-08-30
申请人： Dieter Jahn , Rainer Becker , Michael Keil , Ulrich Schirmer , Bruno Wuerzer , Norbert Meyer
发明人： Dieter Jahn , Rainer Becker , Michael Keil , Ulrich Schirmer , Bruno Wuerzer , Norbert Meyer
IPC分类号： A01N43/20 , C07D303/36 , C07D331/02 , C07D493/04
CPC分类号： C07D493/04 , A01N43/20 , C07D303/36 , C07D331/02
摘要： Cyclohexenone derivatives of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3 and A have the meanings stated in the description, herbicides which contain these compounds as active ingredients, and a method for controlling undesirable plant growth.
摘要翻译：其中R1，R2，R3和A具有说明书中所述含义的式“IMAGE”的环己烯酮衍生物，含有这些化合物作为活性成分的除草剂以及控制不期望的植物生长的方法。

94. 发明授权

US5167690A Tetrahydroindazoles with a phenyl ether structures, herbicidal compositions and use 失效
标题翻译：具有苯基醚结构的四氢吲唑，除草组合物和用途
公开(公告)号：US5167690A
公开(公告)日：1992-12-01
申请号：US592906
申请日：1990-10-04
申请人： Lothar Rueb , KArl Eicken , Peter Plath , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Lothar Rueb , KArl Eicken , Peter Plath , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： C07D231/56 , C07D405/12 , C07D409/12
CPC分类号： C07D231/56 , C07D405/12 , C07D409/12
摘要： N-(Phenyl)-tetrahydroindazole derivatives of the general formula Ia and Ib ##STR1## where R.sup.1 is halogen;R.sup.2 C.sub.1 -C.sub.6 -alkoxycarbonyl-C.sub.3 -C.sub.5 -alkenyl or C.sub.1 -C.sub.3 -alkyl which is substituted in the 1- or 2-position by C.sub.1 -C.sub.6 -alkoxycarbonyl or a 5-or 6-membered saturated or monounsaturated heterocycle which contains one oxygen or sulfur as heteroatom and can be substituted by rom one to four C.sub.1 -C.sub.4 -alkyls, andR.sup.3 is C.sub.2 -C.sub.7 -alkyl, C.sub.3 -C.sub.6 -C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkoxycarbonyl-C.sub.3 -C.sub.5 -alkenyl or C.sub.1 -C.sub.3 -alkyl which is substituted in the 1-or 2-position by C.sub.1 -C.sub.6 -alkoxycarbonyl or a 5- or 6-membered saturated or monounsaturated heterocycle which contains one oxygen or sulfur as heteroatom and can be substituted by from one to four C.sub.1 -C.sub.4 -alkyls,their manufacture and their use.
摘要翻译：通式Ia和Ib的N-（苯基） - 四氢吲唑衍生物，其中R 1是卤素; R2-C1-C6-烷氧基羰基-C3-C5-烯基或C1-C6-烷氧基羰基或5-或6-元饱和或单不饱和杂环被1或2-位取代的C 1 -C 3烷基，氧或硫作为杂原子，可以被一至四个C 1 -C 4烷基取代，R 3是C 2 -C 7 - 烷基，C 3 -C 6 -C 3 -C 6 - 炔基，C 1 -C 6 - 烷氧基羰基-C 3 -C 5 - 烯基或被C1-C6烷氧基羰基取代的1-或2-位的C1-C3-烷基或含有一个氧或硫作为杂原子的5或6元饱和或单不饱和杂环，并可被一个到四个C 1 -C 4烷基，其制备及其用途。

95. 发明授权

US5123952A 5-amino-6-pyridazone derivatives, their preparation and herbicidal mixtures containing these derivatives 失效
标题翻译： 5-氨基-6-吡啶酮衍生物，其制备和除草剂混合物含有这些衍生物
公开(公告)号：US5123952A
公开(公告)日：1992-06-23
申请号：US378798
申请日：1989-07-12
申请人： Ulrich Wriede , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
发明人： Ulrich Wriede , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
IPC分类号： A01N43/58 , C07D237/22 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D413/12 , C07D417/12
CPC分类号： C07D401/12 , C07D237/22 , C07D403/12 , C07D405/12 , C07D409/12 , C07D413/12
摘要： 5-Amino-6-pyridazones of the general formulae Ia and Ib ##STR1## where R.sup.1 is C.sub.1 -C.sub.4 -alkyl which may carry up to three halogen atoms, R.sup.2 is C.sub.1 -C.sub.4 -alkyl or C.sub.3 -C.sub.6 -alkenyl, where these groups may carry up to two phenyl radicals, or C.sub.3 -C.sub.6 -alkynyl, A is --CO-- or --SO.sub.2 --, B is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, where these groups may carry up to three of the following radicals: halogen, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio and/or phenyl; an isocyclic or heterocyclic C.sub.3 -C.sub.7 -cycloalkyl group or an isocyclic or heterocyclic C.sub.3 -C.sub.7 -cycloalkenyl group, where these groups may be fused with one or two cycloalkyl groups of this type or with one or two benzene nuclei, where the total number of ring members is from 3 to 16 and these cyclic radicals may carry up to three of the following groups: halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 - C.sub.6 -alkynyl and/or phenyl; a mononuclear to trinuclear aromatic or heteroaromatic radical which may carry up to three of the following groups: C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, cyano, nitro, carbo-C.sub.1 -C.sub.4 -alkoxy, N,N-di-C.sub.1 -C.sub.4 -alkylcarbamido and/or halogen.These compounds are used as herbicidal active ingredients.
摘要翻译：通式Ia和Ib的5-氨基-6-哒嗪酮其中R 1是可以带有三个卤素原子的C 1 -C 4 - 烷基，R 2是C 1 -C 4 - 烷基或C 3 -C 6 - 烯基，其中这些基团可以带有两个苯基或C 3 -C 6 - 炔基，A是-CO-或-SO 2 - ，B是C 1 -C 6 - 烷基，C 2 -C 6 - 烯基或C 2 -C 6 - 炔基其中这些基团可以带有三个以下基团：卤素，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基和/或苯基; 一个环状或杂环的C 3 -C 7 - 环烷基或者是一个或多个杂环的C 3 -C 7 - 环烯基，其中这些基团可以与一个或两个这样的环烷基或一个或两个苯核稠合，环成员为3至16，并且这些环状基团可以带有三个以下基团：卤素，C 1 -C 4 - 烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基和/或苯基; 可以携带三个以下基团的单核到三核芳族或杂芳族基团：C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基，C 1 C 1-4烷基亚磺酰基，C 1 -C 4 - 烷基磺酰基，氰基，硝基，C 1 -C 4 - 烷氧基，N，N-二-C 1 -C 4烷基氨基甲酰基和/或卤素。这些化合物用作除草活性成分。

96. 发明授权

US5085685A Carboxylic acid derivatives 失效
标题翻译：羧酸衍生物
公开(公告)号：US5085685A
公开(公告)日：1992-02-04
申请号：US566536
申请日：1990-08-13
申请人： Joachim Rheinheimer , Karl Eicken , Uwe J. Vogelbacher , Wolfgang Rohr , Thomas Kuekenhoehner , Karl O. Westphalen , Bruno Wuerzer
发明人： Joachim Rheinheimer , Karl Eicken , Uwe J. Vogelbacher , Wolfgang Rohr , Thomas Kuekenhoehner , Karl O. Westphalen , Bruno Wuerzer
IPC分类号： C07D251/30 , A01N43/54 , A01N43/64 , A01N43/80 , A01N43/82 , A01N43/836 , C07D239/52 , C07D239/60 , C07D251/22 , C07D251/34 , C07D251/38 , C07D401/12 , C07D401/14 , C07D413/12 , C07D413/14 , C07D417/12 , C07D417/14
CPC分类号： C07D401/12 , A01N43/54 , A01N43/80 , A01N43/82 , C07D239/60 , C07D413/12 , C07D413/14
摘要： Carboxylic acid derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy and/or C.sub.1 -C.sub.4 -alkylthio;R.sup.3 is hydrogen, hydroxyl, cyano, nitro, formyl, halogen, unsubstituted or substituted amino, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyl or C.sub.3 -C.sub.6 -alkynyloxy;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is unsubstituted or substituted five-membered hetaryl or isoxazolinyl or --CR.sup.6 .dbd.NOR.sup.7 ;R.sup.6 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl or phenyl;R.sup.7 is unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.8 -cycloalkyl or phenyl;A is oxygen or sulfur;X is nitrogen or methine .dbd.CR.sup.8 --;R.sup.8 is one of the radicals R.sup.3, or R.sup.8 and R.sup.3 together form unsubstituted or substituted 1,3-butadiene-1,4-yl or aza-1,3-butadiene-1,4-yl, andY and Z are each nitrogen or methine .dbd.CH--, their preparation and agents containing them.
摘要翻译：其中R 1和R 2各自为C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷氧基和/或C 1 -C 4 - 烷硫基的通式I的羧酸衍生物; R3是氢，羟基，氰基，硝基，甲酰基，卤素，未取代或取代的氨基，C1-C4-烷基，C1-C4-烷氧基，C3-C6-烯基，C3-C6-烯氧基，C3-C6-炔基或C3 -C 6 - 炔氧基; R4是氢或C1-C4-烷基; R5是未取代的或取代的五元杂芳基或异恶唑啉基或-CR 6 = NOR 7; R6是氢或未取代或取代的C1-C4-烷基，C3-C8-环烷基或苯基; R 7为未取代或取代的C 1 -C 4 - 烷基，C 3 -C 6 - 烯基，C 3 -C 8 - 环烷基或苯基; A是氧或硫; X是氮或次甲基= CR8-; R8是基团R3之一，或R8和R3一起形成未取代或取代的1,3-丁二烯-1,4-基或氮杂-1,3-丁二烯-1,4-基，Y和Z各自为氮或次甲基= CH-，它们的制备物和含有它们的试剂。

97. 发明授权

US5076829A Substituted 2,3-epoxy-5-cyclohexenone derivatives, and fungicides and herbicides containing same 失效
标题翻译：取代的2,3-环氧-5-环己烯酮衍生物，含有其的杀真菌剂和除草剂
公开(公告)号：US5076829A
公开(公告)日：1991-12-31
申请号：US512509
申请日：1990-04-20
申请人： Ulrich Wriede , John-Bryan Speakman , Rudolf Karl , Ernst-Heinrich Pommer , Eberhard Ammermann , Bruno Wuerzer
发明人： Ulrich Wriede , John-Bryan Speakman , Rudolf Karl , Ernst-Heinrich Pommer , Eberhard Ammermann , Bruno Wuerzer
IPC分类号： A01N43/20 , C07D303/32
CPC分类号： C07D303/32 , A01N43/20
摘要： 2-substituted 2,3-epoxy-5-cyclohexenone derivatives of the formula I ##STR1## where W is C.dbd.O or CHOR.sup.1, R.sup.1 is hydrogen, alkyl, alkenyl, alkynyl or alkoxycarbonyl, R is a substituted or unsubstituted hydrocarbon chain, or phenyl or phenylalkyl whose phenyl radical is substituted or unsubstituted and whose alkyl radical may be interrupted by O or S and fungicides and herbicides containing these compounds.
摘要翻译：式（I）的2-取代的2,3-环氧-5-环己烯酮衍生物其中W是C = O或CHOR1，R1是氢，烷基，烯基，炔基或烷氧基羰基，R是取代或未取代的烃链，或其苯基被取代或未取代的苯基或苯基烷基，其烷基可被O或S间隔，并含有这些化合物的杀真菌剂和除草剂。

98. 发明授权

US5059240A 2,3-substituted 1,8-naphthyridines, their preparation and their use as antidotes 失效
标题翻译： 2,3-取代的1,8-萘啶，其制备及其作为抗体使用
公开(公告)号：US5059240A
公开(公告)日：1991-10-22
申请号：US486867
申请日：1990-03-01
申请人： Helmut Hagen , Juergen Pfister , Hans Ziegler , Bruno Wuerzer , Karl-Otto Westphalen
发明人： Helmut Hagen , Juergen Pfister , Hans Ziegler , Bruno Wuerzer , Karl-Otto Westphalen
IPC分类号： A01N25/32 , A01N43/90 , C07D471/04 , C07D471/14
CPC分类号： C07D471/04 , A01N25/32 , C07D471/14
摘要： 2,3-substituted 1,8-naphthyridines of the general formula I ##STR1## where: R is hydrogen or C.sub.1 -C.sub.4 -alkyl (n=1 or 2)R.sup.1 is amino or substituted amino,XR.sup.5, where X is oxygen or sulfur and R.sup.5 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-((C.sub.1 -C.sub.4)-alkyl, C.sub.5 -C.sub.8 -cycloakyl, substituted or unsubstituted phenyl, substituted or unsubstituted phenyl-(C.sub.1 -C.sub.3)-alkyl,halogen,isothiorhonium halide,C.sub.1 -C.sub.12 -alkyl,C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.4 -alkyl,substituted or unsubstituted phenyl or phenyl-(C.sub.1 -C.sub.3)-alkyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, cyano, carboxyl or a group ##STR2## where X is oxygen or sulfur,B is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or alkylthio, amino, mono- or dialkylamino, where each alkyl radical is of 1 to 4 carbon atoms, morpholino, piperidyl, chlorine, bromine or substituted or unsubstituted phenyl,D is C.sub.1 -C.sub.4 alkyl or NH.sub.2 andR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or alkylcarbonyl,or R.sup.1 and R.sup.2 together are --NH--N.dbd.C(CH.sub.2)--,and their environmentally tolerated saltswith the proviso that R.sup.2 is not cyano, carboxyl or a carboxamido or carboxylic ester group when R.sup.1 is methyl, hydroxyl or amino (NH.sub.2), processes for their manufacture, and herbicidal agents containing a naphthyridine I as safener and at least one herbicidal active ingredient selected from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid derivatives andb) cyclohexenone derivatives.
摘要翻译：具有通式I的2,3-取代的1,8-萘啶，其中：R是氢或C 1 -C 4 - 烷基（n = 1或2）R 1是氨基或取代的氨基，XR 5，其中X是氧或（C 1 -C 4） - 烷基，C 5 -C 8 - 环烷基，取代或未取代的苯基，取代或未取代的苯基 - （C 1 -C 3） - 烷基，卤素，异卤卤化物，C 1 -C 12 - 烷基，C 1 -C 4 - 烷氧基羰基-C 1 -C 4烷基，取代或未取代的苯基或苯基 - （C 1 -C 3） - 烷基，R 2为C 1 -C 4烷基，氰基，羧基或基团，其中X为氧或硫，B为C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基或烷硫基，氨基，单或二烷基氨基，其中每个烷基为1至4个碳原子，吗啉代，哌啶基，氯，溴或取代或未取代的苯基，D是C 1 -C 4烷基或NH 2，R 6是氢，C 1 -C 8 - 烷基或烷基羰基，或者R 1和R 2一起是-NH-N = C（CH 2）其环境耐受性盐，条件是R2不是氰基，羧基或a 当R1是甲基，羟基或氨基（NH2）时，羧酰胺基或羧酸酯基，其制备方法和含有萘啶I作为安全剂的除草剂和至少一种除草活性成分，其选自a）2-（4 - 杂芳氧基） - 或2-（4-芳氧基） - 苯氧基乙酸衍生物和b）环己烯酮衍生物。

99. 发明授权

US5034049A Thiophene-2-carboxylic acid derivatives, their preparation and their use for controlling undesirable plant growth 失效
标题翻译：噻吩-2-羧酸衍生物，其制备及其用于控制不期望的植物生长的用途
公开(公告)号：US5034049A
公开(公告)日：1991-07-23
申请号：US463163
申请日：1990-01-09
申请人： Reiner Kober , Rainer Seele , Hans-Juergen Neubauer , Thomas Saupe , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
发明人： Reiner Kober , Rainer Seele , Hans-Juergen Neubauer , Thomas Saupe , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
IPC分类号： A01N43/10 , C07D333/38 , C07D333/40 , C07D333/42
CPC分类号： C07D333/38 , A01N43/10
摘要： Thiophene-2-carboxylic acid derivatives of the general formula I ##STR1## where R.sup.1 to R.sup.3 are each hydrogen, halogen, branched or straight-chain C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -haloalkoxy, nitro, cyano, unsubstituted phenyl or phenyl which is mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen, C.sub.1 -C.sub.5 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.5 -haloalkoxy;X is --OR.sup.4 or --NH--OR.sup.5,R.sup.4 being branched or straight-chain C.sub.3 -C.sub.10 -alkynylalkyl which is unsubstituted or substituted by halogen; andR.sup.5 being branched or straight-chain C.sub.1 -C.sub.5 -alkyl which is unsubstituted or substituted by halogen, or branched or straight-chain C.sub.3 -C.sub.10 -alkynylalkyl which is unsubstituted or substituted by halogen;with the proviso that R.sup.4 is not propargyl when R.sup.2 and R.sup.3 are both hydrogen or when R.sup.2 is halogen or R.sup.3 is chlorine, methyl or methoxy.The compounds I are suitable for combating the growth of unwanted plants.
摘要翻译：通式I的噻吩-2-羧酸衍生物其中R 1至R 3各自为氢，卤素，支链或直链C 1 -C 6 - 烷基，C 1 -C 8 - 烷氧基，C 1 -C 6 - 卤代烷基，C 1 C 1-6卤代烷氧基，硝基，氰基，未取代的苯基或被C 1 -C 4 - 烷基，卤素，C 1 -C 5 - 卤代烷基，C 1 -C 4 - 烷氧基或C 1 -C 5 - 卤代烷氧基单 - X为-OR4或-NH-OR5，R4为未取代或被卤素取代的支链或直链C 3 -C 10 - 炔基烷基; 并且R 5是未被取代或被卤素取代的支链或直链C 1 -C 5 - 烷基，或未被取代或被卤素取代的支链或直链C 3 -C 10 - 炔基烷基; 条件是当R 2和R 3均为氢时或R 2为卤素或R 3为氯，甲基或甲氧基时，R 4不是炔丙基。化合物I适用于对抗不想要的植物的生长。

100. 发明授权

US5022914A Cyclohexenone oxime ethers, their preparation and their use as herbicides 失效
标题翻译：环己烯酮肟醚，它们的制备及其作为除草剂的用途
公开(公告)号：US5022914A
公开(公告)日：1991-06-11
申请号：US429451
申请日：1989-10-31
申请人： Juergen Kast , Dieter Kolassa , Norbert Meyer , Ulrich Schirmer , Albrecht Harreus , Jochen Wild , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Juergen Kast , Dieter Kolassa , Norbert Meyer , Ulrich Schirmer , Albrecht Harreus , Jochen Wild , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： C07D317/26 , A01N35/06 , A01N35/10 , A01N37/22 , A01N43/14 , A01N43/16 , A01N43/18 , A01N43/40 , A01N43/80 , A01P13/00 , C07C251/42 , C07C251/50 , C07C251/52 , C07C255/62 , C07C323/19 , C07C323/47 , C07D213/53 , C07D261/08 , C07D307/16 , C07D309/06 , C07D309/08 , C07D333/22 , C07D335/02 , C07D339/06
CPC分类号： C07D213/53 , A01N35/10 , A01N37/22 , A01N43/14 , A01N43/40 , A01N43/80 , C07C251/42 , C07C251/52 , C07C323/47 , C07D261/08 , C07D309/06 , C07D309/08 , C07D335/02 , C07C2101/16
摘要： Cyclohexenone oxime ethers of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 -alkyl,A is substituted or unsubstituted C.sub.4 -alkylene or C.sub.4 -alkenylene,X is nitro, cyano, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, substituted or unsubstituted benzyloxycarbonyl and/or phenyl,n is from 0 to 3 or from 1 to 5 when X is halogen,R.sup.2 is C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, substituted or unsubstituted C.sub.3 -C.sub.7 -cycloalkyl or C.sub.5 -C.sub.7 -cycloalkenyl,a substituted or unsubstituted 5-membered saturated heterocyclic radical which contains one or two oxygen and/or sulfur atoms as heteroatoms,a substituted or unsubstituted 6- or 7-membered heterocyclic radical which contains one or two oxygen and/or sulfur atoms and one or two double bonds,a substituted or unsubstituted 5-membered heteroaromatic radical containing one or two nitrogen atoms and an oxygen or a sulfur atom,substituted or unsubstituted phenyl or pyridyl,and their agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids, methods of manufacturing them, and their use as herbicides.
摘要翻译：其中R 1为C 1 -C 6 - 烷基，A为取代或未取代的C 4 - 亚烷基或C 4 - 亚烯基，X为硝基，氰基，卤素，C 1 -C 4 - 烷基， C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，羧基，C 1 -C 4烷氧基羰基，取代或未取代的苄氧基羰基和/或苯基，n为0至3或1 当X为卤素时，R 2为C 1 -C 4烷氧基-C 1 -C 6烷基或C 1 -C 4烷硫基-C 1 -C 6烷基，取代或未取代的C 3 -C 7 - 环烷基或C 5 -C 7 - 环烯基，取代或含有一个或两个氧原子和/或硫原子作为杂原子的未取代的5元饱和杂环基，取代或未取代的含有一个或两个氧和/或硫原子的六元或七元杂环基和一个或两个双键，取代或未取代的含有一个或两个氮原子和氧或硫原子的5元杂芳族基团，取代或未取代的苯基或吡啶基，以及它们在农业上可用的C1-C10-羧酸和无机酸的盐和酯，它们的制备方法及其作为除草剂的用途。

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