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    • 92. 发明专利
    • Nuevas amidas y tioamidas heteroaromáticas como plaguicidas
    • ES2524045T3
    • 2014-12-03
    • ES09761421
    • 2009-06-04
    • BAYER CROPSCIENCE AG
    • BRETSCHNEIDER THOMASFRANKEN EVA-MARIAGÖRGENS ULRICHFÜSSLEIN MARTINHENSE ACHIMKLUTH JOACHIM
    • C07D401/04A01N43/56A01N43/78A01N43/82A01N43/88C07D401/14C07D417/04C07D417/14
    • Compuestos de fórmula (I)**Fórmula** en la que G1 representa N y G2 representa**Fórmula** en la que R1 representa hidrógeno o alquilo y G3 representa C(>=X)NR2R3, en la que X representa oxígeno o azufre, R2 representa un resto de la serie de hidrógeno, alquilo, haloalquilo, alcoxi, haloalcoxi, alquenilo, alcoxialquilo, alquilcarbonilo sustituido, dado el caso, con halógeno, alcoxicarbonilo sustituido, dado el caso, con halógeno y cicloalquilcarbonilo sustituido, dado el caso, con halógeno, y R3 representa un resto de la serie de hidrógeno, alquilo, haloalquilo, cianoalquilo, alquenilo, haloalquenilo, alquinilo, haloalquinilo, alcoxi, haloalcoxi, alcoxialquilo sustituido, dado el caso, con halógeno, bis(alcoxi)alquilo sustituido, dado el caso, con halógeno, alquiltioalquilo sustituido, dado el caso, con halógeno, alquilcarbonilalquilo sustituido, dado el caso, con halógeno, alquilsulfinilalquilo sustituido, dado el caso, con halógeno, alquilsulfonilalquilo sustituido, dado el caso, con halógeno, alcoxicarbonilalquilo sustituido, dado el caso, con halógeno, alquiniloxi, alquiniloxicarbonilo, cicloalquilo sustituido dado el caso, cicloalquilcarbonilo sustituido dado el caso, cicloalquilalquilo sustituido dado el caso, heterociclilo sustituido dado el caso, heterociclilalquilo sustituido dado el caso, arilalquilo sustituido dado el caso, hetarilalquilo sustituido dado el caso y NR4R5, en donde R4 y R5 representan independientemente entre sí un resto de la serie de hidrógeno, alquilo, haloalquilo, cicloalquilo, alcoxi, alquilcarbonilo, alcoxicarbonilo, hetarilo y heterociclilo, o R4 y R5 forman, junto con el átomo de nitrógeno al que están unidos, un heterociclo sustituido dado el caso, o R2 y R3 forman, junto con el átomo de nitrógeno al que están unidos, un anillo sustituido dado el caso que contiene, dado el caso, heteroátomos adicionales, así como las sales y los N-óxidos de los compuestos de la fórmula (I).
    • 94. 发明专利
    • BRPI0718274A2
    • 2013-11-12
    • BRPI0718274
    • 2007-10-13
    • BAYER CROPSCIENCE AG
    • FISCHER RAINERLEHR STEFANARNOLD CHRISTIANAULER THOMASDITTGEN JANFEUCHT DIETERFRANKEN EVA-MARIAHEMPEL WALTRAUDHILLS MARTIN JEFFREYKEHNE HEINZLOESEL PETERMALSAM OLGAROSINGER CHRISTOPHER HUGHSANWALD ERICHGOERGENS ULRICHANTONS STEFANEBENBECK WOLFGANGPLESCHKE AXELSCHNEIDER MARIELOUISEWISCHNAT RALF
    • C07D207/38A01N43/36
    • Trifluoromethoxy-phenyl substituted tetramic acid-derivatives (I), are new. Trifluoromethoxy-phenyl substituted tetramic acid-derivatives of formula (I), are new. J1a : trifluoromethoxy; X : H, alkyl, halo, haloalkyl, alkoxy or haloalkoxy; Y1a : H, alkyl or halo, where at least one of J1a, X or Y1a is present at position-2 of the phenyl residue and is at the same time unequally hydrogen; either A : alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, optionally saturated cycloalkyl (all optionally substituted by halo and at least a ring atom is optionally substituted by a heteroatom), aryl, arylalkyl, hetaryl (all optionally substituted by halo, (halo)alkyl, (halo)alkoxy, cyano or nitro) or H; and B1a : H or alkoxyalkyl; and D : H or a residue optionally substituted by alkyl, alkenyl, alkynyl, alkoxyalkyl, optionally saturated cycloalkyl, in which optionally one or more ring members are substituted by heteroatom, arylalkyl, aryl, hetarylalkyl or hetaryl; or C+A+B1a : optionally saturated, substituted and heteroatom containing cyclic group; or A+D : optionally saturated and at least a heteroatom containing, in A, D-parts optionally substituted cyclic group; G : H, carboxy group of formula (-CO-R 1>) or (-C(=L)-M-R 2>), sulfur dioxide group of formula (-SO 2-R 3>), phosphorus group of formula (-P(R 4>)(R 5>)(=L)), E or (-C(=L)-N(R 6>)(R 7>)); E : an equivalent metal ion or an ammonium ion; L, M : O or S; R 1>optionally halo substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl or polyalkoxyalkyl, optionally halo-, alkyl- or alkoxy substituted cycloalkyl, which is interrupted by at least a heteroatom, optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl; R 2>optionally halo substituted alkyl, alkenyl, alkoxyalkyl or polyalkoxyalkyl, optionally substituted cycloalkyl, phenyl or benzyl; R 3>-R 5>optionally halo substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio or cycloalkylthio, or optionally substituted phenyl, benzyl, phenoxy or phenylthio; and either R 6>, R 7>optionally halo substituted alkyl, cycloalkyl, alkenyl, alkoxy or alkoxyalkyl, optionally substituted phenyl or benzyl, or H; or NR 6>R 7>cyclic group interrupted optionally by O or S. Independent claims are included for: (1) the preparation of (I); (2) the preparation of an agent to combat parasite and/or undesirable plant growth comprising mixing (I) with a diluent and/or a surface active material; (3) an agent comprising an active agent combination containing (I), at least a compound, which improves the compatibility of cultured plants, e.g. 4-dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane, 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-one, 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine, 5-chloro-quinolin-8-oxy-acetic acid-(1-methyl-hexylester), 3-(2-chloro-benzyl)-1-(1-methyl-1-phenyl-ethyl)-urea, alpha -(cyanomethoxyimino)-phenylacetonitrile, diethyl-1-(2,4-dichloro-phenyl)-4,5-dihydro-5-methyl-1H-pyrazol-3,5-dicarboxylate, 2-dichloromethyl-2-methyl-1,3-dioxolane, 2-propenyl-1-oxa-4-azaspiro[4.5]decane-4-carbodithioate, 1,8-naphthalic acid anhydride, 1-(2,4-dichloro-phenyl)-5-methyl-1H-pyrazol-3-carboxylic acid-ethylester, 1-(2,4-dichloro-phenyl)-5-isopropyl-1H-pyrazol-3-carboxylic acid-ethylester, 5-chloro-quinolin-8-oxy-acetic acid-1-allyloxy-prop-2-yl-ester, 5-chloro-quinoxalin-8-oxy-acetic acid-methylester, 5-chloro-quinolin-8-oxy-acetic acid-ethylester, 5-chloro-quinoxalin-8-oxy-acetic acid-allylester, 5-chloro-quinolin-8-oxy-acetic acid-2-oxo-prop-1-yl-ester, 5-chloro-quinolin-8-oxy-malonic acid-diethylester, carboxyamide compound of formula (R 1> 6>-CO-N(R 1> 7>)(R 1> 8>)), or a phenyl compound of formula (IId) or (IIe); (4) an N-acylamino acid ester compound of formula (II); (5) a phenyl compound of formula (XV), (XIV) or (XIX); and (6) a phenyl-acetic acid compound of formula (XVII). Either R 1> 7>H, or F, Cl and/or Br substituted 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl, 1-4C alkoxy-1-4C alkyl, dioxolanyl-1-4C alkyl, furyl, furyl-1-4C alkyl, thienyl, thiazolyl, piperidinyl, or optionally F, Cl and/or Br or 1-4C alkyl substituted phenyl; and R 1> 8>H, optionally F, Cl and/or Br substituted 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl, 1-4C alkoxy-1-4C alkyl, dioxolanyl-1-4C alkyl, furyl, furyl-1-4C alkyl, thienyl, thiazolyl, piperidinyl, or optionally F, Cl and/or Br or 1-4C alkyl substituted phenyl; or R 1> 7>R 1> 8>optionally 1-4C alkyl substituted phenyl, furyl or annealed benzene ring; or CR 1> 7>R 1> 8>5- or 6-membered carbocyclic (substituted by 3-6C alkandiyl or 2-5C oxaalkandiyl); either R 2> 5>H, optionally cyano, OH, halogen or 1-4C alkoxy substituted 1-6C alkyl, optionally cyano or halo substituted 3-6C alkenyl or 3-6C alkynyl, optionally cyano, halogen or 1-4C alkyl substituted 3-6C cycloalkyl; and R 2> 6>R 2> 5>, optionally nitro, cyano, halo, 1-4C alkyl, 1-4C haloalkyl, 1-4C alkoxy or 1-4C haloalkoxy substituted phenyl; or R 2> 6>R 2> 5>2-6C alkandiyl (substituted optionally with 1-4C alkyl or 2-5C oxaalkandiyl); and R 1> 6>F, Cl and/or Br substituted 1-4C alkyl. [Image] [Image] [Image] [Image] ACTIVITY : Antiparasitic; Herbicide; Insecticide; Arachnicide; Anthelmintic; Nematocide. MECHANISM OF ACTION : None given.
    • 98. 发明专利
    • 4'4'-DIOXASPIRO-SPIROCYCLICALLY SUBSTITUTED TETRAMATES
    • ZA201006127B
    • 2011-10-26
    • ZA201006127
    • 2010-08-27
    • BAYER CROPSCIENCE AG
    • FISCHER REINERPONTZEN ROLFVERMEER RONALDFRANKEN EVA-MARIAMALSAM OLGAPITTA LEONARDORECKMANN UDO
    • A01N20060101C07D20060101
    • 4'4'-Dioxaspiro-spirocyclically substituted terminates (I), are new. 4'4'-Dioxaspiro-spirocyclically substituted terminates of formula (I), are new. W 1>H, alkyl, alkenyl, alkynyl, halo, alkoxy, haloalkyl, haloalkoxy or CN; X : halo, alkyl, alkenyl, alkynyl, alkoxy, haloalkyl, haloalkoxy, NO 2or CN; Y 1>, Z : H, alkyl, alkenyl, alkynyl, alkoxy, halo, haloalkyl, haloalkoxy, CN or NO 2; AB 1>C : 5-6-membered ketal (optionally substituted by alkyl, haloalkyl, alkoxy, alkoxyalkyl or optionally substituted phenyl); G : metal ion equivalent or ammonium ion; and m, n : 1-2. Independent claims are included for: (1) the preparation of (I); (2) an agent comprising an active agent combination comprising (I), and at least a compound for improving the crop plant compatibility such as: e.g. AD-67, MON-4660, dicyclonone (BAS-145138), benoxacor, 5-chloro-quinolin-8-oxy-acetic acid-(1-methyl-hexylester), cumyluron, cyometrinil, 2,4-D, 2,4-DB, daimuron, dymron, dicamba, dimepiperate, DKA-24, dichlormid, fenclorim, flurazole, fluxofenim, furilazole (MON-13900), lactidichlor, 4-chloro-o-(tolyloxy)-acetic acid, mecoprop, 2-dichloromethyl-2-methyl-1,3-dioxolane, 2-propenyl-1-oxa-4-azaspiro[4.5]decane-4-carbodithioate, 1,8-naphthalic acid anhydride, oxabetrinil, 2,2-dichloro-N-(1,3-dioxolan-2-yl-methyl)-N-(2-propenyl)-acetamide, 3-dichloroacetyl-2,2-dimethyl-oxazolidine, 3-dichloroacetyl-2,2,5-trimethyloxazolidine, 4-(4-chloro-o-tolyl)-butteric acid, 4-(4-chloro-phenoxy)-butteric acid, diphenylmethoxy acetic acid, diphenylmethoxy acetic acid-methylester, diphenylmethoxy acetic acid-ethylester, 1-(2-chloro-phenyl)-5-phenyl-1H-pyrazol-3-carboxylic acid-methylester, 1,2-(dichloro-phenyl)-5-methyl-1H-pyrazol-3-carboxylic acid-ethylester, 1-(2,4-dichlorophenyl)-5-isopropyl-1H-pyrazol-3-carboxylic acid-ethylester, 1-(2,4-dichloro-phenyl)-5-(1,1-dimethyl-ethyl)-1H-pyrazol-3-carboxylic acid-ethylester, 5-(2,4-dichloro-benzyl)-2-isoxazolin-3-carboxylic acid-ethylester, 5-phenyl-2-isoxazolin-3-carboxylic acid-ethylester, 5-chloro-quinolin-8-oxy-acetic acid-4-allyloxy-butylester, 5-chloro-quinolin-8-oxy-acetic acid-1-allyloxy-prop-2-yl-ester, 5-chloroquinioxalin-8-oxy-acetic acid-methylester, 5-chloro-quinolin-8-oxy-acetic acid-ethylester, 5-chloro-quinoxalin-8-oxy-acetic acid-allylester, 4-chloro-phenoxy-acetic acid, 1-[4-(N-2-methoxybenzoylsulfamoyl)-phenyl]-3,3-dimethyl-urea, 1-[4-(N-4, 5-dimethylbenzoylsulfamoyl)-phenyl]-3-methyl-urea, 1-[4-(N-naphthylsulfamoyl)-phenyl]-3,3-dimethyl-urea and/or N-(2-methoxy-5-methylbenzoyl)-4-(cyclopropylaminocarbonyl)-benzene sulfonamide, preferably cloquintocet-mexyl, fenchlorazole-ethyl, isoxadifen-ethyl, mefenpyr-diethyl, furilazole, fenclorim, cumyluron, dymron, or N-cyclopropyl-4-(2-methoxy-5-methyl-benzoylsulfamoyl)-benzamide or N-cyclopropyl-4-(2-methoxy-benzoylsulfamoyl)-benzamide; (3) a first composition comprising a substituted 4-hydroxy-3-phenyl-1-aza-spiro[4.5]dec-3-en-2-one compound of formula (IIa), (I) and at least a solvent; (4) a second composition comprising (I) and at least a salt of formula ([D1 +>(R26a)(R27a)(R28a)(R29a)] n(R30a (n ->))) (IIb); (5) preparing the agent, comprising mixing the first composition with stretching agent and/or surface active materials; and (6) preparing the first composition, comprising adding the components of the composition of a water mixable solvent or water. D1 : N or P; R26a-R29a : 1-8C-alkyl, 1 or more times unsaturated 1-8C-alkylene (both optionally substituted by halo, NO 2or CN), or H; R30a : an inorganic or organic anion; and n : 1-4. [Image] [Image] ACTIVITY : Pesticide; Herbicide; Acaricide; Insecticide; Anthelmintic; Nematocide; Arthropodicide; Antiparasitic; Fungicide; Antibacterial; Virucide. MECHANISM OF ACTION : None given.