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    • 96. 发明专利
    • DE19808489A1
    • 1999-09-02
    • DE19808489
    • 1998-02-27
    • BASF AG
    • MOHRSCHLADT RALFWEBER MARTINHILDEBRANDT VOLKER
    • C08G69/00C08G69/04C08L25/04C08L51/04C08L71/00C08L71/12C08L77/00C08L79/08C08L81/06C08L101/00C08L25/08C08G69/08D01F6/90C08J5/18
    • The invention relates to a method for producing polymer mixtures by reacting at least one amino nitrile with water in the presence of thermoplastic polymers and optional additional monomers which form polyamide. The inventive method comprises the following steps: (1) reacting at least one amino nitrile with water at a temperature ranging from 90 to 400 DEG C and under a pressure ranging from 0.1 to 35 x 10 Pa, whereby a reaction mixture is obtained; (2) additional reaction of the reaction mixture at a temperature ranging from 150 to 400 DEG C and under a pressure which is lower than the pressure in step 1, whereby the temperature and pressure are selected in such a way that a first gas phase and a first liquid or a first solid phase or a mixture comprised of the first solid and first liquid phases are obtained, and the first gas phase is separated off from the first liquid or the first solid phase or from the mixture comprised of the first liquid and first solid phases; and (3) mixing the first liquid or the first solid phase or the mixture comprised of the first liquid and first solid phases with a gaseous or liquid phase which contains water and which can contain thermoplastic polymers and optional additional monomers which form polyamide. Said mixing occurs at a temperature ranging from 150 to 370 DEG C and under a pressure ranging from 0.1 to 30 x 10 Pa, whereby the polymer mixture is obtained and whereby the thermoplastic polymers and optional additional monomers which form polyamide are added in one or more of the steps.
    • 97. 发明专利
    • BR9711401A
    • 1999-08-17
    • BR9711401
    • 1997-09-09
    • BASF AG
    • GUNTHENBERG NORBERTWEBER MARTINKNOLL KONRADLINDENSCHMIDT GERHARD
    • C08J5/18C08F265/04C08L25/02C08L25/12C08L51/00C08L51/04C08L53/02
    • Thermoplastic molding compositions comprisingA) a graft polymer comprising1) an elastomeric graft core, obtainable by copolymerization of one or more C1-C10-alkyl acrylates, and a monomer with crosslinking effect, and2) a graft shell comprising a styrene compound or a C1-C8-alkyl acrylate or methacrylate, or a mixture of the styrene compound and the C1-C8-alkyl acrylate or methacrylate, andB) a thermoplastic polymer comprisingC) an elastomeric block copolymer in which all or virtually all of the olefinic double bonds have been hydrogenated, comprising at least one block A, which forms a hard phase and contains, in its polymer chain, units of a vinylaromatic monomer, and/or a block B, which forms a first elastomeric (soft) phase and contains diene monomers, and at least one elastomeric block B/A, which forms a soft phase, and contains, randomly in its polymer chain, units of both a vinylaromatic monomer and a diene, where the glass transition temperature Tg of the block A is above 25° C. and that of the block B/A is below 25° C. and the phase-volume ratio of block A to block B/A is chosen so that the proportion of the hard phase in the entire block copolymer is from 1 to 40% by volume and the proportion by weight of the diene is less than 50% by weight.