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91. 发明授权

US06433100B1 Process for the preparation of polymers containing N-O terminal groups 有权
标题翻译：制备含有N-O端基的聚合物的方法
公开(公告)号：US06433100B1
公开(公告)日：2002-08-13
申请号：US09763432
申请日：2001-02-22
申请人： Andreas Kramer , Andreas Mühlebach , François Rime
发明人： Andreas Kramer , Andreas Mühlebach , François Rime
IPC分类号： C08F830
CPC分类号： C08F4/00 , C08F2/38
摘要： The invention relates to a process for the preparation of polymers containing N→O terminal groups and to compositions comprising polymers obtained by this process. The process comprises polymerizing by atom transfer radical polymerization (ATRP) an aliphatic monomer of oligomer containing ethylene groups in the presence of a polymerization initiator.
摘要翻译：本发明涉及制备含有N-末端基团的聚合物的方法和包含通过该方法获得的聚合物的组合物。该方法包括在聚合引发剂存在下通过原子转移自由基聚合（ATRP）聚合含有乙烯基团的低聚物的脂族单体。

92. 发明授权

US06417353B1 Preparing amines 失效
标题翻译：制备胺
公开(公告)号：US06417353B1
公开(公告)日：2002-07-09
申请号：US09520908
申请日：2000-03-07
申请人： Frank Funke , Joachim Wulff-Döring , Gerhard Schulz , Wolfgang Siegel , Andreas Kramer , Johann-Peter Melder , Arthur Höhn , Philipp Buskens , Wolfgang Reif , Jan Nouwen
发明人： Frank Funke , Joachim Wulff-Döring , Gerhard Schulz , Wolfgang Siegel , Andreas Kramer , Johann-Peter Melder , Arthur Höhn , Philipp Buskens , Wolfgang Reif , Jan Nouwen
IPC分类号： C07B4304
CPC分类号： C07C209/26 , B01J23/885 , B01J37/03 , C07C213/02 , C07C2601/08 , C07C2602/10 , C07C211/06 , C07C211/07 , C07C211/17 , C07C211/27 , C07C211/30 , C07C211/35 , C07C211/38 , C07C217/58
摘要： Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and with hydrogen in the presence of a catalyst containing copper, wherein the catalytically active mass of the catalyst contains, before the reduction with hydrogen, 20 to 85% by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 14 to 70% by weight of oxygen-containing compounds of nickel, calculated as NiO, 0 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO3, and 0 to 10% by weight of oxygen-containing compounds of aluminum, calculated as Al2O3.
摘要翻译：胺在升高的温度下在升高的温度下与选自氨，伯胺和仲胺的氮化合物和氢气在含催化剂的聚合物的存在下反应制备，其中催化剂活性物质含有，在用氢还原之前，以ZrO 2计为20〜85重量％的含氧化合物，以30重量％计，氧化铝为14〜70重量％，氧化铝为100重量％以NiO表示的镍化合物，以MoO 3计为0〜5重量％的含氧化合物的钼和0〜10重量％的按Al 2 O 3计算的含氧化合物的铝。

93. 发明授权

US06353107B1 1-alkoxy-polyallkyl-piperidine derivatives and their use as polymerization regulators 有权
标题翻译： 1-烷氧基 - 聚烷基哌啶衍生物及其作为聚合调节剂的用途
公开(公告)号：US06353107B1
公开(公告)日：2002-03-05
申请号：US09262804
申请日：1999-03-04
申请人： Andreas Kramer , Peter Nesvadba
发明人： Andreas Kramer , Peter Nesvadba
IPC分类号： C07D21194
CPC分类号： C07D211/46 , C07D211/74 , C07D211/94 , C08F4/00
摘要： The present invention relates to 1-alkoxy-polyalkyl-piperidine derivatives containing a structural element of formula (I) wherein G1, G2, G3, G4 are independently C1-C6alkyl with the proviso that at least one is not methyl or G1 and G2 or G3 and G4, or G1 and G2 and G3 and G4 together form a C5-C12cycloalky group; G5, G6 independently are H, C1-C18alkyl, phenyl, naphthyl or a group COOC1-C18alkyl and X represents a group such that the free radical X. derived from X is capable of initiating polymerization of ethylenically unsaturated monomers, with the proviso that compounds A1 and A2 are excluded Further subjects of the invention are a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a 1-alkoxy-polyalkyl-piperidine derivative, a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-polyalkyl-piperidine derivatives for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X., as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及含有式（I）结构单元的1-烷氧基 - 多烷基 - 哌啶衍生物，其中G 1，G 2，G 3，G 4独立地为C 1 -C 6烷基，条件是至少一个不是甲基或G1和G2或G3 G 4，G 4，G 4，G 4，G 3，G 4，G 3，G 3，G 3，G 3，G 4，G 3，G 4，G 4，衍生自X的化合物能够引发烯键式不饱和单体的聚合，条件是化合物A1和A2被排除。本发明的另外的主题是可聚合组合物，其包含a）至少一种烯属不饱和单体和b）1-烷氧基 - 聚烷基哌啶衍生物，烯键式不饱和单体的聚合方法，以及1-烷氧基 - 聚烷基 - 哌啶衍生物用于受控聚合的用途。中间体N-氧基衍生物，具有烯属不饱和单体的N-氧基衍生物和自由基引发剂X的组合物以及聚合方法也是本发明的主题。

94. 发明授权

US06262206B1 Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds 失效
标题翻译：含有衍生自亚硝基或硝酮化合物的烷氧基胺化合物的可聚合组合物
公开(公告)号：US06262206B1
公开(公告)日：2001-07-17
申请号：US09114621
申请日：1998-07-13
申请人： Peter Nesvadba , Andreas Kramer , Alfred Steinmann , Werner Stauffer
发明人： Peter Nesvadba , Andreas Kramer , Alfred Steinmann , Werner Stauffer
IPC分类号： C08F238
CPC分类号： C08F293/00 , C07C255/64 , C07C2601/14 , C07D207/09 , C07D207/20 , C08F4/00
摘要： A polymerizabie composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, and b) an initiator compound of formula (I) wherein n is O or 1. The compounds of formula (I) are prepared from a free radical and a compound of formula R10NO or Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, novel initiator compounds and their use for polymerization, intermediate compounds and also the polymer or copolymer produced by this process.
摘要翻译：一种聚合物组合物，其包含a）至少一种烯键式不饱和单体或低聚物，和b）式（I）的引发剂化合物，其中n为0或1.式（I）化合物由游离基和式R 10 NO 或者本发明的另外的方面是用于聚合烯属不饱和单体，新型引发剂化合物及其聚合用途，中间体化合物以及通过该方法制备的聚合物或共聚物的方法。

95. 发明授权

US6160178A Racemization of optically active amines 有权
标题翻译：光学活性胺的外消旋化
公开(公告)号：US6160178A
公开(公告)日：2000-12-12
申请号：US303599
申请日：1999-05-03
申请人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
发明人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
IPC分类号： B01J23/72 , B01J23/755 , B01J37/18 , C07B55/00 , C07B61/00 , C07C209/00 , C07C209/68 , C07C211/07 , C07C213/08 , C07C217/08
CPC分类号： C07C213/08 , C07B2200/07 , C07C209/68 , C07C217/08 , C07C211/07
摘要： Optically active amines are racemized by reaction of the optically active amine in the gas phase at elevated temperature in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst.
摘要翻译：光学活性胺通过在氢气和氢化或脱氢催化剂存在下在高温下在气相中的光学活性胺的反应进行外消旋化。

96. 发明授权

US6153797A Racemizing of optically active amines 有权
标题翻译：光学活性胺的外消旋化
公开(公告)号：US6153797A
公开(公告)日：2000-11-28
申请号：US259043
申请日：1999-03-01
申请人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
发明人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
IPC分类号： B01J23/755 , C07B55/00 , C07B57/00 , C07B61/00 , C07C209/68 , C07C211/03 , C07C213/02 , C07C213/08 , C07C217/08 , C07C204/00
CPC分类号： C07C213/08 , C07C209/68
摘要： In a process for racemizing optically active amines by reacting the optically active amine in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperature, the reaction is carried out in liquid phase and the catalyst comprises the catalytically active constituents copper, silver, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium and/or platinum and a support material selected from the group consisting of aluminum oxide, zirconium dioxide, titanium dioxide, carbon and/or oxygen compounds of silicon.
摘要翻译：在通过使光学活性胺在氢气和氢化或脱氢催化剂的存在下在升高的温度下使光学活性胺反应的方法中，反应在液相中进行，催化剂包含催化活性成分铜，银，铁钴，镍，钌，铑，钯，锇，铱和/或铂，以及选自氧化铝，二氧化锆，二氧化钛，碳和/或氧化合物的硅的载体材料。

97. 发明授权

US6127580A Process for the preparation of substituted anthraquinones 失效
标题翻译：制备取代蒽醌的方法
公开(公告)号：US6127580A
公开(公告)日：2000-10-03
申请号：US200936
申请日：1998-11-30
申请人： Wolfgang Siegel , Andreas Kramer
发明人： Wolfgang Siegel , Andreas Kramer
IPC分类号： C07C46/02 , C07C45/00
CPC分类号： C07C46/02
摘要： Process for the preparation of anthraquinones of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which can be identical or different, are hydrogen, a C.sub.1 -C.sub.8 -alkyl or C.sub.2 -C.sub.8 -alkenyl radical, in which 1,4-naphthoquinone is reacted with a 1,3-diene of the general formula II ##STR2## in a cycloaddition step to give the corresponding tetrahydroanthraquinone and the tetrahydroanthraquinone is oxidized with oxygen in the presence of a basic catalyst to give the anthraquinone, in which both the cycloaddition step and the oxidation step are carried out in the presence of an aqueous diluent.Preferably, the cycloaddition step and oxidation step are carried out at a reaction temperature between 90 and 110.degree. C. and at atmospheric pressure.
摘要翻译：用于制备通式I的蒽醌的方法，其中可以相同或不同的R 1，R 2，R 3和R 4是氢，C 1 -C 8 - 烷基或C 2 -C 8 - 烯基，其中1,4 萘醌在环加成步骤中与通式II的1,3-二烯反应，得到相应的四氢蒽醌，四氢蒽醌在碱性催化剂存在下用氧氧化得到蒽醌，其中环加成步骤并且氧化步骤在水性稀释剂的存在下进行。优选环加成步骤和氧化步骤在90-110℃的反应温度和大气压下进行。

98. 发明授权

US6049007A Racemization of optically active amines 有权
标题翻译：光学活性胺的外消旋化
公开(公告)号：US6049007A
公开(公告)日：2000-04-11
申请号：US259042
申请日：1999-03-01
申请人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
发明人： Hartmut Riechers , Joachim Simon , Arthur Hohn , Andreas Kramer , Frank Funke , Wolfgang Siegel , Christoph Nubling
IPC分类号： B01J23/755 , C07B55/00 , C07B57/00 , C07B61/00 , C07C209/68 , C07C211/03 , C07C213/02 , C07C213/08 , C07C217/08 , C07C209/00
CPC分类号： C07C213/08 , C07C209/68
摘要： A process for the preparation of racemic amines of the formula I ##STR1## where R.sup.1 and R.sup.2 are different and R.sup.1, R.sup.2, R.sup.3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R.sup.3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III ##STR2## and the amine of the formula R.sup.3 NH.sub.2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.
摘要翻译：制备式I的外消旋胺的方法，其中R 1和R 2不同，R 1，R 2，R 3是烷基，环烷基，芳烷基，芳基，杂芳基和杂环基，R 3也可以是氢，其中基团可以带有取代基选自烷基，环烷基，烷氧基，芳氧基，氨基，烷基氨基和二烷基氨基，其包括同时使相应的光学活性胺I和式II的仲醇和/或式III的不对称酮和式R 3 NH 2的胺在氢气和氢化催化剂或脱氢催化剂的存在下在升高的温度下进行。

99. 发明授权

US5489447A Carrier-bound ketocarboxylic acids as corrosion inhibitors 失效
标题翻译：载体结合的酮羧酸作为腐蚀抑制剂
公开(公告)号：US5489447A
公开(公告)日：1996-02-06
申请号：US263692
申请日：1994-06-20
申请人： Andreas Kramer , Adalbert Braig
发明人： Andreas Kramer , Adalbert Braig
IPC分类号： C07C65/32 , C07C59/84 , C07C59/88 , C07C59/90 , C07C69/76 , C07C205/56 , C07C229/42 , C07C255/49 , C07C255/57 , C07C323/62 , C07C327/26 , C07C329/04 , C09D5/08 , C09K15/06 , B05D3/02
CPC分类号： C07C59/88 , C07C229/42 , C07C255/49 , C07C59/84 , C07C59/90 , C09D5/086
摘要： A description is given of carrier-bound compounds of the formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently of one another are hydrogen, halogen, nitro, cyano, CF.sub.3, C.sub.1 -C.sub.15 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.2 -C.sub.15 alkenyl, C.sub.1 -C.sub.12 haloalkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aryloxy, C.sub.7 -C.sub.12 arylalkyl, --CO.sub.2 R.sub.6, --COR.sub.6 or ##STR2## in which at least one of the radicals R.sub.1 to R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.15 alkyl, and, in addition, the radicals R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 together with the carbon atoms to which they are attached form a benzo or cyclohexenyl ring,R.sub.6 is C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkyl which is interrupted by oxygen, sulfur or >N--R.sub.9 ; or is C.sub.7 -C.sub.12 arylalkyl,R.sub.7 and R.sub.8 independently of one another are hydrogen, C.sub.1 -C.sub.24 alkyl or C.sub.2 -C.sub.24 alkyl which is interrupted by oxygen, sulfur or >N--R.sub.9,R.sub.9 is hydrogen or C.sub.1 -C.sub.8 alkyl, andn is an integer from the range from 1 to 10,as corrosion inhibitors in coating compositions for protecting metallic surfaces.
摘要翻译：给出式I（I）的载体结合化合物，其中R 1，R 2，R 3，R 4和R 5彼此独立地是氢，卤素，硝基，氰基，CF 3，C 1 -C 15烷基，C 5 -C 12环烷基，C 2 -C 15烯基，C 1 -C 12卤代烷基，C 1 -C 12烷氧基，C 1 -C 12烷硫基，C 6 -C 10芳基，C 6 -C 10芳氧基，C 7 -C 12芳烷基，-CO 2 R 6，-COR 6或其中至少一个基团R 1〜 R 5是氢，卤素或C 1 -C 15烷基，此外，基团R 1和R 2，R 2和R 3，R 3和R 4或R 4和R 5与它们所连接的碳原子一起形成苯并或环己烯基环，R 6 是C 1 -C 20烷基，被氧，硫或> N-R 9中断的C 2 -C 20烷基; 或者是C 7 -C 12芳基烷基，R 7和R 8彼此独立地是氢，C 1 -C 24烷基或被氧，硫或> N-R 9中间的C 2 -C 24烷基，R 9是氢或C 1 -C 8烷基，n是在1至10的范围内，作为用于保护金属表面的涂料组合物中的腐蚀抑制剂。

100. 发明授权

US5013804A Curable mixtures containing a bismaleimide and a propenyl compound 失效
标题翻译：含有双马来酰亚胺和丙烯基化合物的固化混合物
公开(公告)号：US5013804A
公开(公告)日：1991-05-07
申请号：US505097
申请日：1990-04-03
申请人： Andreas Kramer
发明人： Andreas Kramer
IPC分类号： C08F20/52 , C08F222/40 , C08G73/12
CPC分类号： C08J5/24 , C08F222/40 , C08G73/12 , C08J2379/08
摘要： Curable mixtures containing(a) an aromatic bismaleimide of formula ##STR1## wherein R.sub.1 and R.sub.2 are identical or different and each is C.sub.1 -C.sub.4 alkyl, and R.sub.3 and R.sub.4 are each independently of the other a hydrogen or halogen atom, and (a) a propenyl compound of formula II ##STR2## wherein m and n are each independently of the other 1 or 2, Z is a hydrogen atom or C.sub.1 -C.sub.4 alkoxy, and A is a radical of formula IIa, IIb or IIc ##STR3## wherein D is --SO.sub.2 -- or --CO-- or is a radical of formula ##STR4## wherein X and X.sub.1 are each independently of the other --CO--, --SO.sub.2 -- or --O--, and p is 0 or 1, E is phenylene or a radical of formula V ##STR5## wherein G is ##STR6## and q is 0 or 1, are readily processable, well suited for the preparation of prepregs or fibre-reinforced composites, and give mouldings having excellent fracture toughness.
摘要翻译：其包含（a）式（I）的芳族双马来酰亚胺，其中R 1和R 2相同或不同，各自为C 1 -C 4烷基，R 3和R 4各自独立地为氢或卤原子，和（ a）式II的丙烯基化合物其中m和n各自独立地是1或2，Z是氢原子或C 1 -C 4烷氧基，A是式IIa，IIb或IIc的基团（IIa）（IIb）或其中D为-SO 2 - 或-CO-或II为式（II）的基团，或为式（III）或（VI）的基团，其中X 和X 1各自独立地为-CO - ， - SO 2 - 或-O-，p为0或1，E为亚苯基或式V基团，其中G为＆lt; IMAGE＆gt;和q 是0或1，易于加工，非常适合于制备预浸料或纤维增强复合材料，并且具有优异的断裂韧性的模制品。

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