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    • 92. 发明专利
    • SURFACE DECORATIVE MATERIAL AND MANUFACTURE THEREOF
    • JPH09201928A
    • 1997-08-05
    • JP1284196
    • 1996-01-29
    • KYOWA LEATHER CLOTH
    • KAMIMURA HIROYATANIFUJI KIYOAKI
    • B32B33/00
    • PROBLEM TO BE SOLVED: To provide a surface decorative material, which is suitable for wall material, furnishings, household things or the like by a method wherein the material can represent cubic effect and effect of depth more highly vividly even in the case of thin rigid sheet. SOLUTION: By embossing a transparent thermoplastic resin film 1 with a precision embossing roll formed with photoengraving technology, an embosshaving projected parts produced by the specified pattern and groups of a large number of projecting beads formed on the surface of the projected part is firmed. At the respective apex parts of the group of the projected beads, ink application parts 2 with the ink having the bright properties such as pearl ink, metallic effect ink or the like are provided by chipping. On one side of a thermoplastic base sheet 3, colored patterned ink application parts 5 are formed. One the above-mentioned side of the heated thermoplastic base sheet 3, the transparent thermoplastic resin film is doubled through adhesive layer 4 containing metallic effect, pearl effect particles or the like so as to obtain a surface decorative material, in which the projected parts and the groups of the projected projected beads of the transparent thermoplastic resin film 1 are embedded in the thermoplastic base sheet 3.
    • 93. 发明专利
    • RESIN SHEET-LIKE PRODUCT
    • JPH0970910A
    • 1997-03-18
    • JP22678295
    • 1995-09-04
    • KYOWA LEATHER CLOTH
    • NISHI ICHIROKAWAI YASUMASA
    • B32B5/18B32B27/30
    • PROBLEM TO BE SOLVED: To provide a resin sheet-like product which is free from any adverse effect, upon an appearance, which is caused by the expansive penetration of bubbles into a skin layer from a foamed layer and the breaking of the bubbles under heating conditions, and gives a comfortable touch and can be embossed on the skin layer, giving a quality feeling. SOLUTION: This resin sheet-like product is made substantially of a vinyl chloride resin and is composed of at least, a skin layer and a foamed layer, with a thermally embossed pattern formed on the surface layer. In addition, the product has a subskin layer, adjacent to the foamed layer, which has an adequate hardness to substantially prevent bubbles present near the interface between the foamed layer and the skin layer from finding their way into the skin layer, due to heating when embossing the skin layer. The degree of polymerization of the vinyl chloride resin contained in the subskin layer, should preferably be higher than that of the vinyl chloride resin contained in the foamed layer by at least, 500 or more. Besides, the quantity of plasticizer contained in the subskin layer should preferably be less than that contained in the foamed layer by at least, 15 pts.wt.
    • 96. 发明专利
    • SYNTHETIC LEATHER
    • JPH06184950A
    • 1994-07-05
    • JP35026191
    • 1991-12-09
    • KYOWA LEATHER CLOTH
    • SUGIURA KOJIKOSUGI TAKESHISHIMADA KENJI
    • D06N3/14
    • PURPOSE:To obtain a synthetic leather capable of permanently preventing complex unusual sound such as fretting or beating sounds produced by vibration, etc., of an automobile. CONSTITUTION:This synthetic leather is obtained by laminating a wet microporous layer or a dry expanded layer 2 composed of a polyurethane, a polyurethane bonding layer 3 and a silicone-modified polyurethane surface layer 4 on the napped surface side of base fabric 1 composed of single-side napped or double-side napped fabric. The wet microporous layer 2 is formed by coating the base fabric 1 with a solution of the polyurethane in a water-soluble organic solvent, immersing the coated fabric in water, removing the water- soluble organic solvent and coagulating the polyurethane. The dry expanded layer 2 is formed by expanding the bonding layer. This layer 2 or 2 is capable of improving the hand of the synthetic leather and the silicone-modified polyurethane surface layer 4 contributes to the permanent improvement in lubricity of the surface of the synthetic leather.