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    • 94. 发明申请
    • EXPANDABLE VINYL AROMATIC COMPOSITION CONTAINING FUNCTIONALIZED ETHYLENE-VINYL ACETATE COPOLYMER
    • 含有功能化乙烯 - 醋酸乙烯共聚物的可膨胀乙烯基芳香族组合物
    • WO2018020468A1
    • 2018-02-01
    • PCT/IB2017/054599
    • 2017-07-28
    • VERSALIS S.P.A.
    • CUDER, GiovanniCOMBA, StefanoLONGO, Aldo
    • C08J9/00C08J9/14C09D125/04C09D125/02C08J9/16
    • The present invention relates to polymeric compositions that can be used for producing packaging with dynamic cushioning, with a pleasant touch, with reduced abrasive power, in which the expanded particles constituting the packaging adhere well to one another and do not come detached during use. Said compositions comprise: a) from 70% to 90% by weight of a vinyl aromatic polymer and/or copolymer, calculated with respect to (a) + (b); b) from 10% to 30% by weight of an ethylene-vinyl acetate copolymer (EVA) containing a percentage that ranges from 10% to 30% by weight of vinyl acetate, calculated with respect to (a) + (b); c) from 3 to 10 parts by weight of a blowing agent, calculated on 100 parts of component a) added to component b); said copolymer (b) being distributed in the polymer (a) in the form of particles having an average volumetric diameter ranging from 1 nm to 2000nm. The compositions described and claimed do not include styrene-butadiene or styrene-isoprene block copolymers, hydrogenated or non-hydrogenated; thermoplastic polyurethanes, polystyrene- butadiene grafted polymers or styrene core-shell polymers.
    • 本发明涉及聚合物组合物,其可用于生产具有动态缓冲的包装,具有令人愉悦的触感,具有降低的研磨能力,其中构成包装的发泡颗粒相互之间良好粘附并且 在使用过程中不要脱落。 所述组合物包含:a)相对于(a)+(b)计算的70-90重量%的乙烯基芳族聚合物和/或共聚物; b)按重量计10%至30%的乙烯 - 乙酸乙烯酯共聚物(EVA),其含有相对于(a)+(b)计算的乙酸乙烯酯重量百分比为10%至30%; c)3至10重量份发泡剂,按100份加入到组分b)中的组分a)计算; 所述共聚物(b)以平均体积直径在1nm至2000nm范围内的颗粒形式分布于聚合物(a)中。 所述和要求保护的组合物不包括氢化或未氢化的苯乙烯 - 丁二烯或苯乙烯 - 异戊二烯嵌段共聚物; 热塑性聚氨酯,聚苯乙烯 - 丁二烯接枝聚合物或苯乙烯核 - 壳聚合物。
    • 96. 发明申请
    • NON-AQUEOUS REDOX FLOW BATTERIES
    • 非水性氧化还原液流电池
    • WO2018007991A1
    • 2018-01-11
    • PCT/IB2017/054106
    • 2017-07-07
    • ENI S.P.A.
    • TACCA, AlessandraPELLEGRINO, Andrea
    • H01M8/18H01M10/056H01M10/36H01M10/627
    • Non-aqueous redox flow battery (RFB) comprising: a positive compartment in which a positive electrode is positioned and in which a positive non-aqueous liquid electrolyte is caused to flow; a negative compartment in which a negative electrode is positioned and in which a negative non-aqueous liquid electrolyte is caused to flow; an ion-exchange membrane positioned between the positive compartment and the negative compartment in which: said positive non-aqueous liquid electrolyte comprises a solution of copper triflate or tetrafluoroborate complexes [Cu(l) or Cu(ll)] in at least one organic solvent; said negative non-aqueous liquid electrolyte comprises a solution of at least one benzothiadiazole or a derivative thereof in at least one organic solvent. Said non-aqueous redox flow battery (RFB) may advantageously be used in devices which require a moderate to large power output (e.g., about 100 kW - 100 MW) for a number of hours (i.e. > 1 hour) such as, for example, devices for storing energy derived from industrial plants or from alternative energy sources (such as, solar or wind energy) for subsequent use (for example, for domestic use) or for sale.
    • 非水性氧化还原液流电池(RFB)包括:正极室,其中正极定位在正极室中,并且正极非水电解液流入其中; 负极室,在负极室中放置负极,并使负极非水电解液流过; 位于所述正隔室和所述负隔室之间的离子交换膜,其中:所述正非水液体电解质包含三氟甲磺酸铜或四氟硼酸铜络合物[Cu(I)或Cu(II)]在至少一种有机溶剂中的溶液 ; 所述负型非水液体电解质包含至少一种苯并噻二唑或其衍生物在至少一种有机溶剂中的溶液。 所述非水性氧化还原液流电池(RFB)可有利地用于需要中等至大功率输出(例如,大约100kW至100MW)若干小时(即> 1小时)的装置中,例如用于 例如,用于存储来自工业工厂或来自替代能源(例如太阳能或风能)的能量用于随后使用(例如,用于家用)或用于销售的设备。
    • 98. 发明申请
    • PHOTOACTIVE FLUORINATED CONJUGATED COPOLYMER
    • 光活性氟化共轭聚合物
    • WO2017081623A1
    • 2017-05-18
    • PCT/IB2016/056743
    • 2016-11-09
    • ENI S.P.A.
    • PELLEGRINO, AndreaSIMONE, Fiorenza
    • H01L51/00H01L51/46
    • H01L51/0043H01L51/0036H01L51/4253Y02E10/549
    • A photoactive fluorinated conjugated copolymer comprising units having general formula (I): -(D-BTD)- and units having general formula (la): -(D-BTZ)- in which: D represents a donor group having the following general formulae (II), (III), (IV): in which: R 1 , R 2 , R 3 and R 4 , the same or different, represent a hydrogen atom; or they are selected from linear or branched, saturated or unsaturated C 1 -C 20 alkyl groups, preferably C 2 -C 10 , optionally containing heteroatoms; n is 1 or 2; BTD represents a benzothiadiazole group having general formula (V): in which X 1 and X 2 , mutually identical, represent a hydrogen atom; or a fluorine atom; or they are selected from linear or branched, saturated or unsaturated C 1 - C 20 alkyl groups, preferably C 2 -C 10 , optionally containing heteroatoms, linear or branched, saturated or unsaturated C 1 -C 20 alkoxy groups, preferably C 2 -C 10 ; BTZ represents a benzotriazole group having general formula (VI): in which: R 5 is selected from linear or branched, saturated or unsaturated C 1 -C 20 alkyl groups, preferably C 8 -C 18 , optionally containing heteroatoms; X 1 and X 2 , mutually identical, represent a hydrogen atom; or a fluorine atom; or they are selected from linear or branched, saturated or unsaturated C 1 -C 20 alkyl groups, preferably C 2 -C 10 , optionally containing heteroatoms, linear or branched, saturated or unsaturated C 1 -C 20 alkyl groups, preferably C 2 -C 10 ; provided that in at least one from the benzothiadiazole group having general formula (V) and the benzotriazole group having general formula (VI), X 1 and X 2 , mutually identical, represent a fluorine atom. Said photoactive fluorinated conjugated copolymer may be advantageously used in the manufacture of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on rigid support, or on flexible support.
    • 包含具有通式(I)的单元的光活性氟化共轭共聚物: - (D-BTD) - 和具有通式(Ia)的单元: - (D-BTZ) - 其中:D表示 具有以下通式(II),(III),(IV)的供体基团:其中:R 1,R 2,R 3, R 4和R 4相同或不同,代表氢原子; 或者它们选自直链或支链,饱和或不饱和的C 1 -C 20烷基,优选C 2 -C 10 任选含有杂原子; n是1或2; BTD代表具有通式(V)的苯并噻二唑基团:其中X 1和X 2彼此相同,代表氢原子; 或氟原子; 或者它们选自直链或支链,饱和或不饱和的C 1 -C 20烷基,优选C 2 -C 10 任选含有杂原子,直链或支链,饱和或不饱和的C 1 -C 20烷氧基,优选C 2 -C <子> 10 ; BTZ表示具有通式(VI)的苯并三唑基团:其中:R5选自直链或支链,饱和或不饱和的C 1 -C 20烷基, 优选C8-C18烷基,任选地含有杂原子; X 1和X 2彼此相同,代表氢原子; 或氟原子; 或者它们选自直链或支链,饱和或不饱和的C 1 -C 20烷基,优选C 2 -C 10 任选含有杂原子,直链或支链,饱和或不饱和的C 1 -C 20烷基,优选C 2 -C 3 - <子> 10 ; 条件是在具有通式(V)的苯并噻二唑基团和具有通式(VI)的苯并三唑基团中的至少一个中,X 1和X 2彼此相同, 代表氟原子。 所述光敏氟化共轭共聚物可以有利地用于制造光伏设备(或太阳能设备),例如光伏电池(或太阳能电池),光伏模块(或太阳能模块),或者在刚性支撑上,或者在柔性 支持。
    • 99. 发明申请
    • NITROGEN TITANIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID NITROGEN TITANIUM COMPLEX AND PROCESS FOR THE (CO)POLYMERIZATION OF CONJUGATED DIENES
    • 硝酸钛复合物,包含上述硝酸钛复合物的催化体系和(CO)共聚二烯的聚合方法
    • WO2017017203A1
    • 2017-02-02
    • PCT/EP2016/068034
    • 2016-07-28
    • VERSALIS S.P.A.
    • SOMMAZZI, AnnaPAMPALONI, GuidoRICCI, GiovanniMASI, FrancescoLEONE, Giuseppe
    • C07F7/00
    • C08F36/08C07F7/006C07F7/28C08F36/06
    • Nitrogen titanium complex having general formula (I) or (II), wherein: - R 1 represents a hydrogen atom; or is selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; - R 2 , R 3 , R 4 and R 5 , identical or different, represent a hydrogen atom; or are selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted, nitro groups, hydroxyl groups, amino groups; - Y represents a NH-R 6 group wherein R 6 represents a hydrogen atom, or is selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; or a N-R 7 group wherein R 7 is selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; - X 1 , X 2 , X 3 and X 4 , identical or different, represent a halogen atom, such as, for example, chlorine, bromine, iodine, preferably chlorine; or are selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , -OCOR 8 or -OR 8 groups wherein R 8 is selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 ; or one of X 1 , X 2 and X 3 is selected from ethers, such as,for example, diethylether, tetrahydrofuran (THF), dimethoxyethane, preferably tetrahydrofuran (THF); - n is 1 in the case wherein Y represents a NH-R 6 group wherein R 6 has the same meanings reported above; or is 0 in the case wherein Y represents a N-R 7 group wherein R 7 has the same meanings reported above, or in the case wherein one of X 1 , X 2 and X 3 is selected from ethers; - R' 1 , R' 2 , R' 3 , R' 4 , R' 5 , R' 6 and R' 7 , identical or different, represent a hydrogen atom; or are selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; - X' 1 and X' 2 , identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or are selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , -OCOR' 8 groups or -OR' 8 groups wherein R' 8 is selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 ; - Y' is selected from ethers such as, for example,diethylether, tetrahydrofuran (THF), dimethoxyethane, preferably is tetrahydrofuran (THF); or Y' represents a group having general formula (III), wherein R' 1 , R' 2 , R' 3 , R' 4 , R' 5 , R' 6 and R' 7 , have the same meanings as reported above; - m is 0 or 1. Said nitrogen titanium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.
    • 具有通式(I)或(II)的氮钛络合物,其中:-R 1表示氢原子; 或选自直链或支链C 1 -C 20烷基,优选C 1 -C 15,任选被卤代的环烷基任选取代,任选取代的芳基; -R 2,R 3,R 4和R 5相同或不同,表示氢原子; 或选自直链或支链C 1 -C 20烷基,优选C 1 -C 15,任选取代的任选卤代的环烷基,任选取代的芳基,硝基,羟基,氨基; Y表示NH-R6基团,其中R6表示氢原子,或选自直链或支链C1-C20烷基,优选C1-C15,任意卤代的任选取代的环烷基,任选取代的芳基; 或其中R 7选自直链或支链C 1 -C 20烷基,优选C 1 -C 15,任选卤代的任选取代的环烷基,任选取代的芳基的N-R7基团; -X 1,X 2,X 3和X 4相同或不同,表示卤素原子,例如氯,溴,碘,优选氯; 或选自直链或支链C 1 -C 20烷基,优选C 1 -C 15,-OCOR 8或-OR 8基团,其中R 8选自直链或支链C 1 -C 20烷基,优选C 1 -C 15烷基; 或者X 1,X 2和X 3中的一个选自醚,例如二乙醚,四氢呋喃(THF),二甲氧基乙烷,优选四氢呋喃(THF); 在其中Y表示NH-R6基团的情况下,n为1,其中R6具有上述相同的含义; 或者在X表示与上述相同的含义的情况下,或者X1,X2,X3中的一个选自醚类的情况下,为Y表示N-R7基的情况下为0。 -R'1,R'2,R'3,R'4,R'5,R'6和R'7相同或不同,表示氢原子; 或选自直链或支链C 1 -C 20烷基,优选C 1 -C 15,任选卤代的环烷基,任选取代的芳基,任选取代的芳基; - X'1和X'2相同或不同,表示卤素原子,例如氯,溴,碘,优选氯; 或选自直链或支链C1-C20烷基,优选C1-C15,-OCOR'8基团或-OR'8基团,其中R '8选自直链或支链C 1 -C 20烷基,优选C 1 -C 15烷基; - Y'选自醚,例如二乙醚,四氢呋喃(THF),二甲氧基乙烷,优选四氢呋喃(THF); 或Y'表示具有通式(III)的基团,其中R'1,R'2,R'3,R'4,R'5,R'6和R'7具有与上述相同的含义; m为0或1.具有通式(I)或(II)的所述氮钛络合物可有利地用于共轭二烯(共)聚合的催化体系中。