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    • 1. 发明申请
    • CARBONISING AND/OR ACTIVATING CARBONACEOUS MATERIAL
    • 碳化和/或活化碳质材料
    • WO2008043982A2
    • 2008-04-17
    • PCT/GB2007/003755
    • 2007-10-04
    • BRITISH AMERICAN TOBACCO (INVESTMENTS) LIMITEDTENNISON, Stephen, RobertTUNBRIDGE, Jonathan, RobertPLACE, Roger, NicholasBLACKBURN, Andrew, JohnGILES, Alan, Mark
    • TENNISON, Stephen, RobertTUNBRIDGE, Jonathan, RobertPLACE, Roger, NicholasBLACKBURN, Andrew, JohnGILES, Alan, Mark
    • C01B31/08C08F2/18
    • F27B7/167C01B32/30C01B32/336C01B32/342C01B32/39C08F2/18C10B47/30C10B53/07C10B57/12F27B7/162Y02P20/143
    • A method is provided for carbonizing and activating carbonaceous material, which comprises supplying the material to an externally fired rotary kiln maintained at carbonizing and activating temperatures, the kiln having a downward slope to progress the material as it rotates, the kiln having an atmosphere substantially free of oxygen provided by a counter-current of steam or carbon dioxide, and annular weirs being provided at intervals along the kiln to control progress of the material. There may further be provided an externally fired rotary kiln for carbonizing and activating carbonaceous material having a hollow rotary body that has a downward slope towards a discharge end thereof, and which is provided at intervals along its length with annular weirs for controlling progress of the carbonaceous material. In embodiments, there is also provided a process is for producing discrete solid beads of polymeric material e.g. phenolic resin beads having a mesoporous structure, which may be useful as feedstock for the above mentioned carbonization/activation process or which may have other utility e.g. as ion exchange resins. The process may produce resin beads on an industrial scale without aggregates of resin building up speedily and interrupting production. The process comprises the steps of: (a) combining a stream of a polymerizable liquid precursor e.g. a novolac and hexamine as cross- linking agent dissolved in a first polar organic liquid e.g. ethylene glycol with a stream of a liquid suspension medium which is a second non-polar organic liquid with which the liquid precursor is substantially or completely immiscible e.g. transformer oil containing a drying oil; (b) mixing the combined stream to disperse the polymerizable liquid precursor as droplets in the suspension medium e.g. using an in-line static mixer; (c) allowing the droplets to polymerise in a laminar flow of the suspension medium so as to form discrete solid beads that cannot agglomerate; and (d) recovering the beads from the suspension medium. There is also provided apparatus for forming discrete solid beads of polymeric material, said apparatus comprising: a first line for conveying s stream of a polymerizable liquid precursor; a second line for conveying a stream of a dispersion medium with which the polymerizable liquid precursor is substantially or completely immiscible; an in-line mixer configured to receive a combined flow from the first and second lines and to disperse the polymerizable liquid precursor as droplets in the dispersion medium; a vertical polymerization column configured to receive the dispersion medium with the droplets dispersed therein and to permit the polymerizable liquid precursor polymerize while descending the column in a descending flow of polymerization medium; and a vessel at the base of the column for receiving the descending flow of dispersion medium and collecting polymerized solid beads.
    • 提供碳化和活化含碳材料的方法,其包括将材料供应到保持在碳化和活化温度的外部烧制的回转窑中,窑具有向下倾斜以使材料在其旋转时进行,窑具有基本上无空气的气氛 由蒸汽或二氧化碳的逆流提供的氧气,以及沿着窑炉间隔设置的环形堰,以控制材料的进展。 还可以提供一种用于碳化和活化具有中空旋转体的含碳材料的外部旋转窑,所述中空旋转体具有朝向其排出端的向下倾斜,并且沿其长度间隔设置有环形堰,以控制含碳的进程 材料。 在实施方案中,还提供了一种用于生产聚合物材料的离散固体珠粒的方法,例如 具有介孔结构的酚醛树脂珠粒,其可用作上述碳化/活化方法的原料,或者可以具有其它实用性。 作为离子交换树脂。 该工艺可以在工业规模上生产树脂珠而不会迅速建立树脂聚集并中断生产。 该方法包括以下步骤:(a)将可聚合液体前体物流如 溶解在第一极性有机液体中的交联剂的酚醛清漆和六胺作为交联剂。 乙二醇与液体悬浮介质物流,液体悬浮介质是第二非极性有机液体,液体前体基本上或完全不混溶。 变压器油含有干油; (b)混合组合的流以将可聚合液体前体作为液滴分散在悬浮介质中,例如 使用在线静态混合器; (c)允许液滴在悬浮介质的层流中聚合,以便形成不能聚集的不连续的固体珠粒; 和(d)从悬浮介质中回收珠粒。 还提供了用于形成聚合材料的离散固体珠的装置,所述装置包括:用于输送可聚合液体前体的流的第一管线; 用于输送可聚合液体前体基本上或完全不混溶的分散介质流的第二条线; 配置成接收来自第一和第二管线的组合流并将可聚合液体前体作为液滴分散在分散介质中的在线混合器; 垂直聚合塔,其被配置为接收分散介质,其中液滴分散在其中,并且允许可聚合液体前体在聚合介质的下降流中下降时聚合; 以及在塔的底部的用于接收分散介质的下降流并收集聚合的固体珠的容器。
    • 2. 发明申请
    • PREFORMED MODULAR TREFOIL AND INSTALLATION METHOD
    • 预制模块化铁素体和安装方法
    • WO01059382A1
    • 2001-08-16
    • PCT/US2001/003133
    • 2001-02-01
    • F27B7/16F27B7/28F27D1/04
    • F27D1/04F27B7/167F27B7/28
    • A trefoil (10) for a rotary kiln (5) is provided that has at least three spoke-like refractory legs (12a, 12b, 12c). Each one of the legs (12a, 12b, 12c) extends radially outwardly from a center of the trefoil; spans approximately from the kiln shell to the center of the kiln; is pre-formed outside of the kiln for installation as a single-leg unit; and has a mating surface (16) that preferably is uniform and even, thereby lacking interlocking features. The mating surfaces of the legs (16a, 16b, 16c) about one another at the kiln center to provide mutual support. An alignment member, such as a pair of longitudinal angles (30), are welded to the kiln shell (6) to position the legs. A corresponding method of installing the trefoil is disclosed that includes positioning and shimming the first two legs at the 4 o'clock position and 8 o'clock position, and installing the third leg at the 12 o'clock position.
    • 提供了一种用于回转窑(5)的三叶片(10),其具有至少三个辐条状耐火腿(12a,12b,12c)。 每个腿部(12a,12b,12c)从三叶片的中心径向向外延伸; 大约从窑壳到窑的中心; 在窑外预成型,作为单腿单元进行安装; 并且具有优选均匀且均匀的匹配表面(16),从而缺少互锁特征。 腿部(16a,16b,16c)的配合表面在窑中心彼此相邻以提供相互支撑。 对准构件,例如一对纵向角(30),焊接到窑壳(6)以定位腿。 公开了一种安装三叶片的相应方法,其包括在4点钟位置和8点钟位置定位和调整前两个腿部,并将第三腿部安装在12点钟位置。
    • 6. 发明授权
    • Preformed modular trefoil and installation method
    • 预制模块式三叶及安装方式
    • US06672256B2
    • 2004-01-06
    • US09873514
    • 2001-06-05
    • Ronald J. MarrLarry E. Shultz
    • Ronald J. MarrLarry E. Shultz
    • F27B700
    • F27D1/04F27B7/167F27B7/28
    • A trefoil for a rotary kiln is provided that has at least three spoke-like refractory legs. Each one of the legs extends radially outwardly from a center of the trefoil; spans approximately from the kiln shell to the center of the kiln; is pre-formed outside of the kiln for installation as a single-leg unit; and has a mating surface that preferably is uniform and even, thereby lacking interlocking features. The mating surfaces of the legs abut one another at the kiln center to provide mutual support. An alignment member, such as a pair of longitudinal angles, are welded to the kiln shell to position the legs. A corresponding method of installing the trefoil is disclosed that includes positioning and shimming the first two legs at the 4 o'clock position and 8 o'clock position, and installing the third leg at the 12 o'clock position.
    • 提供了一种用于回转窑的三叶片,其具有至少三个辐条状耐火腿。 每条腿从三叶片的中心径向向外延伸; 大约从窑壳到窑的中心; 在窑外预成型,作为单腿单元进行安装; 并且具有优选均匀且均匀的配合表面,由此缺少互锁特征。 腿的配合表面在窑中心彼此邻接以提供相互支撑。 诸如一对纵向角度的对准构件焊接到窑壳以定位腿。 公开了一种安装三叶片的相应方法,其包括在4点钟位置和8点钟位置定位和调整前两个腿部,并将第三腿部安装在12点钟位置。