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1. 发明授权

US06946578B2 Process for producing phenoxyphosphazene compound, flame-retardant resin composition, and flame-retardant resin molding 失效
标题翻译：苯氧基磷腈化合物的制备方法，阻燃树脂组合物和阻燃树脂成型
公开(公告)号：US06946578B2
公开(公告)日：2005-09-20
申请号：US10745255
申请日：2003-12-23
申请人： Shinji Nakano , Yuji Tada , Tadao Yabuhara , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
发明人： Shinji Nakano , Yuji Tada , Tadao Yabuhara , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
IPC分类号： C08J5/00 , C07F9/6581 , C07F9/659 , C08G79/04 , C08K5/5399 , C08K9/00 , C08L101/00 , C09K21/12 , C07F9/02
CPC分类号： C08K5/5399 , C07F9/65812 , C09K21/12
摘要： An improved phenoxyphosphazene compound is produced by treating a phenoxyphosphazene compound with (a) at least one adsorbent selected from activated carbon, silica gel, activated alumina, activated clay, synthetic zeolite and macromolecular adsorbents, (b) at least one reagent selected from metal hydrides, hydrazine, hypochlorites, thiosulfates, dialkyl sulfuric acids, ortho esters, diazoalkanes, lactones, alkanesultones, epoxy compounds and hydrogen peroxide, or (c) both the adsorbent and reagent, thereby reducing the acid value of said phosphazene compound to lower than 0.025 mgKOH/g.
摘要翻译：通过用（a）至少一种选自活性炭，硅胶，活性氧化铝，活性粘土，合成沸石和大分子吸附剂的吸附剂处理苯氧基磷腈化合物，制备改进的苯氧基磷腈化合物，（b）至少一种选自金属氢化物，肼，次氯酸盐，硫代硫酸盐，二烷基硫酸，原酸酯，重氮烷烃，内酯，烷基磺酸盐，环氧化合物和过氧化氢，或（c）吸附剂和试剂两者，从而将所述磷腈化合物的酸值降低至低于0.025mgKOH /G。

2. 发明授权

US06521689B1 Flame-retardant aromatic polyamide resin composition and molded object 有权
标题翻译：阻燃芳香族聚酰胺树脂组合物和成型体
公开(公告)号：US06521689B1
公开(公告)日：2003-02-18
申请号：US09889011
申请日：2001-07-06
申请人： Tadao Yabuhara , Yuji Tada , Shinji Nakano , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
发明人： Tadao Yabuhara , Yuji Tada , Shinji Nakano , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
IPC分类号： C08K535
CPC分类号： C08K7/04 , C08K3/22 , C08K5/5399 , C08K7/02 , C08K2003/2217 , C08L77/10 , C08L85/02 , C08L77/00 , C08L85/00 , C08L2666/84
摘要： An object of this invention is to impart excellent flame retardancy to an aromatic polyamide resin without use of a halogen compound which is responsible for generation of gases harmful to the human body and without decreasing preferred properties (e.g. mechanical properties, and molding processability) inherently possessed by aromatic polyamide resins, the flame-retardant aromatic polyamide resin composition of this invention comprising (a) 100 parts by weight of an aromatic polyamide resin, (b) 0.1 to 100 parts by weight of a crosslinked phosphazene compound which is a compound crosslinked with a crosslinking group, such as phenylene groups, the crosslinking group being interposed between the two oxygen atoms left after the elimination of phenyl groups from the phosphazene compound, no free hydroxyl group being present in the molecule, the amount of all phenyl groups in the crosslinked compound being 50 to 99.9% based on the total amount of the phenyl groups in the phosphazene compounds, (c) 1 to 60 parts by weight of an inorganic fibrous substance and (d) 1 to 60 parts by weight of magnesium hydroxide.
摘要翻译：本发明的目的是赋予芳族聚酰胺树脂优异的阻燃性，而不使用负责产生对人体有害的气体的卤素化合物，而不降低固有地具有的优选性能（例如机械性能和成型加工性）通过芳族聚酰胺树脂，本发明的阻燃芳族聚酰胺树脂组合物包含（a）100重量份的芳族聚酰胺树脂，（b）0.1至100重量份的交联的磷腈化合物，其是与交联基团，例如亚苯基，交联基团置于从磷腈化合物除去苯基后留下的两个氧原子之间，分子中不存在游离羟基，交联的所有苯基的量化合物的含量为磷腈中苯基的总量的50-99.9％（c）1〜60重量份的无机纤维状物质和（d）1〜60重量份的氢氧化镁。

3. 发明授权

US06518336B1 Flame-retardent resin compositions compring thermoplastic resin, thermotropic liquid crystal polymer, and hoalogen-free phosphazen compound 失效
标题翻译：包含热塑性树脂的阻燃树脂组合物，热致液晶聚合物和无磷酸盐的磷腈化合物
公开(公告)号：US06518336B1
公开(公告)日：2003-02-11
申请号：US09720233
申请日：2000-12-19
申请人： Tadao Yabuhara , Yuji Tada , Takashi Kameshima , Shinji Nakano , Yoichi Nishioka , Hiroyuki Takase
发明人： Tadao Yabuhara , Yuji Tada , Takashi Kameshima , Shinji Nakano , Yoichi Nishioka , Hiroyuki Takase
IPC分类号： C08K55357
CPC分类号： C08K5/5399 , C08L55/02 , C08L67/02 , C08L69/00 , C08L71/12 , C08L77/00 , C08L101/00 , C08L2666/18
摘要： This invention provides a flame-retardant resin composition comprising: (A) 100 parts by weight of a thermoplastic resin other than a thermotropic liquid crystal polymer, (B) 0.01 to 50 parts by weight of a thermotropic liquid crystal polymer, and (C) 1 to 30 parts by weight of a halogen-free phosphazene compound, the invention providing a novel flame-retardant resin composition which is free of the problems arising due to the presence of halogen element, the composition being excellent in flame retardancy, mechanical properties, molding processability and the like, and being unlikely to cause dripping.
摘要翻译：本发明提供一种阻燃性树脂组合物，其包含：（A）100重量份热致变液晶聚合物以外的热塑性树脂，（B）0.01〜50重量份的热致液晶聚合物，（C） 1至30重量份的无卤素磷腈化合物，本发明提供了一种新的阻燃树脂组合物，其不存在由于卤素元素的存在而产生的问题，该组合物的阻燃性，机械性能，成型加工性等，不易引起滴落。

4. 发明授权

US06632891B1 Flame-retardant resin, composition thereof, and process for producing the same 有权
标题翻译：阻燃树脂及其组合物及其制造方法
公开(公告)号：US06632891B1
公开(公告)日：2003-10-14
申请号：US09623472
申请日：2000-09-13
申请人： Yuji Tada , Yoichi Nishioka , Tadao Yabuhara , Takashi Kameshima , Shinji Nakano
发明人： Yuji Tada , Yoichi Nishioka , Tadao Yabuhara , Takashi Kameshima , Shinji Nakano
IPC分类号： C08G6391
CPC分类号： C08G64/083 , C08G63/692
摘要： A flame-retardant resin composition comprising a phosphazene flame retardant and a polyester resin, wherein the flame retardant is bonded to the molecules of the polyester resin via the ester group thereof, can retain a high flame retardance for a prolonged term with little or no vaporization with time and is excellent in flame retardance, impact resistance, properties and processability.
摘要翻译：包含磷腈阻燃剂和聚酯树脂的阻燃树脂组合物，其中阻燃剂经由其酯基与聚酯树脂的分子结合，可以在很少或不蒸发的情况下保持长时间的高阻燃性具有时间和优异的阻燃性，耐冲击性，性能和加工性

5. 发明授权

US06627122B1 Powdery flame retardant 失效
标题翻译：粉状阻燃剂
公开(公告)号：US06627122B1
公开(公告)日：2003-09-30
申请号：US09762988
申请日：2001-02-14
申请人： Yuji Tada , Tadao Yabuhara , Shinji Nakano , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
发明人： Yuji Tada , Tadao Yabuhara , Shinji Nakano , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
IPC分类号： C08K500
CPC分类号： C08K7/04 , C08K9/12
摘要： A powdery flame retardant which is obtained by mixing a flame retardant which is liquid or a viscous solid at ordinary temperature with an inorganic fibrous substance to adhere or adsorb the retardant to the fibrous substance, and which comprises 5 to 70 wt. % the flame retardant and 95 to 30 wt. % the fibrous substance. The powdery flame retardant can be easily handled because it is a powder, and is obtained by a simple and industrially advantageous method. It produces a remarkable effect that the performance of the liquid or viscous flame retardant is not impaired.
摘要翻译：一种粉末状阻燃剂，其通过将常温下为液体或粘性固体的阻燃剂与无机纤维物质混合以将阻燃剂粘附或吸附到纤维状物质上，并且其包含5至70重量％％阻燃剂和95〜30wt。％的纤维物质。粉状阻燃剂由于粉末而易于处理，并且通过简单且工业上有利的方法获得。它产生显着的效果，即液体或粘性阻燃剂的性能不受损害。

6. 发明授权

US06528559B1 Crosslinked phenoxyphosphazene compounds, process for the preparation thereof, flame retardants, flame-retardant resin compositions, and moldings of flame-retardant resins 有权
标题翻译：交联苯氧基磷腈化合物，其制备方法，阻燃剂，阻燃树脂组合物和阻燃树脂的模塑
公开(公告)号：US06528559B1
公开(公告)日：2003-03-04
申请号：US09762637
申请日：2001-02-12
申请人： Yoshifumi Nakacho , Tadao Yabuhara , Yuji Tada , Yoichi Nishioka
发明人： Yoshifumi Nakacho , Tadao Yabuhara , Yuji Tada , Yoichi Nishioka
IPC分类号： C08K515
CPC分类号： C07F9/65815 , C07F9/65812 , C08G79/025 , C08K5/5399 , C09K21/14
摘要： This invention provides a halogen-free flame retardant which advantageously has a high melting point and a low volatility and does not impair the inherent properties of resins. The flame retardant of the invention is a phosphazene compound crosslinked with a crosslinking group such as a phenylene group, wherein each of the crosslinking groups is interposed between the two oxygen groups left after the elimination of phenyl groups from the phosphazene compound; the crosslinked phenoxyphosphazene compound does not have any free hydroxyl groups (derived from crosslinking groups); and the amount of the phenyl groups in the crosslinked compound is 50 to 99.9%, based on the total number of the phenyl groups in the phosphazene compound.
摘要翻译：本发明提供一种无卤阻燃剂，其有利地具有高熔点和低挥发性，并且不损害树脂的固有性质。本发明的阻燃剂是与交联基团如亚苯基交联的磷腈化合物，其中每个交联基团插入在从磷腈化合物中除去苯基之后留下的两个氧基之间; 交联的苯氧基磷腈化合物不具有任何游离羟基（衍生自交联基团）; 并且交联化合物中苯基的量基于磷腈化合物中的苯基总数为50-99.9％。

7. 发明授权

US06596893B2 Crosslinked phenoxyphosphazene compounds, flame retardants, flame-retardant resin compositions, and moldings of flame-retardant resins 有权
标题翻译：交联的苯氧基磷腈化合物，阻燃剂，阻燃树脂组合物和阻燃树脂的模塑制品
公开(公告)号：US06596893B2
公开(公告)日：2003-07-22
申请号：US09331013
申请日：1999-08-12
申请人： Yoshifumi Nakacho , Tadao Yabuhara , Yuji Tada , Yoichi Nishioka
发明人： Yoshifumi Nakacho , Tadao Yabuhara , Yuji Tada , Yoichi Nishioka
IPC分类号： C07F902
CPC分类号： C08K5/5399 , C08G75/0204 , C09K21/14
摘要： This invention has an object of providing a flame retardant which advantageously has a high melting point and a low volatility and is unlikely to depress the inherent properties of resins. The flame retardant of the invention is a phosphazene compound crosslinked with a crosslinking group such as phenylene group, each of the crosslinking groups being interposed between the two oxygen groups left after the elimination of phenyl groups from the phosphazene compound, the amount of the phenyl groups in the crosslinked compound being 50 to 99.9% based on the total number of the phenyl groups in the phosphazene compound. The invention also provides a resin composition containing the flame retardant, and a molded article of the resin.
摘要翻译：本发明的目的是提供阻燃剂，其有利地具有高熔点和低挥发性，并且不太可能降低树脂的固有性质。本发明的阻燃剂是与交联基团如亚苯基交联的磷腈化合物，每个交联基团插入在从磷腈化合物中除去苯基后留下的两个氧基之间，苯基的量在交联化合物中，相对于磷腈化合物中的苯基总数为50〜99.9％。本发明还提供含有阻燃剂的树脂组合物和树脂的模制品。

8. 发明授权

US06797750B2 Flame-retardant epoxy resin composition, molded article thereof, and electronic part 失效
标题翻译：阻燃性环氧树脂组合物，其成型体和电子部件
公开(公告)号：US06797750B2
公开(公告)日：2004-09-28
申请号：US10221813
申请日：2002-11-07
申请人： Masatoshi Taniguchi , Yuji Tada , Yoichi Nishioka
发明人： Masatoshi Taniguchi , Yuji Tada , Yoichi Nishioka
IPC分类号： C08K549
CPC分类号： H01L23/49894 , C08G59/4071 , C08G79/025 , C08K5/5399 , C08L63/00 , C08L85/02 , H01L23/145 , H01L23/293 , H01L2924/0002 , H05K1/0373 , C08L85/00 , C08L71/00 , H01L2924/00
摘要： The present invention has an object to provide a flame-retardant epoxy resin composition excellent in heat resistance and moisture resistance. A flame-retardant epoxy resin composition relating to the present invention contains an epoxy resin (A), a phosphazene compound (B), an epoxy hardener (C) and an inorganic filler (D), wherein the phosphazene compound (B) and the epoxy hardener (C) are included in the range of 0.01 to 70% by weight and in the range of 0 to 70% by weight, respectively, relative to a total quantity of the epoxy resin (A), the phosphazene compound (B) and the epoxy hardener (C), and the inorganic filler (D) is included in the range of 0 to 95% by weight relative to a total quantity of the epoxy resin (A), the phosphazene compound (B), the epoxy hardener (C) and the inorganic filler (D), wherein the phosphazene compound (B) is at least one selected from the group consisting of (1) a cyclic and/or a chain phosphazene compound with a specific structure, (2) a polymer of the cyclic and/or the chain phosphazene compound; and (3) a reaction product of the cyclic and/or the chain phosphazene compound with one type of a compound selected from the group consisting of an epoxy compound, a phenol compound, an amine compound and an acid anhydride.
摘要翻译：本发明的目的是提供耐热性和耐湿性优异的阻燃性环氧树脂组合物。本发明的阻燃性环氧树脂组合物含有环氧树脂（A），磷腈化合物（B），环氧硬化剂（C）和无机填料（D），其中磷腈化合物（B）和相对于环氧树脂（A），磷腈化合物（B）的总量，环氧固化剂（C）的含量分别为0.01〜70重量％，0〜70重量％环氧固化剂（C）和无机填料（D）的含量相对于环氧树脂（A），磷腈化合物（B），环氧固化剂（B）的总量为0〜95重量％（C）和无机填料（D），其中磷腈化合物（B）为选自（1）具有特定结构的环状和/或链状磷腈化合物中的至少一种，（2）聚合物的环状和/或链状磷腈化合物; 和（3）环状和/或链状磷腈化合物与一种选自环氧化合物，酚化合物，胺化合物和酸酐的化合物的反应产物。

9. 发明授权

US06909101B2 Water purifying apparatus 失效
标题翻译：净水设备
公开(公告)号：US06909101B2
公开(公告)日：2005-06-21
申请号：US10756050
申请日：2004-01-12
申请人： Yoichi Nishioka
发明人： Yoichi Nishioka
IPC分类号： C02F1/32 , C02F1/36 , C02F1/28
CPC分类号： C02F1/36 , C02F1/325 , C02F2201/3228 , C02F2201/326 , C02F2209/03 , C02F2209/40 , C02F2307/06
摘要： This invention is capable of providing a water purifying apparatus with a comparatively simple configuration that can be used easily.First, a usage state is adopted by operating the knob of the faucet. In doing so, the detection means detects the flow of the water. As a result, the control unit supplies electricity to the ultraviolet light generator based on the detection signal form the detection means, and ultraviolet light is emitted. The emitted ultraviolet light then irradiates water within the passage. Water sterilization can then be carried out as a result of doing this. The ultraviolet light generator only generates light when the faucet is in use. It is therefore possible to utilize the ultraviolet light generator for long periods of time and savings are made with respect to power consumption. Further, a curving part is formed in the passage, and the ultraviolet light generator is arranged in the vicinity of the curving part. The time for which the water is irradiated with ultraviolet rays from the ultraviolet light generator is therefore made long, and the water purification efficiency is improved.
摘要翻译：本发明能够提供可以容易地使用的比较简单的构造的净水装置。首先，通过操作水龙头的旋钮来采用使用状态。在这样做时，检测装置检测水的流动。结果，控制单元根据检测装置的检测信号向紫外线发生器供电，发出紫外线。发射的紫外线然后照射通道内的水。因此，可以进行水灭菌，因为这样做。当使用水龙头时，紫外线发生器只会产生光线。因此，可以长时间地利用紫外线发生器，并且相对于功率消耗进行节省。此外，在通道中形成弯曲部分，并且紫外线发生器布置在弯曲部分附近。因此，紫外线发生器的紫外线照射时间长，水净化效率提高。

10. 发明授权

US06530679B1 Light emitting device 失效
标题翻译：发光装置
公开(公告)号：US06530679B1
公开(公告)日：2003-03-11
申请号：US09596949
申请日：2000-06-16
申请人： Yoichi Nishioka
发明人： Yoichi Nishioka
IPC分类号： F21V502
CPC分类号： F21S9/035 , F21S10/06 , F21V5/02 , F21V31/04 , F21Y2115/10 , Y02B20/72 , Y10S362/80
摘要： There is provided a light emitting device in this invention comprises a light source for supplying light, and plural light scattering devices disposed in front of the light source so as to be opposite to the direction of the light. Each of the light scattering devices comprises at least one striated surface forming plural prisms. The light is scattered by means of the prisms of the light scattering devices. This invention enables a light emitting device to achieve the spread of light with comparatively little light clustering. In particular, the light emitted from a local source can be changed from being directional to being non-directional even in case of use of the LED's source of light which is directional and so on. Therefore, the light emitting device pertaining to this invention is suitably adopted for use in the display of guardrails on the road. Moreover, in the case of using LED elements as the source of light, since LED's have a long lifetime and low power consumption, the device can be provided using a solar battery as a power source, thereby eliminating the trouble of battery replacement. Moreover, the adoption of the LED makes it easy to obtain the required power from a battery, and to eliminate defects such as broken wires caused by vehicular traffic, because conventional electric wires for supplying power are not required. Therefore, for example, the light emitting device with regard to this invention is suitable for use as an alarm light at construction sites.
摘要翻译：本发明提供了一种发光装置，其包括用于提供光的光源和设置在光源前方以与光的方向相反的多个光散射装置。每个光散射装置包括形成多个棱镜的至少一个条纹表面。光通过光散射装置的棱镜散射。本发明使得发光装置能够以相对较少的光聚集实现光的扩散。特别地，即使在使用LED的方向性等等的光源的情况下，也可以将从本地源发射的光从定向改变为无方向性。因此，本发明的发光装置适用于道路上护栏的显示。此外，在使用LED元件作为光源的情况下，由于LED具有长的寿命和低功耗，所以可以使用太阳能电池作为电源来提供该装置，从而消除了电池更换的麻烦。此外，由于不需要用于供电的常规电线，所以采用LED使得能够容易地从电池获得所需的功率，并且消除由车辆交通引起的电线断线等缺陷。因此，例如，本发明的发光装置适用于施工现场的报警灯。

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