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    • 7. 发明授权
    • Radiation surface-curable, room temperature vulcanizing silicone
compositions
    • 辐射表面可固化,室温硫化硅酮组合物
    • US5498642A
    • 1996-03-12
    • US276019
    • 1994-07-15
    • Hsien-Kun ChuRobert P. Cross
    • Hsien-Kun ChuRobert P. Cross
    • B29C70/84C08F2/46C08G77/08C08G77/18C08G77/20C08K5/00C08L83/04C09D4/00H05K3/28
    • B29C70/84C08G77/08C08G77/18C08G77/20C08K5/0025C08L83/04C09D4/00C08G77/16H05K3/287
    • A radiation surface-curable RTV silicone composition which subsequent to radiation surface curing thereof, is interiorly moisture-curable in character. Such radiation surface-curable, interiorly moisture-curable RTV silicone composition comprises: a silanol-containing silicone; a silane cross-linker for the silicone, such cross-linker having joined directly to a silicon atom thereof an ethylenically unsaturated functional group and at least two hydrolyzable functional groups; and a photoinitiator effective for radiation surface curing of the silicone composition. Also disclosed is a "liquid potting system" formulation, which is irradiated subsequent to dispensing thereof at the potting locus, so that the radiation surface-cured skin layer overlies and contains (cooperatively with the associated bounding surface(s) of the potting locus) the uncured liquid, so that the potted structure or material is encapsulated in a liquid (damping) medium.
    • 辐射表面可固化的RTV硅氧烷组合物,其辐射表面固化之后,在内部湿度可固化的性质。 这种辐射表面可固化的,内部湿气固化的RTV硅氧烷组合物包括:含硅烷醇的硅氧烷; 用于硅氧烷的硅烷交联剂,这种交联剂直接与其硅原子连接的烯属不饱和官能团和至少两个可水解官能团; 以及对硅氧烷组合物的辐射表面固化有效的光引发剂。 还公开了一种“液体灌封系统”配方,其在其在灌封区域分配后照射,使得辐射表面固化的表皮层覆盖并包含(与灌封轨迹的相关联的边界表面配合) 未固化的液体,使得盆状结构或材料被包封在液体(阻尼)介质中。
    • 9. 发明授权
    • Photocurable silicone composition, and method of making the same
    • 光固化硅酮组合物及其制造方法
    • US5179134A
    • 1993-01-12
    • US615200
    • 1990-11-19
    • Hsien-Kun ChuRobert P. CrossDavid I. Crossan
    • Hsien-Kun ChuRobert P. CrossDavid I. Crossan
    • C08F2/50C08G77/50C08L83/14C09D183/14C09K3/10
    • C09K3/1018C08G77/50C08L83/14C09D183/14C09K2003/1062C09K2200/0247C09K2200/0625
    • An acryloxy-functional capped silicone formed as a reaction product of:(i) a silyl diacrylate compound of the formula: ##STR1## wherein: R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, and R.sub.10 are independently selected from hydrogen, halo, and organo radicals; andn is an integer having a value of from 1 to 4; and(ii) a silicone having at least one functionality which is reactive with an acryloxy functionality of the silyl diacrylate compound to yield the acryloxy-functional capped silicone.The capped silicone may suitably be formulated with an effective amount of a photoinitiator for curing of the acryloxy-functional capped silicone under photoinitiating curing conditions. The silicone functionality which is reactive with the acryloxy functionality of the silyl diacrylate compound may be --OH, or other labile hydrogen-containing substituent. Preferably, the silicone is a hydroxy-terminated linear polydiorganosiloxane. The compositions of the invention are usefully employed as sealants, conformal coatings, potting materials, and the like, and are readily curable with UV radiation.
    • 形成作为以下反应产物的丙烯酰氧基官能的封端硅氧烷:(i)下式的甲硅烷基二丙烯酸酯化合物:其中:R1,R2,R3,R4,R5,R6,R7,R8,R9和R10为 独立地选自氢,卤素和有机基团; n为1〜4的整数, 和(ii)具有至少一个与甲硅烷基二丙烯酸酯化合物的丙烯酰氧基官能团反应的官能团的硅氧烷,以产生丙烯酰氧基官能的封端硅氧烷。 封端的硅氧烷可以适当地配制有效量的光引发剂,用于在光引发固化条件下固化丙烯酰氧基官能的封端硅氧烷。 与甲硅烷基二丙烯酸酯化合物的丙烯酰氧基官能团反应的硅酮官能团可以是-OH或其它不稳定的含氢取代基。 优选地,硅氧烷是羟基封端的线性聚二有机硅氧烷。 本发明的组合物有效地用作密封剂,保形涂料,灌封材料等,并且易于用UV辐射固化。