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    • 5. 发明授权
    • Substrate for use in crystallization and method for producing the same
    • 用于结晶的基板及其制造方法
    • US07579086B2
    • 2009-08-25
    • US11020063
    • 2004-12-23
    • Norihisa MinoYuusuke Takada
    • Norihisa MinoYuusuke Takada
    • B32B9/04
    • C30B29/58C30B7/00Y10T428/31663
    • A substrate for use in crystallization has a base member, and an organic molecular film on a surface of the base member. The organic molecular film has non-affinity to a liquid, and the surface of the base member and the organic molecular film are covalently bound to each other. The substrate formed with the organic molecular film having non-affinity to the liquid on the surface of the base member is produced by contacting the surface of the base member having an active hydrogen atom or the surface of the base member to which the active hydrogen atom is introduced, with an organic molecule including a terminal-bonding functional group capable of covalently bonding to the surface of the base member at one end thereof, and a functional group showing non-affinity to the liquid at the other end thereof so as to covalently bond the terminal-bonding functional group of the organic molecule to the active hydrogen atom on the surface of the base member by reaction of the terminal-bonding functional group with the active hydrogen atom. The substrate enables to efficiently crystallize polymeric compounds including biomolecules such as proteins, nucleic acids, and sugars; and resins, as well as other organic compounds, and inorganic compounds.
    • 用于结晶的基材具有基材,在基材的表面上具有有机分子膜。 有机分子膜对液体具有非亲和性,并且基材和有机分子膜的表面共价键合。 通过使具有活性氢原子的基材的表面或基体的表面与活性氢原子的表面接触,形成有与基材的表面上的液体不亲和的有机分子膜的基材 引入有机分子,其包括能够在其一端与基材的表面共价结合的末端键合官能团和在其另一端显示与液体非亲和性的官能团,以共价方式 通过末端键合官能团与活性氢原子的反应,将有机分子的末端键合官能团与基体的表面上的活性氢原子键合。 底物使得能够有效地结晶包括生物分子如蛋白质,核酸和糖的聚合物; 和树脂,以及其它有机化合物和无机化合物。
    • 6. 发明授权
    • Organic electronic device and method for manufacturing the same
    • 有机电子器件及其制造方法
    • US07560731B2
    • 2009-07-14
    • US11633924
    • 2006-12-05
    • Shinichi YamamotoNorihisa MinoKazufumi Ogawa
    • Shinichi YamamotoNorihisa MinoKazufumi Ogawa
    • H01L35/24
    • G02F1/13439C08G61/122G02F1/1343G02F2001/136295G02F2202/022H01L51/0021H01L51/0035
    • An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.
    • 本发明的有机电子器件包括基板,形成在基板上的至少两个电极,形成在基板上并电连接电极的导电有机薄膜,以及用于涂覆至少一部分 电极。 导电有机薄膜是含有共轭键合基团的有机分子的聚合物,并且每个有机分子的一端化学键合到基底表面,并且有机分子中的共轭键基团与其它分子聚合 共轭键合基团以形成共轭键链。 涂膜将电极与导电性有机薄膜电连接,与直接连接电极和导电性有机薄膜的情况相比,能够实现较小的连接电阻。 作为涂膜,可以使用由金,铂,银等金属制成的膜,导电性聚合物膜,或与电极化学键合的单分子膜。