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1. 发明申请

WO2008142541A3 RESIN BOARD TO BE SUBJECTED TO OZONE TREATMENT, WIRING BOARD, AND METHOD OF MANUFACTURING THE WIRING BOARD 审中-公开
标题翻译：要经受臭氧处理，接线板的树脂板和制造接线板的方法
公开(公告)号：WO2008142541A3
公开(公告)日：2009-01-29
申请号：PCT/IB2008001270
申请日：2008-05-21
申请人： TOYOTA MOTOR CO LTD , TOYOTA JIDOSHOKKI KK , BESSHO TAKESHI , KUMAGAI KYOKO , YOSHIDA TAKASHI , OSAMURA MANABU , SHIMO TOSHIHISA
发明人： BESSHO TAKESHI , KUMAGAI KYOKO , YOSHIDA TAKASHI , OSAMURA MANABU , SHIMO TOSHIHISA
IPC分类号： C23C18/30
CPC分类号： C23C18/2086 , C23C18/1653 , C23C18/1694 , C23C18/2006 , C23C18/2033 , H05K3/181 , H05K3/381 , H05K2203/087
摘要： A resin board that consists of at least one of a mixture of a plurality of types of resins having different degrees of susceptibility to erosion by an ozone solution, and a resin having, in a molecule, a plurality of types of components having different degrees of susceptibility to erosion by the ozone solution is treated with ozone water to form a reformed layer, and a catalyst metal is adsorbed by the reformed layer so as to form a resin-metal composite layer, on which a plating process is performed. In the resin board, a component or components that is/are likely to be eroded on by the ozone solution dissolves into the ozone solution, and pores or clearances on the order of nanometers are formed between the component(s) and a component or components that is/are less likely to be eroded by the ozone solution. With the plating deposited in the pores or clearances, the adhesion strength is improved due to an anchoring effect. Thus, the adhesion strength of the plating film is improved even where the resin-metal composite layer has a thickness of 10 to 200nm.
摘要翻译：一种树脂板，由至少一种具有与臭氧溶液侵蚀不同程度的树脂的混合物中的至少一种组成，以及分子中具有不同程度的多种成分的树脂用臭氧水处理对臭氧溶液的腐蚀的敏感性，形成重整层，催化剂金属被重整层吸附，形成进行电镀处理的树脂金属复合层。在树脂板中，可能被臭氧溶液侵蚀的成分或成分溶解在臭氧溶液中，在成分和成分之间形成有数毫米级的孔或间隙这是/不太可能被臭氧解决方案所侵蚀。随着电镀沉积在孔隙或间隙中，由于锚定效应，粘附强度得到改善。因此，即使在树脂 - 金属复合层的厚度为10〜200nm的情况下，也能够提高镀膜的附着强度。

2. 发明专利

DE112008001158T5 未知
公开(公告)号：DE112008001158T5
公开(公告)日：2010-04-22
申请号：DE112008001158
申请日：2008-05-21
申请人： TOYOTA JIDOSHOKKI KK , TOYOTA MOTOR CO LTD
发明人： BESSHO TAKESHI , KUMAGAI KYOKO , YOSHIDA TAKASHI , OSAMURA MANABU , SHIMO TOSHIHISA
IPC分类号： C23C18/30
摘要： A resin board that consists of at least one of a mixture of a plurality of types of resins having different degrees of susceptibility to erosion by an ozone solution, and a resin having, in a molecule, a plurality of types of components having different degrees of susceptibility to erosion by the ozone solution is treated with ozone water to form a reformed layer, and a catalyst metal is adsorbed by the reformed layer so as to form a resin-metal composite layer, on which a plating process is performed. In the resin board, a component or components that is/are likely to be eroded on by the ozone solution dissolves into the ozone solution, and pores or clearances on the order of nanometers are formed between the component(s) and a component or components that is/are less likely to be eroded by the ozone solution. With the plating deposited in the pores or clearances, the adhesion strength is improved due to an anchoring effect. Thus, the adhesion strength of the plating film is improved even where the resin-metal composite layer has a thickness of 10 to 200 nm.

3. 发明申请

WO2012052832A3 ELECTROLESS NICKEL PLATING BATH AND ELECTROLESS NICKEL PLATING METHOD USING SAME 审中-公开
标题翻译：电镀镍镀镍浴和电镀镍镀层方法
公开(公告)号：WO2012052832A3
公开(公告)日：2012-11-15
申请号：PCT/IB2011002514
申请日：2011-10-21
申请人： TOYOTA MOTOR CO LTD , KANTO GAKUIN UNIVERSITY , BESSHO TAKESHI , HONMA HIDEO , WATANABE MITSUHIRO , TASHIRO KATSUHIKO
发明人： BESSHO TAKESHI , HONMA HIDEO , WATANABE MITSUHIRO , TASHIRO KATSUHIKO
IPC分类号： C23C18/36
CPC分类号： C23C18/36
摘要： An electroless nickel plating bath that contains a nickel salt, a reducing agent, a stabilizer that contains metal antimony or an antimony compound, and a complexing agent that contains succinic acid or one of malic acid and lactic acid at a chelate molar ratio of 25:75 to 75:25.
摘要翻译：包含镍盐，还原剂，含有金属锑或锑化合物的稳定剂的无电镀镍浴以及螯合摩尔比为25:1的琥珀酸或苹果酸和乳酸的络合剂， 75到75:25。

4. 发明申请

WO2005007929A3 RESIN SUBSTRATE HAVING A RESIN-METAL COMPOSITE LAYER AND METHOD FOR MANUFACTURING THEREOF 审中-公开
标题翻译：具有树脂金属复合层的树脂基材及其制造方法
公开(公告)号：WO2005007929A3
公开(公告)日：2005-05-06
申请号：PCT/JP2004010976
申请日：2004-07-22
申请人： TOYOTA MOTOR CO LTD , HIRAOKA MOTOKI , YOSHINAGA FUMITAKA , DAIZA SETSUTO , BESSHO TAKESHI
发明人： HIRAOKA MOTOKI , YOSHINAGA FUMITAKA , DAIZA SETSUTO , BESSHO TAKESHI
IPC分类号： C08J7/06 , B01J35/02 , C23C18/08 , C23C18/18 , C23C18/31 , C23C26/00 , H05K3/18 , H05K3/38 , C23C18/28
CPC分类号： H05K3/38 , C23C18/08 , C23C18/2033 , C23C18/2086 , C23C18/31 , H05K3/181 , H05K2201/2063 , H05K2203/1152 , Y10T428/25 , Y10T428/26 , Y10T428/31504 , Y10T428/31678
摘要： A resin-metal composite layer is formed by modifying a surface of a resin substrate to a modified layer, contacting the modified layer with a metal compound solution, and adsorbing at least either metal colloids or ions are adsorbed to the polar group, so that metal particles are dispersed into the modified layer. Because of the fineness of the metal particles in the resin-metal composite layer, high transparent can be achieved. The resin-metal composite layer functions as a transparent conductive layer and the like.
摘要翻译：通过将树脂基板的表面改性为改性层，使改性层与金属化合物溶液接触而吸附至少一种金属胶体或离子而形成树脂 - 金属复合层，从而金属颗粒分散在改性层中。由于树脂 - 金属复合层中的金属颗粒的细度，可以实现高透明度。树脂 - 金属复合层用作透明导电层等。

5. 发明申请

WO2011104594A3 INTERNAL COMBUSTION ENGINE CONSTITUENT MEMBER, AND FORMATION METHOD FOR WATER/OIL REPELLENT COATING FILM 审中-公开
标题翻译：内燃机发动机构件及水/油喷涂膜的形成方法
公开(公告)号：WO2011104594A3
公开(公告)日：2014-05-30
申请号：PCT/IB2011000269
申请日：2011-02-14
申请人： TOYOTA MOTOR CO LTD , BESSHO TAKESHI , TAKATA SATOSHI
发明人： BESSHO TAKESHI , TAKATA SATOSHI
IPC分类号： C09D5/00
CPC分类号： C09D5/1662 , B05D5/083
摘要： An internal combustion engine constituent member of the invention has on its surface a water/oil repellent coating film that is formed from a solution that contains a fluoroalkyl group-substituted metal alkoxide that is represented by a general formula: Rf1m-M(OR1 )n-m where Rf is a fluoroalkyl group represented by a formula: CF3-(CF2)3-R2 (where R2 is each of alkylene groups that have a carbon number of 2 to 10, and that are the same as or different from each other), and m is the number of the fluoroalkyl groups, and M is a metal atom, and R1 is each of alkyl groups that have a carbon number of 1 to 5, and that are the same as or different from each other, and n is a valence of the metal atom M.
摘要翻译：本发明的内燃机构成部件在其表面上具有由含有氟烷基取代的金属醇盐的溶液形成的防水斥油涂膜，所述氟烷基取代的金属醇盐由以下通式表示：Rf1m-M（OR1）nm 其中Rf是由式CF 3 - （CF 2）3 -R 2表示的氟烷基（其中R 2各自为碳数为2至10的亚烷基，并且彼此相同或不同）， m为氟代烷基的数量，M为金属原子，R 1为碳数为1〜5的烷基，且相同或不同，n为金属原子的价态M.

6. 发明申请

WO2012052832A8 ELECTROLESS NICKEL PLATING BATH AND ELECTROLESS NICKEL PLATING METHOD USING SAME 审中-公开
标题翻译：化学镀镍浴及化学镀镍方法
公开(公告)号：WO2012052832A8
公开(公告)日：2012-06-21
申请号：PCT/IB2011002514
申请日：2011-10-21
申请人： TOYOTA MOTOR CO LTD , KANTO GAKUIN UNIVERSITY , BESSHO TAKESHI , HONMA HIDEO , WATANABE MITSUHIRO , TASHIRO KATSUHIKO
发明人： BESSHO TAKESHI , HONMA HIDEO , WATANABE MITSUHIRO , TASHIRO KATSUHIKO
IPC分类号： C23C18/36
CPC分类号： C23C18/36
摘要： An electroless nickel plating bath that contains a nickel salt, a reducing agent, a stabilizer that contains metal antimony or an antimony compound, and a complexing agent that contains succinic acid or one of malic acid and lactic acid at a chelate molar ratio of 25:75 to 75:25.
摘要翻译：一种含有镍盐，还原剂，含有金属锑或锑化合物的稳定剂以及含有螯合摩尔比为25:1的琥珀酸或苹果酸和乳酸中的一种的络合剂的无电镀镍浴。 75到75:25。

7. 发明申请

WO2011148242A3 METHOD OF PLATING STAINLESS STEEL AND PLATED MATERIAL 审中-公开
标题翻译：电镀不锈钢和镀层材料的方法
公开(公告)号：WO2011148242A3
公开(公告)日：2012-04-05
申请号：PCT/IB2011001098
申请日：2011-05-23
申请人： TOYOTA MOTOR CO LTD , BESSHO TAKESHI
发明人： BESSHO TAKESHI
IPC分类号： C25D5/14 , C23C10/60 , C23C26/00 , C23C28/02 , C25D5/24 , C25D5/26 , C25D5/36 , C25D5/50
CPC分类号： C25D5/10 , C23C28/02 , C23C28/028 , C25D5/14 , C25D5/34 , C25D5/36 , C25D5/50 , C25D7/00 , Y10T428/12944
摘要： The method of plating a stainless steel substrate including depositing a first plating metal layer over the stainless steel substrate (S13), forming an interdiffusion layer in which elements of the stainless steel substrate and elements of the first plating metal layer interdiffuse, by applying a heat treatment to the stainless steel substrate coated by the first plating metal layer (S14), and coating a second plating metal layer over the surface of the stainless steel substrate over which the interdiffusion layer is coated (S16).
摘要翻译：一种不锈钢基板的镀敷方法，其特征在于，在不锈钢基板上沉积第一镀层金属层（S13），通过加热，形成不锈钢基板的各要素与第一镀层金属层的各元素相互扩散的相互扩散层处理涂覆在第一电镀金属层上的不锈钢基材（S14），并在其上涂覆有相互扩散层的不锈钢基材表面上涂覆第二电镀金属层（S16）。

8. 发明申请

WO2011148242A8 METHOD OF PLATING STAINLESS STEEL AND PLATED MATERIAL 审中-公开
标题翻译：不锈钢和镀层材料的镀层方法
公开(公告)号：WO2011148242A8
公开(公告)日：2012-02-16
申请号：PCT/IB2011001098
申请日：2011-05-23
申请人： TOYOTA MOTOR CO LTD , BESSHO TAKESHI
发明人： BESSHO TAKESHI
IPC分类号： C25D5/14
CPC分类号： C25D5/10 , C23C28/02 , C23C28/028 , C25D5/14 , C25D5/34 , C25D5/36 , C25D5/50 , C25D7/00 , Y10T428/12944
摘要： The method of plating a stainless steel substrate including depositing a first plating metal layer over the stainless steel substrate (S13), forming an interdiffusion layer in which elements of the stainless steel substrate and elements of the first plating metal layer interdiffuse, by applying a heat treatment to the stainless steel substrate coated by the first plating metal layer (S14), and coating a second plating metal layer over the surface of the stainless steel substrate over which the interdiffusion layer is coated (S16).
摘要翻译：电镀不锈钢基板的方法，包括在不锈钢基板上沉积第一电镀金属层（S13），形成相互扩散层，其中不锈钢基板的元件和第一电镀金属层的元件相互扩散，通过施加热量处理到由第一电镀金属层涂覆的不锈钢基材（S14），并在涂覆有相互扩散层的不锈钢基材的表面上涂覆第二电镀金属层（S16）。

9. 发明申请

WO2011042792A2 OZONE GAS TREATMENT METHOD 审中-公开
标题翻译：臭氧气体处理方法
公开(公告)号：WO2011042792A2
公开(公告)日：2011-04-14
申请号：PCT/IB2010002515
申请日：2010-10-05
申请人： TOYOTA MOTOR CO LTD , KURITA WATER IND LTD , YANAGIMOTO HIROSHI , BESSHO TAKESHI , MORITA HIROSHI , NEMOTO ATSUSHI
发明人： YANAGIMOTO HIROSHI , BESSHO TAKESHI , MORITA HIROSHI , NEMOTO ATSUSHI
CPC分类号： C23C18/30 , C23C18/2033 , C23C18/2086 , C23C18/22 , C23C18/285
摘要： A method for performing an ozone gas treatment on a surface of a resin substrate that includes: setting conditions of ozone gas concentration D, treatment time t, and ozone gas temperature T using an ozone gas exposure amount I that is obtained by the following equation: I=Dxtxex?((-L/(273.15+T)) (where D is the ozone gas concentration, t is the treatment time, T is the ozone gas temperature, and L is the temperature coefficient); exposing the surface of the resin substrate to the ozone gas according to the conditions that are set; and treating the surface of the resin substrate with an alkaline solution after the substrate surface has been exposed to the ozone gas.
摘要翻译：一种臭氧气体处理方法，其特征在于，使用通过下式求出的臭氧气体露出量I来设定臭氧气体浓度D，处理时间t，臭氧气体温度T的条件： I = Dxtxex？（（ - L /（273.15 + T））（其中D是臭氧气体浓度，t是处理时间，T是臭氧气体温度，L是温度系数）;暴露根据设定的条件将所述树脂基板粘合到所述臭氧气体上;以及在所述基板表面已经暴露于所述臭氧气体之后用碱性溶液处理所述树脂基板的表面。

10. 发明申请

WO2004033754A3 PRETREATMENT METHOD FOR ELECTROLESS PLATING MATERIAL AND METHOD FOR PRODUCING MEMBER HAVING PLATED COATING 审中-公开
标题翻译：用于化学镀材料的预处理方法和用于生产具有涂覆涂层的部件的方法
公开(公告)号：WO2004033754A3
公开(公告)日：2004-07-15
申请号：PCT/JP0313012
申请日：2003-10-09
申请人： TOYOTA MOTOR CO LTD , HIRAOKA MOTOKI , BESSHO TAKESHI , SIBATA SIGERU
发明人： HIRAOKA MOTOKI , BESSHO TAKESHI , SIBATA SIGERU
IPC分类号： C23C18/16 , C23C18/20 , C23C18/28 , C23C18/22 , C23C18/54
CPC分类号： C23C18/1653 , C23C18/2006 , C23C18/204
摘要： A resin material is brought into contact with a first solution containing ozone, and at the same time, ultraviolet rays are irradiated. The activation due to the treatment with ozone water and the activation due to the treatment with ultraviolet rays are synergistically operated to enable the formation of a plated coating having excellent adhesive strength by a short treatment. In addition, even by a long treatment, the adhesive strength can be restrained from lowering. Consequently, a plated coating having excellent adhesion can be formed without roughening the surface of the resin material by a short pretreatment.
摘要翻译：使树脂材料与含有臭氧的第一溶液接触，同时照射紫外线。由臭氧水处理引起的活化作用和紫外线处理引起的活化作用协同操作，使得能够通过短暂处理形成具有优异粘合强度的镀覆涂层。另外，即使经过长时间的处理，粘合强度也可以被抑制下降。因此，可以形成具有优异粘合性的镀覆涂层，而不用通过短的预处理使树脂材料的表面变粗糙。

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