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1. 发明申请

WO2015071275A1 BALLISTIC RESISTANT ARTICLE WITH NON-UNIFORMLY DISTRIBUTED MATRIX MATERIAL AND METHOD TO MANUFACTURE SAID ARTICLE 审中-公开
标题翻译：具有非均匀分布矩阵材料的耐压制品及其制造方法
公开(公告)号：WO2015071275A1
公开(公告)日：2015-05-21
申请号：PCT/EP2014/074307
申请日：2014-11-12
申请人： TEIJIN ARAMID B.V. , BARRDAY INC.
发明人： GROSSMAN, Jan , DE HAAS, Marc-Jan , POULOPOULOS, Nektarios , WILLIAMS, Alicia , WILSON, Jason
IPC分类号： F41H5/04
CPC分类号： F41H5/0485 , B32B5/26 , B32B7/08 , B32B7/12 , B32B2571/02 , F41H5/0471
摘要： A ballistic resistant article and a method of its manufacture are provided. The article comprises at least one consolidated composite, wherein the at least one consolidated composite comprises a layer A and a layer B bonded to one another, each layer A and B exhibits a first surface, a second surface opposite to the first surface, and a cross-section extending from the first surface to the second surface, each layer A and each layer B comprises a network of fibers having a strength of at least 800 mN/tex (1100 MPa) according to ASTM D 7269-07, and the fibers in each layer A and B are impregnated with a matrix material, characterized in that the matrix material is distributed along the cross-section of each layer in the shape of a concentration gradient, wherein the concentration starts with a maximum value on the first surface, so that the first surface is rich in matrix material, decreases along the cross-section and reaches a minimum value on the second surface, so that the second surface is poor in matrix material, and the matrix material comprises a mixture of 75 to 95 wt.% of a polychloroprene, and 5 to 25 wt.% of a random copolymer of vinyl chloride and an acrylic ester based on a weight of the mixture.
摘要翻译：提供防弹物品及其制造方法。所述制品包括至少一个固结的复合材料，其中所述至少一个固结的复合材料包括彼此结合的层A和层B，每个层A和B表现出第一表面，与第一表面相对的第二表面，横截面从第一表面延伸到第二表面，每个层A和每个层B包括根据ASTM D 7269-07的强度为至少800mN / tex（1100MPa）的纤维网，并且纤维在每个层A和B中浸渍有基质材料，其特征在于基质材料沿浓度梯度的形式沿着各层的横截面分布，其中浓度以第一表面上的最大值开始，使得第一表面富含基质材料，沿着横截面减小并在第二表面上达到最小值，使得第二表面在基体材料中较差，并且基体材料包括混合物 e为75至95重量％的聚氯丁二烯和5至25重量％的氯乙烯和丙烯酸酯的无规共聚物，基于混合物的重量。

2. 发明申请

WO2012150164A1 ANTIBALLISTIC PANEL 审中-公开
标题翻译：防弹面板
公开(公告)号：WO2012150164A1
公开(公告)日：2012-11-08
申请号：PCT/EP2012/057588
申请日：2012-04-26
申请人： TEIJIN ARAMID B.V. , BARRDAY INC. , DE HAAS, Marc-Jan , PATEL, Chinkalben
发明人： DE HAAS, Marc-Jan , PATEL, Chinkalben
IPC分类号： F41H5/04
CPC分类号： F41H5/0485
摘要： The invention pertains to an antiballistic panel. The panel comprises at least a first stack and a second stack, wherein the first stack has a plurality of first laminates made of a first kind of fibers and the second stack has a plurality of second laminates made of a second kind of fibers, wherein the first kind of fibers has a tensile modulus in the range of 40-85 GPa measured according to ASTM D7269 and the second kind of fibers has a tensile modulus in the range of 86-140 GPa measured according to ASTM D7269.
摘要翻译：本发明涉及一种抗菌面板。所述面板包括至少第一堆叠和第二堆叠，其中所述第一堆叠具有由第一种纤维制成的多个第一层压体，所述第二堆叠具有由第二种纤维制成的多个第二层压板，其中，根据ASTM D7269，第一种纤维的拉伸模量在40-85GPa的范围内，第二种纤维的拉伸模量根据ASTM D7269测量在86-140GPa范围内。

3. 发明申请

WO2012098154A1 BALLISTIC RESISTANT ARTICLE COMPRISING A STYRENE BUTADIENE RESIN AND PROCESS TO MANUFACTURE SAID ARTICLE 审中-公开
标题翻译：包含苯乙烯丁二烯树脂的耐药品及其制造方法
公开(公告)号：WO2012098154A1
公开(公告)日：2012-07-26
申请号：PCT/EP2012/050701
申请日：2012-01-18
申请人： TEIJIN ARAMID B.V. , BARRDAY INC. , DE HAAS, Marc-Jan , VAN NOREL, Alex , VAN BOMMEL, Vincent , VAN ROOIJ, Ramon , CUNNINGHAM, Nicolas , PATEL, Chinkalben
发明人： DE HAAS, Marc-Jan , VAN NOREL, Alex , VAN BOMMEL, Vincent , VAN ROOIJ, Ramon , CUNNINGHAM, Nicolas , PATEL, Chinkalben
IPC分类号： F41H5/04
CPC分类号： F41H1/02 , F41H5/0435 , F41H5/0464 , F41H5/0485 , Y10T442/10 , Y10T442/2623
摘要： A ballistic resistant article is presented comprising a plurality of fibrous layers, each of said layers comprising a network of fibers, wherein the fibers have a strength of at least 800 mN/tex (1100 MPa) according to ASTM D 7269-07 and a matrix material, wherein the matrix material comprises a mixture comprising: at least one styrene butadiene random copolymer resin, and at least one tackifier. Compared with an article of the same construction but with a matrix material without a tackifier the article according to the invention comprises a higher adhesion between the fibrous layers both in the unaged and aged state and a lower water pick up after water soak. The article additionally comprising a plate of metal or ceramic exhibits minimal or even no delamination of the fibrous layers after ballistic attack. In contrast an article of the same construction but with a matrix material without the styrene butadiene random copolymer resin exhibits (very strong) interior delamination of the fibrous layers and the article of the same construction with the styrene butadiene random copolymer resin, but without the tackifier as the matrix material exhibits light delamination.
摘要翻译：提供了一种防弹制品，其包括多个纤维层，每个所述层包括纤维网，其中根据ASTM D 7269-07的纤维具有至少800mN / tex（1100MPa）的强度，并且基质材料，其中所述基质材料包括包含至少一种苯乙烯丁二烯无规共聚物树脂和至少一种增粘剂的混合物。与具有相同结构的制品相比，不含增粘剂的基体材料，根据本发明的制品在未老化和老化状态下的纤维层之间具有较高的粘附性，以及在水浸后的较低的水吸收。额外包含金属或陶瓷板的物品在弹道攻击之后表现出最小或甚至不分层的纤维层。相反，具有相同结构但是没有苯乙烯丁二烯无规共聚物树脂的基体材料的物品显示（非常强烈的）纤维层的内部分层和与苯乙烯丁二烯无规共聚物树脂相同构造的制品，但没有增粘剂因为基体材料表现出轻的分层。

4. 发明申请

WO2012150169A1 ANTIBALLISTIC PANEL 审中-公开
标题翻译：防弹面板
公开(公告)号：WO2012150169A1
公开(公告)日：2012-11-08
申请号：PCT/EP2012/057611
申请日：2012-04-26
申请人： TEIJIN ARAMID B.V. , BARRDAY INC. , DE HAAS, Marc-Jan , PATEL, Chinkalben
发明人： DE HAAS, Marc-Jan , PATEL, Chinkalben
IPC分类号： F41H5/04
CPC分类号： F41H5/0485
摘要： The invention pertains to an antiballistic panel comprising at least a first stack and a second stack, wherein the first stack has a plurality of first laminates made of a first kind of yarn and the second stack has a plurality of second laminates made of a second kind of yarn, wherein the first kind of yarn has linear density of at least 1001 dtex measured by ASTM D1907 and a filament linear density of at most 1.2 dtex measured by ASTM D1577-07, option C-2 and the second kind of yarn has a linear density of at most 1000 dtex measured by ASTM D1907 and a filament linear density of at least 1.3 dtex measured by ASTM D1577-07 option C-2.
摘要翻译：本发明涉及一种包括至少第一堆叠和第二堆叠的抗折叠板，其中第一堆叠具有由第一种纱线制成的多个第一层压板，并且第二堆叠体具有由第二种制成的多个第二层压板的纱线，其中第一种纱线具有通过ASTM D1907测量的至少1001dtex的线密度，并且通过ASTM D1577-07，选项C-2测量的丝束线密度为至多1.2dtex，并且第二种纱线具有通过ASTM D1907测量的至多1000dtex的线密度和通过ASTM D1577-07选项C-2测量的至少1.3dtex的丝线密度。

5. 发明申请

WO2014154587A1 BALLISTIC RESISTANT ARTICLE AND PROCESS TO MANUFACTURE SAID ARTICLE 审中-公开
标题翻译：防弹性物品和制造方法制作文章
公开(公告)号：WO2014154587A1
公开(公告)日：2014-10-02
申请号：PCT/EP2014/055735
申请日：2014-03-21
申请人： TEIJIN ARAMID B.V. , BARRDAY INC.
发明人： DE HAAS, Marc-Jan , VAN NOREL, Alex , VAN BOMMEL, Vincent , POULOPOULOS, Nektarios , WILLIAMS, Alicia
IPC分类号： F41H5/04
CPC分类号： F41H5/0478 , B32B5/022 , B32B5/024 , B32B5/26 , B32B37/14 , B32B2260/021 , B32B2260/046 , B32B2262/0269 , B32B2264/0242 , B32B2264/0257 , B32B2571/02 , F41H5/0485
摘要： A ballistic resistant article is provided and a process to manufacture said article. The ballistic resistant articles comprises at least one consolidated composite, wherein the at least one consolidated composite comprises at least two layers, each layer comprises a network of fibers, the fibers have a strength of at least 800 mN/tex (1100 MPa) according to ASTM D 7269-07, the fibers in each layer are impregnated with a matrix material, and each consolidated composite has a front surface and a rear surface. In said ballistic article at least the front surface of each consolidated composite is powder coated with partly molten and solidified powder particles to form a powder coated surface, and the partly molten and solidified powder particles form an island-in-the-sea coating pattern on the powder coated surface.
摘要翻译：提供防弹制品和制造所述制品的方法。防弹制品包括至少一个固结的复合材料，其中所述至少一个固结的复合材料包括至少两个层，每个层包括纤维网，所述纤维的强度至少为800mN / tex（1100MPa），根据 ASTM D 7269-07中，每层中的纤维用基质材料浸渍，并且每个固结复合材料具有前表面和后表面。在所述弹道制品中，至少每个固结复合材料的前表面是粉末涂覆有部分熔融和固化的粉末颗粒以形成粉末涂覆表面，并且部分熔融和固化的粉末颗粒形成岛上海岛涂层图案粉末涂层表面。

6. 发明申请

WO2012098158A1 BALLISTIC RESISTANT ARTICLE COMPRISING A SELF-CROSSLINKING ACRYLIC RESIN AND/OR A CROSSLINKABLE ACRYLIC RESIN AND PROCESS TO MANUFACTURE SAID ARTICLE 审中-公开
标题翻译：包含自交联丙烯酸树脂和/或可交联丙烯酸树脂的防弹性物品及其制造方法
公开(公告)号：WO2012098158A1
公开(公告)日：2012-07-26
申请号：PCT/EP2012/050705
申请日：2012-01-18
申请人： Teijin Aramid B.V. , Barrday Inc. , DE HAAS, Marc-Jan , VAN NOREL, Alex , VAN BOMMEL, Vincent , VAN ROOIJ, Ramon , CUNNINGHAM, Nicolas , PATEL, Chinkalben
发明人： DE HAAS, Marc-Jan , VAN NOREL, Alex , VAN BOMMEL, Vincent , VAN ROOIJ, Ramon , CUNNINGHAM, Nicolas , PATEL, Chinkalben
IPC分类号： F41H5/04
CPC分类号： F41H5/0485 , F41H5/0435 , F41H5/0464 , F41H5/0478 , Y10T156/10
摘要： A ballistic resistant article is presented comprising a plurality of fibrous layers, each of said layers comprising a network of fibers, wherein the fibers have a strength of at least 800 mN/tex (1100 MPa) according to ASTM D 7269-07 and a matrix material, wherein the matrix material comprises a mixture comprising at least one self-crosslinking acrylic resin and/or at least one crosslinkable acrylic resin, and at least one tackifier. Compared with an article of the same construction but with a matrix material without tackifier the article according to the invention comprises a higher adhesion between the fibrous layers both in the unaged and aged state and a lower water pick up after water soak and the article passes the gasoline soak test. The article additionally comprising a plate of metal or ceramic exhibits minimal or even no delamination of the fibrous layers after ballistic attack, whereas an article of the same construction but with a matrix material without tackifier exhibits interior delamination of the fibrous layers.
摘要翻译：提供了一种防弹制品，其包括多个纤维层，每个所述层包括纤维网，其中根据ASTM D 7269-07的纤维具有至少800mN / tex（1100MPa）的强度，并且基质材料，其中所述基质材料包括包含至少一种自交联丙烯酸树脂和/或至少一种可交联丙烯酸树脂的混合物和至少一种增粘剂。与不具有增粘剂的基质材料相比，具有相同结构的物品，但是根据本发明的制品在未老化和老化状态下的纤维层之间具有较高的附着力，并且在水浸泡后的较低的水吸收量，并且制品通过汽油浸泡试验。另外包括金属或陶瓷板的物品在弹道攻击之后表现出最小或甚至没有纤维层的分层，而具有相同结构但是没有增粘剂的基体材料的制品表现出纤维层的内部分层。

7. 发明授权

EP2979056B1 BALLISTIC RESISTANT ARTICLE AND PROCESS TO MANUFACTURE SAID ARTICLE 有权
标题翻译：防弹文章和制造文章的过程
公开(公告)号：EP2979056B1
公开(公告)日：2017-10-25
申请号：EP14712278.2
申请日：2014-03-21
申请人： Teijin Aramid B.V. , Barrday Inc.
发明人： DE HAAS, Marc-Jan , VAN NOREL, Alex , VAN BOMMEL, Vincent , POULOPOULOS, Nektarios , WILLIAMS, Alicia
IPC分类号： F41H5/04
CPC分类号： F41H5/0478 , B32B5/022 , B32B5/024 , B32B5/26 , B32B37/14 , B32B2260/021 , B32B2260/046 , B32B2262/0269 , B32B2264/0242 , B32B2264/0257 , B32B2571/02 , F41H5/0485
摘要： A ballistic resistant article is provided along with a process to manufacture the article. The ballistic resistant articles includes at least one consolidated composite, wherein the at least one consolidated composite includes at least two layers, each layer includes a network of fibers, the fibers have a strength of at least 800 mN/tex (1100 MPa) according to ASTM D 7269-07, the fibers in each layer are impregnated with a matrix material, and each consolidated composite has a front surface and a rear surface. In the ballistic article, at least the front surface of each consolidated composite is powder coated with partly molten and solidified powder particles to form a powder coated surface.

8. 发明公开

EP2804756A1 HIGH DENSITY UNIDIRECTIONAL FABRIC FOR SOFT BALLISTICS APPLICATIONS 审中-公开
标题翻译：高密度单向织物模拟软防弹应用
公开(公告)号：EP2804756A1
公开(公告)日：2014-11-26
申请号：EP13776344.7
申请日：2013-01-17
申请人： Barrday, Inc. , Teijin Aramid B.V.
发明人： VAN HEERDEN, Jason , MACNEIL, Jonathan , PATEL, Chinkal , TOWERY, Matt , WILSON, Jason , DE HAAS, Marc-Jan
IPC分类号： B32B27/00
CPC分类号： F41H5/0478 , B32B5/12 , B32B27/08 , B32B27/12 , B32B27/20 , B32B27/302 , B32B27/32 , B32B2250/02 , B32B2250/20 , B32B2250/24 , B32B2260/021 , B32B2260/046 , B32B2262/0269 , B32B2307/54 , B32B2307/581 , B32B2307/718 , B32B2323/00 , B32B2571/02 , D02J1/18 , F41H5/0485
摘要： A ballistic article is comprised of high density fibers, where the linear mass density of the fibers is greater than 2000 dtex as measured by ASTM D1907 and the fibers in each layer have a total areal density greater than 100 g/m
2. In one example, the ballistic article has two sheets comprising para-aramid fibers in a styrene and isoprene block copolymer matrix material.

9. 发明公开

EP3069096A1 BALLISTIC RESISTANT ARTICLE WITH NON-UNIFORMLY DISTRIBUTED MATRIX MATERIAL AND METHOD TO MANUFACTURE SAID ARTICLE 有权
标题翻译：根据上述制造客体分布不均匀基体材料和方法BALL安全的对象
公开(公告)号：EP3069096A1
公开(公告)日：2016-09-21
申请号：EP14802830.1
申请日：2014-11-12
申请人： Teijin Aramid B.V. , Barrday Inc.
发明人： GROSSMAN, Jan , DE HAAS, Marc-Jan , POULOPOULOS, Nektarios , WILLIAMS, Alicia , WILSON, Jason
IPC分类号： F41H5/04
CPC分类号： F41H5/0485 , B32B5/26 , B32B7/08 , B32B7/12 , B32B2571/02 , F41H5/0471
摘要： A ballistic resistant article and a method of its manufacture are provided. The article comprises at least one consolidated composite, wherein the at least one consolidated composite comprises a layer A and a layer B bonded to one another, each layer A and B exhibits a first surface, a second surface opposite to the first surface, and a cross-section extending from the first surface to the second surface, each layer A and each layer B comprises a network of fibers having a strength of at least 800 mN/tex (1100 MPa) according to ASTM D 7269-07, and the fibers in each layer A and B are impregnated with a matrix material, characterized in that the matrix material is distributed along the cross-section of each layer in the shape of a concentration gradient, wherein the concentration starts with a maximum value on the first surface, so that the first surface is rich in matrix material, decreases along the cross-section and reaches a minimum value on the second surface, so that the second surface is poor in matrix material, and the matrix material comprises a mixture of 75 to 95 wt.% of a polychloroprene, and 5 to 25 wt.% of a random copolymer of vinyl chloride and an acrylic ester based on a weight of the mixture.
摘要翻译：的横截面从所述第一表面延伸到所述第二表面，并且包括具有至少800兆牛顿/特（1100兆帕）的强度纤维网络，并且在每个层A和B的纤维与基质材料的浸渍。该基体材料沿在其与第一表面上的最大值开始，沿着所述横截面的减小并达到第二表面上的最小值的浓度的浓度梯度的各层的横截面分布。所述基质材料包括聚氯丁烯的混合物，和氯乙烯和丙烯酸酯的无规共聚物。

10. 发明公开

EP2665986A1 BALLISTIC RESISTANT ARTICLE COMPRISING A SELF-CROSSLINKING ACRYLIC RESIN AND/OR A CROSSLINKABLE ACRYLIC RESIN AND PROCESS TO MANUFACTURE SAID ARTICLE 有权
标题翻译：固体产物与自交联丙烯酸树脂和/或用于制造这种制品的可交联丙烯酸类树脂和方法SHOT
公开(公告)号：EP2665986A1
公开(公告)日：2013-11-27
申请号：EP12700485.1
申请日：2012-01-18
申请人： Teijin Aramid B.V. , Barrday, Inc.
发明人： DE HAAS, Marc-Jan , VAN NOREL, Alex , VAN BOMMEL, Vincent , VAN ROOIJ, Ramon , CUNNINGHAM, Nicolas , PATEL, Chinkalben
IPC分类号： F41H5/04
CPC分类号： F41H5/0485 , F41H5/0435 , F41H5/0464 , F41H5/0478 , Y10T156/10
摘要： A ballistic resistant article is presented comprising a plurality of fibrous layers, each of said layers comprising a network of fibers, wherein the fibers have a strength of at least 800 mN/tex (1100 MPa) according to ASTM D 7269-07 and a matrix material, wherein the matrix material comprises a mixture comprising at least one self-crosslinking acrylic resin and/or at least one crosslinkable acrylic resin, and at least one tackifier. Compared with an article of the same construction but with a matrix material without tackifier the article according to the invention comprises a higher adhesion between the fibrous layers both in the unaged and aged state and a lower water pick up after water soak and the article passes the gasoline soak test. The article additionally comprising a plate of metal or ceramic exhibits minimal or even no delamination of the fibrous layers after ballistic attack, whereas an article of the same construction but with a matrix material without tackifier exhibits interior delamination of the fibrous layers.

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