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1. 发明专利

JP2011045878A Base-triggered release microcapsule 审中-公开
标题翻译：基本触发释放微波
公开(公告)号：JP2011045878A
公开(公告)日：2011-03-10
申请号：JP2010212853
申请日：2010-09-22
申请人： Syngenta Ltd , シンジェンタリミテッド
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT B , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD R
IPC分类号： B01J13/18 , A01N25/04 , A01N25/28 , A01N47/12 , A01N53/00 , A01N53/08 , A01N57/16 , A01P7/04 , A01P13/00 , B01J13/16
CPC分类号： B01J13/16 , A01N25/28
摘要： PROBLEM TO BE SOLVED: To provide a highly safe pesticide-containing microcapsule whose capsule shell wall is designed so as to quickly disintegrate under the alkaline condition present in an insect gut. SOLUTION: In the pesticide-containing microcapsule, a pesticide is encapsulated in a polymeric shell wall formed by interfacial polymerization and condensation of a mixture of a butylated urea-formaldehyde prepolymer and a cross-linking agent containing sulfhydryl groups and hydroxyl groups, such as a glycolate ester and a mercapto carboxylic acid ester of pentaerythritol. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：为了提供高度安全的含农药微胶囊，其胶囊壳壁被设计成在昆虫肠中存在的碱性条件下快速崩解。解决方案：在含农药的微胶囊中，将农药包封在由丁基化脲 - 甲醛预聚物和含有巯基和羟基的交联剂的混合物的界面聚合和缩合形成的聚合物壳壁中，例如季戊四醇的乙醇酸酯和巯基羧酸酯。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2011037864A Acid-induced release microcapsule 审中-公开
标题翻译：酸诱导释放微生物
公开(公告)号：JP2011037864A
公开(公告)日：2011-02-24
申请号：JP2010212856
申请日：2010-09-22
申请人： Syngenta Ltd , シンジェンタリミテッド
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT BENSON , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD R
IPC分类号： A01N25/28 , A01N25/04 , A01N43/40 , A01N47/12 , A01P13/00 , B01J13/16
CPC分类号： A01N25/28 , B01J13/16
摘要： PROBLEM TO BE SOLVED: To provide a microcapsule which is acid-induced or acid-sensitive and which is useful for the controlled release of a physiologically active substance and an agrochemical substance, preferably of a pesticide for the treatment of leaves.
SOLUTION: This microcapsule is formed with a polyurea shell wall containing at least one oligomer acetal part expressed by formula (I) and an encapsulated component which is included inside this shell wall [in the formula, R is (a) a (5-about 40)C carbon chain which may be substituted, (b) a (4-about 40)C carbon chain having one or more internally-bonded oxygen atoms or the like, or (c) an ethylene chain or propylene chain which may be substituted; Z is a phenyl group which may be substituted or a 1C-20C alkyl group which may be substituted; and n is 1 when R is (a) or (b), and n is 2-20 when R is (c)].
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供酸诱导或酸敏感的微胶囊，其可用于控制释放生理活性物质和农药物质，优选农药用于治疗叶子。解决方案：该微胶囊由含有至少一种由式（I）表示的低聚物缩醛部分的聚脲壳壁和包含在该壳壁内部的包封组分形成[在式中，R是（a）a（ 5〜40）C碳链，（b）具有一个或多个内部键合的氧原子等的（4-约40）C碳链，或（c）乙烯链或丙烯链，可以替代; Z是可以被取代的苯基或可以被取代的1C-20C烷基; 当R为（a）或（b）时，n为1，当R为（c）时，n为2-20）。版权所有（C）2011，JPO＆INPIT

3. 发明专利

DE69905903T2 未知
公开(公告)号：DE69905903T2
公开(公告)日：2003-11-06
申请号：DE69905903
申请日：1999-07-28
申请人： SYNGENTA LTD
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT BENSON , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD R
IPC分类号： A01N25/04 , A01N25/28 , B01J13/16
摘要： Microcapsules of a microcapsule formed of a polyurea shell wall and an encapsulated ingredient or ingredients enclosed within the wall, the wall comprising at least one oligomeric acetal having the moiety represented by formula (I) in which R is (a) a moiety containing a chain of from 5 to about 40 optionally substituted carbon atoms, (b) a moiety containing a chain of from 4 to about 40 carbon atoms and one or more internally linked oxygen or sulfur atoms or -NH-groups, or (c) an optionally substituted ethylene or propylene moiety. Z is (a) an optionally substituted phenyl group, (b) an optionally substituted C1-C20 alkyl, C2-C20 alkenyl, C3-C8 cycloalkyl or C5-C8 cycloalkenyl group, or (c) benzoyl, and n is 1 if R is (a) or (b), or is 2-20 if R is (c). The microcapsules are acid-sensitive and the capsule walls are relatively readily degraded or disintegrated by contacting the microcapsules with an acidic substance, preferably an organic or inorganic acid whereby the encapsulated ingredient or ingredients are released into the surrounding environment. The invention is particularly suitable for encapsulation of biologically active substances and agrochemicals, and most preferably pesticides for foliar treatment.

4. 发明专利

ES2190235T3 未知
公开(公告)号：ES2190235T3
公开(公告)日：2003-07-16
申请号：ES99936789
申请日：1999-07-28
申请人： SYNGENTA LTD
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT BENSON , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD R ZENECA
IPC分类号： A01N25/04 , A01N25/28 , B01J13/16
摘要： Microcapsules of a microcapsule formed of a polyurea shell wall and an encapsulated ingredient or ingredients enclosed within the wall, the wall comprising at least one oligomeric acetal having the moiety represented by formula (I) in which R is (a) a moiety containing a chain of from 5 to about 40 optionally substituted carbon atoms, (b) a moiety containing a chain of from 4 to about 40 carbon atoms and one or more internally linked oxygen or sulfur atoms or -NH-groups, or (c) an optionally substituted ethylene or propylene moiety. Z is (a) an optionally substituted phenyl group, (b) an optionally substituted C1-C20 alkyl, C2-C20 alkenyl, C3-C8 cycloalkyl or C5-C8 cycloalkenyl group, or (c) benzoyl, and n is 1 if R is (a) or (b), or is 2-20 if R is (c). The microcapsules are acid-sensitive and the capsule walls are relatively readily degraded or disintegrated by contacting the microcapsules with an acidic substance, preferably an organic or inorganic acid whereby the encapsulated ingredient or ingredients are released into the surrounding environment. The invention is particularly suitable for encapsulation of biologically active substances and agrochemicals, and most preferably pesticides for foliar treatment.

5. 发明专利

CZ303965B6 Mikrokapsle a zpusob její prípravy, vodná suspenze nebo kompozice obsahující mikrokapsle a zpusob potlacování skudcu 未知
公开(公告)号：CZ303965B6
公开(公告)日：2013-07-24
申请号：CZ2001298
申请日：1999-07-28
申请人： SYNGENTA LTD
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT BENSON , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD R
IPC分类号： A01N25/28 , A01N25/04 , A01N53/00 , A01N53/08 , A01N57/16 , B01J13/16
摘要： Mikrokapsle obsahující slozku nebo slozky zapouzdrené v aminoplastovém plásti, kde materiál pláste obsahuje esterovou skupinu jádro[(A.sub.1.n.-X).sub.t.n.CH.sub.2.n.N

6. 发明专利

ES2198933T3 未知
公开(公告)号：ES2198933T3
公开(公告)日：2004-02-01
申请号：ES99936786
申请日：1999-07-28
申请人： SYNGENTA LTD
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT BENSON , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD
IPC分类号： A01N25/04 , A01N25/28 , A01N53/00 , A01N53/08 , A01N57/16 , B01J13/16
摘要： Microcapsules formed from an aminoplast shell wall and an encapsulated ingredient or ingredients enclosed within the wall in which the wall contains a base-cleavable ester moiety. These capsules have been found to be sensitive to the presence of base such that in the presence of base, the capsule walls are relatively quickly disintegrated or degraded so as to produce a relatively quick release of the encapsulated materials. Microcapsules of this invention are particularly suitable for use in controlling insects having an alkaline gut such as certain lepidoptera in that the capsule shell wall may be designed so as to quickly disintegrate under the alkaline conditions present in the gut of the insect thus providing a microcapsule which is safe to handle but which is selectively effective against certain undesirable insects while not harmful to beneficial insects or insects which do not feed on the capsule materials.

7. 发明专利

AT234004T 未知
公开(公告)号：AT234004T
公开(公告)日：2003-03-15
申请号：AT99936789
申请日：1999-07-28
申请人： SYNGENTA LTD
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT BENSON , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD R
IPC分类号： A01N25/04 , A01N25/28 , B01J13/16
摘要： Microcapsules of a microcapsule formed of a polyurea shell wall and an encapsulated ingredient or ingredients enclosed within the wall, the wall comprising at least one oligomeric acetal having the moiety represented by formula (I) in which R is (a) a moiety containing a chain of from 5 to about 40 optionally substituted carbon atoms, (b) a moiety containing a chain of from 4 to about 40 carbon atoms and one or more internally linked oxygen or sulfur atoms or -NH-groups, or (c) an optionally substituted ethylene or propylene moiety. Z is (a) an optionally substituted phenyl group, (b) an optionally substituted C1-C20 alkyl, C2-C20 alkenyl, C3-C8 cycloalkyl or C5-C8 cycloalkenyl group, or (c) benzoyl, and n is 1 if R is (a) or (b), or is 2-20 if R is (c). The microcapsules are acid-sensitive and the capsule walls are relatively readily degraded or disintegrated by contacting the microcapsules with an acidic substance, preferably an organic or inorganic acid whereby the encapsulated ingredient or ingredients are released into the surrounding environment. The invention is particularly suitable for encapsulation of biologically active substances and agrochemicals, and most preferably pesticides for foliar treatment.

8. 发明专利

HU230140B1 未知
公开(公告)号：HU230140B1
公开(公告)日：2015-09-28
申请号：HU0104417
申请日：1999-07-28
申请人： SYNGENTA LTD
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT BENSON , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD R
IPC分类号： A01N25/28 , A01N25/04 , B01J13/16

9. 发明专利

DK1100326T3 未知
公开(公告)号：DK1100326T3
公开(公告)日：2003-08-11
申请号：DK99936786
申请日：1999-07-28
申请人： SYNGENTA LTD
发明人： VAN KOPPENHAGEN JUANITA E , SCHER HERBERT BENSON , LEE KUO-SHIN , SHIRLEY IAN M , WADE PHILIP P , FOLLOWS RICHARD R ZENECA SPECI
IPC分类号： A01N25/04 , A01N25/28 , A01N53/00 , A01N53/08 , A01N57/16 , B01J13/16
摘要： Microcapsules formed from an aminoplast shell wall and an encapsulated ingredient or ingredients enclosed within the wall in which the wall contains a base-cleavable ester moiety. These capsules have been found to be sensitive to the presence of base such that in the presence of base, the capsule walls are relatively quickly disintegrated or degraded so as to produce a relatively quick release of the encapsulated materials. Microcapsules of this invention are particularly suitable for use in controlling insects having an alkaline gut such as certain lepidoptera in that the capsule shell wall may be designed so as to quickly disintegrate under the alkaline conditions present in the gut of the insect thus providing a microcapsule which is safe to handle but which is selectively effective against certain undesirable insects while not harmful to beneficial insects or insects which do not feed on the capsule materials.

10. 发明专利

MXPA01001073A MICROCAPSULAS DE LIBERACION INICIADA POR PH BASE. 未知
公开(公告)号：MXPA01001073A
公开(公告)日：2002-08-20
申请号：MXPA01001073
申请日：1999-07-28
申请人： SYNGENTA LTD
发明人： VAN KOPPENHAGEN JUANITA E
IPC分类号： A01N25/04 , A01N25/28 , A01N53/00 , A01N53/08 , A01N57/16 , B01J13/16
摘要： Microcapsulas formadas de una pared e cubierta de aminoplasto y un ingrediente encapsulado o ingredientes incluidos dentro de la pared en la cual la pared contiene una porcion de ester de base separable. Se ha encontrado que estas capsulas son sensibles a la presencia de pH base, de tal forma que en la presencia de bases, las paredes de la capsula de desintegran o degradan relativamente rapido para que produzca una liberacion relativamente rapida de los materiales encapsulados. Las microcapsulas de esta invencion son particularmente compatibles para usarse al controlar insectos que tengan una tripa alcalina tal como cierta lepidopter, en la que la pared de cubierta de la capsula puede ser designada para desintegrarse rapidamente bajo las condiciones alcalinas presentes en la tripa del insecto, proporcionando asi una microcapsula que es segura de manejar y que es selectivamente efectiva contra ciertos insectos indeseables mientras que no dana a los insectos beneficos o a los insectos que no se alimenten de los materiales de la capsula.

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