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1. 发明授权

US4786499A Lithium electrochemical cell including aprotic solvent-dialkyl carbonate solvent mixture 失效
标题翻译：锂电化学电池包括非质子溶剂 - 碳酸二烷基酯溶剂混合物
公开(公告)号：US4786499A
公开(公告)日：1988-11-22
申请号：US125642
申请日：1987-11-01
申请人： Steven M. Slane , Edward J. Plichta , Mark Salomon , Michelle C. Uchiyama
发明人： Steven M. Slane , Edward J. Plichta , Mark Salomon , Michelle C. Uchiyama
IPC分类号： H01M4/131 , H01M4/48 , H01M4/485 , H01M10/052 , H01M10/0569 , H01M10/36 , H01M6/14 , H01M4/58
CPC分类号： H01M4/485 , H01M10/052 , H01M10/0569 , H01M4/131
摘要： An electrochemical cell is provided including lithium as the anode, non-stoichiometric V.sub.6 O.sub.13 as the cathode, and a solution of a lithium salt in a mixed organic solvent of a non-aqueous aprotic solvent and a dialkyl carbonate as the electrolyte.
摘要翻译：提供一种电化学电池，其包括锂作为阳极，非化学计量V 6 O 13作为阴极，以及锂盐在非水性非质子溶剂和碳酸二烷基酯的混合有机溶剂中的溶液作为电解质。

2. 发明授权

US4751160A Organic electrolyte for use in a lithium rechargeable electrochemical cell and lithium rechargeable electrochemical cell including said organic electrolyte 失效
标题翻译：用于锂可充电电化学电池的有机电解质和包括所述有机电解质的锂可充电电化学电池
公开(公告)号：US4751160A
公开(公告)日：1988-06-14
申请号：US70753
申请日：1987-07-06
申请人： Edward J. Plichta , Steven M. Slane , Mark Salomon
发明人： Edward J. Plichta , Steven M. Slane , Mark Salomon
IPC分类号： H01M10/0566 , H01M10/40
CPC分类号： H01M10/0566
摘要： 1 to 2 mol dm.sup.-3 LiAsF.sub.6 in dimethylcarbonate or 1 to 2 mol dm.su3 LiAsF.sub.6 in dimethylcarbonate mixtures with methyl formate in which the mass percent of the dimethylcarbonate compound can vary from 25 mass percent to 100 mass percent is used as the electrolyte in a lithium rechargeable electrochemical cell.The cell also includes lithium as the anode and a lithium intercalating compound as the cathode.
摘要翻译：使用二甲基碳酸酯中的1-2摩尔dm-3 LiAsF 6或碳酸二甲酯的1至2摩尔dm-3的LiAsF 6与碳酸甲酯的质量百分比在25质量％至100质量％之间变化的电解质锂可充电电池。该电池还包括作为阳极的锂和插入锂的化合物作为阴极。

3. 发明授权

US4751157A Cathode material for use in lithium electrochemical cell and lithium electrochemical cell including said cathode material 失效
标题翻译：用于锂电化学电池的阴极材料和包括所述阴极材料的锂电化学电池
公开(公告)号：US4751157A
公开(公告)日：1988-06-14
申请号：US059346
申请日：1987-06-08
申请人： Michelle C. Uchiyama , Steven M. Slane , Mark Salomon
发明人： Michelle C. Uchiyama , Steven M. Slane , Mark Salomon
IPC分类号： H01M4/04 , H01M4/131 , H01M4/1391 , H01M4/48 , H01M4/485 , H01M10/052 , H01M10/36 , H01M4/02 , H01M6/16
CPC分类号： H01M4/485 , H01M10/052 , H01M4/04 , H01M4/0404 , H01M4/0409 , H01M4/0471 , H01M4/131 , H01M4/1391
摘要： A cathode is provided for use in a lithium electrochemical cell wherein theathode includes a mix of a mixed metal-oxide prepared from V.sub.2 O.sub.5 and MoO.sub.3, conductive diluent, and aqueous based binder and wherein the mix is rolled onto a nickel screen and sintered under vacuum at about 280.degree. C.
摘要翻译：提供用于锂电化学电池的阴极，其中阴极包括由V2O5和MoO3制备的混合金属氧化物，导电稀释剂和基于水的粘合剂的混合物，并且其中将混合物滚动到镍筛上并在真空下烧结约280℃

4. 依法登记的发明

USH452H Cathode including a non fluorinated linear chain polymer as the binder, method of making the cathode, and lithium electrochemical cell containing the cathode 失效
标题翻译：包括非氟化线性链聚合物作为粘合剂的阴极，制备阴极的方法和含有阴极的锂电化学电池
公开(公告)号：USH452H
公开(公告)日：1988-04-05
申请号：US895015
申请日：1986-08-07
申请人： Edward J. Plichta , Mark Salomon
发明人： Edward J. Plichta , Mark Salomon
IPC分类号： H01M4/62 , H01M10/05
CPC分类号： H01M10/05 , H01M4/04 , H01M4/0404 , H01M4/043 , H01M4/0435 , H01M4/0471 , H01M4/621
摘要： A cathode suitable for use in a lithium electrochemical cell is made from aixture of active cathode material, carbon, and non fluorinated linear chain polymer by a method including the steps of(A) dissolving the non fluorinated linear chain polymer in a non polar solvent at a temperature near the melting point of the polymer,(B) adding the active cathode material and carbon and evaporating the solvent, and(C) grinding the dried mixture into a fine powder and making it into a cathode by pressing the powdered mixture onto both sides of an expanded metal screen and then cutting to the desired dimensions.The cathode can be combined with lithium as the anode and a solution of 0.8 mol dm.sup.-3 LiAlCl.sub.4 in a mixed organic solvent of 24 mass percent 4-butyrolactone in 1, 2 dimethoxyethane as the electrolyte to provide a mechanically stable, relatively inexpensive lithium electrochemical cell having good cell performance.

5. 依法登记的发明

USH519H Cathode including a non fluorinated linear chain polymer as the binder, method of making the cathode, and lithium electrochemical cell containing the cathode 失效
公开(公告)号：USH519H
公开(公告)日：1988-09-06
申请号：US749597
申请日：1985-06-27
申请人： Edward J. Plichta , Mark Salomon
发明人： Edward J. Plichta , Mark Salomon
IPC分类号： H01M4/62 , H01M10/05
CPC分类号： H01M10/05 , H01M4/04 , H01M4/0404 , H01M4/043 , H01M4/0435 , H01M4/621
摘要： A cathode suitable for use in a lithium electrochemical cell is made from aixture of active cathode material, carbon, and non fluorinated linear chain polymer by a method including the steps of(A) dissolving the non fluorinated linear chain polymer in a non polar solvent at a temperature near the melting point of the polymer,(B) adding the active cathode material and carbon and evaporating the solvent, and(C) grinding the dried mixture into a fine powder and making it into a cathode by pressing the powdered mixture onto both sides of an expanded metal screen and then cutting to the desired dimensions.The cathode can be combined with lithium as the anode and a solution of 0.8 mol dm.sup.-3 LiAlCl.sub.4 in a mixed organic solvent of 24 mass percent 4-butyrolactone in 1,2 dimethoxyethane as the electrolyte to provide a mechanically stable, relatively inexpensive lithium electrochemical cell having good cell performance.

6. 发明授权

US4560630A Rechargeable lithium cell having an electrolyte comprising 4-butyrolactone in dimethoxyethane 失效
标题翻译：具有在二甲氧基乙烷中含有4-丁内酯的电解质的可充电锂电池
公开(公告)号：US4560630A
公开(公告)日：1985-12-24
申请号：US655114
申请日：1984-09-27
申请人： Mark Salomon , Edward J. Plichta
发明人： Mark Salomon , Edward J. Plichta
IPC分类号： H01M4/136 , H01M4/58 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M10/36 , H01M6/14
CPC分类号： H01M4/581 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M4/5815 , H01M4/136
摘要： A rechargeable lithium cell is provided comprising a lithium anode, a litm intercalating cathode, and an electrolyte comprising a solution of a lithium salt such as LiAsF.sub.6 or LiAlCl.sub.4 in 24.4 mass percent 4-butyrolactone (4-BL) in dimethoxyethane (DME). The cell exhibits improved low temperature (-40.degree. C..ltoreq.t.ltoreq.0.degree. C.) performance and rate capability.
摘要翻译：提供了一种可再充电锂电池，其包含锂阳极，嵌锂阴极和包含锂盐如LiAsF 6或LiAlCl 4在24.4质量％的4-丁内酯（4-BL）在二甲氧基乙烷（DME）中的溶液）的电解质。该电池表现出改善的低温（-40℃，t = 0℃）的性能和速率能力。

7. 发明授权

US4818647A Method of making a cathode for use in a rechargeable lithium battery, cathode so made, and rechargeable lithium battery including the cathode 失效
标题翻译：制造用于可再充电锂电池的阴极，如此制造的阴极和包括阴极的可再充电锂电池的方法
公开(公告)号：US4818647A
公开(公告)日：1989-04-04
申请号：US28169
申请日：1987-03-20
申请人： Edward J. Plichta , Mark Salomon
发明人： Edward J. Plichta , Mark Salomon
IPC分类号： H01M4/02 , H01M4/131 , H01M4/1391 , H01M4/62 , H01M6/16 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M10/36 , H01M4/58
CPC分类号： H01M4/621 , H01M10/052 , H01M4/02 , H01M4/131 , H01M4/1391 , H01M10/0568 , H01M10/0569 , H01M6/162 , H01M6/168
摘要： A cathode is made for a rechargeable Li/Li.sub.x CoO.sub.2 cell using an aqueous cathode preparation. The Li/LiAsF.sub.6 -MA/Li.sub.x CoO.sub.2 system can deliver between 230-170 Wh/kg at current densities of 2-10mA/cm.sup.2.
摘要翻译：使用水性阴极制备用于可再充电Li / LixCoO 2电池的阴极。 Li / LiAsF6 -MA / LixCoO2系统可以以2-10mA / cm2的电流密度输送230-170Wh / kg。

8. 发明申请

US20120121993A1 Electrolyte containing methoxybenzene for use in lithium-air semi-fuel cells 审中-公开
标题翻译：用于锂空气半燃料电池的含有甲氧基苯的电解液
公开(公告)号：US20120121993A1
公开(公告)日：2012-05-17
申请号：US12927340
申请日：2010-11-12
申请人： David Chua , Owen Crowther , Benjamin Meyer , Mark Salomon
发明人： David Chua , Owen Crowther , Benjamin Meyer , Mark Salomon
IPC分类号： H01M12/06 , H01M10/056
CPC分类号： H01M12/065 , H01M4/382 , H01M2300/0028
摘要： Disclosed herein are electrolyte formulations containing methoxybenzene (also known as anisole or phenoxymethane) for use in lithium-air semi-fuel cells. Lithium-air semi-fuel cells contain a metallic lithium anode and an air (oxygen) fuel cell type porous carbon cathode. The reaction product in the cathode is lithium oxide (Li2O) and/or lithium peroxide (Li2O2). This reaction product is sparingly soluble in common lithium-air cell solvents, and therefore the cathode pores become blocked over time, leading to cell end-of-life. Methoxybenzene is an organic solvent that demonstrates an increased solubility of Li2O, which minimizes the clogging of the cathode. Lithium-air semi-fuel cells with electrolytes containing methoxybenzene demonstrate higher discharge capacities per the same weight, than the cells having electrolytes without methoxybenzene. Higher energy density semi-fuel cells are thus achieved.
摘要翻译：本文公开了含有用于锂空气半燃料电池的甲氧基苯（也称为苯甲醚或苯氧基甲烷）的电解质配方。锂空气半燃料电池含有金属锂阳极和空气（氧）燃料电池型多孔碳阴极。阴极中的反应产物是氧化锂（Li 2 O）和/或过氧化锂（Li 2 O 2）。该反应产物微溶于常见的锂空气电池溶剂，因此阴极孔随时间而变得阻塞，导致电池寿命终止。甲氧基苯是表现出Li2O的溶解度增加的有机溶剂，其使阴极的堵塞最小化。具有含有甲氧基苯的电解质的锂空气半燃料电池比不含甲氧基苯的电解质的电池显示出更高的相同重量的放电容量。因此实现更高能量密度的半燃料电池。

9. 发明申请

US20110177400A1 Protected lithium-air cells by oxygen-selective permeable cathode membranes 审中-公开
标题翻译：通过氧气选择性渗透阴极膜保护锂空气电池
公开(公告)号：US20110177400A1
公开(公告)日：2011-07-21
申请号：US12657481
申请日：2010-01-21
申请人： David Chua , Arthur Driedger , Benjamin Meyer , Michael Morgan , Mark Salomon
发明人： David Chua , Arthur Driedger , Benjamin Meyer , Michael Morgan , Mark Salomon
IPC分类号： H01M4/36
CPC分类号： H01M2/1094 , H01M2/0277 , H01M4/134 , H01M4/661 , H01M8/0239 , H01M10/052 , H01M12/08 , Y02E60/128
摘要： Advanced lithium-air cell with non-aqueous electrolyte solution is provided, having higher energy density over the prior art cells, due to protective oxygen selective permeable membrane placed over the cathode outer surface. Said membrane protects the cell from moisture and evaporation of said electrolyte, which substantially minimizes parasitic losses of lithium and increases the cell efficiency and safety.
摘要翻译：提供了具有非水电解质溶液的高级锂空气电池，由于保护性氧选择性渗透膜放置在阴极外表面上，其具有比现有技术电池更高的能量密度。所述膜保护电池免受所述电解质的湿气和蒸发，其基本上最小化锂的寄生损耗并增加电池的效率和安全性。

10. 发明申请

US20070259234A1 Metal-air semi-fuel cell with an aqueous acid based cathode 审中-公开
标题翻译：金属空气半燃料电池与酸性阴极水溶液
公开(公告)号：US20070259234A1
公开(公告)日：2007-11-08
申请号：US11418629
申请日：2006-05-06
申请人： David Chua , Mark Salomon , Ian Kowalczyk
发明人： David Chua , Mark Salomon , Ian Kowalczyk
IPC分类号： H01M12/06 , H01M2/16
CPC分类号： H01M12/08 , H01M2/1653 , H01M4/38 , H01M4/381 , H01M4/382 , H01M4/40 , H01M4/405 , H01M2300/0002 , H01M2300/0005 , H01M2300/0014 , H01M2300/0025 , H01M2300/0071 , H01M2300/0094 , Y02E60/128
摘要： A metal-air semi-fuel cell is provided, preferably based on lithium anode and a fuel cell type air/oxygen electrode immersed in an aqueous neutral, alkali or acid solution. The lithium anode is comprised of the active metal and one or more separators protecting the anode from reacting with an aqueous solution. The outermost layer on the lithium electrode is a solid-state lithium-ion conducting glass-ceramic which is impervious to and stable towards aqueous solutions. The cathode is comprised of an air or oxygen fuel cell type electrode in contact with the aqueous solution. The lithium anode of this invention also can be replaced by other electroactive metals which react with water and acids, bases and neutral solutions, such as metals from Groups 1 and 2 of the Periodic Table of Elements in addition to Zn, Mg, and Al.
摘要翻译：提供金属 - 空气半燃料电池，优选地基于锂阳极和浸没在中性水溶液，碱或酸溶液中的燃料电池型空气/氧电极。锂阳极由活性金属和一个或多个保护阳极不与水溶液反应的隔板组成。锂电极上的最外层是固态锂离子导电玻璃陶瓷，其对水溶液是不渗透和稳定的。阴极由与水溶液接触的空气或氧燃料电池型电极组成。本发明的锂阳极还可以被除了Zn，Mg和Al之外还与水和酸，碱和中性溶液如元素周期表第1和2族的金属反应的其它电活性金属代替。

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