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1. 发明授权

US3931321A Process for the preparation of O-aminothiophenols 失效
标题翻译：制备O-氨基噻吩酚的方法
公开(公告)号：US3931321A
公开(公告)日：1976-01-06
申请号：US517791
申请日：1974-10-24
申请人： Siegfried Planker , Konrad Baessler
发明人： Siegfried Planker , Konrad Baessler
IPC分类号： C07C85/11
摘要： Preparation and isolation in substance of ortho-aminothiphenols by the reduction of ortho-chloronitrobenzenes with hydrogensulfides or sulfides, subsequent neutralization in the presence of sulfites, hydrogensulfites or disulfites, separation and following purification of the crude products. The ortho-aminothiophenols are obtained in very good yields and with a high degree of purity. Oxydation to the disulfide compound is avoided by the processes of the invention.
摘要翻译：通过用氢硫化物或硫化物还原邻氯硝基苯，随后在亚硫酸盐，亚硫酸氢盐或亚硫酸氢盐存在下中和，分离和纯化粗产物，制备和分离邻氨基苯酚的物质。邻氨基苯硫酚以非常好的产率和高纯度的获得。通过本发明的方法避免了二硫化物化合物的氧化。

2. 发明授权

US4217307A Process for the preparation of 2,2'-dichloro-hydrazobenzene 失效
标题翻译：制备2,2'-二氯 - 苯肼的方法
公开(公告)号：US4217307A
公开(公告)日：1980-08-12
申请号：US927856
申请日：1978-07-25
申请人： Siegfried Planker , Konrad Baessler , Otto Fuchs
发明人： Siegfried Planker , Konrad Baessler , Otto Fuchs
IPC分类号： C07B61/00 , B01J31/00 , B01J31/28 , C07C20060101 , C07C67/00 , C07C241/00 , C07C243/22 , C07C109/04
CPC分类号： C07C241/02
摘要： The catalytic hydrogenation of o-nitro-chlorobenzene in aqueous alkali metal hydroxide solution with addition of an aromatic non-watermiscible solvent at an elevated temperature and under pressure using a noble metal catalyst and a polycyclic quinone as a co-catalyst leads to high and well-reproducible yields of 2,2'-dichloro-hydrazobenzene when the quinone is a derivative of anthraquinone, especially a hydroxy-anthraquinone. The product is obtained in so high a quality that it can be transformed without isolation or purification into 3,3'-dichlorobenzidine.
摘要翻译：使用贵金属催化剂和多环醌作为助催化剂，在升高的温度和压力下加入芳族非水溶性溶剂，邻位硝基氯苯在碱金属氢氧化物水溶液中的催化氢化导致高和良好 - 当醌是蒽醌衍生物，特别是羟基 - 蒽醌时，可以制得2,2'-二氯 - 苯肼的重复产率。该产品的质量非常高，可以不经分离或纯化转化成3,3'-二氯联苯胺。

3. 发明授权

US5543550A Process for the preparation of 5-fluoroanthranilic alkyl esters and/or 5-fluoroanthranilic acid 失效
标题翻译： 5-氟邻氨基烷基酯和/或5-氟邻氨基苯甲酸的制备方法
公开(公告)号：US5543550A
公开(公告)日：1996-08-06
申请号：US319306
申请日：1994-10-06
申请人： Jochen Rapp , Siegfried Planker , Theodor Papenfuhs , G unter Bartels
发明人： Jochen Rapp , Siegfried Planker , Theodor Papenfuhs , G unter Bartels
IPC分类号： B01J27/045 , C07B61/00 , C07C227/04 , C07C227/06 , C07C229/56 , C07C229/52 , C07C63/04 , C07C69/76
CPC分类号： C07C227/06
摘要： The present invention relates to a process for the preparation of 5-fluoroanthranilic alkyl esters and/or 5-fluoroanthranilic acid, which comprises dissolving a 3-fluorobenzoic alkyl ester in sulfuric acid and reacting the solution with a nitrating acid at from -10.degree. to 30.degree. C., then adding water, separating off the nitrated reaction product and reacting it with hydrogen at from 50.degree. to 120.degree. C. under elevated pressure in the presence of a catalyst comprising a metal of the platinum group and sulfur, and, if desired, removing 5-fluoroanthranilic alkyl esters by distillation and hydrolyzing them to give 5-fluoroanthranilic acid.
摘要翻译：本发明涉及5-氟邻氨基烷基酯和/或5-氟邻氨基苯甲酸的制备方法，该方法包括将3-氟苯甲酸烷基酯溶解在硫酸中，并使该溶液与-10℃的硝酸反应 30℃，然后加入水，分离硝化反应产物，并在50-120℃下，在包含铂族金属和硫的催化剂存在下，在高压下反应，如果需要，通过蒸馏除去5-氟邻氨基烷基酯并水解，得到5-氟邻氨基苯甲酸。

4. 发明授权

US5631403A Process for the preparation of hydroxycarboxanilides 失效
标题翻译：羟基羧酰苯胺的制备方法
公开(公告)号：US5631403A
公开(公告)日：1997-05-20
申请号：US493272
申请日：1995-06-21
申请人： Andreas Dierdorf , Siegfried Planker , Theodor Papenfuhs
发明人： Andreas Dierdorf , Siegfried Planker , Theodor Papenfuhs
IPC分类号： C07C231/12 , C07C235/16 , C07C253/30 , C07C233/05 , C07C233/88
CPC分类号： C07C235/16 , C07C231/12 , C07C253/30
摘要： The present invention relates to a process for the preparation of hydroxycarboxanilides of the formula (1) ##STR1## in which R.sup.1 and R.sup.2 are identical or different and are hydrogen, halogen, a nitro group, a cyano group, a straight-chain or branched alkyl, alkenyl, alkynyl or alkoxy group having 1 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, a cycloalkyl group having 6 to 12 carbon atoms or an aryl group having 6 to 12 carbon atoms, R.sup.3 is hydrogen or a straight-chain or branched alkyl group having 1 to 12 carbon atoms and n is an integer from 1 to 12, by reacting a halocarboxanilide of the formula (2) ##STR2## in which R.sup.1, R.sup.2, R.sup.3 and n have the same meaning as in formula (1) and Hal is chlorine, bromine or iodine, with a basic compound in a solvent mixture comprising water and one or more polar aprotic solvents at a temperature of 40.degree. to 180.degree. C.
摘要翻译：本发明涉及制备式（1）的羟基羧酰苯胺的方法，其中R 1和R 2相同或不同，为氢，卤素，硝基，氰基，具有1至12个碳原子的直链或支链烷基，烯基，炔基或烷氧基，具有7至12个碳原子的芳烷基，具有6至12个碳原子的环烷基或具有6至12个碳原子的芳基，R3是氢或具有1至12个碳原子的直链或支链烷基，n为1至12的整数，通过使式（2）的卤代甲酰苯胺（2）反应，其中R 1，R 2，R 3和 n具有与式（1）中相同的含义，Hal是氯，溴或碘，在含有水和一种或多种极性非质子溶剂的溶剂混合物中，在40至180℃的温度下使用碱性化合物。

5. 发明授权

US5693852A Process for the preparation of o-acyloxycarboxanilides 失效
标题翻译：邻酰氧基甲酰苯胺的制备方法
公开(公告)号：US5693852A
公开(公告)日：1997-12-02
申请号：US597884
申请日：1996-02-07
申请人： Andreas Dierdorf , Theodor Papenfuhs , Siegfried Planker
发明人： Andreas Dierdorf , Theodor Papenfuhs , Siegfried Planker
IPC分类号： C07C231/12 , C07C235/16 , C07C67/02
CPC分类号： C07C231/12 , C07C235/16
摘要： The present invention relates to a process for the preparation of O-acyloxycarboxanilides of the formula (I) ##STR1## in which R is a radical having 1 to 6 carbon atoms, n is an integer from 1 to 10, R.sup.1 is hydrogen or an alkyl radical having 1 to 12 carbon atoms, R.sup.2 and R.sup.3 are identical or different and are hydrogen, an alkyl radical having 1 to 12 carbon atoms, an aryl radical having 6 to 12 carbon atoms, a cycloalkyl radical having 5 to 12 carbon atoms in the ring, an alkenyl or alkynyl radical having 3 to 12 carbon atoms, NO.sub.2, F, Cl, Br or CN, by reacting a chlorocarboxanilide of the formula (II) ##STR2## in which n, R.sup.1, R.sup.2 and R.sup.3 have the abovementioned meaning, with an alkali metal carboxylate of the formula (III) R--COOMe (III), in which R has the abovementioned meaning and Me is an alkali metal, in the presence of an inert solvent and of a carboxylic acid having 1 to 6 carbon atoms, at 50.degree. to 200.degree. C.
摘要翻译：本发明涉及一种制备式（I）的O-酰氧基甲酰苯胺的方法，其中R为具有1至6个碳原子的基团，n为1至10的整数，R 1为氢或具有1至12个碳原子的烷基，R 2和R 3相同或不同，为氢，具有1至12个碳原子的烷基，具有6至12个碳原子的芳基，环烷基具有5至12个通过使式（II）的氯代甲酰苯胺（II）反应，其中n，R 1，R 2，R 3， R2和R3具有上述含义，与式（III）的碱金属羧酸盐反应，其中R为具有上述含义的R-COOMe（III），Me为碱金属，在惰性溶剂存在下，具有1至6个碳原子的羧酸，在50至200℃。

6. 发明授权

US5616799A Process for the preparation of glycoloylanilides 失效
标题翻译：糖基酰苯胺的制备方法
公开(公告)号：US5616799A
公开(公告)日：1997-04-01
申请号：US423522
申请日：1995-04-17
申请人： Siegfried Planker , Theodor Papenfuhs
发明人： Siegfried Planker , Theodor Papenfuhs
IPC分类号： B01J23/42 , B01J23/44 , B01J27/045 , C07B61/00 , C07C209/26 , C07C209/36 , C07C231/02 , C07C231/10 , C07C231/12 , C07C235/16 , C07C237/42 , C07C255/08 , C07C311/45 , C07C233/33
CPC分类号： C07C209/26 , C07C209/365 , C07C231/02 , C07C231/12 , C07C235/16
摘要： A process for the preparation of glycoloylanilide of the formula (G) ##STR1## is recited that involves reacting a nitrobenzene with hydrogen and, if desired, with a carbonyl compound, in the presence of a noble metal catalyst and a solvent, reacting the compound produced with chloroacetyl chloride, reacting the resulting product with a benzyl alcohol and with a base, or reacting the resulting compound with an O-benzylglycoloyl chloride, and debenzylating the resulting benzylglycoloylanilide product by reacting with hydrogen in the presence of a noble metal catalyst. The invention also relates to a process for the preparation of O-benzylglycoloylanilide.
摘要翻译：描述了制备式（G）的葡糖酰苯胺的方法（G），其包括在贵金属催化剂和溶剂的存在下使硝基苯与氢反应，如果需要，与羰基化合物反应，使所得化合物与氯乙酰氯反应，使所得产物与苄醇和碱反应，或使所得化合物与O-苄基乙酰氯反应，并将所得苄基乙酰苯胺产物在贵金属存在下与氢反应脱苄基化催化剂。本发明还涉及制备O-苄基乙酰苯胺的方法。

7. 发明授权

US4952697A Process for the preparation of 2-nitro-3-aminopyridine, and the intermediates which are formed in the reaction 失效
标题翻译：制备2-硝基-3-氨基吡啶的方法和在反应中形成的中间体
公开(公告)号：US4952697A
公开(公告)日：1990-08-28
申请号：US238968
申请日：1988-08-25
申请人： Siegfried Planker , Klaus Warning , Gunter H. Herbst, deceased , Ulrike M. Herbst , Bettina S. Herbst , Georg Schaeffer
发明人： Siegfried Planker , Klaus Warning , Gunter H. Herbst, deceased , Ulrike M. Herbst , Bettina S. Herbst , Georg Schaeffer
IPC分类号： C07D213/73 , C07D213/74 , C07D213/75 , C07D213/76
CPC分类号： C07D213/73 , C07D213/74 , C07D213/75 , C07D213/76
摘要： 2-Nitro-3-aminopyridine is prepared by(a) reacting 3-aminopyridine with phosgen COCl.sub.2 or urea H.sub.2 NCONH.sub.2 to give N,N'-di-(3-pyridyl)-urea,(b) nitrating and N,N'-di-(3-pyridyl)-urea with nitric acid or with a mixture of nitric acid and sulfuric acid to give N,N'-di-(2-nitor-3-pyridyl)-urea, and(c) hydrolyzing said N,N'-di-(2-nitro-3-pyridyl)-urea to give 2-nitro-3-amino-pyridine.N,N'-di-(3-pyridyl)-urea and N,N'-di-(2-nitro-3-pyridyl)-urea, which are formed in the course of the reaction as intermediates are new compounds.The end product of the process, 2-nitro-3-aminonpyridine, is an intermediate in various specialized fields.
摘要翻译：通过（a）使3-氨基吡啶与光气COCl 2或尿素H 2 NCONH 2反应，得到N，N'-二（3-吡啶基） - 脲，（b）硝化和N，N'-二硝基-3-氨基吡啶，（3-吡啶基） - 脲与硝酸或硝酸和硫酸的混合物反应，得到N，N'-二（2-硝酰基-3-吡啶基） - 脲，和（c）水解所述N ，N'-二（2-硝基-3-吡啶基） - 脲，得到2-硝基-3-氨基 - 吡啶。在反应过程中形成的N，N'-二（3-吡啶基） - 脲和N，N'-二（2-硝基-3-吡啶基） - 脲是新化合物。该方法的最终产物2-硝基-3-氨基吡啶是各种专业领域的中间体。

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