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    • 10. 发明授权
    • Battery and battery electrode
    • 电池和电池电极
    • US07122277B2
    • 2006-10-17
    • US10170349
    • 2002-06-14
    • Yukiko MoriokaMasaharu SatohShigeyuki IwasaYutaka Ban-NaiKentaro Nakahara
    • Yukiko MoriokaMasaharu SatohShigeyuki IwasaYutaka Ban-NaiKentaro Nakahara
    • H01M4/60
    • H01M4/137H01M4/60H01M10/052
    • The present invention relates to a battery comprising at least a positive electrode, a negative electrode and an electrolyte as composing elements, wherein the positive electrode and/or the negative electrode comprise an active material of nitroxyl radical compound represented by the following general formula (1) as a starting material or a reaction product of at least a discharge reaction of electrode reactions: wherein Ar represents substituted or unsubstituted aromatic heterocyclic group containing nitrogen wherein one endocyclic nitrogen atom or at least one of plural endocyclic nitrogen atoms exists as N-oxide; the substituent R1 represents hydrogen atom, halogen atom, hydroxyl group, nitro group, nitroso group, cyano group, carboxyl group, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenyl group, substituted or unsubstituted cycloalkyl group, substituted or unsubstituted aromatic hydrocarbon group, substituted or unsubstituted aromatic heterocyclic group, substituted or unsubstituted aralkyl group, substituted or unsubstituted amino group, substituted or unsubstituted alkoxy group, substituted or unsubstituted aryloxy group, substituted or unsubstituted alkoxycarbonyl group, substituted or unsubstituted aryloxycarbonyl group, or substituted or unsubstituted acyl group, wherein one or more of the atoms may be substituted with sulfur atom, silicon atom, phosphorus atom or boron atom; R1 may be the identical with Ar and a ring structure may be formed between R1 and Ar.
    • 本发明涉及至少包含作为组成元素的正极,负极和电解质的电池,其中正极和/或负极包含由以下通式(1)表示的硝酰自由基化合物的活性材料 )作为原料或电极反应的放电反应的反应产物:其中Ar表示取代或未取代的含氮的芳族杂环基,其中一个环内氮原子或多个环内氮原子中的至少一个作为N-氧化物存在; 取代基R 1表示氢原子,卤素原子,羟基,硝基,亚硝基,氰基,羧基,取代或未取代的烷基,取代或未取代的烯基,取代或未取代的环烷基 取代或未取代的芳族烃基,取代或未取代的芳族杂环基,取代或未取代的芳烷基,取代或未取代的氨基,取代或未取代的烷氧基,取代或未取代的芳氧基,取代或未取代的烷氧基羰基,取代或未取代的芳氧基羰基 或取代或未取代的酰基,其中一个或多个原子可以被硫原子,硅原子,磷原子或硼原子取代; R 1可以与Ar相同,并且可以在R 1和Ar之间形成环结构。