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1. 发明申请

US20050165126A1 Thioxanthone derivatives, and their use as cationic photoinitiators 有权
标题翻译：噻吨酮衍生物及其作为阳离子光引发剂的用途
公开(公告)号：US20050165126A1
公开(公告)日：2005-07-28
申请号：US10505615
申请日：2003-02-26
申请人： Shaun Herlihy , Robert Davidson
发明人： Shaun Herlihy , Robert Davidson
IPC分类号： C07D335/16 , C08F2/46 , C08F2/50 , C08G59/68 , C08K5/45 , C09D11/02 , C09D11/10 , G03F7/004 , C07D335/10 , C08J3/28
CPC分类号： C09D11/101 , B33Y70/00 , C07D335/16 , C08F2/46 , C08G59/687 , C08K5/45 , G03F7/0045
摘要： Photoinitiator compounds of formula (I): {where: A represents a direct bond or a group of formula —[O(CHR7CHR6)a]y—, —[O(CH2)bCO]y—, or —[O(CH2)bCO](y-1)—[O(CHR7CHR6)a]—, where one of R6 and R7 is hydrogen and the other is hydrogen or methyl; a is a number from 1 to 2; b is a number from 4 to 5; Q is a residue of a polyhydroxy compound having 2 to 6 hydroxy groups; x is a number greater than 1 but no greater than the number of available hydroxyl groups in Q; y is a number from 1 to 10; R1, R2, R3 and R4 are individually the same or different and each is hydrogen, hydroxy, or alkyl; or R1 and R3 are joined to form a fused ring system with the benzene rings to which they are attached; and R5 represents a direct bond, an oxygen atom or a methylene group} are useful as cationic photoinitiators, especially for use in surface coating applications, such as printing inks and varnishes, and which are intended to be cured by polymerisation initiated by radiation.
摘要翻译：式（I）的光引发剂化合物：其中：A表示直接键或式 - [O（CHR 7）CHR 6）的基团。 y - ， - [O（CH 2）2 - ， - CO 2 - ， - 或 - [O（CH 2）（Y-1） - [O（CHR 7）CH 2 O（CH 2 CH 2）其中R 6和R 7中的一个为氢，另一个为氢或甲基; a是从1到2的数字; b是从4到5的数字; Q是具有2至6个羟基的多羟基化合物的残基; x是大于1但不大于Q中可用羟基数的数; y是从1到10的数字; R 1，R 2，R 3和R 4分别相同或不同，各自为氢，羟基或烷基; 或R 1和R 3连接形成稠合环系与其所连接的苯环; 和R 5表示直接键，氧原子或亚甲基}可用作阳离子光引发剂，特别是用于表面涂料应用，例如印刷油墨和清漆，并且其旨在是通过辐射引发的聚合固化。

2. 发明申请

US20080081917A1 MULTIFUNCTIONAL CATIONIC PHOTOINITIATORS, THEIR PREPARATION AND USE 失效
公开(公告)号：US20080081917A1
公开(公告)日：2008-04-03
申请号：US11865338
申请日：2007-10-01
申请人： Shaun Herlihy , Brian Rowatt , Robert Davidson
发明人： Shaun Herlihy , Brian Rowatt , Robert Davidson
IPC分类号： C07D335/12
CPC分类号： C07D333/54 , B33Y70/00 , C07D327/08 , C07D333/76 , C07D335/16 , C07D339/08 , C08F2/50
摘要： Compounds of formula (I): [where: R1 is a direct bond, oxygen, a group >CH2, sulphur, a group >C═O, a group —(CH2)2— or a group-N-Ra, where Ra is hydrogen or alkyl; R3, R4, R5 and R6 are hydrogen or substituents α; R8, R9, R10 and R11 are hydrogen, hydroxy or alkyl; or R9 and R11 are joined to form a fused ring system with the benzene rings to which they are attached; R7 is a direct bond, oxygen or a —CH2-group; p is 0 or 1; substituents α are: alkyl, alkoxy, alkenyl, halogen, nitrile, hydroxyl, aryl, aralkyl, aryloxy, aralkyloxy, arylalkenyl, cycloalkyl, carboxy, carboxyalkoxy, alkoxycarbonyl, aryloxycarbonyl, alkylcarbonyloxy, alkanesulphonyl, arenesulphonyl, alkanoyl or arylcarbonyl; n is 1 to 12; R12 is hydrogen, methyl or ethyl; A is a group —[O(CHR13CHR14)a]y—, —[O(CH2)bCO]y—, or —[O(CH2)bCO](y−1)—[O(CHR13CHR14)a]—, where: one of R13 and R14 is hydrogen and the other is hydrogen, methyl or ethyl; a is 1 to 2; b is 4 to 5; Q is a residue of a polyhydroxy compound having from 2 to 6 hydroxy groups; x is a number greater than 1 but no greater than the number of available hydroxyl groups in Q; y is a number from 1 to 10; and X− is an anion]; and esters thereof are useful as cationic photoinitiators, especially for use in surface coating applications, such as printing inks and varnishes, and which are intended to be cured by polymerisation initiated by radiation.

3. 发明申请

US20050176969A1 Novel fused ring compounds, and their use as cationic photoinitiators 有权
标题翻译：新型稠环化合物及其作为阳离子光引发剂的用途
公开(公告)号：US20050176969A1
公开(公告)日：2005-08-11
申请号：US10505650
申请日：2003-02-26
申请人： Shaun Herlihy , Robert Davidson , Brian Rowatt
发明人： Shaun Herlihy , Robert Davidson , Brian Rowatt
IPC分类号： C07D279/20 , C07D333/76 , C07D335/12 , C07D335/16 , C07D339/08 , C08F2/46 , C07F9/68 , C07D335/10
CPC分类号： C07D279/20 , C07D333/76 , C07D335/12 , C07D335/16 , C07D339/08
摘要： Compounds of formula (I): [in which: R1 represents a direct bond, an oxygen atom, a group >CH2, a sulphur atom, a group >C═O, a group —(CH2)2— or a group of formula —N—Ra, where Ra is hydrogen or an alkyl; R4, R5, R6 and R7 are each hydrogen or various groups or atoms; R8, R9, R10 and R11 are each hydrogen, hydroxy, or alkyl; or R9 and R11 form a fused ring system with the benzene rings to which they are attached; R12 is a direct bond, oxygen atom or methylene; and X is an anion; and esters thereof] are useful as cationic photoinitiators, especially for use in surface coating applications, such as printing inks and varnishes, and which are intended to be cured by polymerisation initiated by radiation.
摘要翻译：式（I）的化合物：[其中：R 1表示直接键，氧原子，基团> CH 2，硫原子，基团> CO ，基团 - （CH 2 CH 2）2 - 或式-NR a a的基团，其中R a，是氢或烷基; R 4，R 5，R 6和R 7各自为氢或各种基团或原子; R 9，R 9，R 10和R 11各自为氢，羟基或烷基; 或R 9和R 11与其所连接的苯环形成稠环体系; R 12是直接键，氧原子或亚甲基; X为阴离子; 和它们的酯）可用作阳离子光引发剂，特别是用于表面涂料应用中，例如印刷油墨和清漆，并且其旨在通过由辐射引发的聚合来固化。

4. 发明申请

US20050037277A1 Multi-functional photoinitiators 有权
标题翻译：多功能光引发剂
公开(公告)号：US20050037277A1
公开(公告)日：2005-02-17
申请号：US10492469
申请日：2002-09-24
申请人： Shaun Herlihy , Roger Burrows , Robert Davidson
发明人： Shaun Herlihy , Roger Burrows , Robert Davidson
IPC分类号： C07C69/738 , C07C69/712 , C08F2/50 , C09D4/00 , C09D5/00 , C09D7/12 , C09D11/02 , C09D157/00 , C09K3/00 , G03C1/76
CPC分类号： C07C69/712 , Y10S522/905
摘要： Compounds of formula (I): {where n is a number from 1 to 6; R3 is hydrogen, methyl or ethyl; A represents a group of formula —[O(CHR2CHR1)a]y—, —[O(CH2)bCO]y—, or —[O(CH2)bCO](y−1)—[O(CHR2CHR1)a]— (where one of R1 and R2 is hydrogen and the other is hydrogen, methyl or ethyl); a is from 1 to 2; b is from 4 to 5; y is from 3 to 10; Q is a residue of a polyhydroxy compound having 2 to 6 hydroxy groups; and x is greater than 1 but no greater than the number of available hydroxyl groups in Q} and esters thereof are useful as photoinitiators for the preparation of energy-curable compositions, such as varnishes and printing inks.
摘要翻译：式（I）化合物：其中n为1至6的数; R 3是氢，甲基或乙基; A表示式 - [O（CHR 2 CHR 1）a] y - ， - [O（CH 2）b CO] y - 或 - [O（CH 2）b CO]（y-1） - [O（CHR 2 CHR 1）a] - （其中R 1和R 2之一是氢，另一个是氢，甲基或乙基）; a为1至2; b为4〜5; y为3〜10; Q是具有2至6个羟基的多羟基化合物的残基; 并且x大于1但不大于Q}中可用羟基的数目，并且其酯可用作制备能量可固化组合物如清漆和印刷油墨的光引发剂。

5. 发明申请

US20080045620A1 Piperazino Based Photoinitiators 有权
标题翻译：基于哌嗪基的光引发剂
公开(公告)号：US20080045620A1
公开(公告)日：2008-02-21
申请号：US11718952
申请日：2005-11-09
申请人： Shaun Herlihy , Brian Rowatt , Robert Davidson
发明人： Shaun Herlihy , Brian Rowatt , Robert Davidson
IPC分类号： C07D413/02 , C07D241/02 , C07D413/14 , C08F2/48
CPC分类号： C07D295/135 , C07D295/112 , C07D295/15
摘要： Compounds of formula (I): [where: the substituents R1 are individually selected from C1-C10 alkyl groups and optionally substituted benzyl groups; the substituents R2 are individually selected from alkyl groups or, together with the nitrogen atom to which they are attached, represent a nitrogen-containing heterocyclic group; Z is selected from C6-C10 arylene groups groups of formula —(CHR3)n—, where R3 is hydrogen, hydroxy or a C1-C4 alkyl group, and n is 0 to 6; Y is carbonyl or a residue of a mono- or poly-hydroxy compound; and x is 1 to 6; and esters thereof] are useful as multi-functional photoinitiators for use in coating compositions to be cured by radiant energy.
摘要翻译：式（I）化合物：其中：取代基R 1分别选自C 1 -C 10烷基和任选取代的苄基团体取代基R 2分别选自烷基或与它们所连接的氮原子一起代表含氮杂环基; Z选自式-C（CHR 3）n N - 的C 6 -C 10亚芳基，其中R 3为氢，羟基或C 1 -C 4烷基，n为0至6; Y是羰基或单羟基或多羟基化合物的残基; x为1〜6; 及其酯]可用作多功能光引发剂，用于通过辐射能固化的涂料组合物。

6. 发明申请

US20110201744A1 ACRYLATED EPOXY-AMINE OLIGOMERS 有权
标题翻译：丙烯酸环氧低聚物
公开(公告)号：US20110201744A1
公开(公告)日：2011-08-18
申请号：US13125260
申请日：2009-10-19
申请人： Shaun Herlihy , Luisa Fuertes
发明人： Shaun Herlihy , Luisa Fuertes
IPC分类号： C08G59/16 , C09D163/10 , C09D11/10
CPC分类号： C08F283/00 , C08F283/10 , C08F289/00 , C08L51/08 , C08L53/00 , C09D151/08 , C09D153/00 , C08L2666/02
摘要： A reactive component suitable for use in a radiation-curable composition, which comprises an acrylated epoxy-amine oligomer represented by the formula (I): C-B-[A-B]n-A-B-C wherein: n is from 2 to 500; each A is individually a unit derived from a diglycidyl ether; each B is individually a unit derived from a difunctional secondary amine or a monofunctional primary amine; and each C is individually a unit derived from a multifunctional acrylate monomer, radiation-curable compositions, such as inks, coatings and adhesives, comprising said reactive component and methods of making said reactive component.
摘要翻译：适用于可辐射固化组合物的反应性组分，其包含由式（I）表示的丙烯酸酯化的环氧 - 胺低聚物：C-B- [A-B] n-A-B-C，其中n为2至500; 每个A分别是衍生自二缩水甘油醚的单元; 每个B分别是衍生自双官能仲胺或单官能伯胺的单元; 并且每个C分别是衍生自多官能丙烯酸酯单体的单元，包含所述反应性组分的可辐射固化组合物，例如油墨，涂料和粘合剂以及制备所述反应性组分的方法。

7. 发明申请

US20070266869A1 Photoinitiators for Use in Intaglio Printing Inks 有权
标题翻译：用于凹版印刷油墨的光引发剂
公开(公告)号：US20070266869A1
公开(公告)日：2007-11-22
申请号：US10599551
申请日：2005-03-30
申请人： Michael Leonard , John Dyer , James Tucker , Shaun Herlihy
发明人： Michael Leonard , John Dyer , James Tucker , Shaun Herlihy
IPC分类号： B41M1/10 , C09D11/02
CPC分类号： C09D11/101 , B41M1/10 , B41M3/14 , B41M5/508 , B41M7/0081 , C08F2/50 , C09D11/102 , Y10S522/909
摘要： An intaglio printing ink, curing by free radical acrylate chemistry, which does not fluoresce in at least the visible region under ultraviolet light is prepared by using an acylphosphine oxide as the photoinitiator.
摘要翻译：通过使用酰基氧化膦作为光引发剂来制备通过自由基丙烯酸酯化学固化的凹版印刷油墨，其在紫外光下至少在可见光区域不发荧光。

8. 发明授权

US09428471B2 Cyclic carbamate compounds useful in energy-curable compositions 有权
标题翻译：可用于能量可固化组合物的环状氨基甲酸酯化合物
公开(公告)号：US09428471B2
公开(公告)日：2016-08-30
申请号：US13256115
申请日：2010-03-11
申请人： Shaun Herlihy , Brian Rowatt
发明人： Shaun Herlihy , Brian Rowatt
IPC分类号： C09D137/00 , C07D413/12 , B32B27/30 , C08J7/04 , C08F2/48 , C07D413/14 , C09K3/00 , C07D263/14
CPC分类号： C07D263/14 , Y10T428/24802 , Y10T428/31935
摘要： Cyclic carbamate functional compounds, which are the reaction product of a cyclic carbamate having an acrylate functional group, such as N-(2-acryloyloxyethyl)oxazolidinone, with aliphatic amine compounds, said cyclic carbamate functional compounds being useful as oxygen scavengers in energy-curable compositions, such as inks, coatings and adhesives, that comprise (a) the cyclic carbamate functional compound, (b) reactive monomers and/or oligomers and, optionally, (c) a photoinitiator.
摘要翻译：作为具有丙烯酸酯官能团的环状氨基甲酸酯如N-（2-丙烯酰氧基乙基）恶唑烷酮与脂族胺化合物的反应产物的环状氨基甲酸酯官能化合物，所述环状氨基甲酸酯官能化合物可用作能量固化型的除氧剂组合物，例如油墨，涂料和粘合剂，其包含（a）环状氨基甲酸酯官能化合物，（b）反应性单体和/或低聚物和任选地（c）光引发剂。

9. 发明申请

US20070244210A1 Piperazino Sensitisers 有权
标题翻译：派培齐诺敏感剂
公开(公告)号：US20070244210A1
公开(公告)日：2007-10-18
申请号：US10587588
申请日：2005-01-28
申请人： Shaun Herlihy , Brian Rowatt
发明人： Shaun Herlihy , Brian Rowatt
IPC分类号： C08F2/50 , C07D403/02
CPC分类号： C07D295/112 , C07D295/15 , G03F7/031
摘要： Compounds of formula (I) [in which: A and B are terminal groups; R1 represents a group of formula (II) or (III); R2 is alkyl or aryl; Z is a group —(CHR3)n, where R3 is hydrogen, hydroxy or alkyl, and n is a number from 0 to 6; Y is carbonyl or a group —CH2—; Q represents a residue of a dihydroxy compound; and x is a number from 1 to 100] are useful sensitisers for use with Type II photoinitiators in the formulation of printing inks and other energy curable coatings.
摘要翻译：式（I）化合物[其中：A和B为末端基团; R 1表示式（II）或（III）的基团; R 2是烷基或芳基; Z是一个基团，其中R 3是氢，羟基或烷基，n是0〜 6; Y是羰基或基团-CH 2 - 。 Q表示二羟基化合物的残基; 和x为1至100的数字]是用于印刷油墨和其它能量可固化涂料配方中的II型光引发剂的有用的敏化剂。

10. 发明申请

US20070066700A1 Piperazine-based sensitisers 有权
标题翻译：基于哌嗪的敏化剂
公开(公告)号：US20070066700A1
公开(公告)日：2007-03-22
申请号：US10567310
申请日：2004-07-02
申请人： Shaun Herlihy , Brian Rowatt
发明人： Shaun Herlihy , Brian Rowatt
IPC分类号： C07D403/14 , C08F2/50
CPC分类号： C07D295/112
摘要： Compounds of formula (I) where: {R1 is methyl, ethyl, cycloalkyl or optionally substituted aryl; Z is arylene or a group of formula —(CHR4)n-, where R4 is hydrogen, hydroxy or alkyl, and n is a number from 0 to 6; Y is carbonyl or a —CH2— group; Q is a residue of a mono- or poly-hydroxyl compound having from I to 6 hydroxy groups; and x is a number from I to 6; and esters thereof} are useful as sensitizers for use in radiationcurable compositions.
摘要翻译：式（I）的化合物，其中：{R 1]为甲基，乙基，环烷基或任选取代的芳基; Z是亚芳基或式 - （CHR 4 SO 4）n - 的基团，其中R 4是氢，羟基或烷基，n是0至6的数; Y是羰基或-CH 2 - Q是具有1至6个羟基的单羟基或多羟基化合物的残基; x是从I到6的数字; 和其酯}可用作用于可辐射固化组合物的敏化剂。

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