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    • 6. 发明授权
    • Microbicidal and growth regulating compositions
    • 杀菌和生长调节组合物
    • US4940481A
    • 1990-07-10
    • US468522
    • 1983-02-22
    • Urs MullerHans ToblerHermann RempflerAlfred Meyer
    • Urs MullerHans ToblerHermann RempflerAlfred Meyer
    • A01N43/50A01N43/653C07D233/60C07D249/08C07D521/00
    • C07D231/12A01N43/50A01N43/653C07D233/56C07D249/08
    • The invention relates to azolylpropane derivatives of the general formula I ##STR1## wherein R.sub.1 is an azolyl group,R.sub.2 and R.sub.3, each independently of the other, is hydrogen, alkyl, alkenyl, alkynyl, aralkyl, cyanoalkyl or alkoxycarbonylalkyl, and one of R.sub.2 and R.sub.3 always has a meaning other than hydrogen,R.sub.4 is C.sub.3 -C.sub.8 cycloalkyl, unsubstituted or substituted by alkyl; unsubstituted or substituted phenyl; or is C.sub.1 -C.sub.10 alkyl, unsubstituted or substituted by phenyl or substituted phenyl,R.sub.5 is an unsubstituted or a mono- or polysubstituted radical selected from the group consisting of C.sub.1 -C.sub.8 alky, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, phenyl, naphthyl, biphenyl, benzylphenyl, benzyloxyphenyl, phenoxyphenyl and aralkyl,R.sub.6 is hydrogen, alkyl or alkyl substituted by cyano, alkoxy or alkoxycarbonyl, or is an unsubstituted or substituted radical selected from the group consisting of alkylcarbonyl, phenylcarbonyl, carbamoyl, aralkyl, alkoxycarbonyl, alkylsulfonyl, phenylsulfonyl or sulfamoyl, andX is oxygen or sulfur,including the acid addition salts, quaternary azolium salts and metal complexes thereof.The invention further discloses methods of preparing these compounds as well as agrochemical compositions which contain one of said compounds as active component. The invention relates further to a method of controlling phytopathogenic microorganisms and/or of regulating plant growth with the compounds of formula I.
    • 本发明涉及通式Ⅰ(I)的吡唑基丙烷衍生物,其中R 1是唑基,R 2和R 3各自独立地是氢,烷基,烯基,炔基,芳烷基,氰基烷基或烷氧羰基烷基,和 R2和R3中的一个总是具有除氢之外的含义,R4是未被取代或被烷基取代的C3-C8环烷基; 未取代或取代的苯基; 或未被取代或被苯基或取代的苯基取代的C1-C10烷基,R5是未取代的或选自C1-C8烷基,C3-C8环烷基,C3-C6链烯基,C3-C6炔基,苯基, 萘基,联苯基,苄基苯基,苄氧基苯基,苯氧基苯基和芳烷基,R6是氢,被氰基,烷氧基或烷氧基羰基取代的烷基或烷基,或是选自烷基羰基,苯基羰基,氨基甲酰基,芳烷基,烷氧基羰基, 烷基磺酰基,苯基磺酰基或氨磺酰基,X是氧或硫,包括酸加成盐,季氮鎓盐及其金属络合物。 本发明还公开了制备这些化合物的方法以及含有所述化合物之一作为活性组分的农用化学组合物。 本发明还涉及用式I化合物控制植物病原微生物和/或调节植物生长的方法。
    • 7. 发明授权
    • Fluorinated azolyl ethanol growth regulators and microbicides
    • 氟化唑类乙醇生长调节剂和杀菌剂
    • US4610716A
    • 1986-09-09
    • US558140
    • 1983-12-05
    • Elmar SturmUrs MullerHans Tobler
    • Elmar SturmUrs MullerHans Tobler
    • A01N43/50A01N43/653C07D233/60C07D249/08C07D303/22C07D303/34C07D521/00
    • C07D303/22A01N43/50A01N43/653C07D231/12C07D233/56C07D249/08
    • The compounds described are those of the general formula I ##STR1## in which R.sub.1 is an azolyl group; R.sub.2 is C.sub.1 -C.sub.12 -alkyl; R.sub.3 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.4 -alkenyl or C.sub.2 -C.sub.4 -alkinyl, or benzyl which is unsubstituted or substituted by C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkyl, halogen and/or cyano; R.sub.4 is hydrogen, fluorine or C.sub.1 -C.sub.6 -alkyl; R.sub.5 is an unsubstituted or substituted radical chosen from the series comprising phenyl, naphthyl, biphenyl, benzylphenyl and benzyloxyphenyl, the substituents being chosen from the series comprising halogen, cyano, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -haloalkoxy, C.sub.1 -C.sub.3 -haloalkylthio, nitro and/or thiocyano; and X is oxygen or sulfur; including the acid addition salts, quaternary azolium salts and metal complexes.Methods for the preparation of these products are also disclosed, as well as agrochemical compositions containing one of these compounds as the active substance. A method of controlling phytopathogenic microorganisms and/or of regulating plant growth with the aid of these substances is furthermore described.
    • 所述的化合物是通式Ⅰ的化合物(Ⅰ),其中R1是唑基; R2是C1-C12-烷基; R3是氢,C1-C12-烷基,C2-C4-烯基或C2-C4-炔基,或未被取代或被C1-C6-烷基,C1-C6-烷氧基,C1-C6-卤代烷基,卤素和 /或氰基; R4是氢,氟或C1-C6-烷基; R5是选自包括苯基,萘基,联苯基,苄基苯基和苄氧基苯基的系列的未取代或取代的基团,所述取代基选自卤素,氰基,C 1 -C 6 - 烷基,C 1 -C 6 - 烷氧基C 1 -C 6 - 卤代烷基 ,C 1 -C 6 - 烷硫基,C 1 -C 6卤代烷氧基,C 1 -C 3卤代烷硫基,硝基和/或氰基氰基; X为氧或硫; 包括酸加成盐,季铵盐和金属络合物。 还公开了制备这些产品的方法,以及含有这些化合物之一作为活性物质的农药组合物。 进一步描述了借助于这些物质控制植物病原微生物和/或调节植物生长的方法。