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1. 发明专利

JPS54149743A Method of coating hydrophobic surface 失效
标题翻译：涂覆疏水表面的方法
公开(公告)号：JPS54149743A
公开(公告)日：1979-11-24
申请号：JP5863678
申请日：1978-05-17
申请人： Nippon Oil & Fats Co Ltd , Nissan Motor Co Ltd
发明人： NISHIKAWA SHIROU , UEDA YOSHIO , MATSUZAKA JIYUNICHI , MATSUMOTO SATORU , ASAJIMA HIROSHI , YAMAZAKI RIYOUSUKE
IPC分类号： B05D7/24 , B05D1/36
摘要： PURPOSE: Hydrophobic surfaces are coated with a specific pretreatment and then coated with water-diluted coating during the pretreatment is yet in wet state, thus being good in coating operability and giving cured coating films with good appearance free from pinhole and cissing.
CONSTITUTION: The same component resin as at least one of the resin components of the water-dilutable coating used for the top coating such as water-dilutable amino-alkyd resin, or along with another water-dilutable resin compatible with the former resin are dissolved in an organic solvent as isopropanol to prepare the resin solution for pretreatment. Hydrophobic surfaces are undercoated with the pretreatment, then while the coating film of the pretreatment is still in wet state, a water- dilutable coating is coated thereon as top coating. Subsequently, the films of pretreatment and top coating are simultaneously dried and cured by heating.
COPYRIGHT: (C)1979,JPO&Japio
摘要翻译：目的：疏水表面用特定的预处理涂布，然后在预处理过程中用水稀释的涂层进行涂布，处于湿润状态，从而具有良好的涂布可操作性，并且具有良好的外观，无针孔和外露的固化涂膜。构成：与顶部涂层（例如水可稀释氨基 - 醇酸树脂）一起使用的水可稀释涂层的树脂组分中的至少一种或与前一种树脂相容的另一种可水稀释的树脂相同的组分树脂溶解在作为异丙醇的有机溶剂中制备用于预处理的树脂溶液。疏水表面用预处理底涂，然后当预处理的涂膜仍处于湿润状态时，将水可稀释的涂层涂覆在其上作为顶涂层。随后，预处理和顶涂膜同时干燥并加热固化。

2. 发明专利

JPS59174620A Thermosetting resin for dispersing pigment 失效
标题翻译：用于分散颜料的热固性树脂
公开(公告)号：JPS59174620A
公开(公告)日：1984-10-03
申请号：JP4835383
申请日：1983-03-23
申请人： Nippon Oil & Fats Co Ltd
发明人： SHIBAFUJI KISHIO , MATSUZAKA JIYUNICHI , NAGURA OSAMU
IPC分类号： C08G63/00 , C08G63/08 , C09D17/00 , C09D167/00 , C09D167/04
摘要： PURPOSE: To provide the titled resin having improved compatibility and pigment ispersibility, and composed of a copolymer of specific amounts of OH-containing, glycidyl-containing and alkyl-containing ethylenic monomers, a lactone compound and an aromatic compound reactive with glycidyl group.
CONSTITUTION: The objective resin is prepared by copolymerizing (A) 5W30wt% of an OH-containing ethylenic unsaturated monomer (e.g. 2-hydroxyethyl methacrylate), (B) 2W20wt% of a glycidyl-containing ethylenic unsaturated monomer (e.g. glycidyl methacrylate), (C) 5W50wt% of an ethylenic unsaturated monomer containing a 4W22C straight, branched or cyclic alkyl group (e.g. lauryl methacrylate), (D) 0W30wt% of other ethylenic unsaturated monomer (e.g. methyl methacrylate), (E) 10W70wt% of a lactone compound (e.g. ε-caprolactone) and (F) 1W20wt% of an aromatic compound reactive with glycidyl group (e.g. p-nitrobenzoic acid).
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：提供具有改善的相容性和颜料分散性的标题树脂，由特定量的含OH，缩水甘油基和含烷基的烯属单体的共聚物，内酯化合物和与缩水甘油基反应的芳族化合物组成。构成：目标树脂通过（A）5-30重量％的含OH烯键式不饱和单体（例如甲基丙烯酸2-羟乙酯），（B）2-20重量％的含缩水甘油基的烯属不饱和单体（例如缩水甘油基甲基丙烯酸酯），（C）含有4-22C直链，支链或环状烷基（例如甲基丙烯酸月桂酯）的乙烯性不饱和单体的5-50重量％，（D）0-30重量％的其它烯属不饱和单体（例如甲基丙烯酸甲酯），（E）10-70wt％的内酯化合物（例如ε-己内酯）和（F）1-20wt％与缩水甘油基反应的芳族化合物（例如对硝基苯甲酸）。

3. 发明专利

JPS59129270A Composition for cationic electrodeposition coating 失效
标题翻译：阳离子电沉积涂料组合物
公开(公告)号：JPS59129270A
公开(公告)日：1984-07-25
申请号：JP552283
申请日：1983-01-17
申请人： Nippon Oil & Fats Co Ltd
发明人： NAGURA OSAMU , TAKEMOTO MASAYUKI , MATSUZAKA JIYUNICHI
IPC分类号： C09D5/44 , C08G59/00 , C08G59/14 , C09D163/00
摘要： PURPOSE: To provide a composition for cationic electrodeposition coating having a pH of 6 or higher and capable of forming a film with excellent rust preventive property, prepared by reacting glycidol with a reaction product obtained from an epoxy resin and a polyamine-ketimine derivative.
CONSTITUTION: An epoxy resin having at least two epoxy groups (e.g. obtained by condensation of bisphenol A with epichlorohydrin) is made to react with a polyamine-ketimine derivative having secondary amino and ketimine groups. Then the ketimine group is decomposed to obtain a reaction product having at least two tertiary amino groups and at least two primary amino groups. The reaction product (A) is made to react with glycidol (B) of the formula in such a ratio that (B) may be in 0.2W2mol per mol of primary amino group of (A). The resultant amino acid-containing resin is partly neutralized to have solubility (dispersibility) in water and it is used as electrodeposition coating as it is or after blended with other amino group-containing resins.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：提供一种pH值为6以上并能形成具有优异防锈性的阳离子电沉积涂料的组合物，其通过缩水甘油与由环氧树脂和多胺 - 酮亚胺衍生物获得的反应产物反应制得。构成：使具有至少两个环氧基的环氧树脂（例如通过双酚A与表氯醇的缩合获得）与具有仲氨基和酮亚胺基的多胺 - 酮亚胺衍生物反应。然后将酮亚胺基团分解，得到具有至少两个叔氨基和至少两个伯氨基的反应产物。使反应产物（A）与下式的缩水甘油（B）反应，其中（B）可以为每摩尔（A）的伯氨基0.2-2摩尔。得到的含有氨基酸的树脂被部分中和以在水中具有溶解性（分散性），并且作为电沉积涂层使用或与其它含氨基树脂共混后使用。

4. 发明专利

JPS58193395A Formation of anticorrosive coating 失效
标题翻译：形成防腐涂料
公开(公告)号：JPS58193395A
公开(公告)日：1983-11-11
申请号：JP7637382
申请日：1982-05-07
申请人： Nippon Oil & Fats Co Ltd
发明人： NAGURA OSAMU , MATSUZAKA JIYUNICHI , SHIBAFUJI KISHIO
IPC分类号： B05D7/14 , B05D1/36 , C25D13/00
摘要： PURPOSE: To effectively prevent the corrosion of the part of an outer plate for the body of an automobile where corrosion is easily formed, by undercoating the desired part of the outer plate for the body of an automobile with electric conductive paint, and then electrodeposition coating it.
CONSTITUTION: Paint dispersing powder having electric conductivity, e.g. electric conductive carbon black, in it is applied as an undercoat onto the part of an outer plate for the body of an automobile where corrosion is easily formed. The intrinsic volume resistivity of said undercoating film is made below 1×10
6 Ω.cm. Thereafter, the undercoated plate is coated with intermediate paint, dipped in the bath of electrodeposition paint and then electrodeposition coated in a conventional manner. By this anticorrosive coating method, the formation of damages in the coating film is eliminated, so that the progress of corrosion from the damaged part can be effectively inhibited.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：为了有效地防止容易形成腐蚀的汽车车体的外板部分的腐蚀，通过用导电涂料底漆涂覆汽车车体外板的所需部分，然后电沉积涂层它。构成：具有导电性的涂料分散粉末，例如导电性炭黑作为底涂层涂敷在易于形成腐蚀的汽车车体的外板的部分上。所述底涂膜的固有体积电阻率低于1×10 -6ΩEG。此后，将底漆涂覆有中间涂料，浸在电沉积涂料浴中，然后以常规方式电沉积。通过这种防腐涂层方法，消除了涂膜中的损伤的形成，从而可以有效地抑制来自损坏部分的腐蚀进展。

5. 发明专利

JPS59197471A Thermosetting resin composition for paint 失效
标题翻译：热固性树脂组合物
公开(公告)号：JPS59197471A
公开(公告)日：1984-11-09
申请号：JP7153783
申请日：1983-04-25
申请人： Nippon Oil & Fats Co Ltd
发明人： ISHIDA HARUHIDE , SHIBAFUJI KISHIO , NAGURA OSAMU , MATSUZAKA JIYUNICHI
IPC分类号： C09D127/12 , C09D133/00 , C09D133/04
摘要： PURPOSE: To provide the titled compsn. which gives a coating film having excellent resistance to water, solvents and weather, consisting of an OH group-contg. fluorocopolymer, a specified acrylic copolymer and a hardener.
CONSTITUTION: At least 20wt% C
10 WC
18 alkyl (meth)acrylate and not more than 80wt% acrylic monomer such as 2-hydroxyethyl acrylate are copolymerized in the presence of a polymn. initiator in an org. solvent at 80W150°C for 3W6hr to obtain an acrylic copolymer (B) having a hydroxyl equivalent of 500W2,000 and an acid value of 0W25. A hardener having a functional group capable of reacting with OH group, such as hexamethylene diisocyanate is added to a mixture of 2W70wt% OH group-contg. fluorocopolymer (A) such as a fluoroolefin/ cyclohexyl vinyl ether copolymer and 98W30wt% component B in such a proportion as to give a molar ratio of isocyanate group to OH group of 0.5W1.5.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：提供标题化合物。其得到具有优异的耐水性，溶剂性和耐候性的涂膜，其由OH基组成。含氟共聚物，指定的丙烯酸共聚物和硬化剂。构成：至少20重量％（甲基）丙烯酸C 10 -C 18烷基酯和不大于80重量％的丙烯酸单体如丙烯酸2-羟基乙酯在聚合物存在下共聚。发起者在组织。溶剂在80-150℃下反应3-6小时，得到羟基当量为500-2,000，酸值为0-25的丙烯酸共聚物（B）。将具有能够与OH基反应的官能团的硬化剂，例如六亚甲基二异氰酸酯加入到2-70重量％的OH基团的混合物中。含氟共聚物（A）如氟烯烃/环己基乙烯基醚共聚物和98-30重量％组分B，使得异氰酸酯基与OH基的摩尔比为0.5-1.5。

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