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1. 发明申请

WO1997036936A1 SELF-CROSS-LINKABLE WATER DISPERSIBLE RESIN COMPOSITION 审中-公开
标题翻译：自交联水分散树脂组合物
公开(公告)号：WO1997036936A1
公开(公告)日：1997-10-09
申请号：PCT/JP1997001132
申请日：1997-04-02
申请人： NIPPON PAINT CO., LTD. , WATANABE, Masakazu , SUZUKI, Satoshi , MIWA, Hiroshi , KUWAJIMA, Teruaki
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C08F02/44
CPC分类号： C09D133/066
摘要： A self-cross-linkable water dispersible resin composition capable of realizing a water-base coating material which forms a coating film having excellent transparency, smoothness, chemical resistance and mechanical strength, ensures excellent applicability and has a satisfactory dispersion stability is produced by the process comprising the steps of: conducting a radical polymerization of a starting mixture in the presence of a polymerization initiator and a hydrogen bond forming organic solvent at or below the boiling point of the organic solvent, the starting mixture comprising: (a) 5 to 95 % by weight of a reactive water insoluble resin containing a reactive functional group and having a water solubility of 1 or below, and (b) 5 to 95 % by weight of a monomer mixture comprising 0.5 to 50 % by weight of a reactive ethylenically unsaturated monomer having a functional group capable of reacting with the above functional group (1), 1 to 40 % by weight of an ethylenically unsaturated monomer having a carboxyl group (2) and 10 to 98.5 % by weight of another ethylenically unsaturated monomer (3) (provided that the total of components (1) to (3) is 100 % by weight), and adding a neutralizer to the resultant resin composition to thereby neutralize the same.
摘要翻译：能够实现形成透明性，平滑性，耐化学性和机械强度优异的涂膜的水性涂布材料的自交联水分散性树脂组合物通过该方法产生良好的适用性和良好的分散稳定性包括以下步骤：在有机溶剂的沸点或低于有机溶剂沸点的聚合引发剂和形成氢键的有机溶剂的存在下进行起始混合物的自由基聚合，起始混合物包含：（a）5至95％的包含反应性官能团并且具有1或更低的水溶解度的反应性水不溶性树脂，和（b）5至95重量％的包含0.5至50重量％反应性烯属不饱和单体的单体混合物具有能够与上述官能团（1）反应的官能团，1〜40重量％的烯属不饱和单体具有羧基（2）和10至98.5重量％的其它烯键式不饱和单体（3）（前提条件是组分（1）至（3）的总量为100重量％），并将中和剂加入到得到树脂组合物，从而使其中和。

2. 发明申请

WO1996001860A1 WATER-DISPERSIBLE RESIN COMPOSITION AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：水不溶性树脂组合物及其制造方法
公开(公告)号：WO1996001860A1
公开(公告)日：1996-01-25
申请号：PCT/JP1995001351
申请日：1995-07-06
申请人： NIPPON PAINT CO., LTD. , WATANABE, Masakazu , MIWA, Hiroshi , KUWAJIMA, Teruaki , SUZUKI, Satoshi
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C08F291/00
CPC分类号： C08F8/44
摘要： A process for producing a water-dispersible resin composition comprising: the step of conducting free-radical polymerization of a starting mixture composed of: (a) 10-95 wt.% of a water-insoluble resin having a solubility in water of 1 or less and (b) 90-5 wt.% of a monomer mixture composed of (1) 2-75 wt.% of an ethylenically unsaturated acid monomer and (2) 98-25 wt.% of another ethylenically unsaturated monomer in the presence of a polymerization initiator, and the step of neutralizing the obtained acidic resin composition with a neutralizing agent. The obtained composition provides a coating composition which is improved in shelf stability and solid content, stable, and excellent in workability in coating. As well-dispersible resin particles serve to improve coating film uniformity, the coating film obtained from the composition is improved in transparency, smoothness, chemical and water resistances, and mechanical strength.
摘要翻译：一种水分散性树脂组合物的制造方法，其特征在于，包括：起始混合物进行自由基聚合的步骤，所述起始混合物由以下组成：（a）10-95重量％的在水中溶解度为1的水不溶性树脂，较少的和（b）90-5重量％的由（1）2-75重量％的烯属不饱和酸单体组成的单体混合物和（2）98-25重量％的另一个烯属不饱和单体，的聚合引发剂，以及用中和剂中和所得酸性树脂组合物的步骤。所得组合物提供了一种提高了贮存稳定性和固含量，涂料稳定性和加工性优异的涂料组合物。分散性好的树脂颗粒用于提高涂膜的均匀性，从组合物获得的涂膜提高了透明度，光滑度，耐化学性和耐水性以及机械强度。

3. 发明申请

WO1991009895A1 POLYMER COMPOSITION, AQUEOUS DISPERSION PREPARED BY USING THE SAME AS EMULSIFIER, AND WATER-BASE COATING COMPOSITION 审中-公开
标题翻译：聚合物组合物，使用相同的乳化剂制备的水分散体和水基涂料组合物
公开(公告)号：WO1991009895A1
公开(公告)日：1991-07-11
申请号：PCT/JP1990001729
申请日：1990-12-28
申请人： NIPPON PAINT CO., LTD. , KUWAJIMA, Teruaki , NINOMIYA, Yusuke , KONISHI, Sakuichi
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C08G18/67
CPC分类号： C08G18/671 , C08G18/0833 , C09D175/16 , C08G18/0819 , C08L2666/16
摘要： The invention provides a polymer composition prepared by dispersing a urethane oligomer, prepared by the reaction of a hydroxyl-terminated diol compound having a molecular weight of 100 to 5.000, a diisocyanate compound, a compound having at least one active hydrogen atom and an amphoteric ion group in its molecule, and an ethylenically unsatured monomer having an active hydrogen atom in its molecule under an isocyanate-rich condition, in an aqueous medium containing a polyamine; an aqueous dispersion prepared by polymerising a monomer with the use of said composition as an emulsifier; and a water-base coating composition containing said dispersion. The polymer composition has a high emulsification stability, while the coating composition exhibits excellent coating performances especially when used as a metallic coating.
摘要翻译：本发明提供一种聚合物组合物，其通过分散通过分子量为100〜5.000的羟基封端的二醇化合物，二异氰酸酯化合物，具有至少一个活性氢原子的化合物和两性离子在分子中具有活性氢原子的烯属不饱和单体，在含异氰酸酯的条件下在含有多胺的水性介质中; 通过使用所述组合物作为乳化剂使单体聚合制备的水性分散体; 和含有所述分散体的水性涂料组合物。聚合物组合物具有高的乳化稳定性，而涂料组合物表现出优异的涂布性能，特别是当用作金属涂层时。

4. 发明申请

WO1995027011A1 CURABLE RESIN COMPOSITION, COATING COMPOSITION, COATING METHOD AND COATED ARTICLE 审中-公开
标题翻译：可固化树脂组合物，涂料组合物，涂料方法和涂料文章
公开(公告)号：WO1995027011A1
公开(公告)日：1995-10-12
申请号：PCT/JP1995000621
申请日：1995-03-31
申请人： NIPPON PAINT CO., LTD. , MIYAZOE, Seigo , FUSHIMI, Akira , INOUE, Masanobu
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C09D133/06
CPC分类号： C09D133/068 , C08L33/062 , C08L33/068 , C08L83/06 , C09D133/064 , C09D183/04 , Y10T428/31663 , C08L2666/02 , C08L2666/28 , C08L2666/54
摘要： The present invention provides a novel curable resin composition insuring good curability even without using an aminoplast curing agent and having an excellent high-solid feature, a sufficient storage stability which consists in a curable resin composition comprising 5 to 80 weight % of a polymer containing free and esterified carboxyl groups and having an acid value of 50 to 300 (mgKOH/g) (1e), 1 to 80 weight % of a polymer containing hydroxyl and epoxy groups and having an epoxy equivalent of 200 to 1000 and a hydroxyl equivalent of 250 to 1500 (2d), and 1 to 50 weight % of an alkoxyl group-containing silicone polymer having an alkoxyl equivalent of 50 to 1500 (3a), 0.1 to 5.0 weight % of a quarternary ammonium salt catalyst (4a) and 0.1 to 5.0 weight % of a monoalkyltin compound (5a).
摘要翻译：本发明提供一种即使不使用氨基塑料固化剂也具有优异的高固体特性，具有良好的固化性的新型固化性树脂组合物，其具有足够的保存稳定性，该组合物含有5〜80重量％和酯化羧基，酸值为50〜300（mgKOH / g）（1e），1〜80重量％的含羟基和环氧基的环氧当量为200〜1000，羟基当量为250 至1500（2d），和1至50重量％的烷氧基当量为50至1500（3a）的烷氧基的硅氧烷聚合物，0.1至5.0重量％的季铵盐催化剂（4a）和0.1至5.0 单烷基锡化合物（5a）的重量％。

5. 发明申请

WO1988009358A1 THERMOSETTING WATER PAINT COMPOSITION 审中-公开
标题翻译：热水涂料组合物
公开(公告)号：WO1988009358A1
公开(公告)日：1988-12-01
申请号：PCT/JP1988000524
申请日：1988-05-27
申请人： NIPPON PAINT CO., LTD. , NODA, Hideyoshi , YOSHIKAWA, Motoyoshi , KONISHI, Sakuichi
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C09D03/48
CPC分类号： C09D5/024
摘要： A water paint composition of resin dispersion type which shows a good workability in painting and particularly can give a coat having high luster and high smoothness, and which is extremely useful as top coat for automobiles. This paint composition is obtained by adding a compound represented by general formula (I) or (II), as a curing catalyst in an amount of 0.1 to 10 wt % based on the total solid content to a system containing an aqueous medium, a water resin, a hydrophobic resin powder or liquid resin particles composed of a hydrophobic resin and an organic solvent, and a curing agent.
摘要翻译：热固性树脂分散水漆。由（1）aq。介质，（2）水溶性树脂（优选具有至少4的耐水性和不超过51达因/厘米的1％水溶液的表面张力）（例如酸值为30的阴离子树脂 -200或H当量为30-300mM / 100g的阳离子树脂）; （3）疏水性树脂粉末（选择有机溶剂）（例如丙烯酸，醇酸树脂，聚酯，环氧树脂，氨基塑料，丙烯酸/醇酸树脂或丙烯酸/聚酯树脂），（4）固化剂，（5）固化催化剂（I）或（II）的化合物的总固体含量的0.1-10重量％，其中R 1是（优选取代的）烃基，苯基，氨基或羧基，R 2是H或Me，A 是2-4C亚烷基，X 1是-CONH-或-OCH 2 CHOHCH 2 COO-; Y1是-COO-或-SO3-，a是0或1，n是0-100，M是单或二价阴离子，铵或低级胺。

6. 发明申请

WO1988009357A1 WATER PAINT COMPOSITION OF RESIN DISPERSION TYPE 审中-公开
标题翻译：树脂分散型水性涂料组合物
公开(公告)号：WO1988009357A1
公开(公告)日：1988-12-01
申请号：PCT/JP1988000523
申请日：1988-05-27
申请人： NIPPON PAINT CO., LTD. , YOSHIKAWA, Motoyoshi , NODA, Hideyoshi , KONISHI, Sakuichi
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C09D03/48
CPC分类号： C09D5/02 , C08G18/0866 , C09D163/00 , C08L2666/02
摘要： A water paint composition of resin dispersion type, which comprises a continuous phase composed of an aqueous medium and a water-based resin and containing dispersed therein a discontinuous phase of a water-insoluble resin. The water-insoluble resin is a resin obtained by reacting a resin which contains functional groups capable of reacting with an epoxy or isocyanato group within the molecule and which is liquid at ordinary temperature with an epoxy compound or an isocyanate compound so that the reaction rate of the epoxy or isocyanato groups reaches 10 to 100 %. This paint composition shows an excellent workability in painting and can give a coat having high luster and high smoothness.
摘要翻译：树脂分散水漆。包含（a）连续相，由aq。介质和水性树脂，（b）由水不溶性树脂制成的分散相。通过使环氧化物或异氰酸酯与cpd反应。 contg。功能性GPS。其与环氧树脂或异氰酸酯gps反应。使环氧或异氰酸酯gps的反应比例。是10-100％。水洗鞋树脂可以用有机溶剂配制。

7. 发明申请

WO1984000971A1 PAINT RESIN COMPOSITION CONTAINING SATURATED ALICYCLIC ACID-MODIFIED AMPHOTERIC POLYESTER RESIN 审中-公开
标题翻译：含有饱和脂肪酸改性聚氨酯树脂的油漆树脂组合物
公开(公告)号：WO1984000971A1
公开(公告)日：1984-03-15
申请号：PCT/JP1983000293
申请日：1983-09-02
申请人： NIPPON PAINT CO., LTD. , UMEMOTO, Hirotoshi , TANABE, Hisaki , KANAKURA, Akihiro , NAKANO, Shinji
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C09D03/66
CPC分类号： C09D167/00 , C08G63/20 , C08G63/48 , C08L61/20
摘要： A novel resin composition for paint vehicle, which comprises a saturated alicyclic acid-modified amphoteric polyester resin controlled as to the kind of acid group responsible for the acid value of the resin and an etherified amino-formaldehyde resin. This composition possesses all merits inherent to oil-free polyester resin composition such as good weathering resistance, mechanical properties of coating, interlayer adhesiveness, etc. and, in addition, the weathering resistance is further improved by modification with the saturated alicyclic acid, hardening properties are improved by controlling the kind of the acid group responsible for the acid value of the residue, and pigment-dispersing ability and compatibility with melamine resin are improved by rendering the resin amphoteric.
摘要翻译：一种用于涂料载体的新型树脂组合物，其包含饱和脂环酸改性的两性聚酯树脂，其控制负责树脂酸值的酸基和醚化氨基甲醛树脂。该组合物具有无油聚酯树脂组合物固有的全部优点，如耐候性好，涂层机械性能，层间粘合性等，另外通过饱和脂环酸改性，硬化性能进一步提高耐候性通过控制负责残基酸值的酸基的种类得到改善，通过使树脂两性改善颜料分散能力和与三聚氰胺树脂的相容性。

8. 发明申请

WO1998003701A1 CATIONIC ELECTRODEPOSITION PROCESS AND COATING COMPOSITION FOR CATIONIC ELECTRODEPOSITION 审中-公开
标题翻译：阳离子电沉积方法和阳离子电沉积涂料组合物
公开(公告)号：WO1998003701A1
公开(公告)日：1998-01-29
申请号：PCT/JP1997002537
申请日：1997-07-23
申请人： NIPPON PAINT CO., LTD. , KAWAKAMI, Ichiro , SAKAMOTO, Hiroyuki , HORI, Hitoshi , SAITO, Takao , NISHIO, Masahiro
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C25D13/00
CPC分类号： C09D5/44
摘要： A cationic electrodeposition process and a coating composition therefor which can attain a high throwing power. The process comprises the step (1) of immersing a substrate in a coating composition for cationic electrodeposition, the step (2) of applying a voltage between the substrate (as a cathode) and an anode to form a deposit, and the step (3) of further applying a voltage to the deposit to thereby increase the electrical resistance of the deposit per unit volume. The step (3) serves to form a deposit in uncoated areas of the substrate and the coating composition is one exhibiting a point of time at which the electrical resistance of the deposit per unit volume increases in the course of electrodeposition under constant-current conditions.
摘要翻译：一种阳离子电沉积方法及其涂料组合物，其可以获得高投掷力。该方法包括将基底浸渍在用于阳离子电沉积的涂料组合物中的步骤（1），在基材（作为阴极）和阳极之间施加电压以形成沉积物的步骤（2），并且步骤（3））进一步向沉积物施加电压，从而增加每单位体积沉积物的电阻。步骤（3）用于在基底的未涂覆区域中形成沉积物，并且涂料组合物是在恒定电流条件下电沉积过程中每单位体积沉积物的电阻增加的时间点。

9. 发明申请

WO1995032250A1 ULTRAVIOLET-CURING LIQUID UNDERCOATING COMPOSITION FOR METALLIZING FRP, COATING METHOD, AND AUTOMOTIVE REFLECTOR 审中-公开
标题翻译：用于金属化FRP，涂层方法和汽车反射器的超紫外线固化液体组合物
公开(公告)号：WO1995032250A1
公开(公告)日：1995-11-30
申请号：PCT/JP1995000984
申请日：1995-05-23
申请人： NIPPON PAINT CO., LTD. , MATSUI, Sakae , NAKAMURA, Hiroyuki , KUDO, Shizuo , KONSE, Hiroaki
发明人： NIPPON PAINT CO., LTD.
IPC分类号： C09D05/00
CPC分类号： F21V7/22 , C08J7/047 , C08J2433/00 , C08J2467/00 , C09D167/08 , F21S41/37 , C08L2666/34
摘要： An ultraviolet-curing liquid undercoating composition for use in metallizing FRP, which is of one pack type, has an unlimited pot life, and is excellent in tenacious adhesion and heat resistance. The composition comprises 20-80 parts by weight of a compound having at least two (meth)acryloyl groups in its molecule, 80-20 parts by weight of an oil-modified alkyd resin, 2-15 parts by weight of a sensitizer, and optionally further 5-20 parts by weight of an amino resin based on 100 parts by weight in total of the above compound and the above alkyd resin. It is suited for the undercoating of an automotive reflector.
摘要翻译：一种包装类型的用于金属化FRP的紫外线固化液体底涂层组合物具有无限的适用期，并且具有优异的坚韧性和耐热性。该组合物包含20-80重量份的在其分子中具有至少两个（甲基）丙烯酰基的化合物，80-20重量份的油改性醇酸树脂，2-15重量份敏化剂和任选地，基于100重量份的上述化合物和上述醇酸树脂，还可以含有5-20重量份的氨基树脂。它适用于汽车反射器的底漆。

10. 发明申请

WO1993016414A1 PHOTOSENSITIVE COMPOSITION FOR FLEXOGRAPHIC PLATE MATERIAL 审中-公开
标题翻译：用于柔性板材的感光组合物
公开(公告)号：WO1993016414A1
公开(公告)日：1993-08-19
申请号：PCT/JP1993000152
申请日：1993-02-05
申请人： NIPPON PAINT CO., LTD. , HAYAKAWA RUBBER CO. LTD. , KANDA, Kazunori , KUSUDA, Hidefumi , SATO, Hisao , KAWAGUCHI, Chitoshi , NINOMIYA, Yusuke , NAKATSUKASA, Sadayoshi , FUJII, Toshihiro
发明人： NIPPON PAINT CO., LTD. , HAYAKAWA RUBBER CO. LTD.
IPC分类号： G03F07/027
CPC分类号： G03F7/027
摘要： To provide a photosensitive composition which can yield a flexographic plate material having good properties as a plate material and a good solvent ink resistance at a high productivity. A photosensitive composition for flexographic plate material comprising: (1) 5-98 wt.% of a photopolymerizable composite rubber having a gel fraction of 0.5 % or less, prepared by reacting; (a) a photopolymerizable diene/urethane-modified acrylate represented by general formula (1), wherein R represents C2-C8 alkylene or polyoxyalkylene; R1 represents H or CH3; R2 and R3 represent each the residue of a diisocyanate compound; R4 represents the residue of a dihydric alcohol having a molecular weight of 2,000 or less and represented by general formula (2), (wherein R5 represents C2-C8 alkylene or polyoxyalkylene, and R6 and R7 represent each H, CH3, (meth)acryloyloxy or allyloxy); X represents a non-hydroxylated part of a liquid hydroxylated diene rubber; l represents an integer of 1 to 4; 1
摘要翻译：提供一种光敏组合物，其可以以高生产率产生具有良好性能的柔性版材料作为板材和良好的溶剂耐油墨性。一种柔性版材料用感光性组合物，其特征在于，含有：（1）5-98重量％的通过反应制备的凝胶分数为0.5％以下的光聚合复合橡胶; （a）由通式（1）表示的可光聚合的二烯/氨基甲酸酯改性的丙烯酸酯，其中R表示C2-C8亚烷基或聚氧化烯; R1表示H或CH3; R2和R3表示二异氰酸酯化合物的残基; R4表示分子量为2,000以下，由通式（2）表示的二元醇的残基，（其中，R5表示C2-C8亚烷基或聚氧化烯，R6和R7表示H，CH3，（甲基）丙烯酰氧基或烯丙氧基）; X表示液体羟基化二烯橡胶的非羟基化部分; l表示1〜4的整数， 1

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