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1. 发明授权

US4847339A Process for preparing interpolymers of ethylene, vinyl acetate, and reactive halogen-containing monomers 失效
标题翻译：制备乙烯，乙酸乙烯酯和反应性含卤素单体互聚物的方法
公开(公告)号：US4847339A
公开(公告)日：1989-07-11
申请号：US10243
申请日：1987-02-02
申请人： Manfred Heimberg , Louis J. Rekers
发明人： Manfred Heimberg , Louis J. Rekers
IPC分类号： C08F2/24 , C08F210/02 , C08F218/08
CPC分类号： C08F218/08 , C08F210/02
摘要： An improved emulsion polymerization process for the preparation of high Mooney viscosity terpolymers of ethylene, vinyl acetate, and reactive halogen-containing monomers is provided. In the process, the reactive halogen-containing monomer is added during the polymerization. The ethylene pressure may also be increased during the polymerization.

2. 发明授权

US5338609A Fractional melt flow rate polymer powders and process for their preparation 失效
公开(公告)号：US5338609A
公开(公告)日：1994-08-16
申请号：US66358
申请日：1993-05-21
申请人： Daniel J. Ondrus , Manfred Heimberg
发明人： Daniel J. Ondrus , Manfred Heimberg
IPC分类号： C08J3/12 , B32B5/16
CPC分类号： C08J3/12 , C08J2323/08 , C08J2343/04 , Y10T428/2982
摘要： The present invention relates to fractional melt flow rate powders wherein the particles are substantially spherical in shape and range in size from about 10 up to about 200 microns. The invention also relates to a process whereby a dispersible olefin copolymer resin can be converted into a microfine powder with reduced melt index. The process entails dispersing a molten olefin copolymer resin containing silane functionality in a liquid medium in the presence of a nonionic surfactant and catalyst and, after the melt flow rate is reduced to the desired level, cooling the dispersion to below the melt point of the olefin polymer.

3. 发明授权

US5336731A Fractional melt flow rate polymer powders and process for their preparation 失效
标题翻译：分子熔体流动速率聚合物粉末及其制备方法
公开(公告)号：US5336731A
公开(公告)日：1994-08-09
申请号：US066359
申请日：1993-05-21
申请人： Daniel J. Ondrus , Manfred Heimberg
发明人： Daniel J. Ondrus , Manfred Heimberg
IPC分类号： C08J3/12 , C08C19/00
CPC分类号： C08J3/12 , C08J2323/08 , C08J2343/04 , Y10T428/2982
摘要： The present invention relates to fractional melt flow rate powders wherein the particles are substantially spherical in shape and range in size from about 10 up to about 200 microns. The invention also relates to a process whereby a dispersible olefin copolymer resin can be converted into a microfine powder with reduced melt index. The process entails dispersing a molten olefin copolymer resin containing silane functionality in a liquid medium in the presence of a nonionic surfactant and catalyst and, after the melt flow rate is reduced to the desired level, cooling the dispersion to below the melt point of the olefin polymer.
摘要翻译：本发明涉及分级熔体流动速率粉末，其中颗粒基本上是球形，尺寸范围为约10至约200微米。本发明还涉及将可分散的烯烃共聚物树脂转化为具有降低的熔体指数的微细粉末的方法。该方法需要在非离子表面活性剂和催化剂的存在下将含有硅烷官能团的熔融烯烃共聚物树脂分散在液体介质中，并且在熔体流动速率降低到所需水平之后，将分散体冷却至低于烯烃熔点聚合物。

4. 发明授权

US4917849A Process for preparing ionomers 失效
标题翻译：制备离聚物的方法
公开(公告)号：US4917849A
公开(公告)日：1990-04-17
申请号：US112586
申请日：1987-10-26
申请人： Jeffrey A. Jones , Manfred Heimberg
发明人： Jeffrey A. Jones , Manfred Heimberg
IPC分类号： C08F8/44 , C08G81/02
CPC分类号： C08G81/021 , C08F8/44
摘要： A process for preparing ionomers is disclosed. In this process a vinyl acetate polymer is contacted with a hydroxide of an alkali metal or an alkaline earth metal. The in situ formed acetate of an alkali metal or an alkaline earth metal of this reaction is in turn reacted with a polymer having carboxylic acid or diacid anhydride funtionality to produce the ionomer.
摘要翻译：公开了一种制备离聚物的方法。在该方法中，乙酸乙烯酯聚合物与碱金属或碱土金属的氢氧化物接触。该反应的碱金属或碱土金属的原位形成的乙酸盐又与具有羧酸或二酸酐的聚合物反应以产生离聚物。

5. 发明授权

US4287329A Emulsion process for preparing elastomeric vinyl acetate-ethylene copolymer and high Mooney viscosity low gel content elastomer obtained therefrom 失效
标题翻译：用于制备弹性体乙酸乙烯酯 - 乙烯共聚物的乳液法和由其获得的高门尼粘度低凝胶含量弹性体
公开(公告)号：US4287329A
公开(公告)日：1981-09-01
申请号：US132946
申请日：1980-03-24
申请人： Manfred Heimberg
发明人： Manfred Heimberg
IPC分类号： C08F2/30 , C08F218/08
CPC分类号： C08F218/08
摘要： In a process for preparing an elastomeric vinyl acetate-ethylene copolymer having high Mooney viscosity and low gel content wherein vinyl acetate monomer is copolymerized with ethylene monomer in an aqueous emulsion reaction medium containing surface active agent, polymerization catalyst and protective colloid to provide a latex and vinyl acetate-ethylene elastomer is recovered from the latex, an improvement is disclosed which comprises:copolymerizing from about 40% to about 70% by weight of vinyl acetate monomer with from about 60% to about 30% by weight of ethylene monomer in an aqueous emulsion reaction medium to provide a latex, the reaction medium for vinyl acetate-ethylene elastomer containing:(i) at least one surface active agent having a hydrophilic lipophilic balance value of at least 22 in an amount above about 2.0% by weight of the total monomer,(ii) a polymerization catalyst, and(iii) at least one protective colloid in an amount of less than about one part for each part by weight of total surface active agent, with the total weight of the surface active agent and vinyl acetate being present in the reaction medium at the commencement of copolymerization.
摘要翻译：在制备具有高门尼粘度和低凝胶含量的弹性体乙酸乙烯酯 - 乙烯共聚物的方法中，其中醋酸乙烯酯单体与含有表面活性剂的水乳液反应介质中的乙烯单体共聚，聚合催化剂和保护胶体以提供胶乳和从胶乳中回收乙酸乙烯酯 - 乙烯弹性体，公开了一种改进，其包括：将约40重量％至约70重量％的乙酸乙烯酯单体与约60重量％至约30重量％的乙烯单体在水性乳液反应介质以提供胶乳，用于乙酸乙烯酯 - 乙烯弹性体的反应介质包含：（i）至少一种具有至少22的亲水亲油平衡值的表面活性剂，其量超过总量的约2.0重量％单体，（ii）聚合催化剂，和（iii）至少一种保护胶体，其量小于每份的约一份的总表面活性剂，在共聚开始时，表面活性剂和乙酸乙烯酯的总重量存在于反应介质中。

6. 发明授权

US5209977A Crosslinkable ethylene copolymer powders and processes 失效
标题翻译：可交联乙烯共聚物粉末和方法
公开(公告)号：US5209977A
公开(公告)日：1993-05-11
申请号：US797834
申请日：1991-11-26
申请人： Manfred Heimberg , Daniel J. Ondrus
发明人： Manfred Heimberg , Daniel J. Ondrus
IPC分类号： C08J3/12 , C08L43/04
CPC分类号： C08J3/12 , C08L43/04 , C08J2323/08 , Y10T428/2982
摘要： The present invention relates to crosslinkable microfine ethylene copolymer powders which are substantially spherical in shape and range in size from about 10 up to about 500 microns and to the process of crosslinking the powders to reduce their melt flow rate. The powders are crosslinked by contacting with water in the presence of a silanol condensation catalyst at temperatures from ambient up to about 110.degree. C. The reduction in melt flow rate is accomplished without substantially changing the powder characteristics, i.e., particle size and particle size distribution.
摘要翻译：本发明涉及在大约10至大约500微米的尺寸范围内基本上是球形的交联性微细乙烯共聚物粉末以及使粉末交联以降低其熔体流动速率的方法。在硅烷醇缩合催化剂存在下，在环境温度高达约110℃的温度下，通过与水接触来使粉末交联。熔体流动速率的降低不会实质上改变粉末特性，即粒度和粒度分布。

7. 发明授权

US4522999A Vinylcyclopropane dicarboxylate polyester oligomer interpolymer, process for its preparation and semi-gloss latex paint of improved wet adhesion containing the interpolymer 失效
标题翻译：乙烯基环丙烷二羧酸酯聚酯低聚物互聚物，其制备方法和半光泽乳胶漆，其改进的湿粘合性包含互聚物
公开(公告)号：US4522999A
公开(公告)日：1985-06-11
申请号：US562556
申请日：1983-12-19
申请人： Manfred Heimberg
发明人： Manfred Heimberg
IPC分类号： C08F218/04 , C08F299/04 , C08G63/553 , C09D131/04 , C08F32/04 , C08F232/04
CPC分类号： C08F218/04 , C08F299/0478 , C08G63/553 , C09D131/04
摘要： Interpolymers are provided which are based upon the interpolymerization of a vinyl ester of an alpha-unbranched saturated monocarboxylic acid, a monomer selected from the group consisting of an alkyl ester of an alpha, beta ethylenically unsaturated monocarboxylic acid and a vinyl ester of an alpha-branched saturated monocarboxylic acid and a vinylcyclopropanedicarboxylate polyester oligomer or mixture thereof. Optionally, an alpha, beta ethylenically unsaturated carboxylic acid may be added. The interpolymers are particularly useful for formulating surface coatings such as semi-gloss paints where they have been found to significantly improve the wet adhesion properties thereof.
摘要翻译：提供了基于α-非支化饱和一元羧酸的乙烯基酯共聚合的共聚物，选自α，β-烯属不饱和一元羧酸的烷基酯和α-烯属不饱和一元羧酸的乙烯基酯的单体，支链饱和一元羧酸和乙烯基环丙烷二羧酸酯聚酯低聚物或其混合物。任选地，可以加入α，β烯键式不饱和羧酸。互聚物特别可用于配制表面涂层，例如半光泽涂料，其中已经发现它们显着改善其湿粘合性能。

8. 发明授权

US5246779A Microfine propylene polymer powders and process for their preparation 失效
标题翻译：微细丙烯聚合物粉末及其制备方法
公开(公告)号：US5246779A
公开(公告)日：1993-09-21
申请号：US927750
申请日：1992-08-10
申请人： Manfred Heimberg , Daniel J. Ondrus
发明人： Manfred Heimberg , Daniel J. Ondrus
IPC分类号： C08F8/50
CPC分类号： B29C47/92 , C08F8/50 , B29C2947/92704 , B29C47/0004 , B29C47/38 , B29C47/805 , C08F2800/20 , C08F2810/10 , Y10S525/938 , Y10T428/2982
摘要： The present invention is directed to improved microfine propylene polymer powders having reduced fines which are comprised of spherical or substantially spherical particles and have a number average particle size from about 25 to about 60. A process for preparing the improved powders is also provided. The process involves dispersing a molten propylene homopolymer or copolymer which has been visbroken in a liquid medium in the presence of a nonionic surfactant, cooling the dispersion below the melt point of the propylene polymer and recovering the powder.
摘要翻译：本发明涉及具有减小的细粒的改进的微细丙烯聚合物粉末，其由球形或基本上为球形的颗粒组成，并且具有约25至约60的数均粒径。还提供了制备改进粉末的方法。该方法包括在非离子表面活性剂的存在下分散已经在液体介质中被分解的熔融丙烯均聚物或共聚物，将分散体冷却到低于丙烯聚合物的熔点并回收粉末。

9. 发明授权

US4522998A Interpolymer, process for its preparation and adhesive of improved creep resistance containing the interpolymer 失效
标题翻译：互聚物，其制备方法和具有包含互聚物的抗蠕变性的粘合剂
公开(公告)号：US4522998A
公开(公告)日：1985-06-11
申请号：US562555
申请日：1983-12-19
申请人： Manfred Heimberg
发明人： Manfred Heimberg
IPC分类号： C08F218/04 , C08F299/04 , C08G63/553 , C09J131/04 , C08F32/04 , C08F232/04
CPC分类号： C08F218/04 , C08F299/0478 , C08G63/553 , C09J131/04
摘要： Interpolymers are provided which are based upon the interpolymerization of a vinyl ester, a lower alpha olefin, optionally an alpha, beta ethylenically unsaturated carboxylic acid and a vinylcyclopropanedicarboxylate polyester oligomer or mixtures thereof. The interpolymers are particularly useful for formulating latex adhesives where they have been found to significantly improve the creep resistance properties thereof.
摘要翻译：提供了基于乙烯基酯，低级α-烯烃，任选的α，β-烯键式不饱和羧酸和乙烯基环丙烷二羧酸酯聚酯低聚物或其混合物的共聚的共聚物。互聚物特别可用于配制胶乳粘合剂，其中已经发现它们显着改善其抗蠕变性能。

10. 发明授权

US4409355A Process for preparing high solids copolymer latices with low viscosity 失效
标题翻译：制备低粘度高固含量共聚物胶乳的方法
公开(公告)号：US4409355A
公开(公告)日：1983-10-11
申请号：US344234
申请日：1982-01-29
申请人： Manfred Heimberg
发明人： Manfred Heimberg
IPC分类号： C08F218/04 , C08F263/04 , C08F265/04 , C08L33/08 , C08L33/10
CPC分类号： C08F218/04 , C08F263/04 , C08F265/04
摘要： A process is disclosed for preparing copolymer latices possessing a solids content of at least about 60 weight percent and a viscosity not exceeding 15,000 cp. Brookfield Viscosity (RVF, Spindle No. 4) at 2 rpm from (a) vinyl acetate in an amount representing from about 10 weight percent to about 95 weight percent of total monomer charge, and (b) at least one monomer selected from the group consisting of acrylate ester, methacrylate ester and vinyl ester of an alpha-branched saturated monocarboxylic acid representing the balance of the total monomer charge. The aforesaid latices are prepared by polymerizing in a single reaction stage at least 10 weight percent of the total vinyl acetate monomer (a) and from 0 to about 50 weight percent of the total acrylate ester, methacrylate ester and/or vinyl ester of alpha-branched saturated monocarboxylic acid monomer (b) in an aqueous emulsion reaction medium containing a polymerization catalyst, and thereafter polymerizing in said reactor in a second stage the remaining portion of the total vinyl acetate monomer (a) together with the remaining portion of the acrylate ester, methacrylate ester, and/or vinyl ester of alpha-branched saturated carboxylic acid monomer (b) in the reaction medium containing additional catalyst if needed, polymerization being continued substantially to completion.
摘要翻译：公开了一种制备具有至少约60重量％的固体含量和不超过15,000cp的粘度的共聚物胶乳的方法。来自（a）乙酸乙烯酯的2rpm的布鲁克菲尔德粘度（RVF，主轴No.4）的量占总单体电荷的约10重量％至约95重量％，和（b）至少一种选自组由α-支链饱和一元羧酸的丙烯酸酯，甲基丙烯酸酯和乙烯基酯组成，代表总单体电荷的平衡。上述胶乳通过在单个反应阶段中聚合至少10重量％的总乙酸乙烯酯单体（a）和0至约50重量％的总丙烯酸酯，甲基丙烯酸酯和/或α-烯烃的乙烯基酯来制备，支链饱和一元羧酸单体（b）在含有聚合催化剂的水乳液反应介质中，然后在第二阶段在所述反应器中聚合，将总的乙酸乙烯酯单体（a）的剩余部分与剩余部分的丙烯酸酯，甲基丙烯酸酯和/或α-支链饱和羧酸单体（b）的乙烯基酯，如果需要，在含有另外的催化剂的反应介质中，聚合继续基本上完成。

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