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    • 5. 发明授权
    • Crash box collision damper for motor vehicle
    • 汽车碰撞碰撞阻尼器
    • US06672438B2
    • 2004-01-06
    • US10108821
    • 2002-03-28
    • Manfred Beck
    • Manfred Beck
    • B62D2704
    • B60R19/34B60R2021/0023F16F7/12
    • An automotive crashbox damper member (26) has a sequenced pre-collapse surface (34) providing sequential energy absorbing compression such that at application of longitudinal (28) force, longitudinal compression initially occurs at the pre-collapse surface (34), prior to compression of the remainder (36) of the crashbox damper member (26). In one embodiment, the pre-collapse surface (34) is a mounting surface (7) beveled (40) in roof-like fashion to a frontmost leading edge (38) over the end (32) of the crashbox damper member (26). In another embodiment, the pre-collapse surface (34) is a mounting surface (7) formed as an arched cap (11) in the form of a spherical segment over the end (32) of the crashbox damper member (26).
    • 汽车碰撞箱阻尼器构件(26)具有顺序的预塌缩表面(34),其提供顺序的能量吸收压缩,使得在施加纵向(28)的力时,纵向压缩最初在预塌陷表面(34)处发生, 撞击箱阻尼器构件(26)的其余部分(36)的压缩。 在一个实施例中,预塌陷表面(34)是以类似屋顶的方式倾斜(40)的安装表面(7),其位于碰撞箱阻尼器构件(26)的端部(32)上方的最前面的前缘(38) 。 在另一个实施例中,预塌陷表面(34)是形成为在碰撞箱阻尼器构件(26)的端部(32)上的球形部分形式的拱形盖(11)的安装表面(7)。
    • 10. 发明授权
    • Catalyst, its preparation and use in the polymerization of butadiene
    • 催化剂,其制备和用于丁二烯聚合
    • US4216121A
    • 1980-08-05
    • US5445
    • 1979-01-22
    • Gerd SylvesterManfred BeckJosef WitteGottfried Pampus
    • Gerd SylvesterManfred BeckJosef WitteGottfried Pampus
    • C08F4/00C08F4/60C08F4/619C08F4/64C08F36/00C08F136/06
    • C08F136/06
    • A catalyst composition comprising (a) TiI.sub.4 and/or TiOR.sup.1 I.sub.3, (b) AlR.sub.3 and/or HAlR.sub.2 and (c) TiXCl.sub.3 can be used for polymerizing butadiene. Said catalyst can be obtained by mixing the components a, b and c in any order at temperatures from -10.degree. to +80.degree. C. R' represents C.sub.1-8 alkyl and X represents a C.sub.1-12 alkoxy radical optionally substituted one or more times by halogen, C.sub.6 or C.sub.7 cycloalkyl and/or phenyl, a C.sub.5-7 cycloalkoxy radical optionally substituted one or more times by C.sub.1-5 alkyl groups, a phenoxy group corresponding to the formula ##STR1## wherein R.sub.2 and R.sub.6 can be the same or different and are hydrogen or C.sub.1-5 alkyl, a carboxyl group having the formula R.sup.7 --COO wherein R.sup.7 is C.sub.1-12 alkyl optionally substituted one or more times by halogen, C.sub.5-7 cycloalkyl and/or phenyl, a C.sub.5-7 cycloalkyl radical optionally substituted one or more times by C.sub.1-5 alkyl groups, or phenyl.
    • 包含(a)TiI4和/或TiOR1I3,(b)AlR3和/或HA1R2和(c)TiXCl3的催化剂组合物可用于聚合丁二烯。 所述催化剂可以通过在-10℃至+ 80℃的温度下以任何顺序混合组分a,b和c来获得.R'表示C1-8烷基,X表示任选被一个或多个取代基取代的C 1-12烷氧基 卤素,C6或C7环烷基和/或苯基,C5-7环烷​​氧基任选被C1-5烷基取代一次或多次,苯酚基团相应于通式其中R2和R6可以相同 或不同的是氢或C 1-5烷基,具有式R7-COO的羧基,其中R7是任选被卤素,C 5-7环烷​​基和/或苯基取代一次或多次的C 1-12烷基,C 5-7环烷​​基 任选地被C 1-5烷基取代的一个或多个自由基,或苯基。