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1. 发明公开

EP0008536A1 Process for manufacturing regenerated cellulose hollow fiber 失效
标题翻译： Verfahren zur Herstellung von hohlen Fasern aus再生器Zellulose。
公开(公告)号：EP0008536A1
公开(公告)日：1980-03-05
申请号：EP79301711.2
申请日：1979-08-21
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Ishida, Masamichi , Kamo, Jun , Takemura, Toru , Minami, Shunsuke , Kamada, Kensuke
IPC分类号： D01D5/24 , B01D13/04
CPC分类号： B01D71/10 , B01D69/08 , D01D5/24
摘要： A regenerated cellulose hollow fiber used as a permeable membrane for dialysis and ultrafiltration, which is prepared by hydrolyzing a cellulose ester hollow fiber and characterized as (a) containing a cellulose II crystal structure at a degree of crystallinity of from 40 to 75%, said cellulose II crystal structure having a degree of crystallite orientation of from 78 to 90% and having a crystallite size of from 60 to 150 angstroms as measured along the fiber axis, and (b) exhibiting a wet strength/wet elongation ratio of from 1.50 to 8.0.
The regenerated cellulose hollow fiber, of which figure 1A is an X-ray diffraction photograph, is prepared by a process wherein: a dope comprised of cellulose ester in a non-volatile organic solvent is extruded through an annular slit defined between inner and outer tubes of a spinning nozzle having a double tube structure, while a core liquid is forced through the inner tube of said nozzle; the hollow fibrous extrudate is coagulated in a coagulating bath; the coagulated hollowfibr- ous extrudate is drawn 1.05 to 2.00 times its original length; and then, the drawn hollow fiber still containing a core liquid in the hollow is treated with an aqueous caustic alkali solution containing at least 0.5% by weight of water soluble metal salt, thereby hydrolyzing the cellulose ester into cellulose.
摘要翻译：一种再生纤维素中空纤维，其用作透析和超滤的渗透膜，其通过水解纤维素酯中空纤维制备，其特征在于（a）含有结晶度为40-75％的纤维素II晶体结构，所述纤维素中空纤维的所述纤维素II晶体结构，其微晶取向度为78〜90％，沿着纤维轴测得的微晶尺寸为60〜150埃，（b）湿强度/湿伸长率为1.50〜 8.0。图1A是X射线衍射照片的再生纤维素中空纤维通过以下方法制备，其中：由非挥发性有机溶剂中的纤维素酯组成的涂料通过限定在内管和外管之间的环形狭缝挤出具有双管结构的纺丝喷嘴，而芯液被迫通过所述喷嘴的内管; 中空纤维挤出物在凝固浴中凝结; 凝固的中空纤维挤出物的原始长度为1.05〜2.00倍; 然后，用含有至少0.5重量％的水溶性金属盐的苛性碱水溶液处理在中空体中仍含有核心液体的拉伸中空纤维，从而将纤维素酯水解成纤维素。

2. 发明公开

EP0206354A3 Multilayer composite hollow fibers and method of making same 失效
标题翻译：多层复合中空纤维及其制造方法
公开(公告)号：EP0206354A3
公开(公告)日：1988-06-08
申请号：EP86108786
申请日：1986-06-27
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Takemura, Tohru , Itoh, Hajime , Kamo, Jun , Yoshida, Haruhiko
IPC分类号： B01D13/04 , D01D05/24
CPC分类号： D01D5/24 , B01D67/0027 , B01D69/08 , B01D69/12 , B01D2323/08 , Y10T428/2929 , Y10T428/2935 , Y10T428/2973 , Y10T428/2975
摘要： Disclosed are a multilayer composite hollow fiber comprising at least one nonporous separating membrane layer (A) performing a separating function and two or more porous layers (B) performing a reinforcing function, the layer (A) and the layers (B) being alternately laminated so as to give a structure having internal and external surfaces formed by the porous layers (B), as well as a method of making such a hollow fiber. In this multilayer composite hollow fiber, the separating membrane can be formed as an ultrathin, homogeneous membrane. Moreover, the separating membrane is not liable to get damaged owing to the unique structure of the hollow fiber. Furthermore, such hollow fibers can be readily and stably produced on an industrial scale.

3. 发明公开

EP0164468A3 Porous membrane 失效
标题翻译：多孔膜
公开(公告)号：EP0164468A3
公开(公告)日：1987-01-21
申请号：EP84305401
申请日：1984-08-08
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Kamo, Jun
IPC分类号： B01D13/04 , C08J07/06 , A61M01/16
CPC分类号： B01D67/0088
摘要： A micropdrous membrane having a stable hydrophilicity and an excelfent safety which is a hydrophobic microporous membrane having a porosity ranging from 20% by volume to 90%by volume, wherein at least a part of the pore surface of said microporous membrane has a layer hydrophilized with a complex lipid.
摘要翻译：一种具有稳定的亲水性和优异的安全性的微孔膜，其是具有20体积％至90体积％的孔隙率的疏水性微孔膜，其中所述微多孔膜的孔表面的至少一部分具有亲水化的层，一种复杂的脂质。

4. 发明公开

EP0164468A2 Porous membrane 失效
标题翻译： PoröseMembran。
公开(公告)号：EP0164468A2
公开(公告)日：1985-12-18
申请号：EP84305401.6
申请日：1984-08-08
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Kamo, Jun
IPC分类号： B01D13/04 , C08J7/06
CPC分类号： B01D67/0088
摘要： A micropdrous membrane having a stable hydrophilicity and an excelfent safety which is a hydrophobic microporous membrane having a porosity ranging from 20% by volume to 90%by volume, wherein at least a part of the pore surface of said microporous membrane has a layer hydrophilized with a complex lipid.
摘要翻译：一种具有稳定的亲水性和优异的安全性的微孔膜，其是具有20体积％至90体积％的孔隙率的疏水性微孔膜，其中所述微多孔膜的孔表面的至少一部分具有亲水化的层，一种复杂的脂质。

5. 发明授权

EP0206354B1 Multilayer composite hollow fibers and method of making same 失效
标题翻译：多层复合中空纤维及其制造方法
公开(公告)号：EP0206354B1
公开(公告)日：1992-01-02
申请号：EP86108786.4
申请日：1986-06-27
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Takemura, Tohru , Itoh, Hajime , Kamo, Jun , Yoshida, Haruhiko
IPC分类号： B01D63/02 , B01D67/00 , D01D5/24
CPC分类号： D01D5/24 , B01D67/0027 , B01D69/08 , B01D69/12 , B01D2323/08 , Y10T428/2929 , Y10T428/2935 , Y10T428/2973 , Y10T428/2975

6. 发明授权

EP0157941B1 Blood oxygenator using a hollow fiber membrane 失效
标题翻译：使用中空纤维膜的血液氧化剂
公开(公告)号：EP0157941B1
公开(公告)日：1988-07-27
申请号：EP84116102.9
申请日：1984-12-21
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Hamada, Eiichi , Nakashima, Atushi , Kamo, Jun
IPC分类号： A61M1/18
CPC分类号： A61M1/1698 , A61M1/1625 , B01D63/02 , B01D63/04 , B01D2313/08

7. 发明公开

EP0160268A3 Blood oxygenator using a hollow-fiber membrane 失效
标题翻译：使用中空纤维膜的血液氧化剂
公开(公告)号：EP0160268A3
公开(公告)日：1987-10-21
申请号：EP85104974
申请日：1985-04-24
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Takemura, Tohru , Nakashima, Atushi , Yoshida, Haruhiko , Kamo, Jun , Hamada, Eiichi
IPC分类号： A61M01/18 , B01D13/01
CPC分类号： A61M1/1698 , A61M1/1625 , A61M1/1629 , B01D63/02 , B01D63/04 , B01D2313/08 , B01D2313/38 , B01D2319/06 , Y10S128/03
摘要： The present invention provides a blood oxygenator of the outside perfusion type using hollow fibers (2) as the gas exchange membrane. In this blood oxygenator, a plurality of contact chambers (5) each containing a bundle or bundles of hollow fibers (2) for gas exchange use and communicating with a blood inlet (9) and a blood outlet (10) are disposed to make blood flow in multiple paths within a housing (1), and each bundle of hollow fibers (2) is arranged so as to be substantially perpendicular to the direction of blood flow. In spite of its compact construction, this blood oxygenator has high oxygen and carbon dioxide exchange rates per unit of membrane even when used in the gas exchange of blood having high flow rate, exhibits only a small pressure toss, and causes little channeling of the blood gas. Moreover, it is easy to manufacture because of its relatively simple structure.

8. 发明授权

EP0008536B1 Process for manufacturing regenerated cellulose hollow fiber 失效
标题翻译：制造再生纤维素中空纤维的方法
公开(公告)号：EP0008536B1
公开(公告)日：1984-08-01
申请号：EP79301711.2
申请日：1979-08-21
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Ishida, Masamichi , Kamo, Jun , Takemura, Toru , Minami, Shunsuke , Kamada, Kensuke
IPC分类号： D01D5/24 , B01D13/04
CPC分类号： B01D71/10 , B01D69/08 , D01D5/24

9. 发明授权

EP0160268B1 Blood oxygenator using a hollow-fiber membrane 失效
标题翻译：使用中空纤维膜的血液氧化剂
公开(公告)号：EP0160268B1
公开(公告)日：1991-12-18
申请号：EP85104974.2
申请日：1985-04-24
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Takemura, Tohru , Nakashima, Atushi , Yoshida, Haruhiko , Kamo, Jun , Hamada, Eiichi
IPC分类号： A61M1/18
CPC分类号： A61M1/1698 , A61M1/1625 , A61M1/1629 , B01D63/02 , B01D63/04 , B01D2313/08 , B01D2313/38 , B01D2319/06 , Y10S128/03

10. 发明授权

EP0176651B1 Heat exchanger and blood oxygenating device furnished therewith 失效
标题翻译：热交换器和血液氧化装置
公开(公告)号：EP0176651B1
公开(公告)日：1990-01-03
申请号：EP85101629.5
申请日：1985-02-14
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Hamada, Eiichi , Yoshihara, Toshio , Nakashima, Atushi , Kamo, Jun
IPC分类号： A61M1/18 , A61M1/36
CPC分类号： F28F21/062 , A61M1/1625 , A61M1/1627 , A61M1/1629 , A61M1/1698 , B01D63/02 , B01D63/024 , B01D2313/38 , Y10S128/03

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