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    • 1. 发明专利
    • Method for manufacturing high nitrogen steel
    • 制造高氮钢的方法
    • JP2014128822A
    • 2014-07-10
    • JP2012287831
    • 2012-12-28
    • Kobe Steel Ltd株式会社神戸製鋼所
    • KAMIYAMA TAIICHIFUKUDA HIRONARINAGAO MOTOHIROARAI HIROTADADEURA TETSUSHIISHIDA HITOSHI
    • B22D18/06B22D7/00
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing an ingot containing nitrogen of 0.02 mass% or more under a reduced pressure atmosphere.SOLUTION: A high nitrogen steel manufacturing method of the present invention is provided for manufacturing an ingot containing nitrogen N of 0.02 mass% or more by injecting a molten steel into a casting mold under a reduced pressure atmosphere. In the method, a vacuum casting is performed such that a degree of vacuum A (torr) in casting, a casting time t (min), a nitrogen concentration [N](mass%) in the molten steel before injecting the molten steel into the casting mold, and a target nitrogen concentration [N](mass%) at the completion of casting satisfy A≥(a×[N]-b×[N]), where (a) is -0.062t+3.437t+300.820 and b is -0.0655t+3.7216t+58.528.
    • 要解决的问题:提供一种在减压气氛下制造含有0.02质量%以上的氮的锭的方法。解决方案:提供本发明的高氮钢制造方法,用于制造含氮量为0.02的锭 通过在减压气氛下将钢水注射到铸模中,质量%以上。 在该方法中,进行真空铸造,使得在将钢水注入钢水之前的铸造中的真空度A(torr),铸造时间t(min),氮浓度[N](质量%)) 铸造完成时的目标氮浓度[N](质量%)满足A≥(a×[N] -b×[N]),其中(a)为-0.062t + 3.437t + 300.820,b为-0.0655t + 3.7216t + 58.528。
    • 4. 发明专利
    • Steel material superior in toughness of weld heat-affected zone and fatigue characteristics of base metal, and method for manufacturing the same
    • 焊接热影响区域的钢质材料及其基体的疲劳特性及其制造方法
    • JP2010209433A
    • 2010-09-24
    • JP2009058630
    • 2009-03-11
    • Kobe Steel Ltd株式会社神戸製鋼所
    • KANEKO MASAHITODEURA TETSUSHISUGIMURA TOMOKO
    • C22C38/00B21B3/00C21C7/04C21C7/06C21D8/02C22C38/14C22C38/58
    • PROBLEM TO BE SOLVED: To provide a steel material which shows superior HAZ toughness even when having been welded at such a high heat input as an amount of 50 kJ/mm or more, and besides, has improved fatigue characteristics of a base metal itself. SOLUTION: The steel material has following characteristics of: (a) including an oxide containing Zr, a REM and Ca; (b) having the composition satisfying 5-50% ZrO 2 , 10-50% oxide of a REM and 5.0-50% CaO, when the compositions of all oxides have been measured and converted into the composition of single oxide; (c) containing 120 pieces per 1 mm 2 or more of oxides with circle equivalent diameters of 0.1-2.0 μm, and 5 pieces per 1 mm 2 or less of oxides with circle equivalent diameters of more than 5.0 μm; (d) having a metal structure in which an average circle equivalent diameter D of crystal grains that are surrounded by a large-angle grain boundary having a crystal orientation difference of 15 degrees or more is 25 μm or less, and a ratio R of random grain boundaries occupying in the large-angle grain boundaries is 70 area% or less, when observed with an EBSP method; and (e) having an average hardness of 170 Hv or more. COPYRIGHT: (C)2010,JPO&INPIT
    • 解决的问题:为了提供即使在以50kJ / mm以上的量的高热输入下进行焊接也显示出优异的HAZ韧性的钢材,此外,具有改善的基体的疲劳特性 金属本身 钢材具有以下特征:(a)包括含有Zr,REM和Ca的氧化物; (b)当所有氧化物的组成被测量并转化为组合物时,具有满足5-50%ZrO 2 SBR,10-50%REM的氧化物和5.0-50%的CaO的组成 的单一氧化物; (c)每1毫米 2 或更多的圆当量直径为0.1-2.0微米的氧化物和每1毫米SP 2以下的氧化物含有120个氧化物, 圆当量直径大于5.0μm; (d)具有由结晶取向差为15度以上的大角度晶界包围的晶粒的平均圆当量直径D为25μm以下的金属结构,以及随机的 当用EBSP法观察时,占据大角度晶界的晶界为70面积%以下; 和(e)具有170Hv或更高的平均硬度。 版权所有(C)2010,JPO&INPIT
    • 5. 发明专利
    • High-tensile-strength thick steel plate to be welded having superior toughness of base metal
    • 要焊接的高强度厚钢板具有基体金属的超级韧性
    • JP2009084656A
    • 2009-04-23
    • JP2007258326
    • 2007-10-02
    • Kobe Steel Ltd株式会社神戸製鋼所
    • NAKO HIDENORIOKAZAKI YOSHIOMIOTA HIROMIDEURA TETSUSHISUGIMURA TOMOKO
    • C22C38/00C21D8/02C22C38/14C22C38/58
    • PROBLEM TO BE SOLVED: To provide a high-tensile-strength thick steel plate to be welded having a superior toughness of a base metal.
      SOLUTION: This high-tensile-strength thick steel plate has a chemical composition comprising, by mass%, 0.02 to 0.12% C, 0 to 0.25% Si, 1.0 to 2.0% Mn, 0 to 0.03% P, 0 to 0.02% S, 0 to 0.050% Al, 0.005 to 0.100% Ti, 0.0001 to 0.0500% REM, 0.0001 to 0.0500% Zr, 0.0005 to 0.0100% Ca, 0.0040 to 0.0300% N, 0.0005 to 0.0100% O and the balance Fe with unavoidable impurities. A ratio of oxides of REM
      2 O
      3 , ZrO
      2 , CaO and MnO calculated based on the concentrations of elements such as REM, Zr, Ca and Mn which form the oxides in the steel is 10 to 50% for REM
      2 O
      3 , 5 to 50% for ZrO
      2 , 5 to 50% for CaO, and 1 to 20% for MnO. When a cross section of the steel material is observed, the steel plate includes Ti-containing nitrides with circle equivalent diameters of less than 0.10 μm in an amount of 5.0×10
      6 pieces/mm
      2 or more, Ti-containing nitrides with circle equivalent diameters of 0.10 to 1.0 μm in an amount of 1.0×10
      4 pieces/mm
      2 or less, and Ti-containing nitrides with circle equivalent diameters of more than 1.0 μm in an amount of 5 pieces/mm
      2 or less. The area rate of MA to be observed in the cross section of the steel material is 5.0% or less.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有优异的贱金属韧性的待焊接的高强度高强度钢板。 解决方案:该高拉伸强度的厚钢板具有以质量%计含有0.02〜0.12%的C,0〜0.25%的Si,1.0〜2.0%的Mn,0〜0.03%的P,0〜 0.02%S,0〜0.050%的Al,0.005〜0.100%的Ti,0.0001〜0.0500%的REM,0.0001〜0.0500%的Zr,0.0005〜0.0100%的Ca,0.0040〜0.0300%的N,0.0005〜0.0100%的O, 不可避免的杂质。 基于REM,Zr等元素的浓度计算的REM 2 3 ,ZrO 2 SB 3,CaO和MnO的氧化物比例, 在钢中形成氧化物的Ca和Mn为REM 2 3 为10〜50%,ZrO 2 SBB为5〜50% CaO为5〜50%,MnO为1〜20%。 当观察到钢材的横截面时,钢板包括5.0×10 -6个/ mm 2的圆当量直径小于0.10μm的含钛氮化物 以上,含有1.0×10 4 / SP以上的圆当量直径为0.10〜1.0μm的含钛氮化物或更小,以及 具有5个/ mm 2以上的圆当量直径大于1.0μm的含钛氮化物以下。 在钢材的截面中观察到的MA的面积率为5.0%以下。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Steel material with excellent toughness in weld heat-affected zone, and its manufacturing method
    • 焊接热影响区具有优异韧性的钢材及其制造方法
    • JP2008291347A
    • 2008-12-04
    • JP2008044870
    • 2008-02-26
    • Kobe Steel Ltd株式会社神戸製鋼所
    • DEURA TETSUSHISUGIMURA TOMOKOOKAZAKI YOSHIOMINAKO HIDENORIOTA HIROMISUITO HIDEAKIINOUE AKIRA
    • C22C38/00C21C7/04C21C7/06C22C38/14C22C38/58
    • PROBLEM TO BE SOLVED: To provide a steel material in which toughness in HAZ (weld heat-affected zone) is improved and variations in the HAZ toughness are reduced and also to provide its manufacturing method.
      SOLUTION: With respect to a steel material which has a composition containing 0.01 to 0.2% C, ≤0.5% (not including 0%) Si, ≤2.5% (not including 0%) Mn, ≤0.03% (not including 0%) Ti and ≤0.01% (not including 0%) N, also containing ≤0.02% (not including 0%) P, ≤0.015% (not including 0%) S and ≤0.01% (including 0%) Al, further containing 0.0010 to 0.1% REM and 0.001 to 0.05% Zr and having the balance iron with inevitable impurities, the above REM and Zr are regulated in such a way that they are contained in inclusions and solid-solution REM and solid-solution Zr become ≤0.0010% (including 0%) and ≤0.0010% (including 0%), respectively.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供HAZ(焊接热影响区)的韧性提高,HAZ韧性的变化降低的钢材,也可以提供其制造方法。 < P>解决方案:对于含有0.01至0.2%C,≤0.5%(不包括0%)Si,≤2.5%(不包括0%)Mn,≤0.03%(不包括 0%)Ti和≤0.01%(不含0%)N,还含有≤0.02%(不包括0%)P,≤0.015%(不包括0%)S和≤0.01%(包括0%)Al, 进一步含有0.0010〜0.1%的REM和0.001〜0.05%的Zr,余量为铁与不可避免的杂质,上述REM和Zr的调节方式使其含有夹杂物,固溶体REM和固溶体Zr成为 ≤0.0010%(含0%),≤0.0010%(含0%)。 版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Steel material excellent in toughness and fatigue crack progress resistance of welding heat-affected zone, and producing method therefor
    • 焊接热影响区的韧性和疲劳裂纹耐腐蚀性优良的钢材及其制造方法
    • JP2008088485A
    • 2008-04-17
    • JP2006269023
    • 2006-09-29
    • Kobe Steel Ltd株式会社神戸製鋼所
    • OGAKI SEIICHIDEURA TETSUSHI
    • C22C38/00B22D1/00B22D11/00B22D11/108C21C7/04C21D8/02C22C38/38C22C38/58
    • PROBLEM TO BE SOLVED: To provide a steel material having excellent HAZ toughness and improving fatigue crack progress resistance by restraining the fatigue crack progress speed under repeated stress.
      SOLUTION: The steel material comprises 0.03-0.18% C, ≤0.5% Si, 0.9-2.0% Mn, 0.003-0.01 N, and satisfying ≤0.02% P, ≤0.015% S, ≤0.01% Al, and containing 0.001-0.1% REM and/or 0.0003-0.02% Ca and 0.001-0.05% Zn, and the balance Fe with inevitable impurities, wherein; REM and/or Ca and Zn are contained as a single oxide or a compound oxide and also, a composite structure composed of a soft phase and a hard phase, is contained in this steel material, and a ratio (Hv
      1 /Hv
      2 ) of Vickers hardness Hv
      1 of the hard phase and Vickers hardness Hv
      2 of the soft phase, is 1.5-5.0, and the grain diameter of the soft phase is ≤20 μm diameter equivalent to the circle.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:通过抑制重复应力下的疲劳裂纹进行速度,提供具有优异的HAZ韧性并提高疲劳裂纹进行阻力的钢材。

      解决方案:钢材含有0.03-0.18%C,≤0.5%Si,0.9-2.0%Mn,0.003-0.01N,满足≤0.02%P,≤0.015%S,≤0.01%Al,含 0.001-0.1%REM和/或0.0003-0.02%Ca和0.001-0.05%Zn,余量为Fe与不可避免的杂质,其中; 在该钢材中含有REM和/或Ca和Zn作为单一氧化物或复合氧化物,并且还包含由软质相和硬相组成的复合结构,并且比率(Hv 1 < /软硬相的维氏硬度Hv 1 ,软相的维氏硬度Hv 2 为1.5〜 5.0,软相的粒径相当于圆的直径≤20μm。 版权所有(C)2008,JPO&INPIT

    • 9. 发明专利
    • Low yield ratio high tensile steel having excellent toughness of weld heat-affected zone and manufacturing method therefor
    • 焊接热影响区具有优异韧性的低屈服强度高钢及其制造方法
    • JP2007247004A
    • 2007-09-27
    • JP2006073303
    • 2006-03-16
    • Kobe Steel Ltd株式会社神戸製鋼所
    • IMAMURA HIROKIDEURA TETSUSHI
    • C22C38/00C21C7/04C21C7/06C21D8/02C22C38/28C22C38/58
    • PROBLEM TO BE SOLVED: To provide a low yield ratio high tensile steel having excellent toughness of a weld heat-affected zone.
      SOLUTION: The low yield ratio high tensile steel having the excellent toughness of the weld heat-affected zone contains 0.03 to 0.2% C, ≤0.5% (not inclusive of 0%) Si, 1.0 to 2.0% Mn, and ≤0.01% (not inclusive of 0%) N, satisfies ≤0.02% (not inclusive of 0%) P, ≤0.015% (not inclusive of 0%) S, and ≤0.01% (not inclusive of 0%) Al, and contains 0.001 to 0.1% REM and/or 0.0003 to 0.005% Ca, and 0.001 to 0.05% Zr, and the balance iron and inevitable impurities, wherein when the composition of the entire oxide included in the steel is measured, the steel contains the oxide of the REM and/or CaO and ZrO
      2 and the ferrite fraction occupying in the entire structure is 4 to 24% and the balance bainite structure and/or martensite structure.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供具有优异的焊接热影响区的韧性的低屈服比的高张力钢。 解决方案:焊接热影响区具有优异韧性的低屈服比高张力钢包含0.03-0.2%C,≤0.5%(不包括0%)Si,1.0-2.0%Mn和≤ 0.01%(不包括0%)N满足≤0.02%(不包括0%)P,≤0.015%(不包括0%)S,≤0.01%(不包括0%)Al,和 含有0.001〜0.1%的REM和/或0.0003〜0.005%的Ca和0.001〜0.05%的Zr,余量为铁和不可避免的杂质,其中,当测量钢中包含的全部氧化物的组成时,钢含有氧化物 的REM和/或CaO和ZrO 2 ,占整个结构的铁素体部分为4〜24%,平衡贝氏体组织和/或马氏体组织。 版权所有(C)2007,JPO&INPIT