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1. 发明授权

US5662786A Electrochemical sensor 失效
标题翻译：电化学传感器
公开(公告)号：US5662786A
公开(公告)日：1997-09-02
申请号：US807163
申请日：1991-12-13
申请人： Karl-Hermann Friese , Helmut Weyl , Werner Wieland , Hans-Martin Wiedenmann
发明人： Karl-Hermann Friese , Helmut Weyl , Werner Wieland , Hans-Martin Wiedenmann
IPC分类号： G01N27/407 , G01N27/409
CPC分类号： G01N27/4075
摘要： The electrochemical sensor for determination of an oxygen content of exhaust gases, includes a probe element including a tube made from a raw material mixture consisting essentially of an ionically conductive solid electrolyte; an outer electrode located on the outer surface of the tube; a substantially pore-free conductor strip layer located on the outer surface, connected to the outer electrode, and extending toward the open end, the conductor strip layer having a portion in close proximity to the tube open end; and a substantially pore-free cover layer hermetically covering at least the portion of the pore-free conductor strip layer in close proximity to the open end of the tube, the cover layer being made from a cover layer material including the ionically conductive solid electrolyte. The cover layer material advantageously a sintering activity which is at least equal to that of the raw material mixture from which the tube is made. The conductor strip layer consists essentially of a ceramic supporting framework and an electron-conducting material. The ceramic ceramic binder has at least the same sintering activity as the cover layer material.
摘要翻译：用于确定废气氧含量的电化学传感器包括探针元件，其包括由基本上由离子导电固体电解质组成的原料混合物制成的管; 位于所述管的外表面上的外电极; 位于所述外表面上的基本上无孔的导体条带层，其连接到所述外电极并且朝向所述开口端延伸，所述导体带层具有紧邻所述管开口端的部分; 以及基本无孔的覆盖层，其至少密封地覆盖无孔导体带层的靠近管的开口端的部分，覆盖层由包括离子导电固体电解质的覆盖层材料制成。覆盖层材料有利地是至少等于制造管的原料混合物的烧结活性。导体带层基本上由陶瓷支撑框架和电子传导材料组成。陶瓷陶瓷粘合剂具有与覆盖层材料至少相同的烧结活性。

2. 发明授权

US5846391A Seal for a sensor element of a gas sensor 失效
标题翻译：气体传感器传感器元件的密封
公开(公告)号：US5846391A
公开(公告)日：1998-12-08
申请号：US836425
申请日：1997-04-29
申请人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann , Anton Hans
发明人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann , Anton Hans
IPC分类号： G01N27/409 , G01N27/407
CPC分类号： G01N27/4078
摘要： A seal for a sensor element for a gas sensor for determining the oxygen content in a gas to be measured including exhaust gases of internal combustion engines, the seal including a metallic housing having defined therein a longitudinal bore; a sensor element inserted into the longitudinal bore; and a sealing arrangement provided in the longitudinal bore, surrounding at least a portion of the sensor element, and comprised of at least one seal element comprised of steatite and an additional seal element comprised of boron nitride arranged in contact with one another and in a stack having a side near the gas to be measured so that, when there is one seal element comprised of steatite, the one seal element comprised of steatite is positioned on the side of the stack near the gas to be measured, and so that, when there are two seal elements comprised of steatite, the additional seal element is positioned between the two seal elements comprised of steatite, wherein the at least one seal element comprised of steatite and the additional seal element comprised of boron nitride are inserted into the longitudinal bore of the housing as deformable rings and are pressed-in therein, and wherein, during the pressing-in, the deformable rings are deformed in such a way that the at least one seal element comprised of steatite and the additional seal element comprised of boron nitride are pushed against the sensor element and the housing.
摘要翻译： PCT No.PCT / DE96 / 00567 Sec。 371日期1997年04月29日 102（e）日期1997年4月29日PCT 1996年3月21日PCT公布。公开号WO97 / 08542 日期1997年3月6日用于气体传感器的传感器元件的密封件，用于确定包括内燃机废气的待测气体中的氧含量，所述密封件包括金属壳体，其中限定有纵向孔; 插入纵向孔中的传感器元件; 以及设置在所述纵向孔中的密封装置，围绕所述传感器元件的至少一部分，并且包括至少一个由滑石组成的密封元件和由氮化硼组成的另外的密封元件，所述氮化硼彼此接触并且在堆叠具有靠近要测量的气体的一侧，使得当存在由滑石组成的一个密封元件时，由滑石组成的一个密封元件位于靠近待测量气体的堆叠侧，并且当那里是由滑石组成的两个密封元件，附加的密封元件位于由滑石组成的两个密封元件之间，其中由滑石组成的至少一个密封元件和由氮化硼组成的另外的密封元件被插入到壳体作为可变形环并被压入其中，并且其中，在压入期间，可变形环以这样的方式变形，使得至少一个由滑石组成的气体元件和由氮化硼组成的另外的密封元件被推靠在传感器元件和壳体上。

3. 发明授权

US5795454A Seal for a sensor element of a gas sensor 失效
标题翻译：气体传感器传感器元件的密封
公开(公告)号：US5795454A
公开(公告)日：1998-08-18
申请号：US569074
申请日：1995-12-04
申请人： Karl-Hermann Friese , Helmut Weyl , Romuald Fries , Hans-Martin Wiedenmann , Anton Hans
发明人： Karl-Hermann Friese , Helmut Weyl , Romuald Fries , Hans-Martin Wiedenmann , Anton Hans
IPC分类号： G01N27/409 , G01N27/12 , G01N27/407 , F16J15/14
CPC分类号： G01N27/4078 , G01N27/407 , G01N27/4077 , Y10S277/936 , Y10S277/938 , Y10S277/939 , Y10S277/941 , Y10S277/943
摘要： A seal for a sensor element of a gas sensor for determining the oxygen content in gases including exhaust gases of an internal combustion engine, which seal seals the sensor element in a longitudinal bore of a housing, the seal including a sealing stack which is positioned within the longitudinal bore of the housing and around the sensor element in use and which is comprised of two sealing bodies and an additional seal positioned between the two sealing bodies. The two sealing bodies are comprised of a pre-sintered ceramic material. The additional seal is comprised of a pre-pressed powder material and has a porosity which is lower than that of the two sealing bodies. The two sealing bodies and the additional seal are compressed together within the longitudinal bore in use, whereby at least the additional seal is deformed so that the sensor element is sealed in a gap-free manner within the longitudinal bore. The pre-pressed powder material of the additional seal may consist essentially of a ductile metal, which may be one of nickel or copper, or graphite which may be fiber-reinforced.
摘要翻译： PCT No.PCT / DE94 / 00537 Sec。 371 1995年12月4日第 102（e）日期1995年12月4日PCT 1994年5月11日PCT公布。公开号WO94 / 29710 日期1994年12月22日用于确定包括内燃机的废气在内的气体中的氧含量的气体传感器的传感器元件的密封件，该密封件将传感器元件密封在壳体的纵向孔中，所述密封件包括密封件堆叠，其位于壳体的纵向孔内并且在使用中围绕传感器元件，并且由两个密封体和位于两个密封体之间的附加密封件组成。两个密封体由预烧结的陶瓷材料组成。附加密封件由预压粉末材料组成，并且具有低于两个密封体的孔隙率。两个密封体和附加密封件在使用中在纵向孔内压缩在一起，由此至少附加的密封件变形，使得传感器元件以无间隙的方式密封在纵向孔内。附加密封件的预压粉末材料可以由可以是镍或铜之一的延性金属或可以是纤维增强的石墨组成。

4. 发明授权

US06408680B1 Sensor and method for the manufacture 有权
公开(公告)号：US06408680B1
公开(公告)日：2002-06-25
申请号：US09171717
申请日：1999-04-08
申请人： Karl-Hermann Friese , Heinz Geier , Helmut Weyl , Hans-Martin Wiedenmann
发明人： Karl-Hermann Friese , Heinz Geier , Helmut Weyl , Hans-Martin Wiedenmann
IPC分类号： G01N2712
摘要： A sensor for determining an oxygen content in an exhaust gas of an internal combustion engine includes a receptacle, arranged in a longitudinal bore of a metal housing, for a sensing element. The sensing element is received in the receptacle in a gas-tight fashion via a sensing element seal, which includes a glass seal. The receptacle has a measured-gas-side ceramic shaped element and a connector-side ceramic shaped element, which are arranged axially one behind the other. A cavity into which the glass seal is pressed while hot is configured between the two ceramic shaped elements.

5. 发明授权

US6164120A Detector and method for the production thereof 失效
标题翻译：检测器及其制造方法
公开(公告)号：US6164120A
公开(公告)日：2000-12-26
申请号：US171688
申请日：1999-02-22
申请人： Karl-Hermann Friese , Heinz Geier , Helmut Weyl , Hans-Martin Wiedenmann
发明人： Karl-Hermann Friese , Heinz Geier , Helmut Weyl , Hans-Martin Wiedenmann
IPC分类号： G01N27/409 , G01N27/12 , G01N27/407
CPC分类号： G01N27/4078 , G01N27/407
摘要： A sensor for determining an oxygen level in an exhaust gas of an internal combustion engine includes a receptacle arranged in a longitudinal bore of a metallic enclosure for a sensor element. The sensor element is accommodated in a gas-tight manner using a sensor element seal. The receptacle has a measured gas-side ceramic molded component and a connection-side ceramic molded component, which are arranged one behind the other axially. A hollow space is formed between the measured gas-side ceramic molded component and the connection-side ceramic molded component, in which a metallic sealing element is hot-pressed.
摘要翻译： PCT No.PCT / DE97 / 02916 Sec。一九九九年二月二十二日 102（e）1999年2月22日PCT 1997年12月16日PCT公布。第WO98 / 38500号公报日期1998年9月3日用于确定内燃机排气中的氧气含量的传感器包括布置在用于传感器元件的金属外壳的纵向孔中的容器。使用传感器元件密封件以气密方式容纳传感器元件。容器具有一个沿轴向布置的测量气体侧陶瓷成型部件和连接侧陶瓷成形部件。在被测量的气体侧陶瓷成型部件和连接侧陶瓷成型部件之间形成中空空间，其中金属密封元件被热压。

6. 发明授权

US06347543B1 Measuring sensor and method for its fabrication 失效
标题翻译：测量传感器及其制造方法
公开(公告)号：US06347543B1
公开(公告)日：2002-02-19
申请号：US09434667
申请日：1999-11-05
申请人： Heinz Geier , Helmut Weyl , Hans-Martin Wiedenmann , Karl-Hermann Friese
发明人： Heinz Geier , Helmut Weyl , Hans-Martin Wiedenmann , Karl-Hermann Friese
IPC分类号： G01N2704
CPC分类号： G01N27/4078 , G01N27/407 , Y10T29/49211
摘要： A measuring sensor, in particular, for determining the oxygen content in exhaust gases of internal combustion engines, includes a ceramic molding arranged in a metal housing for the accommodation of a sensor element, in particular, planar, the sensor element being sealed by a seal element made of warm-deformable temperature-resistant material. The molded housing is designed in one piece and has a cylindrically shaped longitudinal hole on the connector side, around the sensor element, and the seal element is compressed between a first compressing element on the measuring-gas side and a second compressing element on the connector side, such that it tightly encloses the sensor element and hermetically seals the sensor element with respect to the molded housing.
摘要翻译：特别地，用于确定内燃机排气中的氧含量的测量传感器包括布置在金属壳体中用于容纳传感器元件，特别是平面的陶瓷模制件，传感器元件由密封件元件由耐温变形的耐温材料制成。模制壳体被设计成一体并且在连接器侧上具有围绕传感器元件的圆柱形纵向孔，并且密封元件在测量气体侧的第一压缩元件和连接器上的第二压缩元件之间被压缩使得其紧密地包围传感器元件并相对于模制壳体气密地密封传感器元件。

7. 发明授权

US6096181A Sealing element for a sensor 失效
标题翻译：用于传感器的密封元件
公开(公告)号：US6096181A
公开(公告)日：2000-08-01
申请号：US91198
申请日：1998-06-10
申请人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann , Anton Hans
发明人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann , Anton Hans
IPC分类号： G01N27/409 , G01N27/407
CPC分类号： G01N27/4078 , G01N27/4077 , Y10S277/936 , Y10S277/939 , Y10S277/94 , Y10S277/941
摘要： An electrochemical sensor for determining the oxygen content of gases of internal combustion engines includes a ceramic element that is inserted with a sealing ring into a housing. The sealing ring is built up from different metal layers. The arrangement of the metal layers proceeds from a metal support which is composed of a steel alloy. The sealing ring is covered on both sides with a roll-clad copper layer. A nickel layer can additionally be arranged beneath the copper layer.
摘要翻译： PCT No.PCT / DE97 / 02197 Sec。 371日期1999年1月6日 102（e）1999年1月6日PCT PCT 1997年9月26日PCT公布。公开号WO98 / 15820PC 日期1998年04月16日用于确定内燃机气体的氧含量的电化学传感器包括一个陶瓷元件，其中密封环插入壳体中。密封环由不同的金属层构成。金属层的布置从由钢合金构成的金属支撑体进行。密封圈两侧均覆盖有卷绕铜层。镍层可另外设置在铜层的下方。

8. 发明授权

US5670032A Electro-chemical measuring sensor with a potential-free sensor element and method for producing it 失效
标题翻译：具有无电位传感器元件的电化学测量传感器及其制造方法
公开(公告)号：US5670032A
公开(公告)日：1997-09-23
申请号：US592381
申请日：1996-01-25
申请人： Karl-Hermann Friese , Helmut Weyl , Siegfried Nees , Hans-Martin Wiedenmann
发明人： Karl-Hermann Friese , Helmut Weyl , Siegfried Nees , Hans-Martin Wiedenmann
IPC分类号： G01N27/409 , G01N27/407 , G01N27/26
CPC分类号： G01N27/407 , G01N27/4078
摘要： An electro-chemical measuring sensor (10) for determining the oxygen content of gases, in particular for determining the oxygen content in exhaust gases of internal combustion engines, with a potential-free disposed sensor element (14). The sensor element (14) has an oxygen-ion-conducting solid electrolyte body (23), preferably in the shape of a pipe or tube closed at one end, which has an exterior electrode (25) disposed on the exterior surface with a strip conductor (27) on the side toward the contact and also extending on the exterior surface, and which is inserted by means of a sealing ring (20) in a metal housing (11). The sensor element (14) has an electrically insulating layer (21) at least in the area of the sealing ring (20), which covers at least the strip conductor (27) in the direction toward the housing (11). The insulating layer (21) is formed from a mixture of a crystalline, non-metallic material and a glass-forming material. In the course of production the insulating layer (21) is subjected to a thermal treatment above the melting temperature of the glass-forming material, in the course of which the insulating layer (21) forms a glaze filled with the crystalline, non-metallic material.
摘要翻译： PCT No.PCT / DE94 / 00791 Sec。 371日期：1996年1月25日 102（e）日期1996年1月25日PCT 1994年7月9日PCT公布。公开号WO95 / 04273 日期1995年2月9日，一种用于确定气体氧含量的电化学测量传感器（10），特别是用于确定内燃机排气中氧含量的电化学测量传感器（10）。传感器元件（14）具有氧离子传导固体电解质体（23），优选地为在一端封闭的管或管的形状，其具有设置在外表面上的外部电极（25）导体（27），并且还在外表面上延伸，并且通过密封环（20）插入到金属外壳（11）中。传感器元件（14）至少在密封环（20）的区域中具有电绝缘层（21），其至少在朝向壳体（11）的方向上覆盖带状导体（27）。绝缘层（21）由结晶，非金属材料和玻璃形成材料的混合物形成。在制造过程中，将绝缘层（21）进行高于玻璃形成材料的熔化温度的热处理，其中绝缘层（21）形成填充有结晶非金属的釉料材料。

9. 发明授权

US5486279A Electrochemical measuring probe 失效
标题翻译：电化学测量探头
公开(公告)号：US5486279A
公开(公告)日：1996-01-23
申请号：US227568
申请日：1994-04-14
申请人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann
发明人： Karl-Hermann Friese , Helmut Weyl , Hans-Martin Wiedenmann
IPC分类号： G01N27/407
CPC分类号： G01N27/4075 , G01N27/4077
摘要： An electrochemical measuring probe for determining the oxygen content of gases, in particular of exhaust gases of internal combustion engines, whose measuring probe body consists essentially of a solid electrolyte, for example stabilised ZrO.sub.2 and whose electrode exposed to the gas to be measured is a cermet electrode which is coated with a finely porous ion-conducting covering layer composed of an ion-conducting supporting matrix material having no sintering activity of the type standard for cermet electrodes the covering layer is covered by a porous protective layer. The ion-conducting porous covering layer appreciably increases the activity of the cermet electrode.
摘要翻译：用于确定气体，特别是内燃机废气的氧含量的电化学测量探针，其测量探针主体基本上由固体电解质组成，例如稳定的ZrO 2，并且其暴露于待测气体的电极是金属陶瓷涂覆有不含金属陶瓷电极类型标准物的烧结活性的离子传导性支撑基体材料的细孔离子传导性覆盖层的电极覆盖层被多孔保护层覆盖。离子导电多孔覆盖层显着提高了金属陶瓷电极的活性。

10. 发明授权

US5423973A Exhaust gas sensor and method of producing the same 失效
标题翻译：废气传感器及其制造方法
公开(公告)号：US5423973A
公开(公告)日：1995-06-13
申请号：US211083
申请日：1994-06-20
申请人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Helmut Weyl
发明人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Helmut Weyl
IPC分类号： G01N27/12 , G01N27/407 , G01N27/409 , G01N27/41 , G01N27/26
CPC分类号： G01N27/4075
摘要： An exhaust gas sensor which is exposed to exhaust gas, includes a measuring electrode; and a porous ceramic coating provided on the measuring electrode and comprised of at least two layers, a first porous ceramic layer which is provided on the measuring electrode and at least a second porous ceramic layer which is provided on the first porous ceramic layer and which is directly exposed to the exhaust gas, wherein the first porous ceramic layer contains getter substances for removal of substances that are harmful to the measuring electrode, and wherein the second porous ceramic layer is provided with one of a diffusion resistance or a catalytic effect relative to exhaust gas constituents such that, at the boundary of the first and second porous ceramic layers, a gas composition is present in use which is comprised of one of oxidizable or reducible gas constituents and which sets a control position for the exhaust gas sensor.
摘要翻译： PCT No.PCT / DE92 / 00714 Sec。 371日期：1994年6月20日 102（e）日期1994年6月20日PCT提交1992年8月27日PCT公布。公开号WO93 / 06472 日本1997年4月1日。一种暴露于废气的排气传感器，包括测量电极; 以及设置在所述测量电极上并且包括至少两层的多孔陶瓷涂层，设置在所述测量电极上的第一多孔陶瓷层和设置在所述第一多孔陶瓷层上的至少第二多孔陶瓷层，直接暴露于废气中，其中第一多孔陶瓷层含有用于除去对测量电极有害的物质的吸气剂物质，并且其中第二多孔陶瓷层具有相对于排气的扩散阻力或催化作用之一气体成分，使得在第一和第二多孔陶瓷层的边界处，存在使用中的气体组合物，其由可氧化或可还原的气体成分之一组成，并且设置用于排气传感器的控制位置。

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