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1. 发明授权

US06838175B2 Carbon microrod and method of producing the same 失效
标题翻译：碳微球及其制造方法
公开(公告)号：US06838175B2
公开(公告)日：2005-01-04
申请号：US10058301
申请日：2002-01-30
申请人： Kaoru Katoh , Masahiro Yamada , Hiroko Kaneko , Yoshihisa Suda
发明人： Kaoru Katoh , Masahiro Yamada , Hiroko Kaneko , Yoshihisa Suda
IPC分类号： B81B7/02 , B01J20/20 , C01B31/02 , C04B35/52 , C04B35/524 , C04B35/634 , D01F9/12 , B32B9/00
CPC分类号： C04B35/524 , B01J20/20 , C04B35/522 , C04B35/632 , C04B35/634 , C04B2235/425 , C04B2235/48 , C04B2235/6021 , C04B2235/94 , C04B2235/96 , D01F9/12 , Y10T428/298 , Y10T428/30
摘要： A carbon microrod that holds a fine object by chemically adsorbing the object on the surface to make a dynamic measurement possible. An organic substance that leaves, after firing, glassy carbon that hardly becomes graphite, such as a chlorinated vinyl chloride resin, is mixed with a fine graphite powder having an average particle size of 1 μm, and the mixture is extrusion molded with a die having a diameter of 50 μm; the molded article is fired to give a carbon microrod comprising glassy carbon and crystalline carbon.
摘要翻译：通过化学吸附表面上的物体来保持细微物体以进行动态测量的碳微轨道。在烧成之后，将几乎不成为石墨的玻璃碳（例如氯化氯乙烯树脂）与平均粒径为1μm的细石墨粉末混合，并将该混合物用具有直径50um; 将模塑制品烧制，得到包含玻璃碳和结晶碳的碳微球。

2. 发明授权

US08163556B2 Method of cell culture observation, carbon substrate for cell culture observation, and method for manufacture thereof 有权
标题翻译：细胞培养观察方法，细胞培养观察用碳底物及其制造方法
公开(公告)号：US08163556B2
公开(公告)日：2012-04-24
申请号：US11276263
申请日：2006-02-21
申请人： Yoshihisa Suda , Kunitaka Yamada , Hiroko Kaneko , Kaoru Katoh , Harumasa Okamoto
发明人： Yoshihisa Suda , Kunitaka Yamada , Hiroko Kaneko , Kaoru Katoh , Harumasa Okamoto
IPC分类号： C01B31/00 , B32B5/02 , B32B27/04 , G01N21/00 , C12N5/00
CPC分类号： C12N5/0068 , B82Y30/00 , C12N2533/10 , G01N21/6458 , Y10T436/11
摘要： The invention provides a substrate suitable for cell culture observation and a method of observation using the same. Crystalline carbon such as a graphite powder is mixed into a thermosetting resin such as a furan resin, and the mixture is molded in the shape of a sheet and carbonized to produce a carbon substrate; then, a cell is made to adhere to the carbon substrate, and the cell is caused to proliferate on the carbon substrate and observed using a microscope.
摘要翻译：本发明提供适用于细胞培养观察的底物和使用其的观察方法。将诸如石墨粉末的结晶碳混合到诸如呋喃树脂的热固性树脂中，并将该混合物模制成片状并碳化以产生碳基底; 然后，使电池附着在碳基板上，并使电池在碳基板上增殖并用显微镜观察。

3. 发明授权

US5218757A Tapered carbon microelectrode and process for production thereof 失效
标题翻译：碳化硅微电极及其制造方法
公开(公告)号：US5218757A
公开(公告)日：1993-06-15
申请号：US722545
申请日：1991-06-25
申请人： Hiroko Kaneko , Masahiro Yamada , Yukifumi Shigematsu , Wataru Mizutani , Akira Negishi , Takamasa Kawakubo , Yoshihisa Suda
发明人： Hiroko Kaneko , Masahiro Yamada , Yukifumi Shigematsu , Wataru Mizutani , Akira Negishi , Takamasa Kawakubo , Yoshihisa Suda
IPC分类号： G01Q60/00 , C01B31/02 , C04B35/52 , C04B41/00 , C04B41/85 , C25B11/04 , C25B11/12 , G01N27/30 , H01B1/12
CPC分类号： G01N27/308 , Y10T29/49117 , Y10T29/49169 , Y10T29/49171 , Y10T29/49224
摘要： A tapered carbon microelectrode is produced by extruding an organic material or a composition composed of crystalline carbon fine powder and an organic binder into a thin rod form, carbonizing said rod by calcining to produce a pure carbon thin rod, soaking the resulting thin rod as an anode in an electrolytic solution, gradually pulling up the thin rod while electrochemically oxidizing the tip portion of the thin rod. Then a lead wire is connected with the thick portion of the thin rod followed by coating all the surface except the conically sharp tip portion.The tapered carbon electrode can be used for various electrochemical measurements and scanning tunneling microscope.
摘要翻译：通过将有机材料或由结晶碳细粉末和有机粘合剂组成的组合物挤出成薄棒状制成锥形碳微电极，通过煅烧将所述棒碳化，生产纯碳细棒，将所得细棒浸泡成阳极在电解液中，逐渐拉起薄棒，同时电化学氧化细棒的尖端部分。然后，引线与薄棒的厚部连接，然后涂覆除了锥形尖端部分之外的所有表面。锥形碳电极可用于各种电化学测量和扫描隧道显微镜。

4. 发明授权

US5281319A Carbon micro-sensor electrode and method for preparing it 失效
公开(公告)号：US5281319A
公开(公告)日：1994-01-25
申请号：US905767
申请日：1992-06-29
申请人： Hiroko Kaneko , Masahiro Yamada , Akira Negishi , Takamasa Kawakubo , Yoshihisa Suda
发明人： Hiroko Kaneko , Masahiro Yamada , Akira Negishi , Takamasa Kawakubo , Yoshihisa Suda
IPC分类号： C12Q1/00 , G01N27/30 , G01N27/327 , G01N27/333 , G01N27/38 , G01N27/26
CPC分类号： C12Q1/001 , Y10S435/817
摘要： A carbon micro-sensor electrode is disclosed which is prepared by impregnating, adsorbing or chemically modifying a pure composite carbon wire having many micropores extending to its surface and interior with a reactant such as an enzyme, a metal complex compound, an organic compound or a metabolite; and a method for preparing this carbon micro-sensor electrode is also disclosed.The above-mentioned electrode can be used for a long period of time, since the reactant is received in the many micropores. Furthermore, after used, the electrode may be cut off to expose a new electrode surface, and this new electrode surface may be coated with a material which does not impede an electrode reaction, whereby the reactant can be prevented from flowing out. Thus, the carbon micro-sensor electrode of the present invention can be repeatedly utilized.

5. 发明授权

US5376251A Carbon micro-sensor electrode and method for preparing it 失效
标题翻译：碳微传感器电极及其制备方法
公开(公告)号：US5376251A
公开(公告)日：1994-12-27
申请号：US147780
申请日：1993-11-04
申请人： Hiroko Kaneko , Masahiro Yamada , Akira Negishi , Takamasa Kawakubo , Yoshihisa Suda
发明人： Hiroko Kaneko , Masahiro Yamada , Akira Negishi , Takamasa Kawakubo , Yoshihisa Suda
IPC分类号： C12Q1/00 , G01N27/30 , G01N27/327 , G01N27/333 , G01N27/38 , G01N27/26
CPC分类号： C12Q1/001 , Y10S435/817
摘要： A carbon micro-sensor electrode is disclosed which is prepared by impregnating, adsorbing or chemically modifying a pure composite carbon wire having many micropores extending to its surface and interior with a reactant such as an enzyme, a metal complex compound, an organic compound or a metabolite; and a method for preparing this carbon micro-sensor electrode is also disclosed.The above-mentioned electrode can be used for a long period of time, since the reactant is received in the many micropores. Furthermore, after used, the electrode may be cut off to expose a new electrode surface, and this new electrode surface may be coated with a material which does not impede an electrode reaction, whereby the reactant can be prevented from flowing out. Thus, the carbon micro-sensor electrode of the present invention can be repeatedly utilized.
摘要翻译：公开了一种碳微传感器电极，其通过浸渍，吸附或化学改性具有许多微孔的纯复合碳丝，其通过反应物例如酶，金属络合物，有机化合物或代谢物还公开了一种制备该碳微传感器电极的方法。上述电极可以长期使用，因为反应物被接收在许多微孔中。此外，在使用之后，可以切断电极以暴露新的电极表面，并且该新的电极表面可以涂覆有不妨碍电极反应的材料，由此可以防止反应物流出。因此，可以重复利用本发明的碳微传感器电极。

6. 发明申请

US20050214164A1 Optical measurement substrate and fabrication method for the same 失效
标题翻译：光学测量基板及其制造方法
公开(公告)号：US20050214164A1
公开(公告)日：2005-09-29
申请号：US10971702
申请日：2004-10-25
申请人： Yoshihisa Suda , Atsunori Satake , Kunitaka Yamada , Hiroko Kaneko , Kaoru Kato
发明人： Yoshihisa Suda , Atsunori Satake , Kunitaka Yamada , Hiroko Kaneko , Kaoru Kato
IPC分类号： G01N33/483 , C04B35/52 , C04B35/532 , G01N21/01 , G01N31/22
CPC分类号： C04B35/532 , B01J2219/00527 , B01J2219/00722 , B82Y30/00 , C04B35/522 , C04B2235/425 , C04B2235/48 , C04B2235/5248 , C04B2235/5276 , C04B2235/5288 , C04B2235/5436 , C04B2235/6025 , C04B2235/6581 , Y10T436/11
摘要： The invention provides at a relatively low cost a carbon substrate that is formed from an opaque material and that has an extremely flat surface so that optical measurements can be made on the substrate. Graphite powder with a particle size of 10 μm or less is mixed in a thermosetting resin such as a furan resin, and the mixture is molded into a sheet and calcined at 1400° C. in an inert atmosphere to produce a carbon substrate whose surface is then ground flat.
摘要翻译：本发明以相对较低的成本提供由不透明材料形成且具有非常平坦的表面的碳基底，以便能够在基底上进行光学测量。将粒径为10μm以下的石墨粉末在呋喃树脂等热固性树脂中混合，将该混合物成型为片材，在惰性气氛中在1400℃下煅烧，制成表面为然后平地。

7. 发明授权

US07264756B2 Optical measurement substrate and fabrication method for the same 失效
标题翻译：光学测量基板及其制造方法
公开(公告)号：US07264756B2
公开(公告)日：2007-09-04
申请号：US10971702
申请日：2004-10-25
申请人： Yoshihisa Suda , Atsunori Satake , Kunitaka Yamada , Hiroko Kaneko , Kaoru Kato
发明人： Yoshihisa Suda , Atsunori Satake , Kunitaka Yamada , Hiroko Kaneko , Kaoru Kato
IPC分类号： C01B31/00 , B32B5/02 , B32B27/04 , B32B27/12 , G01N21/00
CPC分类号： C04B35/532 , B01J2219/00527 , B01J2219/00722 , B82Y30/00 , C04B35/522 , C04B2235/425 , C04B2235/48 , C04B2235/5248 , C04B2235/5276 , C04B2235/5288 , C04B2235/5436 , C04B2235/6025 , C04B2235/6581 , Y10T436/11
摘要： The invention provides at a relatively low cost a carbon substrate that is formed from an opaque material and that has an extremely flat surface so that optical measurements can be made on the substrate. Graphite powder with a particle size of 10 μm or less is mixed in a thermosetting resin such as a furan resin, and the mixture is molded into a sheet and calcined at 1400° C. in an inert atmosphere to produce a carbon substrate whose surface is then ground flat.
摘要翻译：本发明以相对较低的成本提供由不透明材料形成且具有非常平坦的表面的碳基底，以便能够对基底进行光学测量。将粒径为10μm以下的石墨粉末在呋喃树脂等热固性树脂中混合，将该混合物成型为片材，在惰性气氛中在1400℃下煅烧，制成表面为然后平地。

8. 发明授权

US5380422A Micro-electrode and method for preparing it 失效
标题翻译：微电极及其制备方法
公开(公告)号：US5380422A
公开(公告)日：1995-01-10
申请号：US905768
申请日：1992-06-29
申请人： Akira Negishi , Hiroko Kaneko , Takamasa Kawakubo , Yoshihisa Suda
发明人： Akira Negishi , Hiroko Kaneko , Takamasa Kawakubo , Yoshihisa Suda
IPC分类号： G01N27/30 , G01N27/38 , G01N27/403 , G01N27/26
CPC分类号： G01N27/4035
摘要： A working micro-electrode with a reference electrode prepared by coating a working micro-electrode with an insulating material except a working electrode portion, forming a silver layer on the coated surface, and then changing a portion of the silver layer into silver chloride which is the reference electrode; a working micro-electrode with a reference electrode and a counter electrode prepared by coating the working micro-electrode with the reference electrode with an insulating material, and then forming the counter electrode on the surface of the insulating material; and methods for preparing these composite micro-electrodes.Heretofore, even if the working electrode is thinly constituted, the merit of the micro-electrode has not been sufficiently utilized, since the reference electrode and the counter electrode have been thick. However, the present invention can solve this problem and can facilitate experiments in which the micro-electrode is necessary.Since an inexpensive material such as carbon can be used, the working electrode may be constituted so as to be disposable or can be cut off the used portion to repeatedly obtain a new electrode surface. Therefore, the working electrode of the present invention is economical.
摘要翻译：具有参考电极的工作微电极，其通过用除了工作电极部分之外的绝缘材料涂覆工作微电极而制备，在涂覆表面上形成银层，然后将银层的一部分改变为氯化银，其为参比电极; 具有参考电极和对电极的工作微电极，其通过用绝缘材料涂覆具有参考电极的工作微电极，然后在绝缘材料的表面上形成对电极; 以及制备这些复合微电极的方法。迄今为止，即使工作电极被薄构成，由于参考电极和对电极较厚，所以微电极的优点尚未充分利用。然而，本发明可以解决这个问题，并且可以促进需要微电极的实验。由于可以使用诸如碳的便宜材料，工作电极可以被构造成一次性的或可以被切断使用部分以重复获得新的电极表面。因此，本发明的工作电极是经济的。

9. 发明授权

US5504029A Method of producing semiconductor integrated circuit device having memory cell and peripheral circuit MISFETs 失效
标题翻译：具有存储单元和外围电路MISFET的半导体集成电路器件的制造方法
公开(公告)号：US5504029A
公开(公告)日：1996-04-02
申请号：US254562
申请日：1994-06-06
申请人： Jun Murata , Yoshitaka Tadaki , Isamu Asano , Mitsuaki Horiuchi , Jun Sugiura , Hiroko Kaneko , Shinji Shimizu , Atsushi Hiraiwa , Hidetsugu Ogishi , Masakazu Sagawa , Masami Ozawa , Toshihiro Sekiguchi
发明人： Jun Murata , Yoshitaka Tadaki , Isamu Asano , Mitsuaki Horiuchi , Jun Sugiura , Hiroko Kaneko , Shinji Shimizu , Atsushi Hiraiwa , Hidetsugu Ogishi , Masakazu Sagawa , Masami Ozawa , Toshihiro Sekiguchi
IPC分类号： H01L27/10 , H01L21/8242 , H01L27/105 , H01L27/108 , H01L21/70 , H01L27/00
CPC分类号： H01L27/105 , H01L27/10808
摘要： A semiconductor integrated circuit device having a switching MISFET, and a capacitor element formed over the semiconductor substrate, is disclosed. The impurity concentration of the semiconductor region of the switching MISFET to which the capacitor element is connected is less than the impurity concentration of semiconductor regions of MISFETs of peripheral circuitry. The Y-select signal line overlaps the lower electrode layer of the capacitor element. A potential barrier layer, provided at least under the semiconductor region of the switching MISFET to which the capacitor element is connected, is formed by diffusion of an impurity for a channel stopper region. The dielectric film of the capacitor element is co-extensive with the capacitor electrode layer over it. The capacitor dielectric film is a silicon nitride film having a silicon oxide layer thereon, the silicon oxide layer being formed by oxidizing a surface layer of the silicon nitride under high pressure. An aluminum wiring layer and a protective (and/or barrier) layer are formed by sputtering in the same vacuum sputtering chamber without breaking the vacuum between forming the layers; and a refractory metal, or a refractory metal silicide QSi.sub.x, where Q is a refractory metal and x is between 0 and 2, is used as a protective layer, for an aluminum wiring containing an added element (e.g., Cu) to prevent migration.
摘要翻译：公开了一种具有开关MISFET的半导体集成电路器件和形成在半导体衬底上的电容器元件。电容器元件连接的开关MISFET的半导体区域的杂质浓度小于外围电路的MISFET的半导体区域的杂质浓度。 Y选择信号线与电容器元件的下电极层重叠。至少在与电容器元件连接的开关MISFET的半导体区域下方设置的势垒层通过用于沟道阻挡区域的杂质的扩散而形成。电容器元件的电介质膜与其上的电容器电极层共同扩展。电容器电介质膜是其上具有氧化硅层的氮化硅膜，氧化硅层通过在高压下氧化氮化硅的表面层而形成。通过溅射在相同的真空溅射室中形成铝布线层和保护（和/或阻挡层），而不破坏形成层之间的真空; 和难熔金属或难熔金属硅化物QSix，其中Q是难熔金属，x在0和2之间，用作含有添加元素（例如Cu）以防止迁移的铝布线的保护层。

10. 发明授权

US5273639A Probe electrode 失效
标题翻译：探头电极
公开(公告)号：US5273639A
公开(公告)日：1993-12-28
申请号：US905238
申请日：1992-06-29
申请人： Hiroko Kaneko , Ken Nozaki , Akira Negishi
发明人： Hiroko Kaneko , Ken Nozaki , Akira Negishi
IPC分类号： G01N27/30
CPC分类号： G01N27/308
摘要： A method of making a probe electrode includes the steps of kneading a mixture of 75-80% by weight of a carbon material, 10-14% by weight of an organic binder and 7-9% by weight of mineral oil, forming the kneaded mixture into a predetermined shape, heating the shaped mixture in air the temperature of up to 300.degree. C. and raising the temperature in an atmosphere of inert gas up to 1000.degree. C.
摘要翻译：制造探针电极的方法包括以下步骤：将75-80重量％的碳材料，10-14重量％的有机粘合剂和7-9重量％的矿物油混合，形成捏合的混合物形成预定形状，在空气中将成形混合物加热至高达300℃，并将其在惰性气体气氛中升温至1000℃。

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