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1. 发明申请

US20080306311A1 Method for Producing an Alpha-Chiral Chloromethyl Compound in a Pure Form 审中-公开
标题翻译：以纯形式生产α-手性氯甲基化合物的方法
公开(公告)号：US20080306311A1
公开(公告)日：2008-12-11
申请号：US12158543
申请日：2006-12-13
申请人： Juergen Daeuwel , Volker Ruediger Sporys , Martin Voelkert , Holger Buehler
发明人： Juergen Daeuwel , Volker Ruediger Sporys , Martin Voelkert , Holger Buehler
IPC分类号： C07C33/46
CPC分类号： C07C41/42 , C07B2200/07 , C07C41/22 , C07C43/225
摘要： The present invention relates to a process for preparing a specific α-chiral chloromethyl compound in pure or enriched form by distillative removal of the compound mentioned from substance mixtures which comprise this compound and higher-boiling impurities. The α-chiral chloromethyl compound in question is present in crystalline form at room temperature and is a central intermediate for the preparation of a class of medicaments.
摘要翻译：本发明涉及通过蒸馏除去包含该化合物和较高沸点杂质的物质混合物提及的化合物来制备纯或富集形式的特定α-手性氯甲基化合物的方法。所讨论的α-手性氯甲基化合物在室温下以结晶形式存在，并且是制备一类药物的中间体。

2. 发明授权

US07527652B2 Dithiol compositions and methods of treating animal hides using the same 失效
标题翻译：二硫醇组合物及使用其处理动物皮的方法
公开(公告)号：US07527652B2
公开(公告)日：2009-05-05
申请号：US10571772
申请日：2004-09-10
申请人： Holger Buehler , Joaquim Henrique Teles , Gunther Pabst , Tilman Luedecke Taeger
发明人： Holger Buehler , Joaquim Henrique Teles , Gunther Pabst , Tilman Luedecke Taeger
IPC分类号： C14C1/00 , C07D301/12 , C07C323/02 , C07F11/00
CPC分类号： C07D407/04 , C07C323/12
摘要： Mixtures of (A) from 55 to 65 mol % of erythro-dithiol of formula erythro-IV: and (B) from 35 to 45 mol % of threo-dithiol of formula threo-IV or threo-IV′: and their corresponding alkali metal salts and ammonium salts, are useful for treating animal hides.
摘要翻译：（A）55至65摩尔％的赤藓-4-肟的赤式二硫醇和（B）35至45摩尔％的式Ⅳ-Ⅳ或钍-IV'的二硫代硫醇的混合物及其相应的碱金属盐和铵盐可用于治疗动物皮肤。

3. 发明申请

US20070124868A1 Method for the extraction of keratin from dead animal skins 审中-公开
标题翻译：从死亡动物皮肤中提取角蛋白的方法
公开(公告)号：US20070124868A1
公开(公告)日：2007-06-07
申请号：US10579714
申请日：2004-11-12
申请人： Holger Buehler , Joaquim Teles , Carsten Suling , Tilman Taeger , Gunther Pabst
发明人： Holger Buehler , Joaquim Teles , Carsten Suling , Tilman Taeger , Gunther Pabst
IPC分类号： C07F9/22 , C07F9/28
CPC分类号： C14C1/06 , C07C323/12 , C07C323/15 , C07C323/16 , C07C323/17 , C07C2601/08 , C07C2601/14 , C14C1/065
摘要： horny substances are removed from hides of dead animals by a process wherein the hides of dead animals are treated with at least one substance of the formula I or at least one corresponding alkali metal, alkaline earth metal, ammonium or phosphonium salt, where R1 and R4 are identical or different and are selected from hydrogen, C6-C14-aryl and C1-C12-alkyl, unsubstituted or substituted by one or more SH or OH groups, R2 and R3 are identical or different and are selected from hydrogen, C6-C14-aryl and C1-C12-alkyl, unsubstituted or substituted by one or more SH or OH groups, at least one radical R2 or R3 not being hydrogen or R1 and R4 not being hydrogen, and it being possible in each case for two vicinal radicals R1 to R4 together to be C3-C10-alkylene, R5 is selected from hydrogen, C1-C12-alkyl, H—C═O or C1-C4-alkyl-C═O, X1, X2, X3 and X4 are selected from OH, SH and NHR5, where, if R1 to R4 contain at least one sulfur atom, at least one radical X1 to X4 is SH, and, if R1 to R4 contain no sulfur atom, at least two radicals X1 to X4 are SH.
摘要翻译：角质物质通过其中用至少一种式I物质或至少一种相应的碱金属，碱土金属，铵或鏻盐处理死亡动物的皮肤的方法从死亡动物的皮革中除去，其中R ^{1和R 4相同或不同，并且选自氢，C 6 -C 14 - 芳基和C 6 - 未取代或被一个或多个SH或OH基团取代的C 1 -C 12 - C 12 - 烷基，R 2和R 3 >相同或不同，并且选自氢，C 6 -C 14 - 芳基和C 1 -C 12 - 未被取代或被一个或多个SH或OH基取代的亚烷基，至少一个R 2或R 3不是氢或R 1， / SUP>和R 4不是氢，并且在每种情况下可以将两个邻位基团R 1至R 4一起成为 C 3 -C 10 - 亚烷基，R 5 s选自氢，C 1 -C 12 - 烷基，HCO或C 1 -C 4 - 烷基 -CO，X 1，X 2，X 3和X 4选自OH，SH和NHR 其中，如果R 1至R 4含有至少一个硫原子，则至少一个基团X 1或O 2 >至X 4是SH，并且如果R 1至R 4不含硫原子，则至少两个基团X 1 至X 4是SH。}

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