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1. 发明授权

US6087538A Addition reaction of hydroxyl-containing compounds with alkynes or allenes 失效
标题翻译：含羟基的化合物与炔或丙烯的加成反应
公开(公告)号：US6087538A
公开(公告)日：2000-07-11
申请号：US92059
申请日：1998-06-05
申请人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Christopher William Rieker , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
发明人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Christopher William Rieker , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
IPC分类号： B01J23/06 , B01J37/02 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/303 , C07C67/04 , C07C69/145 , C07C69/16 , C07C43/30 , B01J21/08 , C07C2/02
CPC分类号： B01J37/0203 , B01J23/06 , C07C41/06 , C07C41/08 , C07C41/54
摘要： Compounds of the formula I and II ##STR1## where R.sup.1 is hydrogen or an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical or an acyl radical, it being possible for these radicals to carry further substituents which do not react with acetylenes or allenes, and the radicals R, independently of one another, are hydrogen or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radicals which may be linked to one another with formation of a ring and m is 0 or 1, are prepared by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## where R.sup.1 and R have the abovementioned meanings, in the gas phase at elevated temperatures in the presence of a heterogeneous, silicate-containing catalyst, by a process in which the catalyst used contains, as an active component, an X-ray amorphous zinc silicate or cadmium silicate containing from 1 to 40% by weight, calculated as oxide, of zinc or cadmium and is obtainable by applying a zinc salt or cadmium salt of an organic acidic compound which is decomposable at below 400.degree. C., to an amorphous silica and forming the catalyst at from 50 to 500.degree. C., in the presence of a hydroxyl-containing compound selected from the group consisting of water, alkanols with up to 10 carbon atoms, diols and polyols having 2 to 6 carbon atoms and 2 or 3 OH groups and carboxylic acids of 1 to 6 carbon atoms.
摘要翻译：式I和II的化合物，其中R 1是氢或脂族，脂环族，芳脂族，芳族或杂环基或酰基，这些基团可能携带另外不与炔或炔反应的取代基和基团 R 2彼此独立地是氢或脂族，脂环族，芳脂族，芳族或杂环基团，其可以通过形成环而彼此连接并且m为0或1，其通过将化合物式IIIR1OHIII具有式IV或V的乙炔或二烯，其中R1和R具有上述含义，在气相中，在非均相含硅酸盐催化剂存在下，在升高的温度下，通过所用催化剂包含的方法，作为活性成分，含有以氧化物计为1〜40重量％的锌或镉的X射线无定形硅酸锌或铯硅酸盐，可通过应用在低于400℃下可分解的有机酸性化合物的锌锌盐或镉盐加入到无定形二氧化硅中，并在50-500℃下，在含羟基化合物存在下，在选自具有至多10个碳原子的链烷醇，具有2至6个碳原子的二醇和多元醇以及2或3个OH基团以及1至6个碳原子的羧酸组成的组。

2. 发明授权

US6060035A Addition reaction of hydroxyl-containing compounds with alkynes or allenes 失效
标题翻译：含羟基的化合物与炔或丙烯的加成反应
公开(公告)号：US6060035A
公开(公告)日：2000-05-09
申请号：US92058
申请日：1998-06-05
申请人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
发明人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst , Alfred Hagemeyer
IPC分类号： B01J23/08 , B01J21/16 , B01J23/06 , B01J37/03 , C01B33/20 , C07B41/00 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/303 , C01B15/14
CPC分类号： B01J21/16 , B01J23/06 , B01J37/03 , C01B33/20 , C07B41/00 , C07C41/06 , C07C41/08 , C07C41/54
摘要： Compounds of the formulae I and II ##STR1## are prepared by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## where R.sup.1 and R are as defined, in the gas phase at elevated temperatures in the presence of a heterogeneous, silicate-containing catalyst, by a process in which the catalyst used is one which contains or consists of, as the active component, a zinc silicate obtained by precipitation in aqueous solution from a soluble silicon compound and zinc compound, zinc silicate beinga) an essentially X-ray amorphous zinc silicate of the formula VIZn.sub.a Si.sub.c O.sub.a+2c-0.5e (OH).sub.e.fH.sub.2 O VI, where e is from 0 to 2a+4c and the ratio a:c is from 1 to 3.5, and the ratio f:a is from 0 to 200, and/orb) a crystalline zinc silicate having the structure of hemimorphite of the formula Zn.sub.4 Si.sub.2 O.sub.7 (OH).sub.2.H.sub.2 O.
摘要翻译：式I和II的化合物通过在存在下在升高的温度下在气相中通过式III R1OHIII的化合物与式IV或V的炔或其中R1和R如所定义的二烯的加成反应来制备，的不均一硅酸盐催化剂，其中使用的催化剂是含有或由作为活性组分的组成的方法，所述方法是通过在可溶性硅化合物和锌化合物的水溶液中沉淀而获得的硅酸锌，硅酸锌 a）基本上是式VI ZnaSicOa + 2c-0.5e（OH）e.fH2OVI的X射线无定形硅酸锌，其中e为0至2a + 4c，a:c为1至3.5，以及比例f：a为0至200，和/或b）具有式Zn 4 Si 2 O 7（OH）2·H 2 O的半偏氟结构的结晶硅酸锌。

3. 发明授权

US06211416B1 Method for producing enol ethers 失效
标题翻译：烯醇醚的制备方法
公开(公告)号：US06211416B1
公开(公告)日：2001-04-03
申请号：US09424855
申请日：1999-12-06
申请人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst , Heinz Etzrodt , Udo Rheude
发明人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst , Heinz Etzrodt , Udo Rheude
IPC分类号： C07C4128
CPC分类号： C07C41/08 , C07C41/28 , C07C41/54 , C07C43/303 , C07C43/16 , C07C43/15
摘要： Enol ethers of the formula I where R1 is an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical which may carry further substituents which do not react with acetylenes or allenes, and the radicals R, independently of one another, are hydrogen or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radicals, which may be bonded to one another to form a ring, and m is 0 or 1, are prepared by reacting an acetal or ketal of the formula II with an acetylene or allene of the formula III or IV where R and R1 have the abovementioned meanings, in the gas phase at elevated temperatures in the presence of a zinc- or cadmium- and silicon- and oxygen-containing heterogeneous catalyst.
摘要翻译：式I的烯醇醚，其中R 1是脂族，脂环族，芳脂族，芳族或杂环基团，其可以进一步携带不与炔或全烯反应的取代基，并且基团R彼此独立地为氢或脂族，脂环族，芳族或芳族杂环基，其可以彼此结合形成环，并且m为0或1，通过使式II的缩醛或缩酮与式III或IV的炔或丙烯的反应来制备，其中R和 R1在具有锌或镉和含硅和含氧异相催化剂存在下的高温下在气相中具有上述含义。

4. 发明授权

US6120744A Addition reaction of hydroxy1-containing compounds with alkynes or allenes 失效
标题翻译：含羟基的化合物与炔或丙烯的加成反应
公开(公告)号：US6120744A
公开(公告)日：2000-09-19
申请号：US97818
申请日：1998-06-16
申请人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst
发明人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst
IPC分类号： B01J23/06 , B01J37/02 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/303 , C01G9/00 , C01G11/00 , C22B13/00 , C22B17/00 , C22B43/00
CPC分类号： C07C41/54 , B01J23/06 , B01J37/0203 , C07C41/06 , C07C41/08
摘要： A process for preparing compounds of the formulae I and II ##STR1## where R.sup.1 and R have the meanings indicated in the specification by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## in the gas phase at elevated temperatures in the presence of a heterogeneous catalyst. The catalyst is obtained by impregnating silica with a zinc salt, by a process in which the reaction is carried out at below 200.degree. C. and the catalyst contains, as an active component, an X-ray amorphous zinc silicate or cadmium silicate containing from 1 to 40% by weight, calculated as oxide, of zinc or cadmium, obtainable by applying a salt of zinc or cadmium and an inorganic oxo acid, which salt is decomposable at below 400.degree. C., to amorphous silica and forming the catalyst before the reaction at from 50 to 500.degree. C. or during the reaction in situ at from 50 to 200.degree. C. in the presence of a hydroxyl-containing compound such as water, alkanols of 1 to 6 carbon atoms, diols and polyols having 2 to 6 carbon atoms and 2 or 3 OH groups and low molecular weight carboxylic acids.
摘要翻译：制备式I和II化合物的方法，其中R1和R具有本说明书中通过式III的化合物R1OH III与乙炔或式IV或V的烯在气相中的加成反应所示的含义在非均相催化剂存在下在升高的温度下进行。通过在低于200℃下进行反应的方法，用锌盐浸渍二氧化硅得到催化剂，催化剂含有作为活性成分的X射线无定形硅酸锌或含有以氧化物计的锌或镉1〜40重量％，可通过将该盐在低于400℃下分解的锌或镉和无机含氧酸盐与无定形二氧化硅反应而形成催化剂在50至500℃的反应或在50-200℃下在含羟基的化合物如水，1至6个碳原子的链烷醇存在下的反应期间的反应，二醇和多元醇具有2 至6个碳原子和2或3个OH基团和低分子量羧酸。

5. 发明授权

US06184420B2 Preparation of unsaturated ketones 失效
标题翻译：不饱和酮的制备
公开(公告)号：US06184420B2
公开(公告)日：2001-02-06
申请号：US09150925
申请日：1998-09-10
申请人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst , Stefan Kaeshammer , Heinz Etzrodt , Wulf Kaiser
发明人： Joaquim Henrique Teles , Norbert Rieber , Klaus Breuer , Dirk Demuth , Hartmut Hibst , Stefan Kaeshammer , Heinz Etzrodt , Wulf Kaiser
IPC分类号： C07C49203
CPC分类号： C07C45/513 , Y02P20/582 , C07C49/203
摘要： Unsaturated ketones of the formulae Ia and Ib are prepared by a process consisting of the combination of the following reactions: a) The conventional reaction of an allyl alcohol of the formula IIa or a propargyl alcohol of the formula IIb with an isopropenyl ether of the formula III with formation of a ketal of the formula IV as a byproduct, b) preparation of the isopropenyl ether of the formula III by reacting a ketal of the formula IV with propyne or allene, or a mixture thereof in the gas phase at elevated temperatures in the presence of a heterogeneous catalyst containing zinc or cadmium together with silicon or oxygen, and c) feeding the ketal of the formula IV formed in the reaction (a) into stage (b) for the preparation of the isopropenyl ether of the formula III again.
摘要翻译：式Ia和Ib的不饱和酮通过由以下反应的组合组成的方法制备：a）式IIa的烯丙醇或式IIb的炔丙醇与式III的异丙烯基醚的常规反应，形成的式I的缩酮化合物是一种副产物，b）通过使式IV的缩酮与丙炔或丙烯或其混合物在升高的温度下在存在下进行反应来制备式III的异丙烯基醚含有锌或镉以及硅或氧的非均相催化剂，和c）将反应（a）中形成的式IV的缩酮进料到步骤（b）中，以再次制备式III的异丙烯基醚。

6. 发明授权

US07071363B2 Structured catalyst bed 失效
标题翻译：结构催化剂床
公开(公告)号：US07071363B2
公开(公告)日：2006-07-04
申请号：US10617859
申请日：2003-07-14
申请人： Hartmut Hibst , Sebastian Storck , Dirk Demuth , Wolfram Stichert , Jens Klein , Stephan A. Schunk , Andreas Sundermann
发明人： Hartmut Hibst , Sebastian Storck , Dirk Demuth , Wolfram Stichert , Jens Klein , Stephan A. Schunk , Andreas Sundermann
IPC分类号： C07C45/00 , B01J23/48 , B01J23/50
CPC分类号： C07C45/34 , B01J8/0453 , B01J23/002 , B01J23/50 , B01J23/66 , B01J23/8885 , B01J27/1806 , B01J35/0006 , B01J2208/025 , B01J2523/00 , C07C45/58 , C07C47/21 , B01J2523/18 , B01J2523/31 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/11 , B01J2523/51
摘要： The invention relates to a novel structured catalyst bed which optionally comprises at least one part bed comprising at least one catalytically active mixture of oxides of the main group metals and transition metals and additionally comprises at least one catalytically active part bed comprising at least silver, at least one alkali metal and a porous support material and finally and necessarily at least one catalytically active part bed comprising at least one alkali metal phosphate and at least one sheet silicate.
摘要翻译：本发明涉及一种新颖的结构化催化剂床，其任选地包含至少一部分床，其包含至少一种主要金属和过渡金属的氧化物的催化活性混合物，并且还包含至少一种至少包含银的催化活性部分床，至少一种碱金属和多孔载体材料，最后并且必需至少一种包含至少一种碱金属磷酸盐和至少一种片状硅酸盐的催化活性部分床。

7. 发明授权

US06790322B2 Production of material libraries using sputter methods 失效
标题翻译：使用溅射法生产材料库
公开(公告)号：US06790322B2
公开(公告)日：2004-09-14
申请号：US10149753
申请日：2002-11-13
申请人： Stephan A. Schunk , Dirk Demuth , Hartmut Hibst
发明人： Stephan A. Schunk , Dirk Demuth , Hartmut Hibst
IPC分类号： C23C1434
CPC分类号： C23C14/3407 , B01J19/0046 , B01J2219/00436 , B01J2219/00443 , B01J2219/00518 , B01J2219/00527 , B01J2219/00533 , B01J2219/00536 , B01J2219/00585 , B01J2219/0059 , B01J2219/00596 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00617 , B01J2219/00635 , B01J2219/00641 , B01J2219/00659 , B01J2219/00707 , B01J2219/00745 , B01J2219/00747 , B01J2219/0075 , B01J2219/00752 , B01J2219/00754 , C23C14/3464 , C40B30/08 , C40B40/18 , C40B60/14
摘要： In a process for the combinatorial production of a library of materials in the form of a two-dimensional matrix in the surface region of a planar substrate by sputtering, the planar target used for the sputtering is arranged in parallel to the planar substrate and has surface regions of different chemical composition.
摘要翻译：在通过溅射在平面基板的表面区域中以二维矩阵的形式组合制造材料库的方法中，用于溅射的平面靶被平行于平面基板布置，并且具有表面不同化学成分的区域。

8. 发明申请

US20060127287A1 Combinatorial preparation and testing of heterogeneous catalysts 审中-公开
标题翻译：组合制备和非均相催化剂的试验
公开(公告)号：US20060127287A1
公开(公告)日：2006-06-15
申请号：US11336843
申请日：2006-01-23
申请人： Hartmut Hibst , Andreas Tenten , Dirk Demuth , Ferdi Schueth , Stephan Schunk
发明人： Hartmut Hibst , Andreas Tenten , Dirk Demuth , Ferdi Schueth , Stephan Schunk
IPC分类号： D21C11/00
CPC分类号： B01J19/0046 , B01J37/0215 , B01J37/0217 , B01J2219/00286 , B01J2219/00306 , B01J2219/00511 , B01J2219/00585 , B01J2219/0059 , B01J2219/00599 , B01J2219/00747
摘要： The array of heterogeneous catalysts and/or their precursors, is made up of a body which has, preferably parallel, through-channels and in which at least n channels comprise n different heterogeneous catalysts and/or their precursors, where n is 2, preferably 10, particularly preferably 100, in particular 1000, especially 10,000. A process for preparing arrays comprising the following steps: a1) preparing solutions, emulsions and/or dispersions of elements and/or element compounds of the elements present in the catalyst and/or catalyst precursor and, if appropriate preparing dispersions of inorganic support materials, a2) if appropriate introducing adhesion promoters, binders, viscosity regulators, pH regulators and/or solid inorganic supports into the solutions, emulsions and/or dispersions, a3) simultaneously or successively coating the channels of the body with the solutions, emulsions and/or dispersions, a predetermined amount of the solutions, emulsions and/or dispersions being introduced into each channel to obtain a predetermined composition and a4) if appropriate heating the coated body in the presence or absence of inert gases or reactive gases to a temperature in the range from 20 to 1500° C. to dry, with or without sintering or calcining, the catalysts and/or catalyst precursors.
摘要翻译：非均相催化剂和/或其前体的阵列由具有优选平行的通道的主体组成，其中至少n个通道包含n个不同的非均相催化剂和/或其前体，其中n为2，优选为 10，特别优选100，特别是1000，特别是10,000。一种制备阵列的方法，包括以下步骤：a1）制备存在于催化剂和/或催化剂前体中的元素和/或元素化合物的溶液，乳液和/或分散体，以及如果合适的话，制备无机载体材料的分散体， a2）如果合适，将粘合促进剂，粘合剂，粘度调节剂，pH调节剂和/或固体无机载体引入溶液，乳液和/或分散体中，a3）用溶液，乳液和/或分散体同时或连续地涂覆身体的通道分散体，预定量的溶液，乳液和/或分散体被引入每个通道以获得预定的组合物和a）如果在存在或不存在惰性气体或反应气体的情况下适当地加热涂覆体到达该范围内的温度 20至1500℃，用或不用烧结或煅烧来干燥催化剂和/或催化剂前体。

9. 发明申请

US20050037426A1 Combinatorial preparation and testing of heterogeneous catalysts 审中-公开
标题翻译：组合制备和非均相催化剂的试验
公开(公告)号：US20050037426A1
公开(公告)日：2005-02-17
申请号：US10726185
申请日：2003-12-03
申请人： Stephan Schunk , Dirk Demuth , Hartmut Hibst
发明人： Stephan Schunk , Dirk Demuth , Hartmut Hibst
IPC分类号： B01J19/00 , B01J35/04 , B01J37/02 , C40B30/08 , C40B40/18 , G01N33/53 , G01N33/543
CPC分类号： B01J37/02 , B01J19/0046 , B01J35/04 , B01J2219/0052 , B01J2219/00585 , B01J2219/00603 , B01J2219/00659 , B01J2219/00704 , B01J2219/00745 , B01J2219/00747 , C40B30/08 , C40B40/18 , Y10T436/175383 , Y10T436/18 , Y10T436/20 , Y10T436/205831 , Y10T436/25875
摘要： A process for preparing arrays of heterogeneous catalysts and/or their precursors, made up of a body which has, preferably parallel, through-channels and in which at least n channels comprise n different heterogeneous catalysts and/or their precursors, where n is 2, preferably 10, particularly preferably 100, comprises the following steps: a1) preparing solutions, emulsions and/or dispersions of elements and/or element compounds of the chemical elements present in the catalyst and/or catalyst precursor and, if appropriate preparing dispersions of inorganic support materials, a2) if appropriate introducing adhesion promoters, binders, viscosity regulators, pH regulators and/or solid inorganic supports into the solutions, emulsions and/or dispersions, a3) simultaneously or successively coating the channels of the body with the solutions, emulsions and/or dispersions, a predetermined amount of the solutions, emulsions and/or dispersions being introduced into each channel to obtain a predetermined composition, a4) treating and reacting with one or more reactive gases the freshly impregnated moist channels obtained after the coating, and a5) if appropriate heating the coated body in the presence or absence of inert gases or reactive gases to a temperature in the range from 20 to 1500° C. to dry, with or without sintering or calcining, the catalysts and/or catalyst precursors.
摘要翻译：一种制备非均相催化剂和/或其前体阵列的方法，其由具有优选平行通过通道并且其中至少n个通道包含n个不同的非均相催化剂和/或其前体的主体组成，其中n为2 ，优选10，特别优选100，包括以下步骤：a1）制备催化剂和/或催化剂前体中存在的化学元素的元素和/或元素化合物的溶液，乳液和/或分散体，并且如果合适，制备无机载体材料，a2）如果合适的话，将粘合促进剂，粘合剂，粘度调节剂，pH调节剂和/或固体无机载体引入溶液，乳液和/或分散体中，a3）用溶液同时或连续地涂覆身体的通道，乳液和/或分散体，将预定量的溶液，乳液和/或分散体引入每个通道以获得预 a4）在涂覆后获得的新鲜浸渍的湿通道处理和反应一种或多种反应性气体，以及a）如果在存在或不存在惰性气体或反应性气体的情况下适当地加热涂覆体到达该范围内的温度 20至1500℃，用或不用烧结或煅烧来干燥催化剂和/或催化剂前体。

10. 发明授权

US06896783B2 Method for producing material libraries by means of electrochemical deposition 失效
标题翻译：通过电化学沉积法生产材料库的方法
公开(公告)号：US06896783B2
公开(公告)日：2005-05-24
申请号：US10168099
申请日：2000-12-12
申请人： Stephan A. Schunk , Dirk Demuth , Hartmut Hibst
发明人： Stephan A. Schunk , Dirk Demuth , Hartmut Hibst
IPC分类号： B01J19/00 , B01J35/00 , B01J37/34 , C40B40/18 , C40B60/14 , C25D5/00
CPC分类号： B01J35/0006 , B01J19/0046 , B01J37/348 , B01J2219/00283 , B01J2219/00286 , B01J2219/00306 , B01J2219/00333 , B01J2219/00511 , B01J2219/0052 , B01J2219/00585 , B01J2219/00596 , B01J2219/00707 , B01J2219/00713 , B01J2219/00745 , B01J2219/00752 , C40B40/18 , C40B60/14
摘要： The invention relates to a method for combinatorially producing a library of materials by means of an electrochemical deposition in an array. The inventive library is made from an array of containers that consist of an electroconductive material, are open to the top and are electroconductively connected to a shared current supply device and is made from a corresponding array of auxiliary electrodes that are electroconductively connected to a shared current supply device and are arranged in such a way that an auxiliary electrode plunges into a container respectively or can be introduced therein without touching said container. The inventive method comprises the following steps: filling the containers with electrolytes having different compositions and containing electrolytically separable elements and applying an electric voltage between the current supply devices of the containers and auxiliary electrodes for obtaining an electrolytic deposition on the surfaces of the containers.
摘要翻译：本发明涉及通过阵列中的电化学沉积来组合地制备材料库的方法。本发明的库由一组由导电材料构成的容器组成，该导电材料通向顶部，并且电导连接到共享电流供应装置，并且由相应的辅助电极阵列制成，所述辅助电极阵列电导连接到共享电流供给装置并且以这样的方式布置，使得辅助电极分别插入容器中或可以在其中引入而不接触所述容器。本发明的方法包括以下步骤：用不同组成的电解质填充容器并含有电解分离元件，并在容器的电流供应装置和辅助电极之间施加电压，以在容器的表面上获得电解沉积。

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