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1. 发明申请

US20110009576A1 POLYMERISATION PROCESS 审中-公开
标题翻译：聚合过程
公开(公告)号：US20110009576A1
公开(公告)日：2011-01-13
申请号：US12736148
申请日：2009-02-24
申请人： Jean-Louis Chamayou , Claudine Viviane Lalanne-Magne , Melanie Muron
发明人： Jean-Louis Chamayou , Claudine Viviane Lalanne-Magne , Melanie Muron
IPC分类号： C08F10/14 , C08F4/00
CPC分类号： C08F210/16 , C08F4/6565 , C08F4/6495 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18
摘要： The present invention relates to a polymerisation process and in particular to a process for the copolymerisation of ethylene and an α-olefin comonomer having 7 to 10 carbon atoms in a fluidised bed gas phase reactor in the presence of a multi-site Ziegler-Natta polymerisation catalyst characterised in that (i) said process is operated in condensed mode, (ii) the amount of said α-olefin is maintained below that at which substantial condensation in the reactor occurs and (iii) at least one of the following apply:a) the catalyst has an uptake rate of 1-octene of at least 700;b) the polymerisation is performed in the presence of an activity promoter.
摘要翻译：本发明涉及一种聚合方法，特别涉及一种在多位点齐格勒 - 纳塔聚合存在下，在流化床气相反应器中共聚乙烯和具有7至10个碳原子的α-烯烃共聚单体的方法催化剂的特征在于：（i）所述方法以冷凝模式运行，（ii）所述α-烯烃的量保持低于反应器发生基本冷凝的量，以及（iii）以下至少一种适用：）催化剂具有至少700的1-辛烯的吸收速率; b）聚合在活性促进剂存在下进行。

2. 发明申请

US20090233091A1 Polymer Films 失效
标题翻译：聚合物膜
公开(公告)号：US20090233091A1
公开(公告)日：2009-09-17
申请号：US12225098
申请日：2007-03-06
申请人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
发明人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
IPC分类号： C08F210/02 , C08F210/08 , C08F210/14 , C08F4/42 , B32B5/00 , B29C49/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08J5/18 , C08J2323/08 , Y10T428/268 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/26
摘要： A method for the preparation of a polymer film containing 300-600 gels/m2 of size in the range 100-2000 μm as measured by an optical control system (OCS) as hereinbefore described, said film being derived from an ethylene-α-olefin copolymer is characterised in that said copolymer is prepared in a particle forming polymerisation process in the presence of a single site catalyst system. The preferred single site catalyst system comprises a metallocene and the preferred polymerisation process is a gas phase process. The invention is particularly directed to blown films.
摘要翻译：制备聚合物膜的方法，该聚合物膜含有300-600凝胶/ m 2的尺寸，其范围为100-2000μm，如通过如上所述的光学控制系统（OCS）所测量的，所述膜衍生自乙烯-α-烯烃共聚物的特征在于所述共聚物是在单点催化剂体系的存在下在颗粒形成聚合方法中制备的。优选的单中心催化剂体系包含茂金属，优选的聚合方法是气相方法。本发明特别涉及吹塑薄膜。

3. 发明授权

US08338551B2 Polymer films 失效
标题翻译：聚合物膜
公开(公告)号：US08338551B2
公开(公告)日：2012-12-25
申请号：US12225098
申请日：2007-03-06
申请人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
发明人： Grant Berent Jacobsen , Claudine Viviane Lalanne-Magne , Sergio Mastroianni , Melanie Muron , Eric Nicolas Vincent Osmont
IPC分类号： C08F4/64 , C08F4/76 , C08F4/52 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08J5/18 , C08J2323/08 , Y10T428/268 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/26
摘要： Method for the preparation of a blown film containing 300-600 gels/m2 of size in the range 100-2000 μm as measured by an optical control system, in which the film is derived by extrusion from an ethylene-α-olefin copolymer. The method is carried out by preparing the copolymer in a particle forming polymerization process in the presence of a single site catalyst system containing a single site catalyst, a cocatalyst, and a support material.
摘要翻译：制备通过光学控制系统测量的100-2000μm范围内的300-600凝胶/ m2尺寸的吹塑薄膜的方法，其中通过乙烯-α-烯烃共聚物的挤出得到薄膜。该方法通过在含有单中心催化剂，助催化剂和载体材料的单中心催化剂体系的存在下，在颗粒形成聚合方法中制备共聚物来进行。

4. 发明授权

US07442750B2 Supported olefin polymerization catalyst 失效
标题翻译：负载型烯烃聚合催化剂
公开(公告)号：US07442750B2
公开(公告)日：2008-10-28
申请号：US10539557
申请日：2003-12-03
申请人： Grant Berent Jacobsen , Brian Stephen Kimberley , Claudine Viviane Lalanne-Magne , Sergio Mastroianni
发明人： Grant Berent Jacobsen , Brian Stephen Kimberley , Claudine Viviane Lalanne-Magne , Sergio Mastroianni
IPC分类号： C08F4/613 , C08F4/64 , C08F4/643 , C08F4/6592
CPC分类号： C08F10/02 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F210/16 , C08F4/025 , C08F4/65916 , C08F210/14 , C08F2500/12
摘要： Supported catalyst systems are provided comprising (a) a transition metal compound, (b) an activator comprising (iii) an aluminoxane or (iv) a Group lilA metal or metalloid compound, and (c) a support material comprising an inorganic metal oxide, inorganic metal halide or polymeric material or mixtures thereof characterised in that the support material has been pretreated with a source of a transition metal atom. The preferred transition metal compounds are metallocenes and the source of the transition metal atom is typically a ferrous or cupric metal salt. The supported catalyst systems show improved activity and also may reduce fouling in gas phase fluidised bed processes.
摘要翻译：提供了负载催化剂体系，其包含（a）过渡金属化合物，（b）活化剂，其包含（iii）铝氧烷或（iv）组合的LiAl金属或准金属化合物，和（c）包含无机金属氧化物的载体材料，无机金属卤化物或聚合物材料或其混合物，其特征在于支撑材料已用过渡金属原子源预处理。优选的过渡金属化合物是金属茂，过渡金属原子的来源通常是亚铁或二价金属盐。负载型催化剂体系显示出改善的活性，并且还可以减少气相流化床方法中的结垢。

5. 发明授权

US06646074B2 Process for the continuous gas-phase (co-) polymerisation of olefins in a fluidized bed reactor 失效
标题翻译：流化床反应器中烯烃连续气相（共）聚合的方法
公开(公告)号：US06646074B2
公开(公告)日：2003-11-11
申请号：US10092432
申请日：2002-03-08
申请人： Marc Herzog , Jean-Pierre Isnard , Claudine Viviane Lalanne-Magne , Myung Je Shin
发明人： Marc Herzog , Jean-Pierre Isnard , Claudine Viviane Lalanne-Magne , Myung Je Shin
IPC分类号： C08F444
CPC分类号： C08F10/00 , Y10S526/901 , Y10S526/941 , C08F2/40 , C08F2/34 , C08F2/005
摘要： A process for the continuous gas-phase (co-)polymerisation of olefins in a fluidised bed reactor using a Ziegler-Nata type catalyst wherein the polymerisation is performed in the presence of a process aid additive selected from at least one of (1) a polysulphone copolymer; (2) a polymeric polyamine or (3) an oil-soluble sulphonic acid.
摘要翻译：一种使用齐格勒 - 纳塔型催化剂在流化床反应器中连续气相（共）聚合烯烃的方法，其中聚合反应在加工助剂添加剂的存在下进行，所述加工助剂添加剂选自（1）聚砜共聚物; （2）聚合多胺或（3）油溶性磺酸。

6. 发明申请

US20110160414A1 PROCESS FOR START-UP OF A POLYMERISATION REACTION FLUIDISED BED 审中-公开
标题翻译：聚合反应流化床启动方法
公开(公告)号：US20110160414A1
公开(公告)日：2011-06-30
申请号：US12737880
申请日：2009-09-21
申请人： Andreas Harald Gondorf , Jose Andre Laille , Claudine Viviane Lalanne-Magne
发明人： Andreas Harald Gondorf , Jose Andre Laille , Claudine Viviane Lalanne-Magne
IPC分类号： C08F2/34 , C08F210/14 , C08F4/42
CPC分类号： C08F2/34 , B01J8/1809 , B01J2208/00646 , B01J2208/00716 , C08F210/16 , C08F2400/02 , C08F210/14
摘要： The present invention relates to a process for polymerisation, and, in particular, to a process for start-up of a gas phase fluidised bed polymerisation reaction, said reaction comprising polymerisation of one or more monomers using a catalyst in a reactor, and said process comprising: a) providing a start-up bed of particles in the reactor in the presence of the one or more monomers but in the absence of the catalyst, b) introducing catalyst to the reactor to initiate reaction and start-up polymer production, said introduction being designated as time T0, c) at a time Ti, Ti being between 1 and 6 hours after T0, the value of Xi is less than a threshold value, wherein: Xi=Cumulative production in the time period T0 to Ti (Cumulative catalyst injection the time period T0 to Ti*PiC2=), PiC2= being the ethylene partial pressure in the reactor at the time Ti, d) subsequently stopping the injection of catalyst, e) taking a corrective action to address the low value of Xi.
摘要翻译：本发明涉及一种聚合方法，特别涉及一种启动气相流化床聚合反应的方法，所述反应包括在反应器中使用催化剂聚合一种或多种单体，所述方法包括：a）在所述一种或多种单体的存在下，但在不存在所述催化剂的情况下，在所述反应器中提供颗粒起始床，b）将催化剂引入所述反应器以引发反应和启动聚合物的生产，所述引用被指定为时间T0，c）在时间Ti，Ti在T0之后1至6小时之间，Xi的值小于阈值，其中：Xi =时间段T0到Ti的累计产生（累积催化剂注入时间T0到Ti * PiC2 =），PiC2 =时间Ti时反应器中的乙烯分压，d）随后停止催化剂的注入，e）采取纠正措施来解决Xi的低值。

7. 发明授权

US06187878B1 Polymerisation process 有权
标题翻译：聚合过程
公开(公告)号：US06187878B1
公开(公告)日：2001-02-13
申请号：US09471419
申请日：1999-12-23
申请人： Claudine Viviane Lalanne-Magne , Erick Dominique Daire , Bruno Patrice Soulier , Jean-Pierre Isnard
发明人： Claudine Viviane Lalanne-Magne , Erick Dominique Daire , Bruno Patrice Soulier , Jean-Pierre Isnard
IPC分类号： C08F234
CPC分类号： C08F10/00 , Y10S526/901 , C08F2/34
摘要： A continuous gas fluidized bed process for the polymerization of olefin monomer(s) wherein the recycled gaseous stream withdrawn from the reactor is divided into two streams (A and B) and that (a) a first stream (A) having been cooled to a temperature at which liquid condenses out is then reintroduced directly into the fluidized bed in the reactor in such a way that, at any time, the condensed liquid is continuously introduced into the bed at a minimum rate of 10 liters of liquid per cubic meter of fluidized bed material per hour, and (b) a second stream (B), which by-passes the above cooling/condensing step, is passed through an exchanger and is then reintroduced into the reactor. The continuous introduction of a liquid into the reactor reduces or even eliminates fouling problems which can be encountered in conventional gas phase olefin polymerization processes.
摘要翻译：用于烯烃单体聚合的连续气体流化床方法，其中从反应器中排出的循环气流被分成两股流（A和B），和（a）已冷却至液体冷凝出的温度然后直接重新引入反应器中的流化床，使得在任何时候，冷凝的液体以每立方米流化床10升液体的最小速率连续引入床中每小时的床料，和（b）通过上述冷却/冷凝步骤的第二料流（B）通过交换器，然后再被引入反应器。将液体连续引入反应器减少或甚至消除了在常规气相烯烃聚合方法中可能遇到的结垢问题。

8. 发明申请

US20110177313A1 COPOLYMERS AND FILMS THEREOF 审中-公开
标题翻译：共聚物及其薄膜
公开(公告)号：US20110177313A1
公开(公告)日：2011-07-21
申请号：US12998254
申请日：2009-10-09
申请人： Choon Kooi Chai , Claudine Viviane Lalanne-Magne , Eric Osmont
发明人： Choon Kooi Chai , Claudine Viviane Lalanne-Magne , Eric Osmont
IPC分类号： B32B3/00 , C08F210/14 , C08F4/6592 , C08F2/34
CPC分类号： C08F210/16 , B29C48/0018 , B29C48/022 , B29C48/10 , B29K2105/256 , C08F4/65908 , C08F4/65916 , C08J5/18 , C08J2323/08 , C08F4/6592 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/11 , C08F2500/26
摘要： Copolymers of ethylene and α-olefins having C7—C12 carbon atoms having: (a) a density (D) in the range 0.900-0.940 g/cm3, (b) a melt index MI2 (2.16 kg, 190° C.) in the range of 0.01-50 g/10 min, (c) a melt elastic modulus G′ (G″=500 Pa) in the range 20 to 150 Pa, and (d) a tear strength (MD) of ≧220 g, a tear strength (TD) of ≧470 g, and a Dart Drop Impact (DDI) of ≧1800 g of a blown film having a thickness of 25 μm produced from the copolymer; where MD is referred to the machine direction and TD is the transverse direction of the blown film are suitably prepared in the gas phase by use of a supported metallocene catalyst system. Particularly suitable are copolymers of ethylene and 1-octene and the resultant blown films show improved processability and exhibit an improved balance of film properties of dart impact and tear strength.
摘要翻译：乙烯和具有C7-C12碳原子的α-烯烃的共聚物具有：（a）密度（D）在0.900-0.940g / cm3范围内，（b）熔体指数MI2（2.16kg，190℃） 0.01-50g / 10分钟的范围，（c）20〜150Pa的熔体弹性模量G'（G“= 500Pa），（d）≥220g的撕裂强度（MD）撕裂强度（TD）≥470g，由共聚物制成的厚度为25μm的吹塑薄膜的Dart Drop Impact（DDI）为1800g; 其中MD被称为机器方向，TD是吹塑薄膜的横向方向通过使用负载的茂金属催化剂体系在气相中适当地制备。特别合适的是乙烯和1-辛烯的共聚物，所得到的吹塑薄膜显示出改善的加工性能，并且显示飞镖冲击和撕裂强度的薄膜性能的改善平衡。

9. 发明授权

US07273912B2 Supported olefin polymerization catalyst 失效
标题翻译：负载型烯烃聚合催化剂
公开(公告)号：US07273912B2
公开(公告)日：2007-09-25
申请号：US10539518
申请日：2003-12-03
申请人： Grant Berent Jacobsen , Brian Stephen Kimberley , Claudine Viviane Lalanne-Magne , Sergio Mastroianni
发明人： Grant Berent Jacobsen , Brian Stephen Kimberley , Claudine Viviane Lalanne-Magne , Sergio Mastroianni
IPC分类号： C08F4/78 , B01J27/053
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65916 , C08F210/14 , C08F2500/12
摘要： Supported catalyst systems are provided comprising (a) a transition metal compound, (b) a non aluminoxane activator comprising, and (c) a support material comprising an inorganic metal oxide, inorganic metal halide or polymeric material or mixtures thereof characterised in that the support material has been pretreated with an SO4 containing compound. The preferred transition metal compounds are metallocenes and the SO4 containing compound is typically sulphuric acid. The supported catalyst systems show improved activity and also may reduce fouling in gas phase fluidised bed processes.
摘要翻译：提供了负载型催化剂体系，其包括（a）过渡金属化合物，（b）非铝氧烷活化剂，其包含和（c）包含无机金属氧化物，无机金属卤化物或聚合物材料或其混合物的载体材料或其混合物，其特征在于，材料已经用含SO 4的化合物预处理。优选的过渡金属化合物是金属茂，含SO 4的化合物通常是硫酸。负载型催化剂体系显示出改善的活性，并且还可以减少气相流化床方法中的结垢。

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