会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 1. 发明授权
    • Aryllithium products and processes
    • 芳基锂产品和工艺
    • US5626798A
    • 1997-05-06
    • US587813
    • 1996-01-05
    • James A. SchwindemanDouglas E. SuttonRobert C. MorrisonSonia S. Stryker
    • James A. SchwindemanDouglas E. SuttonRobert C. MorrisonSonia S. Stryker
    • C07F1/02
    • C07F1/02
    • An improved process for producing high purity solutions of aryllithium compounds comprising reacting a particulate alkali metal having a particle size in the range of 10 to 300 microns, with an aryl halide in a normally liquid etheral solvent of the formula ROR.sup.1, wherein R and R.sup.1 are selected from the group of alkyl radicals containing from 3 to 6 carbon atoms, in the presence of a Lewis base compound selected from compounds of the formula: R.sup.2 AR.sup.3 (R.sup.4).sub.z and ##STR1## wherein A is selected from oxygen, nitrogen, phosphorus or sulfur; R.sup.2, R.sup.3, and R.sup.4 are selected from alkyl radicals containing from 1 to 6 carbon atoms; R.sup.5 and R.sup.6 are independently selected from hydrogen or alkyl radicals containing one to six carbon atoms; y is an integer from 4 to 6; but when A is oxygen or sulfur, z is zero; and when A is nitrogen or phosphorus, z is one, and provided there is a mole ratio of ether to aryl halide of at least 1.3 to 1 and a mole ratio of Lewis base to aryl halide of from 0.01 to 0.50; and products of the process.
    • 一种用于生产芳族锂化合物的高纯度溶液的改进方法,包括使粒度在10-300微米范围内的颗粒状碱金属与式ROR1的通常液体的醚类溶剂中的芳基卤反应,其中R和R 1是 在选自下列化合物的路易斯碱化合物存在下,选自含有3至6个碳原子的烷基基团:R2AR3(R4)z和其中A选自氧,氮,磷或 硫; R2,R3和R4选自含有1至6个碳原子的烷基; R 5和R 6独立地选自氢或含有1至6个碳原子的烷基; y为4〜6的整数; 但当A为氧或硫时,z为零; 当A为氮或磷时,z为1,并且其醚与芳基卤的摩尔比至少为1.3:1,路易斯碱与芳基卤的摩尔比为0.01至0.50; 和产品的过程。