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1. 发明授权

US4435550A Method for polymerizing .alpha.-olefin 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US4435550A
公开(公告)日：1984-03-06
申请号：US356475
申请日：1982-03-09
申请人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
发明人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F4/02 , C08F10/04
CPC分类号： C08F10/00 , Y10S526/904
摘要： Poly-.alpha.-olefin, for example, polypropylene, is produced by subjecting a feed containing an .alpha.-olefin having 3 or more carbon atoms, to a preliminary polymerization at 40.degree. C. or less in the presence of a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound of the formula, R.sup.3 MgX wherein R.sup.3 =C.sub.1-8 alkyl and X=halogen, with a reaction product of an aluminium halide with an organic silicon compound of the formula, R.sub.n.sup.1 Si(OR.sup.2).sub.4-n, wherein R.sup.1 =C.sub.1-8 alkyl or phenyl, R.sup.2 =C.sub.1-8 alkyl, n=0, or 1 to 3, (b) bringing the resultant solid carrier into a first contact with titanium tetrahalide, (c) treating the resultant titanium-containing solid product with an organic acid ester, and, finally, (d) bringing the treated solid product into a second contact with titanium tetrahalide; (B) another catalytic ingredient consisting of a trialkyl aluminium of the formula, AlR.sub.3.sup.4 wherein R.sup.4 =C.sub.2-6 alkyl; and a further catalytic ingredient consisting of an organic acid ester, and then, by subjecting a polymerization mixture containing the above-mentioned catalyst, the preliminary polymer and free .alpha.-olefin to a final polymerization at a temperature above 40.degree. C.
摘要翻译：聚-α-烯烃，例如聚丙烯，是通过使含有3个或更多个碳原子的α-烯烃的原料在40℃或更低的预聚合下，在含有（A ）固体催化成分（a）通过使下式的格利雅化合物，其中R3 = C1-8烷基和X =卤素的R3MgX与卤化铝与下式的有机硅化合物的反应产物Rn1Si（ OR 2）4-n，其中R 1 = C 1-8烷基或苯基，R 2 = C 1-8烷基，n = 0或1至3，（b）使所得固体载体与四卤化钛进行第一次接触，（c ）用有机酸酯处理得到的含钛固体产物，最后（d）使经处理的固体产物与四卤化钛进行第二次接触; （B）由下式的三烷基铝，其中R 4 = C 2-6烷基的AlR 34组成的另一种催化成分; 和由有机酸酯组成的另外的催化成分，然后通过使含有上述催化剂的聚合混合物，预聚合物和游离α-烯烃在40℃以上的温度下进行最终聚合。

2. 发明授权

US4297463A Method for polymerizing .alpha.-olefin 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US4297463A
公开(公告)日：1981-10-27
申请号：US147279
申请日：1980-05-06
申请人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
发明人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
IPC分类号： C08F4/00 , C08F4/60 , C08F10/00 , C08F4/02 , C08F10/06
CPC分类号： C08F10/00
摘要： Poly-.alpha.-olefin having an excellent H. I. is produced with an excellent yield by bringing, in the presence of an organic acid ester, a feed, containing at least one .alpha.-olefin having 3 or more carbon atoms, into contact with a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound with an aluminium halide-tetraalkoxysilane reaction product, (b) bringing the resultant reaction product into a first contact with titanium tetrahalide, (c) treating the resultant titanium-containing solid product with an organic acid ester, and, finally, (d) bringing the treated solid product into a second contact with titanium tetrahalide, and; (B) another catalytic ingredient consisting of a trialkyl aluminium.
摘要翻译：通过在有机酸酯的存在下，将含有至少一个具有3个或更多个碳原子的α-烯烃的进料与含有3个或更多个碳原子的α-烯烃进行接触来制备具有优异的HI的聚-α-烯烃，包括（A）通过使格氏化合物与卤化铝 - 四烷氧基硅烷反应产物反应制备的（a）固体催化剂成分，（b）使得到的反应产物与四卤化钛进行第一次接触，（c）含有固体产物的有机酸酯，最后，（d）将经处理的固体产物与四卤化钛进行第二次接触，（B）由三烷基铝组成的另一催化成分。

3. 发明授权

US4365048A Method for polymerizing .alpha.-olefin 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US4365048A
公开(公告)日：1982-12-21
申请号：US263573
申请日：1981-05-14
申请人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
发明人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Yoshiyuki Kai , Michimasa Shimizu
IPC分类号： C08F4/00 , C08F4/02 , C08F4/50 , C08F4/58 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00
摘要： Poly.alpha.-olefin, for example, polypropylene, is produced with an excellent yield by bringing, in the presence of an organic acid ester, a feed, containing at least one .alpha.-olefin having 3 or more carbon atoms, for example, propylene, into contact with a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound of the formula, R.sup.3 MgX wherein R.sup.3 =C.sub.1-8 alkyl and X=halogen, with a reaction product of an aluminium halide with an organic silicon compound of the formula, R.sub.n.sup.1 Si(OR.sup.2).sub.4-n, wherein R.sup.1 =C.sub.1-8 alkyl or phenyl, R.sup.2 =C.sub.1-8 alkyl, n=1, 2 or 3, (b) bringing the resultant reaction product into a first contact with titanium tetrahalide, (c) treating the resultant titanium-containing solid product with an organic acid ester, and, finally, (d) bringing the treated solid product into a second contact with titanium tetrahalide, and; (B) another catalytic ingredient consisting of a trialkyl aluminium of the formula, AlR.sub.3.sup.4 wherein R.sup.4 =C.sub.2-6 alkyl.
摘要翻译：通过在有机酸酯的存在下，含有至少一种具有3个或更多个碳原子的α-烯烃的进料，例如丙烯，丙烯，与催化剂接触，该催化剂包含（A）通过使下式的格利雅化合物，其中R3 = C1-8烷基和X =卤素的R3MgX与卤化铝的反应产物与 Rn1Si（OR2）4-n的有机硅化合物，其中R1 = C1-8烷基或苯基，R2 = C1-8烷基，n = 1,2或3，（b）将所得反应产物置于首先与四卤化钛接触，（c）用有机酸酯处理所得的含钛固体产物，最后，（d）使经处理的固体产物与四卤化钛进行第二次接触; （B）由下式的三烷基铝，其中R 4 = C 2-6烷基的AlR 34组成的另一种催化成分。

4. 发明授权

US4324877A Method for polymerizing .alpha.-olefin 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US4324877A
公开(公告)日：1982-04-13
申请号：US208302
申请日：1980-11-19
申请人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Masanori Tamura , Sakae Yuasa
发明人： Haruo Ueno , Takefumi Yano , Tokuji Inoue , Shigeru Ikai , Masanori Tamura , Sakae Yuasa
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F4/02 , C08F10/06
CPC分类号： C08F10/00
摘要： An .alpha.-olefin polymer having an excellent H.I. is produced with a high yield by bringing, in the presence of an organic acid ester, a feed containing at least one .alpha.-olefin, having 3 or more carbon atoms, into contact with a catalyst composed of:a solid catalytic ingredient which has been prepared in such a manner that an aluminosiloxy compound of the formula, ##STR1## wherein X.sup.1 represents a chlorine atom, a bromine atom or an iodine atom, is reacted with a Grignard compound of the formula R.sup.1 MgX.sup.2 [II] wherein R.sup.1 represents an alkyl radical having 1 to 8 carbon atoms and X.sup.2 represents a halogen atom, the resultant solid reaction product is brought into contact with a titanium tetrahalide, the resultant titanium-containing solid product is treated with an organic acid ester, and the treated solid product is brought into contact with a titanium tetrahalide; anda trialkyl aluminum.
摘要翻译：具有优异的H.I.的α-烯烃聚合物。通过在有机酸酯的存在下，将含有至少一种具有3个或更多个碳原子的α-烯烃的进料与由以下物质组成的催化剂接触来制备：高固含量的固体催化成分以如下方式制备：其中X1表示氯原子，溴原子或碘原子的下式的铝硅氧烷化合物，其中X1表示氯原子，溴原子或碘原子，与式R1MgX2 [II]的格利雅化合物反应，其中R1表示具有1至8个碳原子的烷基，X 2表示卤素原子，使所得固体反应产物与四卤化钛接触，所得含钛固体产物用有机酸酯处理，并将处理过的固体产物与四卤化钛接触; 和三烷基铝。

5. 发明授权

US4420594A Method for polymerizing ethylene 失效
标题翻译：乙烯聚合方法
公开(公告)号：US4420594A
公开(公告)日：1983-12-13
申请号：US349872
申请日：1982-02-18
申请人： Haruo Ueno , Takefumi Yano , Michimasa Shimizu , Masanori Tamura , Sakae Yuasa
发明人： Haruo Ueno , Takefumi Yano , Michimasa Shimizu , Masanori Tamura , Sakae Yuasa
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00
摘要： An ethylene polymer is produced with an excellent yield by bringing a feed containing ethylene into contact with a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound with a reaction product of an aluminum halide with an organic silicon compound of the formula, R.sup.1.sub.n Si(OR.sup.2).sub.4-n, wherein R.sup.1 =C.sub.1-8 alkyl or phenyl, R.sup.2 =C.sub.1-8 alkyl and n=1, 2 or 3 and (b) by bringing the resultant solid reaction product into contact with titanium tetrahalide and (B) another catalytic ingredient consisting of at least one trialkyl aluminum.
摘要翻译：通过使含有乙烯的进料与催化剂接触来生产乙烯聚合物，该催化剂包括（A）通过使格氏化合物与卤化铝与有机硅的反应产物反应制备的（a）固体催化成分化学式为R 1 n Si（OR 2）4-n，其中R 1 = C 1-8烷基或苯基，R 2 = C 1-8烷基和n = 1,2或3，和（b）通过使得到的固体反应产物接触与四卤化钛和（B）由至少一种三烷基铝组成的另一种催化成分。

6. 发明授权

US4306046A Method for polymerizing ethylene by means of a novel titanium containing catalyst 失效
标题翻译：通过新型含钛催化剂聚合乙烯的方法
公开(公告)号：US4306046A
公开(公告)日：1981-12-15
申请号：US196095
申请日：1980-10-10
申请人： Haruo Ueno , Takefumi Yano , Michimasa Shimizu , Masanori Tamura , Sakae Yuasa
发明人： Haruo Ueno , Takefumi Yano , Michimasa Shimizu , Masanori Tamura , Sakae Yuasa
IPC分类号： C08F4/00 , C08F4/60 , C08F10/02 , C08F4/02
CPC分类号： C08F10/02
摘要： An ethylene polymer is produced with an excellent yield by bringing a feed containing ethylene into contact with a catalyst which comprises (A) a solid catalytic ingredient prepared (a) by reacting a Grignard compound with an aluminium halide-tetraalkoxysilane reaction product and (b) bringing the resultant reaction product into contact with titanium tetrahalide and; (B) another catalytic ingredient consisting of a trialkyl aluminium.
摘要翻译：通过使含有乙烯的进料与催化剂接触来制备乙烯聚合物，该催化剂包含（A）通过使格利雅化合物与卤化铝 - 四烷氧基硅烷反应产物反应制备的（a）固体催化剂成分和（b）使所得反应产物与四卤化钛接触; （B）由三烷基铝组成的另一催化成分。

7. 发明授权

US08247504B2 Catalyst component, catalyst for olefin polymerization, and process for producing olefin polymer using catalyst 有权
标题翻译：催化剂组分，烯烃聚合催化剂和使用催化剂生产烯烃聚合物的方法
公开(公告)号：US08247504B2
公开(公告)日：2012-08-21
申请号：US11997924
申请日：2006-08-04
申请人： Takefumi Yano , Motoki Hosaka , Maki Sato , Kohei Kimura
发明人： Takefumi Yano , Motoki Hosaka , Maki Sato , Kohei Kimura
IPC分类号： C08F4/44 , C07F7/02 , B01J31/00 , B01J37/00 , C08K3/34
CPC分类号： C08F10/00 , C07F7/1804 , C08F110/06 , C08F4/6465 , C08F2500/12 , C08F2500/18 , C08F2500/04
摘要： A polymer having high catalyst activity, excellent hydrogen response, high stereoregularity and high yield can be obtained by polymerizing olefins in the presence of a catalyst for olefin polymerization comprising (A) a solid catalyst component containing magnesium, titanium, a halogen, and an electron donor compound, (B) an organoaluminum compound shown by the formula R6pAlQ3-p(R1R2N)m, and (C) an aminosilane compound shown by the formula (R3HN)nR4pSi(OR5)q.
摘要翻译：通过在烯烃聚合催化剂存在下聚合烯烃，可以获得具有高催化剂活性，优异的氢响应，高立构规整性和高收率的聚合物，其包含（A）含有镁，钛，卤素和电子的固体催化剂组分供体化合物，（B）式R6pAlQ3-p（R1R2N）m所示的有机铝化合物，（C）由式（R3HN）nR4pSi（OR5）q表示的氨基硅烷化合物。

8. 发明授权

US07704910B2 Catalyst for polymerization of olefins and method for polymerization of olefins 有权
标题翻译：烯烃聚合催化剂和烯烃聚合方法
公开(公告)号：US07704910B2
公开(公告)日：2010-04-27
申请号：US11569229
申请日：2005-05-17
申请人： Motoki Hosaka , Takefumi Yano , Hiroyuki Kono
发明人： Motoki Hosaka , Takefumi Yano , Hiroyuki Kono
IPC分类号： C08F4/64 , C08F4/642 , C08F4/647 , C08F4/649 , B01J31/14
CPC分类号： C08F10/00 , C08F4/6548 , C08F4/651 , C08F4/6465 , C08F2500/04
摘要： A catalyst for olefin polymerization comprising (A) a solid catalyst component prepared by causing (a) a magnesium compound, (b) a tetravalent titanium halide compound, and (c) an electron donor compound to come in contact with each other, (B) an organoaluminum compound of the general formula R1pAlQ3-p, and (C) an oligomer of an organosilicon compound of the following chemical formula; R4—(R2R3SiO)m—R5 can produce olefin polymers having higher stereoregularity and a broader molecular weight distribution in a higher yield than conventional catalysts.
摘要翻译：一种用于烯烃聚合的催化剂，包括（A）通过使（a）镁化合物，（b）四价卤化钛化合物和（c）电子给体化合物彼此接触而制备的固体催化剂组分，（B ）通式为R1pAlQ3-p的有机铝化合物，（C）下列化学式的有机硅化合物的低聚物; R4-（R2R3SiO）m-R5可以以比常规催化剂更高的产率生产具有较高立构规整性和较宽分子量分布的烯烃聚合物。

9. 发明申请

US20120053310A1 Aminosilane Compounds, Catalyst Components and Catalysts for Olefin Polymerization, and Process for Production of Olefin Polymers with the Same 有权
标题翻译：用于烯烃聚合的氨基硅烷化合物，催化剂组分和催化剂及其生产烯烃聚合物的方法
公开(公告)号：US20120053310A1
公开(公告)日：2012-03-01
申请号：US13289728
申请日：2011-11-04
申请人： Motoki Hosaka , Takefumi Yano , Maki Sato , Kohei Kimura
发明人： Motoki Hosaka , Takefumi Yano , Maki Sato , Kohei Kimura
IPC分类号： C08F4/52 , C07F7/10 , C08F4/72
CPC分类号： C07F7/10 , C08F10/00 , C08F110/06 , C08F4/6492 , C08F4/6495 , C08F4/65927 , C08F2500/18 , C08F2500/12 , C08F2500/04 , C08F4/6465 , C08F4/6548 , C08F4/6565
摘要： A catalyst for polymerization of olefins formed from (A) a solid catalyst component containing magnesium, titanium, halogen, and an electron donor compound, (B) an organoaluminum compound shown by the formula, R6pAlQ3-p, and (C) an aminosilane compound shown by the formula, R3nSi(NR4R5)4-n; and a process for producing a catalyst for polymerization of olefins in the presence of the catalyst are provided. A novel aminosilane compound, a catalyst component for polymerization of olefins having a high catalytic activity, capable of producing polymers with high stereoregularity in a high yield, and exhibiting an excellent hydrogen response, a catalyst, and a process for producing olefin polymers using the catalyst are provided.
摘要翻译：由（A）含有镁，钛，卤素和电子给体化合物的固体催化剂组分形成的烯烃聚合催化剂，（B）由式R6pAlQ3-p表示的有机铝化合物和（C）氨基硅烷化合物如下式所示：R3nSi（NR4R5）4-n; 提供了在催化剂存在下制备烯烃聚合催化剂的方法。一种新型氨基硅烷化合物，具有高催化活性的烯烃聚合催化剂组分，能够以高产率制备具有高立构规整性的聚合物，并表现出优异的氢响应，催化剂和使用该催化剂生产烯烃聚合物的方法被提供。

10. 发明申请

US20100190942A1 AMINOSILANE COMPOUNDS, CATALYST COMPONENTS AND CATALYSTS FOR OLEFIN POLYMERIZATION, AND PROCESS FOR PRODUCTION OF OLEFIN POLYMERS WITH THE SAME 审中-公开
标题翻译：用于烯烃聚合的氨基甲酸酯化合物，催化剂组分和催化剂以及用于生产烯烃聚合物的方法
公开(公告)号：US20100190942A1
公开(公告)日：2010-07-29
申请号：US11916039
申请日：2006-05-26
申请人： Motoki Hosaka , Takefumi Yano , Maki Sato , Kohei Kimura
发明人： Motoki Hosaka , Takefumi Yano , Maki Sato , Kohei Kimura
IPC分类号： C08F2/00 , C07F7/10 , C08F4/602
CPC分类号： C07F7/10 , C08F10/00 , C08F110/06 , C08F4/6492 , C08F4/6495 , C08F4/65927 , C08F2500/18 , C08F2500/12 , C08F2500/04 , C08F4/6465 , C08F4/6548 , C08F4/6565
摘要： A catalyst for polymerization of olefins formed from (A) a solid catalyst component containing magnesium, titanium, halogen, and an electron donor compound, (B) an organoaluminum compound shown by the formula, R6pAlQ3-p, and (C) an aminosilane compound shown by the formula, R3nSi(NR4R5)4-n; and a process for producing a catalyst for polymerization of olefins in the presence of the catalyst are provided. A novel aminosilane compound, a catalyst component for polymerization of olefins having a high catalytic activity, capable of producing polymers with high stereoregularity in a high yield, and exhibiting an excellent hydrogen response, a catalyst, and a process for producing olefin polymers using the catalyst are provided.
摘要翻译：由（A）含有镁，钛，卤素和电子给体化合物的固体催化剂组分形成的烯烃聚合催化剂，（B）由式R6pAlQ3-p表示的有机铝化合物和（C）氨基硅烷化合物如下式所示：R3nSi（NR4R5）4-n; 提供了在催化剂存在下制备烯烃聚合催化剂的方法。一种新型氨基硅烷化合物，具有高催化活性的烯烃聚合催化剂组分，能够以高产率制备具有高立构规整性的聚合物，并表现出优异的氢响应，催化剂和使用该催化剂生产烯烃聚合物的方法被提供。

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