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1. 发明授权

US4272637A Catalyst for oxidation of isobutylene 失效
标题翻译：用于氧化异丁烯的催化剂
公开(公告)号：US4272637A
公开(公告)日：1981-06-09
申请号：US971302
申请日：1978-12-20
申请人： Haruhisa Yamamoto , Nobuaki Yoneyama , Shinichi Akiyama
发明人： Haruhisa Yamamoto , Nobuaki Yoneyama , Shinichi Akiyama
IPC分类号： B01J23/887 , B01J27/00 , B01J27/192 , C07C45/00 , C07C45/35 , C07C47/22 , C07C67/00
CPC分类号： B01J27/192 , B01J23/8876 , C07C45/35 , B01J2523/00
摘要： A catalyst for oxidation of isobutylene which has a composition of the general formulaMo.sub.a Bi.sub.b Fe.sub.c Co.sub.d Ni.sub.e P.sub.f Pb.sub.g X.sub.h O.sub.iwherein X is at least one alkali metal element selected from K, Rb and Cs; a, b, c, d, e, f, g and h respectively represent the number of Mo, Bi, Fe, Co, Ni, P, Pb and X atoms, and when a is 12, b is 0.1-10, c is 9-20, d is 0-12, e is 0-12 with the proviso that the sum of d and e is 0.5-15, f is 0.1-5, g is 0.05-8 and h is 0.01-5; and i is the number of oxygen atoms which satisfies the atomic valences of the other elements.
摘要翻译：用于氧化异丁烯的催化剂，其具有通式为MoaBibFecCodNiePfPbgXhOi的组成，其中X为选自K，Rb和Cs中的至少一种碱金属元素; a，b，c，d，e，f，g和h分别表示Mo，Bi，Fe，Co，Ni，P，Pb和X原子的数量，当a为12时，b为0.1-10，c 为9-20，d为0-12，e为0-12，条件是d和e的和为0.5-15，f为0.1-5，g为0.05-8，h为0.01-5; i是满足其他元素的原子价的氧原子数。

2. 发明授权

US4220802A Process for the preparation of acrylic acid 失效
标题翻译：制备丙烯酸的方法
公开(公告)号：US4220802A
公开(公告)日：1980-09-02
申请号：US848668
申请日：1977-11-04
申请人： Shinichi Akiyama , Haruhisa Yamamoto
发明人： Shinichi Akiyama , Haruhisa Yamamoto
IPC分类号： B01J23/28 , B01J27/00 , B01J27/199 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C51/32 , C07C57/04
CPC分类号： B01J23/28 , B01J23/002 , B01J27/199 , C07C51/252 , B01J2523/00
摘要： A process for the preparation of acrylic acid which comprises reacting acrolein with molecular oxygen in the vapor phase in the presence of an oxidation catalyst composition having the following empirical formulaMo.sub.a P.sub.b V.sub.c L.sub.d M.sub.e O.sub.fwherein L is at least one element selected from the group consisting of Rb, Cs and K; M is at least one element selected from the group consisting of Sr, Nb, Cd, B, Zn and Pb; and a, b, c, d, e and f each represent the number of atoms of each element; the atomic ratio of a:b:c:d:e being 12:0.1-8:0.1-8:0.1-8:0-6; and f being the number of oxygen atoms determined by the valence requirement of the other elements present; and an oxidation catalyst used therefor.
摘要翻译：一种制备丙烯酸的方法，其包括在具有以下经验式MoaPbVcLdMeOf的氧化催化剂组合物存在下，使气相中的丙烯醛与分子氧反应，其中L是选自Rb，Cs和 K; M是选自Sr，Nb，Cd，B，Zn和Pb中的至少一种元素; 和a，b，c，d，e和f各自表示每个元素的原子数; a:b:c:d:e的原子比为12:1-8:0.1:8:0.1:8:0-6; 和f是由其他元素存在的化合价要求确定的氧原子数; 和用于其的氧化催化剂。

3. 发明授权

US3976688A Process for preparing unsaturated carboxylic acids 失效
标题翻译：制备不饱和羧酸的方法
公开(公告)号：US3976688A
公开(公告)日：1976-08-24
申请号：US523683
申请日：1974-11-14
申请人： Shinichi Akiyama , Haruhisa Yamamoto
发明人： Shinichi Akiyama , Haruhisa Yamamoto
IPC分类号： B01J23/28 , B01J23/31 , B01J27/186 , C07C51/25 , C07C57/055 , C07C51/32
CPC分类号： B01J27/186 , B01J23/28 , B01J23/31 , C07C51/252
摘要： A process for the preparation of an unsaturated carboxylic acid which comprises reacting an unsaturated aldehyde with molecular oxygen in the vapor phase in the presence of an oxidation catalyst composition having the following empirical formulaMo.sub.a P.sub.b L.sub.c T.sub.d O.sub.ewherein L is at least one element selected from the group consisting of Rb, Cs and K; T is at least one element selected from the group consisting of Ba, Cd, W, Bi, Nb, B, Pb and Pd; and a, b, c, d, and e each represent the number of atoms of each element; the atomic ratio of a:b:c:d is 12:0.1-8:0.1-8:0.1-8 and e is the number of oxygen atoms determined by the valence requirement of the other elements present.
摘要翻译：一种制备不饱和羧酸的方法，其包括在具有以下经验式的氧化催化剂组合物存在下，使不饱和醛与气相中的分子氧反应，其中Moa Pb Lc Td Oe WHEREIN L是至少一种选自由Rb，Cs和K组成的组; T是选自Ba，Cd，W，Bi，Nb，B，Pb和Pd中的至少一种元素; 和a，b，c，d和e各自表示每个元素的原子数; a:b:c:d的原子比为12:1-8:0.1:8:1-8，e是由其它元素的化合价要求决定的氧原子数。

4. 发明授权

US4564703A Process for preparing methacrylic acid 失效
标题翻译：制备甲基丙烯酸的方法
公开(公告)号：US4564703A
公开(公告)日：1986-01-14
申请号：US30647
申请日：1979-04-16
申请人： Haruhisa Yamamoto , Shinichi Akiyama
发明人： Haruhisa Yamamoto , Shinichi Akiyama
IPC分类号： C07C51/00 , C07C51/25 , C07C51/48 , C07C57/055 , C07C67/00
CPC分类号： C07C51/252 , C07C51/48
摘要： In a process for preparing methacrylic acid by the vapor-phase catalytic oxidation of methacrolein or a methacrolein-containing mixture with molecular oxygen in the presence of an oxidation catalyst; the improvement wherein said process comprisesa first-stage oxidation step of oxidizing methacrolein or a methacrolein-containing mixture as a starting material,a first-stage separating step of separating the resulting methacrylic acid from the reaction product obtained in the first-stage oxidation step,a second-stage oxidation step of oxidizing the mixture containing the unreacted methacrolein and obtained in the first-stage separating step, anda second-stage separating step of separating the resulting methacrylic acid from the reaction product obtained in the second-stage oxidation step, andwith or without at least one additional oxidation step and separating step subsequent to the second-stage separating step,and wherein the conversion of methacrolein in the first-stage oxidation step is adjusted to 30-85 mole % and the final conversion of methacrolein is adjusted to at least 90 mole %.
摘要翻译：在氧化催化剂存在下，通过气相催化氧化甲基丙烯醛或含有异丁烯醛的混合物与分子氧制备甲基丙烯酸的方法; 改进之处在于，所述方法包括氧化异丁烯醛或含异丁烯醛的混合物作为原料的第一阶段氧化步骤，从第一阶段氧化步骤获得的反应产物中分离得到的甲基丙烯酸的第一阶段分离步骤在第一阶段分离工序中氧化含有未反应的甲基丙烯醛的混合物的第二阶段氧化步骤和从后段氧化步骤得到的反应产物中分离得到的甲基丙烯酸的第二阶段分离步骤，并且在第二阶段分离步骤之后有或没有至少一个额外的氧化步骤和分离步骤，并且其中将第一阶段氧化步骤中的甲基丙烯醛的转化率调节至30-85摩尔％，并且甲基丙烯醛的最终转化率调节至至少90摩尔％。

5. 发明授权

US4113770A Process for preparing unsaturated carboxylic acids 失效
标题翻译：制备不饱和羧酸的方法
公开(公告)号：US4113770A
公开(公告)日：1978-09-12
申请号：US777679
申请日：1977-03-15
申请人： Shinichi Akiyama , Haruhisa Yamamoto
发明人： Shinichi Akiyama , Haruhisa Yamamoto
IPC分类号： B01J23/28 , B01J23/30 , B01J23/31 , B01J27/186 , C07C51/25 , C07C51/32
CPC分类号： B01J27/186 , B01J23/28 , B01J23/30 , B01J23/31 , C07C51/252
摘要： A process for the preparation of an unsaturated carboxylic acid which comprises reacting an unsaturated aldehyde with molecular oxygen in the vapor phase in the presence of an oxidation catalyst composition having the following empirical formulaMo.sub.a P.sub.b Cr.sub.c Q.sub.d L.sub.e O.sub.fwherein Q is at least one element selected from the group consisting of Tl, Rb, Cs and K; L is at least one element selected from the group consisting of Sr, Zn, Cd, V, Nb, B, Pb, Bi and W; and a, b, c, d, e and f each represent the number of atoms of each element; the atomic ratio of a:b:c:d:e is 12:0.1-8:0.1-8:0.1-8:0.01-6; and f is the number of oxygen atoms determined by the valence requirement of the other elements present.
摘要翻译：一种制备不饱和羧酸的方法，其包括使不饱和醛与气相中的分子氧在存在具有以下经验式的氧化催化剂组合物的存在下反应，其中WHAEIN Q为至少一种元素来自由Tl，Rb，Cs和K组成的组; L是选自Sr，Zn，Cd，V，Nb，B，Pb，Bi和W中的至少一种元素; 和a，b，c，d，e和f各自表示每个元素的原子数; a:b:c:d:e的原子比为12:1-8:0.1:8:0.1:8:0.01-6; 而f是由其它元素的化合价要求决定的氧原子数。

6. 发明授权

US4238359A Process for preparing spherical shaped pelletized oxide catalysts comprising molybdenum and phosphorus 失效
标题翻译：制备包含钼和磷的球形颗粒状氧化物催化剂的方法
公开(公告)号：US4238359A
公开(公告)日：1980-12-09
申请号：US38057
申请日：1979-05-11
申请人： Shinichi Akiyama , Haruhisa Yamamoto , Nobuaki Yoneyama , Shinji Matsumoto
发明人： Shinichi Akiyama , Haruhisa Yamamoto , Nobuaki Yoneyama , Shinji Matsumoto
IPC分类号： B01J23/28 , B01J23/31 , B01J27/19 , B01J35/10 , B01J37/00 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , B01J21/18 , B01J21/14 , C07C57/04
CPC分类号： B01J27/19 , B01J23/28 , B01J23/31 , C07C51/252
摘要： A catalyst composition for use in preparing unsaturated carboxylic acids by the vapor-phase oxidation of unsaturated aldehydes, said catalyst composition comprising an oxide composition containing as essential ingredients (1) phosphorus, (2) molybdenum and (3) X in which X is at least one element selected from the group consisting of thallium and metals of Groups IA and II of the periodic table, characterized in that said oxide composition has a surface area of 4 to 20 m.sup.2 /g and a pore volume of 0.08 to 0.5 ml/g, whereby said catalyst composition has an excellent reproducibility of catalytic activity and a process for preparing aforesaid catalyst composition.
摘要翻译：一种用于通过不饱和醛的气相氧化制备不饱和羧酸的催化剂组合物，所述催化剂组合物包含含有作为必要成分（1）磷，（2）钼和（3）X中的X的氧化物组合物选自铊和元素周期表第IA和II族金属的至少一种元素，其特征在于所述氧化物组合物的表面积为4至20m 2 / g，孔体积为0.08至0.5ml / g 由此所述催化剂组合物具有优异的催化活性再现性和制备上述催化剂组合物的方法。

7. 发明授权

US4245118A Oxidation of unsaturated aldehydes 失效
标题翻译：不饱和醛的氧化
公开(公告)号：US4245118A
公开(公告)日：1981-01-13
申请号：US1783
申请日：1979-01-08
申请人： Haruhisa Yamamoto , Kiyomori Ooura , Shinichi Akiyama
发明人： Haruhisa Yamamoto , Kiyomori Ooura , Shinichi Akiyama
IPC分类号： C07C57/055 , B01J23/28 , B01J23/31 , B01J27/00 , B01J27/186 , C07C51/00 , C07C51/235 , C07C51/25 , C07C67/00
CPC分类号： B01J27/186 , B01J23/28 , B01J23/31 , C07C51/252
摘要： Catalysts for the oxidation of unsaturated aldehydes, said catalysts being expressed by the formulaA.sub.a B.sub.b C.sub.c Mo.sub.d P.sub.e O.sub.fwherein A represents at least one element selected from K, Rb, Cs and Tl; B represents at least one element selected from Be, Ag, Y, La, Nd, Sm and Hf; C represents at least one element selected from V, Cr, Ba, Sr, Al, Sn, Pb, Mn, Zr, W and Bi; a, b, c, d, e and f are the number of the atoms of A, B, C, Mo, P and O, respectively; and when d is 12, a, b and e are independently 0.05 to 12, c is 0 to 12, and f is the number of oxygen atoms which satisfies the valences of the other elements.
摘要翻译：用于氧化不饱和醛的催化剂，所述催化剂由式AaBbCcModPeOf表示，其中A表示选自K，Rb，Cs和T1中的至少一种元素; B表示选自Be，Ag，Y，La，Nd，Sm和Hf中的至少一种元素; C表示选自V，Cr，Ba，Sr，Al，Sn，Pb，Mn，Zr，W和Bi中的至少一种元素; a，b，c，d，e和f分别是A，B，C，Mo，P和O的原子数; 当d为12时，a，b和e独立地为0.05〜12，c为0〜12，f为满足其他元素的化合价的氧原子数。

8. 发明授权

US4186152A Oxidation of olefins 失效
标题翻译：烯烃的氧化
公开(公告)号：US4186152A
公开(公告)日：1980-01-29
申请号：US821315
申请日：1977-08-02
申请人： Haruhisa Yamamoto , Shinichi Akiyama
发明人： Haruhisa Yamamoto , Shinichi Akiyama
IPC分类号： C07C27/14 , B01J23/88 , B01J23/89 , B01J27/198 , B01J27/199 , B01J37/02 , C07B61/00 , C07C27/00 , C07C45/00 , C07C45/35 , C07C47/22 , C07C51/00 , C07C57/055 , C07C67/00 , C07C45/04
CPC分类号： B01J23/887 , B01J23/8993 , B01J37/0236 , C07C45/35 , B01J2523/00
摘要： A catalyst for oxidation of olefins which has a composition of the general formulaMo.sub.a Bi.sub.b Fe.sub.c Co.sub.d Ni.sub.e Be.sub.f Q.sub.g R.sub.h X.sub.i O.sub.jwherein Q is at least one element selected from K, Rb, Cs and Tl; R is at least one element selected from P, As and B; X is at least one element selected from Ce, Ti, Te, Zn, Ge, Sn, Cr, Ga, La, In, Al, Cd, Pd, Mn, V, Pb, Nb, Ag, Zr, Cu, Nd and U; a, b, c, d, e, f, g, h and i respectively represent the numbers of Mo, Bi, Fe, Co, Ni, Be, Q, R and X atoms, and when a is 12, b is 0.1-10, c is 0.5-40, d is 0-12, e is 0-12 with the proviso that the sum of d and e is 0.5-15, f is 0.1-35, g is 0.01-5, h is 0-5, i is 0-12; and j is the number of oxygen atoms which satisfies the atomic valences of the other elements.Unsaturated aldehydes can be prepared in a high selectivity and a high one-pass yield by oxidizing olefins containing 3 carbon atoms in the straight chain in the vapor phase in the presence of the aforesaid catalyst at a temperature of 250.degree. to 700.degree. C.
摘要翻译：用于烯烃氧化的催化剂，其具有通式为MoaBibFecCodNieBefQgRhXiOj的组成，其中Q为选自K，Rb，Cs和T1中的至少一种元素; R是选自P，As和B中的至少一种元素; X是选自Ce，Ti，Te，Zn，Ge，Sn，Cr，Ga，La，In，Al，Cd，Pd，Mn，V，Pb，Nb，Ag，Zr，Cu，Nd中的至少一种元素， U; a，b，c，d，e，f，g，h和i分别表示Mo，Bi，Fe，Co，Ni，Be，Q，R和X原子的数，当a为12时，b为0.1 -10，c为0.5-40，d为0-12，e为0-12，条件是d和e的和为0.5-15，f为0.1-35，g为0.01-5，h为0 -5，我是0-12; 并且j是满足其它元素的原子价的氧原子数。在上述催化剂存在下，在250〜700℃的温度下，通过在蒸气相中在直链中含有3个碳原子的烯烃进行氧化，可以高选择性和高一次收率制备不饱和醛。

9. 发明授权

US4155938A Oxidation of olefins 失效
标题翻译：烯烃的氧化
公开(公告)号：US4155938A
公开(公告)日：1979-05-22
申请号：US831672
申请日：1977-09-08
申请人： Haruhisa Yamamoto , Novuaki Yoneyama , Shinichi Akiyama
发明人： Haruhisa Yamamoto , Novuaki Yoneyama , Shinichi Akiyama
IPC分类号： C07C57/05 , B01J23/88 , B01J23/89 , B01J27/192 , B01J37/02 , C07B61/00 , C07C45/00 , C07C45/34 , C07C45/35 , C07C47/21 , C07C47/22 , C07C51/00 , C07C67/00
CPC分类号： B01J23/8871 , B01J23/887 , B01J23/8876 , B01J23/8993 , B01J37/0236 , C07C45/35 , B01J2523/00
摘要： A catalyst for oxidation of olefins which has a composition of the general formulaMo.sub.a Bi.sub.b Fe.sub.c Co.sub.d Ni.sub.e Q.sub.f R.sub.g X.sub.h Z.sub.i O.sub.jwherein Q is at least one element selected from Au and Nd; R is at least one elemet selected from K, Rb, Cs and Tl; X is at least one lement selected from P, As and B; Z is at least one element selected from Ce, Ti, Te, Zn, Ge, Sn, Cr, Ga, La, In, Al, Cd, Pd, Mn, V, W, Pb, Nb, Ag, Zr, Cu and U; a, b, c, d, e, f, g, h and i respectively represent the numbers of Mo, Bi, Fe, Co, Ni, Q, R, X and Z atoms, and when a is 12, b is 0.1-10, c is 0.5-40, d is 0-12, e is 0-12 with the proviso that the sum of d and e is 0.5-15, f is 0.1-8, g is 0.01-5, h is 0-5, i is 0-12; and j is the number of oxygen atoms which satisfies the atomic valences of the other elements.
摘要翻译：用于烯烃氧化的催化剂，其具有通式为MoaBibFecCodNieQfRgXhZiOj的组成，其中Q为选自Au和Nd中的至少一种元素; R是选自K，Rb，Cs和T1中的至少一个元素; X是选自P，As和B中的至少一种; Z是选自Ce，Ti，Te，Zn，Ge，Sn，Cr，Ga，La，In，Al，Cd，Pd，Mn，V，W，Pb，Nb，Ag，Zr，Cu和 U; a，b，c，d，e，f，g，h和i分别表示Mo，Bi，Fe，Co，Ni，Q，R，X和Z原子的数，当a为12时，b为0.1 -10，c为0.5-40，d为0-12，e为0-12，条件是d和e的和为0.5-15，f为0.1-8，g为0.01-5，h为0 -5，我是0-12; 并且j是满足其它元素的原子价的氧原子数。

10. 发明授权

US4075244A Process for preparing methacrylic acid 失效
标题翻译：制备甲基丙烯酸的方法
公开(公告)号：US4075244A
公开(公告)日：1978-02-21
申请号：US735550
申请日：1976-10-26
申请人： Shinichi Akiyama , Haruhisa Yamamoto
发明人： Shinichi Akiyama , Haruhisa Yamamoto
IPC分类号： B01J27/199 , C07C51/25 , C07C57/055 , C07C51/32
CPC分类号： B01J23/002 , B01J27/199 , C07C51/252 , B01J2523/00
摘要： A process for the preparation of methacrylic acid which comprises reacting methacrolein with molecular oxygen in the vapor phase in the presence of an oxidation catalyst composition having the following empirical formulaMo.sub.a P.sub.b V.sub.c L.sub.d M.sub.e O.sub.fwherein L is at least one element selected from the group consisting of Rb, Cs and K; M is at least one element selected from the group consisting of Sr, Zn, Cd, Nb, B, Pb, and W; and a, b, c, d, e and f each represent the number of atoms of each element; the atomic ratio of a:b:c:d:e is 12:0.1-8:0.1-8:0.1-8:0-6; and f is the number of oxygen atoms determined by the valence requirement of the other elements present.
摘要翻译：一种制备甲基丙烯酸的方法，其包括在具有以下经验式的氧化催化剂组合物存在下，使气相中的甲基丙烯醛与分子氧反应，其中WHAEIN L为至少一种选自以下的元素：的Rb，Cs和K; M是选自Sr，Zn，Cd，Nb，B，Pb和W中的至少一种元素; 和a，b，c，d，e和f各自表示每个元素的原子数; a:b:c:d:e的原子比为12:1-8:0.1:8:0.1:8:0-6; 而f是由其它元素的化合价要求决定的氧原子数。

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