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1. 发明授权

US06699925B2 Flame-retardant thermoplastic resin composition and manufacturing method thereof 有权
标题翻译：阻燃热塑性树脂组合物及其制造方法
公开(公告)号：US06699925B2
公开(公告)日：2004-03-02
申请号：US09938251
申请日：2001-08-23
申请人： Hidekatsu Hatanaka , Koji Nakanishi , Haruhiko Furukawa , Koji Shiromoto , Hiroshi Ueki , Yoshitsugu Morita
发明人： Hidekatsu Hatanaka , Koji Nakanishi , Haruhiko Furukawa , Koji Shiromoto , Hiroshi Ueki , Yoshitsugu Morita
IPC分类号： C08K320
CPC分类号： C08L23/04 , C08L83/04 , C08L2201/02 , C08L83/00
摘要： A flame-retardant thermoplastic resin composition comprising (A) 100 weight parts of a thermoplastic resin, (B) 10 to 300 weight parts of particulate metal hydroxide; (C) 0.01 to 50 weight parts of a branched polyorganosiloxane having alkoxy groups and described by average unit formula R1a(R2O)bSiO(4−a−b)/2, where R1 and R2 are monovalent hydrocarbon groups selected from the group consisting of alkyl, alkenyl, and aryl groups, a is 0 or a positive number; b is a positive number; and a+b is a number from 0.75 to 2.5; (D) 0.01 to 50 weight parts of a branched polyorganosiloxane having silanol groups and described by average unit formula R3a(HO)bSiO(4−a−b)/2, where R3 is a monovalent hydrocarbon group selected from the group consisting of alkyl, alkenyl, and aryl groups, a is 0 or a positive number, b is a positive number, and a+b is a number from 0.75 to 2.5; and (E) 0.01 to 10 weight parts of a condensation reaction promoting catalyst. The present invention further relates to a method for manufacturing the flame-retardant thermoplastic resin composition.
摘要翻译：一种阻燃热塑性树脂组合物，其包含（A）100重量份的热塑性树脂，（B）10〜300重量份的颗粒状金属氢氧化物; （C）0.01至50重量份的具有烷氧基且由平均单元式R a a（R 2 O）b SiO（4-ab）/ 2表示的支链聚有机硅氧烷，其中R 1和R 2， 2>是选自烷基，烯基和芳基的一价烃基，a是0或正数; b是正数; a + b为0.75〜2.5的数; （D）0.01〜50重量份具有硅烷醇基且由平均单元式R 3 a（HO）b SiO（4-ab）/ 2表示的支链聚有机硅氧烷，其中R 3为选自由烷基，烯基和芳基组成的组，a为0或正数，b为正数，a + b为0.75至2.5的数; 和（E）0.01〜10重量份缩合反应促进催化剂。本发明还涉及一种阻燃热塑性树脂组合物的制造方法。

2. 发明授权

US06303681B1 Flame-retardant polyolefin-type resin composition, method for the preparation thereof, and flame retardant cables 有权
标题翻译：阻燃聚烯烃类树脂组合物，其制备方法和阻燃电缆
公开(公告)号：US06303681B1
公开(公告)日：2001-10-16
申请号：US09662371
申请日：2000-09-15
申请人： Haruhiko Furukawa , Hidekatsu Hatanaka , Koji Shiromoto , Hiroshi Ueki , Koji Nakanishi , Yoshitsugu Morita
发明人： Haruhiko Furukawa , Hidekatsu Hatanaka , Koji Shiromoto , Hiroshi Ueki , Koji Nakanishi , Yoshitsugu Morita
IPC分类号： C08K322
CPC分类号： C08L23/04 , C08K3/22 , C08K2003/2217 , C08K2003/2227 , C08L23/08 , C08L83/06 , C08L2201/02 , C08L83/00 , C08L2666/04
摘要： A flame-retardant polyolefin-type resin composition comprising (A) 100 weight parts polyolefin-type resin, (B) 30 to 200 weight parts powder of a hydrated metal compound, and (C) 0.01 to 50 weight parts branched organopolysiloxane with average unit formula RaSiO(4−a)/2 where each R is a selected from the group consisting of monovalent organic groups selected from the group consisting of C1 to C12 alkyl and C6 to C12 aryl and hydroxyl, wherein aryl constitutes from 50 to 100 mole % of the total monovalent organic groups and the hydroxyl content in each molecule is from 1 to 10 weight %, a is a number from 0.75 to 2.5, and the organopolysiloxane contains at least one RSiO3/2 siloxane unit in each molecule, where R is as previously described. The composition is useful as a flame-retardant coating on electrical cables.
摘要翻译：一种阻燃聚烯烃类树脂组合物，其包含（A）100重量份聚烯烃类树脂，（B）30〜200重量份水合金属化合物粉末，和（C）0.01〜50重量份平均单位的支链有机聚硅氧烷每个R选自由选自C1至C12烷基和C6至C12芳基和羟基的一价有机基团组成的组，其中芳基构成总一价有机基团的50至100摩尔％，羟基每个分子中的含量为1至10重量％，a为0.75至2.5的数，并且有机聚硅氧烷在每个分子中含有至少一个RSiO 3/2硅氧烷单元，其中R如前所述。该组合物可用作电缆上的阻燃涂层。

3. 发明授权

US06534576B2 Flame retardant organic resin composition 有权
标题翻译：阻燃有机树脂组合物
公开(公告)号：US06534576B2
公开(公告)日：2003-03-18
申请号：US09907281
申请日：2001-07-17
申请人： Koji Nakanishi , Hidekatsu Hatanaka , Haruhiko Furukawa , Koji Shiromoto , Hiroshi Ueki , Yoshitsugu Morita
发明人： Koji Nakanishi , Hidekatsu Hatanaka , Haruhiko Furukawa , Koji Shiromoto , Hiroshi Ueki , Yoshitsugu Morita
IPC分类号： C08K504
CPC分类号： C08L69/00 , C08F283/12 , C08K5/5419 , C08L27/12 , C08L55/02 , C08L83/04 , C08L2666/02 , C08L83/00
摘要： A flame retardant organic resin composition comprising (A) 100 parts by weight of an aromatic ring-containing organic resin and (B) 0.01-50 parts by weight of a branched organopolysiloxane described by average molecular formula (R13SiO1/2)a(R2SiO3/2)b(SiO4/2)c(R3O1/2)d(HO1/2)e, where each R1 is independently selected from alkyl groups comprising 1 to 12 carbon atoms and alkenyl groups comprising 2 to 12 carbon atoms; each R2 is independently selected from alkyl groups comprising 1 to 12 carbon atoms, alkenyl groups comprising 2 to 12 carbon atoms, and aryl groups comprising 6 to 12 carbon atoms, where the aryl groups of R2 are at least 30 mol % based on total monovalent hydrocarbon in R1 and R2, R3 represents an alkyl group, subscripts a and b are positive numbers, and subscripts c, d, and e are 0 or positive numbers.
摘要翻译：一种阻燃有机树脂组合物，其包含（A）100重量份的含芳环的有机树脂和（B）0.01-50重量份的由平均分子结构域所述的支链有机基聚硅氧烷，每个R 1独立地选自烷基， 1至12个碳原子和2至12个碳原子的链烯基; 每个R 2独立地选自包含1至12个碳原子的烷基，包含2至12个碳原子的烯基和包含6至12个碳原子的芳基，其中R 2的芳基基于总单价为至少30摩尔％ R 1和R 2中的烃，R 3表示烷基，下标a和b为正数，下标c，d和e为0或正数。

4. 发明授权

US07105614B2 Curable epoxy resin composition 有权
标题翻译：可固化环氧树脂组合物
公开(公告)号：US07105614B2
公开(公告)日：2006-09-12
申请号：US10482323
申请日：2002-06-28
申请人： Yoshitsugu Morita , Hiroshi Ueki , Koji Nakanishi , Haruhiko Furukawa
发明人： Yoshitsugu Morita , Hiroshi Ueki , Koji Nakanishi , Haruhiko Furukawa
IPC分类号： C08L63/00
CPC分类号： C08L61/06 , C08L61/04 , C08L63/00 , C08L83/04 , C08L83/06 , C08L2205/03 , C08L2666/22 , C08L2666/14 , C08L83/00
摘要： A curable epoxy resin composition comprising at least: (A) a crystalline epoxy resin, (B) a phenol resin, and (C) a silicone resin composed of epoxy-containing organic groups and phenyl groups that define an average unit formula of this component. Component (C) is used in an amount of 0.1 to 500 parts by weight for 100 parts by weight of the sum of weights of components (A) and (B). The composition of the invention is suitable for transfer and injection molding and may find use as a curable epoxy resin composition for sealing parts of electrical and electronic devices.
摘要翻译：一种可固化环氧树脂组合物，其至少包含：（A）结晶环氧树脂，（B）酚醛树脂，和（C）由含环氧基的有机基团和苯基构成的有机硅树脂，其定义该组分的平均单元式。对于100重量份的组分（A）和（B）的重量之和，组分（C）的用量为0.1至500重量份。本发明的组合物适用于转印和注射成型，可用作密封电子和电子器件部件的可固化环氧树脂组合物。

5. 发明申请

US20050080204A1 Silicone resin composition, curable resin composition, and curable resin 有权
标题翻译：硅树脂组合物，可固化树脂组合物和可固化树脂
公开(公告)号：US20050080204A1
公开(公告)日：2005-04-14
申请号：US10504338
申请日：2003-02-14
申请人： Haruhiko Furukawa , Koji Nakanishi , Yoshitsugu Morita , Hiroshi Ueki
发明人： Haruhiko Furukawa , Koji Nakanishi , Yoshitsugu Morita , Hiroshi Ueki
IPC分类号： C08G77/14 , C08K5/00 , C08L61/06 , C08L63/00 , C08L83/04 , C08L83/06 , C08L101/00
CPC分类号： C08L61/06 , C08K5/0066 , C08L63/00 , C08L83/04 , C08L83/06 , C08L83/00 , C08L2666/22 , C08L2666/14 , C08L2666/02
摘要： The present invention relates to a silicone resin composition of low melt viscosity and excellent reactivity and dispersibility in organic resins. The present invention also relates to a curable resin composition for forming a cured resin of excellent moldability and superior flame retardant properties while having little adverse impact on the human body and the environment as a result of containing no antimony oxides or halogenated epoxy resins. The present invention also relates to a cured resin having little adverse impact on the human body or the environment and possessing superior flame retardant properties.
摘要翻译：本发明涉及一种熔体粘度低，反应性和分散性优异的有机树脂组合物。本发明还涉及一种用于形成固化树脂的固化树脂组合物，其具有优异的成型性和优异的阻燃性能，同时由于不含氧化锑或卤化环氧树脂而对人体和环境几乎没有不利的影响。本发明还涉及对人体或环境几乎没有不利影响且具有优异的阻燃性能的固化树脂。

6. 发明授权

US07138467B2 Silicone resin composition, curable resin composition, and curable resin 有权
标题翻译：硅树脂组合物，可固化树脂组合物和可固化树脂
公开(公告)号：US07138467B2
公开(公告)日：2006-11-21
申请号：US10504338
申请日：2003-02-14
申请人： Haruhiko Furukawa , Koji Nakanishi , Yoshitsugu Morita , Hiroshi Ueki
发明人： Haruhiko Furukawa , Koji Nakanishi , Yoshitsugu Morita , Hiroshi Ueki
IPC分类号： C08L63/00
CPC分类号： C08L61/06 , C08K5/0066 , C08L63/00 , C08L83/04 , C08L83/06 , C08L83/00 , C08L2666/22 , C08L2666/14 , C08L2666/02
摘要： The present invention relates to a silicone resin composition of low melt viscosity and excellent reactivity and dispersibility in organic resins. The present invention also relates to a curable resin composition for forming a cured resin of excellent moldability and superior flame retardant properties while having little adverse impact on the human body and the environment as a result of containing no antimony oxides or halogenated epoxy resins. The present invention also relates to a cured resin having little adverse impact on the human body or the environment and possessing superior flame retardant properties.
摘要翻译：本发明涉及一种熔体粘度低，反应性和分散性优异的有机树脂组合物。本发明还涉及一种用于形成固化树脂的固化树脂组合物，其具有优异的成型性和优异的阻燃性能，同时由于不含氧化锑或卤化环氧树脂而对人体和环境几乎没有不利的影响。本发明还涉及对人体或环境几乎没有不利影响且具有优异的阻燃性能的固化树脂。

7. 发明申请

US20070244287A1 Room-Temperature-Curable Organopolysiloxane Composition 有权
标题翻译：室温固化有机聚硅氧烷组合物
公开(公告)号：US20070244287A1
公开(公告)日：2007-10-18
申请号：US11765811
申请日：2007-06-20
申请人： Hidekatsu Hatanaka , Harumi Kodama , Masayuki Onishi , Hiroji Enami , Koji Nakanishi
发明人： Hidekatsu Hatanaka , Harumi Kodama , Masayuki Onishi , Hiroji Enami , Koji Nakanishi
IPC分类号： C08G77/06
CPC分类号： C08K5/0025 , C08G77/045 , C08G77/06 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/24 , C08G77/70 , C08K3/016 , C08K5/0066 , C08K9/10 , C08L83/04 , Y10S528/901 , C08L83/00 , C08L2666/54 , C08L2666/52 , C08L2666/44
摘要： A room-temperature-curable organopolysiloxane composition comprising: (A) an organopolysiloxane having 1.5 or more end groups having at least one hydroxyl group on the average; (B) a silane or a siloxane oligomer having three or more silicon-bonded hydrolyzable groups; (D) an inorganic powder; and either (C) microparticles of thermoplastic resin containing a platinum compound having an average diameter from 0.1 to 20 μm; or (C1) a platinum compound; and (C2) an organosiloxane oligomer which contains aryl and alkenyl groups and has 8 or less silicon atoms in each molecule and which contains in each molecule at least one divalent organosiloxane as represented by the formula: —(R2)(R3)SiO—(R2)(R3)Si—, (where R2 is an aryl group, and R3 is an alkenyl group), in a quantity of at least 2 moles of component (C2) per 1 mole platinum atoms in component (C1).
摘要翻译：一种室温可固化的有机聚硅氧烷组合物，其包含：（A）平均具有至少一个羟基的具有1.5个或更多个端基的有机聚硅氧烷; （B）具有三个或更多个硅键合的可水解基团的硅烷或硅氧烷低聚物; （D）无机粉末; 和（C）含有平均直径为0.1〜20μm的铂化合物的热塑性树脂微粒; 或（C1）铂化合物; 和（C2）含有芳基和烯基并且在每个分子中具有8个或更少的硅原子并且在每个分子中含有至少一个如下式所示的二价有机硅氧烷的有机硅氧烷低聚物：<？in-line-formula description =“ - （R 2）（R 3） - （R 2）（R 3）（R 3） Si-，<β在线公式描述=“In-line formula”end =“tail”？>（其中R 2是芳基，和R 3为链烯基），其量为组分（C1）中每1摩尔铂原子至少2摩尔组分（C2）。

8. 发明授权

US07250467B2 Room-temperature-curable organopolysiloxane composition 有权
标题翻译：室温可固化的有机聚硅氧烷组合物
公开(公告)号：US07250467B2
公开(公告)日：2007-07-31
申请号：US10482904
申请日：2002-07-26
申请人： Hidekatsu Hatanaka , Harumi Kodama , Masayuki Onishi , Hiroji Enami , Koji Nakanishi
发明人： Hidekatsu Hatanaka , Harumi Kodama , Masayuki Onishi , Hiroji Enami , Koji Nakanishi
IPC分类号： C08L83/06
CPC分类号： C08K5/0025 , C08G77/045 , C08G77/06 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/24 , C08G77/70 , C08K3/016 , C08K5/0066 , C08K9/10 , C08L83/04 , Y10S528/901 , C08L83/00 , C08L2666/54 , C08L2666/52 , C08L2666/44
摘要： A room-temperature-curable organopolysiloxane composition comprising: (A) an organopolysiloxane having 1.5 or more end groups having at least one hydroxyl group on the average; (B) a silane or a siloxane oligomer having three or more silicon-bonded hydrolyzable groups; (D) an inorganic powder; and either (C) microparticles of thermoplastic resin containing a platinum compound having an average diameter from 0.1 to 20 μm; or (C1) a platinum compound; and (C2) an organosiloxane oligomer which contains aryl and alkenyl groups and has 8 or less silicon atoms in each molecule and which contains in each molecule at least one divalent organosiloxane as represented by the formula: —(R2)(R3)SiO—(R2)(R3)Si—, (where R2 is an aryl group, and R3 is an alkenyl group), in a quantity of at least 2 moles of component (C2) per 1 mole platinum atoms in component (C1).
摘要翻译：一种室温可固化的有机聚硅氧烷组合物，其包含：（A）平均具有至少一个羟基的具有1.5个或更多个端基的有机聚硅氧烷; （B）具有三个或更多个硅键合的可水解基团的硅烷或硅氧烷低聚物; （D）无机粉末; 和（C）含有平均直径为0.1〜20μm的铂化合物的热塑性树脂微粒; 或（C1）铂化合物; 和（C2）含有芳基和烯基并且在每个分子中具有8个或更少的硅原子并且在每个分子中含有至少一个如下式所示的二价有机硅氧烷的有机硅氧烷低聚物：<？in-line-formula description =“ - （R 2）（R 3） - （R 2）（R 3）（R 3） Si - ，<？在线公式描述=“在线公式”end =“tail”？>（其中R 2是芳基，和R 3为链烯基），其量为组分（C1）中每1摩尔铂原子至少2摩尔组分（C2）。

9. 发明授权

US07550548B2 Room-temperature-curable organopolysiloxane composition 有权
标题翻译：室温可固化的有机聚硅氧烷组合物
公开(公告)号：US07550548B2
公开(公告)日：2009-06-23
申请号：US11765811
申请日：2007-06-20
申请人： Hidekatsu Hatanaka , Harumi Kodama , Masayuki Onishi , Hiroji Enami , Koji Nakanishi
发明人： Hidekatsu Hatanaka , Harumi Kodama , Masayuki Onishi , Hiroji Enami , Koji Nakanishi
IPC分类号： C08G77/04
CPC分类号： C08K5/0025 , C08G77/045 , C08G77/06 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/24 , C08G77/70 , C08K3/016 , C08K5/0066 , C08K9/10 , C08L83/04 , Y10S528/901 , C08L83/00 , C08L2666/54 , C08L2666/52 , C08L2666/44
摘要： A room-temperature-curable organopolysiloxane composition comprising: (A) 100 parts by weight of an organopolysiloxane having a viscosity of from 100 to 500,000 mPa·s at 25° C. and having in one molecule 1.5 or more end groups represented by the general formula: (X)aR13-aSi—, where each X is independently a hydroxyl group or a hydrolyzable group, each R1 is independently a monovalent hydrocarbon group or a halogen-substituted monovalent hydrocarbon group, and a is 1, 2, or 3; (B) 0.01 to 40 parts by weight of a cross-linking agent selected from a silane or a siloxane oligomer where the cross-linking agent has three or more silicon-bonded hydrolyzable groups per molecule; and (C) microparticles of thermoplastic resin containing a platinum compound in such an amount that the content of metallic platinum in component (C) is within the range of 0.01 to 5 wt. %, where the microparticles have an average diameter from 0.1 to 20 μm, component (C) is present in an amount sufficient to provide 1 to 2,000 ppm of metallic platinum in the composition; and (D) 5 to 300 parts by weight of an inorganic powder.
摘要翻译：一种室温可固化的有机基聚硅氧烷组合物，其包含：（A）100重量份在25℃下粘度为100至500,000mPa.s并且在一个分子中具有由一般分子表示的1.5个或更多个端基的有机聚硅氧烷公式：<？in-line-formula description =“In-line Formulas”end =“lead”？>（X）aR13-aSi-，其中<？in-line-formula description =“In-line Formulas”end = “尾”→“X”各自独立地为羟基或可水解基团，每个R 1独立地为一价烃基或卤素取代的一价烃基，a为1,2或3; （B）0.01〜40重量份选自硅烷或硅氧烷低聚物的交联剂，其中交联剂每分子具有三个或更多个硅键合的可水解基团; 和（C）含有铂化合物的热塑性树脂微粒的量使得组分（C）中金属铂的含量在0.01至5重量％的范围内。％，其中微粒的平均直径为0.1-20μm，组分（C）的存在量足以在组合物中提供1至2,000ppm的金属铂; 和（D）5〜300重量份的无机粉末。

10. 发明授权

US5959057A Polyorganosiloxane and method for the preparation thereof 失效
标题翻译：聚有机硅氧烷及其制备方法
公开(公告)号：US5959057A
公开(公告)日：1999-09-28
申请号：US9150
申请日：1998-01-20
申请人： Haruhiko Furukawa , Koji Nakanishi
发明人： Haruhiko Furukawa , Koji Nakanishi
IPC分类号： C08G77/38 , C08G77/388 , C08G77/06 , C08G77/14 , C08G77/26
CPC分类号： C08G77/388 , C08G77/38
摘要： There is disclosed a polyorganosiloxane and a method for the preparation thereof, said polyorganosiloxane having the formula ##STR1## in which R is independently selected from substituted or unsubstituted monovalent hydrocarbon groups, m is an integer having a value of 0 to 500, n is an integer having a value of 0 to 500 and X is selected from a substituted or an unsubstituted monovalent hydrocarbon group or a hindered phenol group which is linked through either a carboxylate ester or an amide moiety, with the proviso that at least one of the X groups is said hindered phenol group.
摘要翻译：公开了一种聚有机硅氧烷及其制备方法，所述具有下式的聚有机硅氧烷，其中R独立地选自取代或未取代的一价烃基，m是0-500的整数，n是具有值为0〜500，X选自经取代或未取代的单价烃基或通过羧酸酯或酰胺部分连接的受阻酚基团，条件是至少一个X基团为所述受阻的苯酚基团。

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