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1. 发明申请

WO2006036545A1 PROCESS TO MAKE POLYCARBONATE FROM BISMETHYLSALICYLCARBONATE 审中-公开
标题翻译：从二氯甲烷制备聚碳酸酯的方法
公开(公告)号：WO2006036545A1
公开(公告)日：2006-04-06
申请号：PCT/US2005/032655
申请日：2005-09-13
申请人： GENERAL ELECTRIC COMPANY , MCCLOSKEY, Patrick, Joseph , SILVI, Norberto , NISOLI, Alberto , GIAMMATTEI, Mark
发明人： MCCLOSKEY, Patrick, Joseph , SILVI, Norberto , NISOLI, Alberto , GIAMMATTEI, Mark
IPC分类号： C08G64/30
CPC分类号： B29C47/76 , B29C47/0009 , C08G64/307
摘要： The present invention relates to a method of preparing polycarbonate comprising the steps of: (i) introducing to an extruder through a feed port a plurality of reaction components comprising a polycarbonate oligomer, an activated carbonate residue, and a transesterification catalyst, wherein the extruder comprises the feed port, a first back vent port, and a polycarbonate exit port, wherein the feed port is located between the first back vent port and the polycarbonate exit port, and wherein the resistance to flow of the reaction components from the feed port to the first back vent port is less than or equal to the resistance to flow of the reaction components from the feed port to the polycarbonate exit port; and (ii) extruding the reaction components at one or more temperatures in a range between 100 ° C and 400 ° C, wherein during the extrusion of the reaction components, activated carbonate residue is removed through the first back vent port, thereby preparing a polycarbonate.
摘要翻译：本发明涉及一种制备聚碳酸酯的方法，包括以下步骤：（i）通过进料口将包含聚碳酸酯低聚物，活性碳酸酯残余物和酯交换催化剂的多个反应组分引入挤出机，其中挤出机包含所述进料口，第一后排气口和聚碳酸酯出口，其中所述进料口位于所述第一后排气口和所述聚碳酸酯出口之间，并且其中所述反应组分从所述进料口流向第一后排气口小于或等于反应组分从进料口到聚碳酸酯出口的流动阻力; 和（ii）在一个或多个温度下在100℃下挤出反应组分

2. 发明申请

WO2005105890A1 METHOD FOR PREPARATING A POLYCARBONATE OLIGOMER MIXTURE AT LOW TEMPERATURE FOR MANUFACTURING POLYCARBONATE 审中-公开
标题翻译：低温制备聚碳酸酯低聚物混合物制备聚碳酸酯的方法
公开(公告)号：WO2005105890A1
公开(公告)日：2005-11-10
申请号：PCT/US2005/012434
申请日：2005-04-11
申请人： GENERAL ELECTRIC COMPANY , MARTINEZ, Maria, Tomas , NISOLI, Alberto , LOPEZ-CARRETERO, Alfredo , KAILASAM, Ganesh , DOMINGO, David , MCCLOSKEY, Patrick, Joseph
发明人： MARTINEZ, Maria, Tomas , NISOLI, Alberto , LOPEZ-CARRETERO, Alfredo , KAILASAM, Ganesh , DOMINGO, David , MCCLOSKEY, Patrick, Joseph
IPC分类号： C08G64/30
CPC分类号： C08G64/307 , B01J19/18 , B01J19/1806 , B01J19/1887 , B01J19/20 , B01J2219/00031 , B01J2219/0004 , B01J2219/00083 , B01J2219/00094 , B01J2219/00166 , B01J2219/00184 , B01J2219/00186 , C08G64/205
摘要： The present invention provides a method of making polycarbonate oligomers, polycarbonate, molded articles formed from polycarbonate, and an apparatus for making polycarbonate. An oligomer mixture is first prepared by the steps of providing an equilibration system comprising a vessel, a reaction mixture contained within the vessel, and means for mixing the reaction mixture contained within the vessel wherein the reaction mixture comprises a melted activated diaryl carbonate composition, and a catalyst present in sufficient amount to initiate an oligomerization reaction between a dihydroxy composition and the activated diaryl carbonate to form polycarbonate oligomers. The method further includes the steps of introducing a melted dihydroxy composition to the reaction mixture contained within the equilibration system, maintaining the reaction mixture contained within the vessel at an oligomerization temperature, said oligomerization temperature being the melting point the dihydroxy composition, and sufficiently high to allow formation of a homogeneous melt within the vessel, and continuously drawing off a product stream from the equilibration system, wherein the product stream comprises a polycarbonate oligomer mixture. The polycarbonate oligomer mixture is suitably used as a feed stock for producing polycarbonate in a polycondensation system. The polycarbonate is suitably used for the preparation of molded articles.
摘要翻译：本发明提供一种制备聚碳酸酯低聚物，聚碳酸酯，由聚碳酸酯形成的模制品的方法和用于制备聚碳酸酯的装置。首先通过以下步骤制备低聚物混合物，所述步骤包括提供包含容器，容器内的反应混合物的平衡系统和用于混合包含在容器内的反应混合物的装置，其中反应混合物包含熔融的活化碳酸二芳基酯组合物和存在足够量的催化剂以引发二羟基组合物和活化的碳酸二芳基酯之间的低聚反应以形成聚碳酸酯低聚物。该方法还包括将熔融的二羟基组合物引入平衡系统中所含的反应混合物中，将反应混合物保持在容器内的低聚温度，所述低聚温度为二羟基组合物的熔点，足够高至允许在容器内形成均匀的熔体，并且从平衡系统连续地抽出产物流，其中产物流包含聚碳酸酯低聚物混合物。聚碳酸酯低聚物混合物适合用作在缩聚体系中生产聚碳酸酯的原料。聚碳酸酯适合用于制备模塑制品。

3. 发明申请

WO2005000776A2 METHOD AND APPARATUS FOR PRODUCTION OF ALKYL ARYL ETHER AND DIARYL CARBONATE 审中-公开
标题翻译：用于生产烷基芳基醚和二芳基碳酸酯的方法和设备
公开(公告)号：WO2005000776A2
公开(公告)日：2005-01-06
申请号：PCT/US2004/018957
申请日：2004-06-15
申请人： GENERAL ELECTRIC COMPANY , MURTHY, Vutukuru, Lakshmi, Narasimha , VIC, Ignacio, Fernandez , KAILASAM, Ganesh , NISOLI, Alberto
发明人： MURTHY, Vutukuru, Lakshmi, Narasimha , VIC, Ignacio, Fernandez , KAILASAM, Ganesh , NISOLI, Alberto
IPC分类号： C07C41/00
CPC分类号： C07C68/08 , B01D3/009 , B01D3/146 , C07C41/16 , C07C68/06 , Y02P20/127 , C07C69/96 , C07C43/205
摘要： A method and apparatus for continuously producing an alkyl aryl ether and a diaryl carbonate by reacting a dialkyl carbonate and an aromatic alcohol in presence of a transesterification catalyst.
摘要翻译：通过在酯基转移催化剂存在下使碳酸二烷基酯和芳香醇反应来连续制备烷基芳基醚和碳酸二芳基酯的方法和设备

4. 发明申请

WO2006049987A1 METHOD FOR MAKING POLYCARBONATES 审中-公开
标题翻译：制备聚碳酸酯的方法
公开(公告)号：WO2006049987A1
公开(公告)日：2006-05-11
申请号：PCT/US2005/038553
申请日：2005-10-27
申请人： GENERAL ELECTRIC COMPANY , HIDALGO, Gerardo , MCCLOSKEY, Patrick, J. , NISOLI, Alberto , PRADA, Lina
发明人： HIDALGO, Gerardo , MCCLOSKEY, Patrick, J. , NISOLI, Alberto , PRADA, Lina
IPC分类号： C08G64/30
CPC分类号： B01D3/146 , B01J2219/00038 , B01J2219/0004 , C08G64/307 , Y02P20/582
摘要： A method of making polycarbonates comprises melt-polymerizing an aromatic dihydroxy compound and a carbonic acid diester in a presence of a polymerization catalyst in a reactor system producing a byproduct stream, wherein the polymerization catalyst comprises a quaternary phosphonium compound; and purifying the byproduct stream to separate phenol, wherein the separated phenol has a phosphorus concentration of less than or equal to about 3 part per million, based upon the total weight of the phenol separated.
摘要翻译：制备聚碳酸酯的方法包括在聚合催化剂存在下在产生副产物流的反应器系统中使芳族二羟基化合物和碳酸二酯熔融聚合，其中聚合催化剂包含季鏻化合物; 和纯化副产物流以分离苯酚，其中基于分离的苯酚的总重量，分离的苯酚的磷浓度小于或等于约3ppm。

5. 发明申请

WO2006049955A1 METHOD FOR MAKING POLYCARBONATE 审中-公开
标题翻译：制备聚碳酸酯的方法
公开(公告)号：WO2006049955A1
公开(公告)日：2006-05-11
申请号：PCT/US2005/038376
申请日：2005-10-27
申请人： GENERAL ELECTRIC COMPANY , HIDALGO, Gerardo , MCCLOSKEY, Patrick, J. , NISOLI, Alberto , PRADA, Lina
发明人： HIDALGO, Gerardo , MCCLOSKEY, Patrick, J. , NISOLI, Alberto , PRADA, Lina
IPC分类号： C08G64/30
CPC分类号： B01D3/146 , B01J2219/00038 , B01J2219/0004 , C08G64/307 , Y02P20/582
摘要： A method of making polycarbonate comprises melt-polymerizing an aromatic dihydroxy compound and a carbonic acid diester in a presence of a polymerization catalyst in a reactor system producing a byproduct stream, wherein the polymerization catalyst comprises a quaternary phosphonium compound; and purifying the byproduct stream to separate the carbonic acid diester, wherein the separated carbonic acid diester has a phosphorous concentration of less than or equal to about 30 parts per million.
摘要翻译：制备聚碳酸酯的方法包括在聚合催化剂存在下在产生副产物流的反应器系统中使芳族二羟基化合物和碳酸二酯熔融聚合，其中聚合催化剂包含季鏻化合物; 并纯化副产物流以分离碳酸二酯，其中分离的碳酸二酯的磷浓度小于或等于约30ppm。

6. 发明申请

WO2003106149A1 METHOD FOR MAKING AN AROMATIC POLYCARBONATE 审中-公开
标题翻译：制备芳香族聚碳酸酯的方法
公开(公告)号：WO2003106149A1
公开(公告)日：2003-12-24
申请号：PCT/US2003/016354
申请日：2003-05-23
申请人： GENERAL ELECTRIC COMPANY
发明人： SILVI, Norberto , GIAMMATTEI, Mark, Howard , MCCLOSKEY, Patrick, Joseph , NISOLI, Alberto , DAY, James , RAMESH, Narayan , SMIGELSKI, Paul, Michael, Jr. , WILSON, Paul, Russell
IPC分类号： B29C67/24
CPC分类号： B29C47/0004 , B29C47/0009 , B29C47/60 , B29C47/76 , B29C47/767 , B29C67/246 , B29K2069/00 , C08G64/081 , C08G64/14 , C08G64/205 , C08G64/307
摘要： This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl) carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising estersubstituted phenoxy terminal groups.
摘要翻译：本发明涉及从低聚聚碳酸酯溶液制备聚碳酸酯的挤压方法。首先在中等温度下平衡双（甲基水杨酸）碳酸酯（BMSC），BPA和酯交换催化剂的混合物，以提供聚碳酸酯低聚物在水杨酸甲酯中的溶液。然后将溶液进料到脱挥发分挤出机中，其中聚合反应完成并除去水杨酸甲酯溶剂。包含低聚物聚碳酸酯的溶液也可以在压力下预加热到高于水杨酸甲酯沸点的温度，随后进料到脱挥发分的挤出机中，以便迅速地从溶剂中闪蒸。该方法提供聚碳酸酯比未反应的单体进料到挤出机的相应方法具有更高的效率。另外，本发明的方法不需要分离包含酯取代的苯氧基末端基团的前体聚碳酸酯。

7. 发明申请

WO2003016257A1 METHOD AND APPARATUS FOR PREPARING A DIALKYL CARBONATE, AND ITS USE IN THE PREPARATION OF DIARYL CARBONATES AND POLYCARBONATES 审中-公开
标题翻译：用于制备碳酸二烷基酯的方法和装置及其在制备二元碳酸酯和聚碳酸酯中的用途
公开(公告)号：WO2003016257A1
公开(公告)日：2003-02-27
申请号：PCT/US2002/024364
申请日：2002-07-30
申请人： GENERAL ELECTRIC COMPANY
发明人： BODEN, Eugene, Pauling , KAILASAM, Ganesh , LEWIS, Larry, Neil , NISOLI, Alberto , OFORI, John, Yaw , SANCHEZ GONZALEZ, Angel , VIC FERNANDEZ, Ignacio
IPC分类号： C07C68/00
CPC分类号： B01J19/002 , B01J2219/00006 , B01J2219/00247 , B01J2219/00272 , C07C68/005 , C07C69/96
摘要： Unexpected corrosion of downstream sections of a diakyl carbonate manufacturing apparatus has been traced to alkyl chloroformate impurities, which slowly decompose to yield hydrochloric acid. An improved process and apparatus for dialkyl carbonate synthesis reduce corrosion by physically removing or chemically decomposing the alkyl chloroformate impurities within the corrosion-resistant upstream sections of the apparatus.
摘要翻译：碳酸二烷基酯制造装置的下游部分的意外腐蚀已经被追溯到烷基氯甲酸酯杂质，其缓慢分解以产生盐酸。用于碳酸二烷基酯合成的改进方法和装置通过物理去除或化学分解装置的耐腐蚀上游部分中的氯甲酸烷基酯杂质来减少腐蚀。

8. 发明申请

WO2003014188A1 METHOD FOR MAKING POLYCARBONATE 审中-公开
标题翻译：制备聚碳酸酯的方法
公开(公告)号：WO2003014188A1
公开(公告)日：2003-02-20
申请号：PCT/US2002/023175
申请日：2002-07-19
申请人： GENERAL ELECTRIC COMPANY
发明人： MCCLOSKEY, Patrick, Joseph , NISOLI, Alberto , REILLY, Warren, William
IPC分类号： C08G64/30
CPC分类号： C08G64/307
摘要： Polycarbonates having a high level of endcapping and containing a low level of Fries rearrangement product are prepared from dihydroxy aromatic compounds, such as bisphenol A, and diaryl carbonates such as diphenyl carbonate in a two stage process involving a tetraalkyl phosphonium carboxylate catalyzed oligomerization of the reactants in a first reaction stage followed by the addition of an alkali metal hydroxide co-catalyst in the second stage of the polymerization reaction. The late addition of the co-catalyst provides improved polymerization reaction rates as judged by higher polycarbonate molecular weights. The amount of alkali metal hydroxide co-catalyst is small thus avoiding the formation of excessive amounts of Fries product. The method has been used to provide Fries product levels between 200 and 1000 parts per million in polycarbonates having M n values of at least 7,500 Daltons.
摘要翻译：具有高水平的封端并含有低含量的Fries重排产物的聚碳酸酯由二羟基芳族化合物如双酚A和碳酸二芳基酯如碳酸二苯酯在涉及四烷基鏻羧酸酯催化的反应物低聚的两步法中制备在第一反应阶段，然后在聚合反应的第二阶段加入碱金属氢氧化物助催化剂。通过较高的聚碳酸酯分子量判断，辅助催化剂的晚期添加提供了改进的聚合反应速率。碱金属氢氧化物助催化剂的量很小，从而避免形成过量的油炸产品。该方法已被用于在具有至少7,500道尔顿Mn值的聚碳酸酯中提供200至1000ppm之间的Fries产品水平。

9. 发明公开

EP1751211A1 METHOD FOR PREPARING A POLYCARBONATE OLIGOMER MIXTURE AT LOW TEMPERATURE FOR MANUFACTURING POLYCARBONATE 有权
标题翻译：用于生产POLYCARBONATOLIGOMERENGEMISCHS低温用于生产聚碳酸酯
公开(公告)号：EP1751211A1
公开(公告)日：2007-02-14
申请号：EP05735187.6
申请日：2005-04-11
申请人： GENERAL ELECTRIC COMPANY
发明人： MARTINEZ, Maria, Tomas , NISOLI, Alberto , LOPEZ-CARRETERO, Alfredo , KAILASAM, Ganesh , DOMINGO, David , MCCLOSKEY, Patrick, Joseph
IPC分类号： C08G64/30
CPC分类号： C08G64/307 , B01J19/18 , B01J19/1806 , B01J19/1887 , B01J19/20 , B01J2219/00031 , B01J2219/0004 , B01J2219/00083 , B01J2219/00094 , B01J2219/00166 , B01J2219/00184 , B01J2219/00186 , C08G64/205
摘要： The present invention provides a method of making polycarbonate oligomers, polycarbonate, molded articles formed from polycarbonate, and an apparatus for making polycarbonate. An oligomer mixture is first prepared by the steps of providing an equilibration system comprising a vessel, a reaction mixture contained within the vessel, and means for mixing the reaction mixture contained within the vessel wherein the reaction mixture comprises a melted activated diaryl carbonate composition, and a catalyst present in sufficient amount to initiate an oligomerization reaction between a dihydroxy composition and the activated diaryl carbonate to form polycarbonate oligomers. The method further includes the steps of introducing a melted dihydroxy composition to the reaction mixture contained within the equilibration system, maintaining the reaction mixture contained within the vessel at an oligomerization temperature, said oligomerization temperature being the melting point the dihydroxy composition, and sufficiently high to allow formation of a homogeneous melt within the vessel, and continuously drawing off a product stream from the equilibration system, wherein the product stream comprises a polycarbonate oligomer mixture. The polycarbonate oligomer mixture is suitably used as a feed stock for producing polycarbonate in a polycondensation system. The polycarbonate is suitably used for the preparation of molded articles.

10. 发明公开

EP1417248A1 METHOD FOR MAKING POLYCARBONATE 审中-公开
标题翻译：一种用于制造聚碳酸酯的
公开(公告)号：EP1417248A1
公开(公告)日：2004-05-12
申请号：EP02761147.4
申请日：2002-07-19
申请人： GENERAL ELECTRIC COMPANY
发明人： MCCLOSKEY, Patrick, Joseph , NISOLI, Alberto , REILLY, Warren, William
IPC分类号： C08G64/30
CPC分类号： C08G64/307
摘要： Polycarbonates having a high level of endcapping and containing a low level of Fries rearrangement product are prepared from dihydroxy aromatic compounds, such as bisphenol A, and diaryl carbonates such as diphenyl carbonate in a two stage process involving a tetraalkyl phosphonium carboxylate catalyzed oligomerization of the reactants in a first reaction stage followed by the addition of an alkali metal hydroxide co-catalyst in the second stage of the polymerization reaction. The late addition of the co-catalyst provides improved polymerization reaction rates as judged by higher polycarbonate molecular weights. The amount of alkali metal hydroxide co-catalyst is small thus avoiding the formation of excessive amounts of Fries product. The method has been used to provide Fries product levels between 200 and 1000 parts per million in polycarbonates having Mn values of at least 7,500 Daltons.

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