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1. 发明申请

WO2014150841A3 A METHOD FOR MAKING AN OPTICAL ASSEMBLY COMPRISING DEPOSITING A SOLID SILICONE-CONTAINING HOT MELT COMPOSITION IN POWDER FORM AND FORMING AN ENCAPSULANT THEREOF 审中-公开
标题翻译：一种制造光学组件的方法，所述光学组件包括沉积粉末形式的含固体含硅热熔体组合物并形成其包封物
公开(公告)号：WO2014150841A3
公开(公告)日：2014-09-25
申请号：PCT/US2014/024374
申请日：2014-03-12
申请人： DOW CORNING CORPORATION , DOW CORNING TORAY CO., LTD.
发明人： AMAKO, Masaaki , GARDNER, Geoffrey Bruce , MIZUKAMI, Mayumi , SWIER, Steven , YOSHIDA, Hiroaki , YOSHIDA, Shin
IPC分类号： C09D5/03 , B29D11/00 , C09D183/04 , C08L83/10 , G02B1/04 , H01L31/0216 , H01L31/048 , H01L33/56 , H01L23/29 , C08G77/44
摘要： Methods of making optical assemblies and electronic devices comprising, depositing a solid silicone-containing hot melt composition in powder form onto an optical surface of an optical device; and forming, from the silicone-containing hot melt composition, an encapsulant that substantially covers the optical surface of the optical device.. In some embodiments, the silicone containing hot melt composition is a reactive or unreactive silicone- containing hot melt. In some embodiments, the composition is a resin- linear silicone-containing hot melt composition and the composition comprises a phase separated resin-rich phase and a phase separated linear-rich phase.
摘要翻译：制造光学组件和电子器件的方法包括：将粉末形式的固体含硅热熔组合物沉积到光学器件的光学表面上; 以及由含硅氧烷的热熔组合物形成基本上覆盖光学装置的光学表面的密封剂。在一些实施方案中，含硅氧烷的热熔组合物是反应性或非反应性含硅氧烷的热熔体。在一些实施方案中，所述组合物是树脂 - 线性含硅氧烷的热熔组合物，并且所述组合物包含相分离的富树脂相和相分离的线性富集相。

2. 发明申请

WO2016063509A1 OPTICAL MEMBER, OPTICAL SEMICONDUCTOR DEVICE, AND ILLUMINATION APPARATUS 审中-公开
标题翻译：光学元件，光学半导体器件和照明设备
公开(公告)号：WO2016063509A1
公开(公告)日：2016-04-28
申请号：PCT/JP2015/005238
申请日：2015-10-16
申请人： DOW CORNING TORAY CO., LTD. , DOW CORNING CORPORATION
发明人： YOSHIDA, Shin , YOSHIDA, Hiroaki , MORI, Kazutaka , MCMILLAN, Christopher S.
IPC分类号： C08J7/12 , H01L33/56
CPC分类号： C08J7/126 , C08J2383/04 , C08J2383/16 , H01L33/56 , H01L33/58 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
摘要： The present invention provides an optical member comprising a silicone material having excellent antifouling property while having good light transmittance, heat resistance, and strength, and an optical semiconductor device and illumination apparatus having excellent antifouling property. The present invention is an optical member comprising a silicone material containing a fluorinated surface, the proportion of F atoms being from 0.1 to 45 at% and/or the ratio of F atoms relative to C atoms being from 0.01 to 1.00 in the atomic composition percentage according to X-ray photoelectron spectroscopy (XPS) of the fluorinated surface.
摘要翻译：本发明提供一种光学构件，其具有优异的防污性，同时具有良好的透光性，耐热性和强度的光学构件，以及具有优异的防污性能的光学半导体器件和照明装置。本发明是一种光学部件，其包含含有氟化表面的硅酮材料，F原子的比例为0.1〜45原子％，和/或F原子相对于C原子的比例为0.01〜1.00原子组成百分比根据氟化表面的X射线光电子能谱（XPS）。

3. 发明申请

WO2014130784A1 CURABLE SILICONE COMPOSITION, CURED PRODUCT THREREOF, AND OPTICAL SEMICONDUCTOR DEVICE 审中-公开
标题翻译：可固化硅酮组合物，固化产品和光学半导体器件
公开(公告)号：WO2014130784A1
公开(公告)日：2014-08-28
申请号：PCT/US2014/017623
申请日：2014-02-21
申请人： DOW CORNING TORAY CO., LTD. , DOW CORNING CORPORATION
发明人： DENT, Stanton James , IIMURA, Tomohiro , MIYAMOTO, Yusuke , MORITA, Yoshitsugu , NISHIDA, Fumito , RADKOV, Emil , STEINBRECHER, Jacob William , YOSHIDA, Hiroaki , YOSHITAKE, Makoto
IPC分类号： C08L83/14
CPC分类号： C08G77/08 , C08G77/12 , C08G77/20 , C08G77/398 , C08G77/58 , C08G2190/00 , C08K5/56 , C08L83/00 , C08L83/14 , C09K11/025 , C09K11/7706 , H01L33/50 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00012 , H01L2924/00014 , H01L2924/00
摘要： This invention relates to a curable silicone composition comprising: (A) a straight-chain organopolysiloxane having at least two alkenyl groups in a molecule; (B) an organopolysiloxane represented by the following average unit formula: (R 1 SiO 3/2 ) a (R 1 2 SiO 2/2 ) b (R 1 3 SiO 1/2 ) c (SiO 4/2 ) d (XO 1/2 ) e wherein, R 1 each independently represent an alkyl group having from 1 to 12 carbons, an alkenyl group having from 2 to 12 carbons, an aryl group having from 6 to 20 carbons, an aralkyl group having from 7 to 20 carbons, or a group in which some or all of the hydrogen atoms of these groups are substituted with halogen atoms, with the proviso that at least two R 1 in a molecule are the alkenyl groups, X is a hydrogen atom or an alkyl group, a is a number from 0 to 0.3, b is 0 or a positive number, c is a positive number, d is a positive number, e is a number from 0 to 0.4, a + b + c + d = 1, c/d is a number from 0 to 10, and b/d is a number from 0 to 0.5; (C) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule; (D) a cerium-containing organopolysiloxane; and (E) a hydrosilylation reaction catalyst. The curable silicone composition does not develop cracks due to thermal aging and can form a cured product having little yellow discoloration.
摘要翻译：本发明涉及可固化的有机硅组合物，其包含：（A）在分子中具有至少两个烯基的直链有机聚硅氧烷; （B）由以下平均单元式表示的有机聚硅氧烷：（R1SiO3 / 2）a（R1 2SiO2 / 2）b（R1 3SiO1 / 2）c（SiO4 / 2）d（XO1 / 2）e其中，R1各自独立地表示具有1至12个碳的烷基，具有2至12个碳的烯基，具有6至20个碳的芳基，具有7至20个碳的芳烷基，或其中部分或全部这些基团的氢原子被卤素原子取代，条件是分子中至少两个R 1为烯基，X为氢原子或烷基，a为0至0.3的数，b为0 或正数，c为正数，d为正数，e为0〜0.4的数，a + b + c + d = 1，c / d为0〜10的数，b / d是从0到0.5的数字; （C）在分子中具有至少两个与硅键合的氢原子的有机聚硅氧烷; （D）含铈有机聚硅氧烷; 和（E）氢化硅烷化反应催化剂。可固化的硅氧烷组合物由于热老化而不会产生裂纹，并且可以形成黄色变色少的固化产物。

4. 发明授权

EP2958961B1 CURABLE SILICONE COMPOSITION, CURED PRODUCT THREREOF, AND OPTICAL SEMICONDUCTOR DEVICE 有权转让
标题翻译：可固化的硅氧烷组合物，固化的产品，以及光学半导体装置
公开(公告)号：EP2958961B1
公开(公告)日：2018-05-16
申请号：EP14708752.2
申请日：2014-02-21
申请人： Dow Corning Toray Co., Ltd. , Dow Corning Corporation
发明人： DENT, Stanton James , IIMURA, Tomohiro , MIYAMOTO, Yusuke , MORITA, Yoshitsugu , NISHIDA, Fumito , RADKOV, Emil , STEINBRECHER, Jacob William , YOSHIDA, Hiroaki , YOSHITAKE, Makoto
IPC分类号： C08L83/14
CPC分类号： C08G77/08 , C08G77/12 , C08G77/20 , C08G77/398 , C08G77/58 , C08G2190/00 , C08K5/56 , C08L83/00 , C08L83/14 , C09K11/025 , C09K11/7706 , H01L33/50 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00012 , H01L2924/00014 , H01L2924/00
摘要： This invention relates to a curable silicone composition comprising: (A) a straight-chain organopolysiloxane having at least two alkenyl groups in a molecule; (B) an organopolysiloxane represented by the following average unit formula: (R1SiO3/2)a(R12SiO2/2)b(R13SiO1/2)c(SiO4/2)d(XO1/2)e wherein, R1 each independently represent an alkyl group having from 1 to 12 carbons, an alkenyl group having from 2 to 12 carbons, an aryl group having from 6 to 20 carbons, an aralkyl group having from 7 to 20 carbons, or a group in which some or all of the hydrogen atoms of these groups are substituted with halogen atoms, with the proviso that at least two R1 in a molecule are the alkenyl groups, X is a hydrogen atom or an alkyl group, a is a number from 0 to 0.3, b is 0 or a positive number, c is a positive number, d is a positive number, e is a number from 0 to 0.4, a+b+c+d=1, c/d is a number from 0 to 10, and b/d is a number from 0 to 0.5; (C) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule; (D) a cerium-containing organopolysiloxane; and (E) a hydrosilylation reaction catalyst. The curable silicone composition does not develop cracks due to thermal aging and can form a cured product having little yellow discoloration.

5. 发明公开

EP2958961A1 CURABLE SILICONE COMPOSITION, CURED PRODUCT THREREOF, AND OPTICAL SEMICONDUCTOR DEVICE 有权转让
标题翻译： HÄRTBARESILIKONZUSAMMENSETZUNG，GEHÄRTETESPRODUKT DARAUS UND OPTISCHES HALBLEITERBAUELEMENT
公开(公告)号：EP2958961A1
公开(公告)日：2015-12-30
申请号：EP14708752.2
申请日：2014-02-21
申请人： Dow Corning Toray Co., Ltd. , Dow Corning Corporation
发明人： DENT, Stanton James , IIMURA, Tomohiro , MIYAMOTO, Yusuke , MORITA, Yoshitsugu , NISHIDA, Fumito , RADKOV, Emil , STEINBRECHER, Jacob William , YOSHIDA, Hiroaki , YOSHITAKE, Makoto
IPC分类号： C08L83/14
CPC分类号： C08G77/08 , C08G77/12 , C08G77/20 , C08G77/398 , C08G77/58 , C08G2190/00 , C08K5/56 , C08L83/00 , C08L83/14 , C09K11/025 , C09K11/7706 , H01L33/50 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00012 , H01L2924/00014 , H01L2924/00
摘要： This invention relates to a curable silicone composition comprising: (A) a straight-chain organopolysiloxane having at least two alkenyl groups in a molecule; (B) an organopolysiloxane represented by the following average unit formula: (R1SiO3/2)a(R12SiO2/2)b(R13SiO1/2)c(SiO4/2)d(XO1/2)e wherein, R1 each independently represent an alkyl group having from 1 to 12 carbons, an alkenyl group having from 2 to 12 carbons, an aryl group having from 6 to 20 carbons, an aralkyl group having from 7 to 20 carbons, or a group in which some or all of the hydrogen atoms of these groups are substituted with halogen atoms, with the proviso that at least two R1 in a molecule are the alkenyl groups, X is a hydrogen atom or an alkyl group, a is a number from 0 to 0.3, b is 0 or a positive number, c is a positive number, d is a positive number, e is a number from 0 to 0.4, a+b+c+d=1, c/d is a number from 0 to 10, and b/d is a number from 0 to 0.5; (C) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule; (D) a cerium-containing organopolysiloxane; and (E) a hydrosilylation reaction catalyst. The curable silicone composition does not develop cracks due to thermal aging and can form a cured product having little yellow discoloration.
摘要翻译：本发明涉及可固化的有机硅组合物，其包含：（A）在分子中具有至少两个烯基的直链有机聚硅氧烷; （B）由以下平均单元式表示的有机聚硅氧烷：（R1SiO3 / 2）a（R12SiO2 / 2）b（R13SiO1 / 2）c（SiO4 / 2）d（XO1 / 2）e其中，R1各自独立地表示具有1至12个碳的烷基，具有2至12个碳的烯基，具有6至20个碳的芳基，具有7至20个碳的芳烷基，或其中部分或全部氢这些基团的原子被卤素原子取代，条件是分子中至少两个R 1为烯基，X为氢原子或烷基，a为0至0.3的数，b为0或a 正数，c为正数，d为正数，e为0〜0.4的数，a + b + c + d = 1，c / d为0〜10，b / d为从0到0.5的数字; （C）在分子中具有至少两个与硅键合的氢原子的有机聚硅氧烷; （D）含铈有机聚硅氧烷; 和（E）氢化硅烷化反应催化剂。可固化的硅氧烷组合物由于热老化而不会产生裂纹，并且可以形成黄色变黄的固化产物。

6. 发明公开

EP3209712A1 OPTICAL MEMBER, OPTICAL SEMICONDUCTOR DEVICE, AND ILLUMINATION APPARATUS 无效转让
标题翻译：光学构件，光学半导体装置和照明装置
公开(公告)号：EP3209712A1
公开(公告)日：2017-08-30
申请号：EP15853289.5
申请日：2015-10-16
申请人： Dow Corning Toray Co., Ltd. , Dow Corning Corporation
发明人： YOSHIDA, Shin , YOSHIDA, Hiroaki , MORI, Kazutaka , MCMILLAN, Christopher S.
IPC分类号： C08J7/12 , H01L33/56
CPC分类号： C08J7/126 , C08J2383/04 , C08J2383/16 , H01L33/56 , H01L33/58 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
摘要： The present invention provides an optical member comprising a silicone material having excellent antifouling property while having good light transmittance, heat resistance, and strength, and an optical semiconductor device and illumination apparatus having excellent antifouling property. The present invention is an optical member comprising a silicone material containing a fluorinated surface, the proportion of F atoms being from 0.1 to 45 at % and/or the ratio of F atoms relative to C atoms being from 0.01 to 1.00 in the atomic composition percentage according to X-ray photoelectron spectroscopy (XPS) of the fluorinated surface.
摘要翻译：本发明提供一种光学构件，其具有良好的透光性，耐热性和强度，并且具有优异的防污性，并且具有优异的防污性的光学半导体装置和照明装置。本发明是包含含有氟化表面的硅酮材料的光学元件，其中原子组成百分比中F原子的比例为0.1-45原子％和/或F原子相对于C原子的比例为0.01-1.00 根据氟化表面的X射线光电子能谱（XPS）。

7. 发明公开

EP2970695A2 POWDERED RESIN LINEAR ORGANOPOLYSILOXANE COMPOSITIONS 无效转让
标题翻译： PULVERHARZLINEARE ORGANOPOLYSILOXANZUSAMMENSETZUNGEN
公开(公告)号：EP2970695A2
公开(公告)日：2016-01-20
申请号：EP14721053.8
申请日：2014-03-12
申请人： Dow Corning Corporation , Dow Corning Toray Co., Ltd.
发明人： AMAKO, Masaaki , GARDNER, Geoffrey Bruce , MIZUKAMI, Mayumi , SWIER, Steven , YOSHIDA, Hiroaki , YOSHIDA, Shin
IPC分类号： C09D5/03 , B29D11/00 , C09D183/04 , C08L83/10 , G02B1/04 , H01L31/0216 , H01L31/048 , H01L33/56 , H01L23/29 , C08G77/44
CPC分类号： C09D183/10 , B29C43/00 , B29C45/14811 , B29D11/00865 , B29K2083/00 , C08G77/70 , C08G77/80 , C08L83/04 , C09D5/03 , H01L23/296 , H01L31/02327 , H01L31/048 , H01L31/0543 , H01L31/0547 , H01L33/56 , H01L2924/0002 , Y02E10/52 , H01L2924/00
摘要： A solid silicone-containing hot melt composition in powder form is disclosed. In some embodiments, the silicone containing hot melt composition is a reactive or unreactive silicone-containing hot melt. In some embodiments, the composition is a resin-linear silicone-containing hot melt composition and the composition comprises a phase separated resin-rich phase and a phase separated linear-rich phase. Methods of making optical assemblies and electronic devices comprising such solid silicone-containing hot melt compositions are also disclosed.
摘要翻译：制造光学组件和电子设备的方法包括：将粉末形式的固体含硅氧烷热熔体组合物沉积到光学器件的光学表面上; 以及从含硅氧烷的热熔组合物形成基本上覆盖光学装置的光学表面的密封剂。在一些实施方案中，含硅氧烷的热熔组合物是反应性或未反应的含硅氧烷的热熔体。在一些实施方案中，组合物是含树脂线性含硅氧烷的热熔组合物，并且该组合物包含相分离的富含树脂的相和相分离的富铁相。

8. 发明申请

WO2014038727A3 CURABLE SILICONE COMPOSITION AND OPTICAL SEMICONDUCTOR DEVICE 审中-公开
公开(公告)号：WO2014038727A3
公开(公告)日：2014-03-13
申请号：PCT/JP2013/074780
申请日：2013-09-06
申请人： DOW CORNING TORAY CO., LTD.
发明人： MIYAMOTO, Yusuke , YOSHITAKE, Makoto , YOSHIDA, Hiroaki , NAKATA, Toshiki , HIRAI, Kazuo
IPC分类号： C08G77/50 , C08L83/04 , H01L23/29 , C08L83/07
摘要： The present invention relates to a curable silicone composition which is a hydrosilylation reaction curable silicone composition for sealing, coating, or adhering of an optical semiconductor element, and includes at least one type of compound selected from triazole-based compounds with the exception of benzotriazole. The curable silicone composition, for example, includes (A) an organopolysiloxane having at least 2 aliphatic unsaturated hydrocarbon groups per molecule, (B) an organopolysiloxane having at least two silicon-bonded hydrogen atoms per molecule, (C) at least one type of compound selected from among triazole-based compounds with the exception of non-substituted benzotriazole, and (D) a hydrosilylation reaction catalyst. The curable silicone composition forms a cured product having excellent transparency and thermal shock resistance, and the optical semiconductor device utilizing the composition has excellent reliability.

9. 发明申请

WO2011078405A1 SILICONE ELASTOMER COMPOSITION 审中-公开
标题翻译：硅胶弹性体组合物
公开(公告)号：WO2011078405A1
公开(公告)日：2011-06-30
申请号：PCT/JP2010/073859
申请日：2010-12-22
申请人： Dow Corning Toray Co., Ltd. , YOSHIDA, Hiroaki , ISHIGAMI, Nozomi
发明人： YOSHIDA, Hiroaki , ISHIGAMI, Nozomi
IPC分类号： C08L83/04 , C09D183/04 , B32B7/12 , B32B25/20 , C08L83/07 , C08L83/05
CPC分类号： B32B7/12 , B32B25/20 , C08G77/12 , C08G77/20 , C08K5/3467 , C08K5/56 , C08L83/04 , C09D183/04 , Y10T428/31663 , C08L83/00
摘要： The present invention has an objective to provide a silicone elastomer composition in which a cured product thereof is flexible, which provides a silicone elastomer with a small hardness change even due to thermal aging, and in which superior adhesive properties with respect to other silicone elastomers and superior curing properties are exhibited. The objective of the present invention can be achieved by a silicone elastomer composition comprising: (A) an organopolysiloxane having two or more silicon atom-bonded alkenyl groups on average in a molecule, in which the content of the alkenyl group is less than 0.2% by weight with respect to the amount of component (A); (B) an organopolysiloxane having two or more silicon atom-bonded hydrogen atoms on average in a molecule, in which the amount of the silicon atom-bonded hydrogen atoms in component (B) ranges from 2.5 to 10 mol with respect to one mol of the silicon atom- bonded alkenyl group in component (A); (C) a platinum-group metal-based catalyst, in a specified amount; and (D) a phthalocyanine compound, in which the amount thereof ranges from 5 to 50 mol with respect to one mol of the platinum- based metal in component (C).
摘要翻译：本发明的目的是提供一种硅酮弹性体组合物，其中其固化产物是柔性的，其提供即使由于热老化而具有小硬度变化的硅氧烷弹性体，并且其中相对于其它有机硅弹性体和表现出优异的固化性能。本发明的目的可以通过一种硅氧烷弹性体组合物来实现，所述硅氧烷弹性体组合物包含：（A）分子中平均具有两个或多个硅原子键合的烯基的有机聚硅氧烷，其中烯基的含量小于0.2％相对于组分（A）的量; （B）在分子中平均具有两个以上与硅原子键合的氢原子的有机聚硅氧烷，其中组分（B）中与硅原子键合的氢原子的量相对于1摩尔的量为2.5至10摩尔组分（A）中硅原子键合的烯基; （C）规定量的铂族金属类催化剂; 和（D）酞菁化合物，其量相对于组分（C）中的一种铂基金属为5至50摩尔。

10. 发明申请

WO2010087525A1 CURABLE SILICONE RUBBER COMPOSITION 审中-公开
标题翻译：可固化硅橡胶组合物
公开(公告)号：WO2010087525A1
公开(公告)日：2010-08-05
申请号：PCT/JP2010/051663
申请日：2010-01-29
申请人： DOW CORNING TORAY CO., LTD. , YOSHIDA, Hiroaki , ISHIGAMI, Nozomi , HASEGAWA, Chiichiro , YOSHITAKE, Makoto
发明人： YOSHIDA, Hiroaki , ISHIGAMI, Nozomi , HASEGAWA, Chiichiro , YOSHITAKE, Makoto
IPC分类号： C08L83/04 , C09D183/04
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20 , C09D183/04 , Y10T428/31663 , C08L83/00
摘要： A curable silicone rubber composition characteristically comprising (A) an alkenyl-containing organopolysiloxane comprising (A-1) a dialkylpolysiloxane that has an average of at least two alkenyl groups in each molecule and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO?4/2#191 unit, Rｿ1??2#191Rｿ2?SiO?1/2#191 unit, and Rｿ1??3#191SiO?1/2#191 unit wherein Rｿ1? is C1-10 alkyl and Rｿ2? is alkenyl and that contains the alkenyl group in the range from more than 2.5 mass% to not more than 5.0 mass%; (B) an organopolysiloxane that contains the silicon-bonded hydrogen atom; and (C) a hydrosilylation reaction catalyst in a catalytic quantity and provides a cured silicone material that has a hardness is not more than 75 and the elongation is at least 35%. Also, a composite in which the cured silicone material provided by the thermosetting of the curable silicone rubber composition is integrated into a single article with a substrate.
摘要翻译：一种可固化的硅橡胶组合物，其特征在于包含（A）含有烯基的有机聚硅氧烷，其包含（A-1）在每个分子中平均具有至少两个烯基的二烷基聚硅氧烷和（A-2）含烯基的树脂形式包含SiO 4/2＃191单元的有机聚硅氧烷，R 1 1 2 2＃191R 2 2 SiO 1/2＃191单元和R 1 1〜3＃191SiO 1/2＃191单元，其中 R'1？是C 1-10烷基和R 2 是烯基并且含有在大于2.5质量％至不大于5.0质量％范围内的烯基; （B）含有硅键合氢原子的有机聚硅氧烷; 和（C）催化剂的氢化硅烷化反应催化剂，并提供硬度不大于75且伸长率至少为35％的固化的硅氧烷材料。另外，其中通过可固化硅橡胶组合物的热固化提供的固化的硅氧烷材料与基材整合成单个制品的复合材料。

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