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    • 7. 发明申请
    • Duarable Pd-based alloy and hydrogen generation membrane thereof
    • 可再生Pd基合金及其氢生成膜
    • US20070240566A1
    • 2007-10-18
    • US11712200
    • 2007-02-28
    • Raymond BennSusanne OpalkaThomas Vanderspurt
    • Raymond BennSusanne OpalkaThomas Vanderspurt
    • B01J20/28B01D53/22
    • C01B3/505B01D71/022B01D2325/22C01B2203/041C01B2203/047C01B2203/0475H01M8/0687
    • A durable Pd-based alloy is used for a H2-selective membrane in a hydrogen generator, as in the fuel processor of a fuel cell plant. The Pd-based alloy includes Cu as a binary element, and further includes “X”, where “X” comprises at least one metal from group “M” that is BCC and acts to stabilize the β BCC phase for stability during operating temperatures. The metal from group “M” is selected from the group consisting of Fe, Cr, Nb, Ta, V, Mo, and W, with Nb and Ta being most preferred. “X” may further comprise at least one metal from a group “N” that is non-BCC, preferably FCC, that enhances other properties of the membrane, such as ductility. The metal from group “N” is selected from the group consisting of Ag, Au, Re, Ru, Rh, Y, Ce, Ni, Ir, Pt, Co, La and In. The at. % of Pd in the binary Pd—Cu alloy ranges from about 35 at. % to about 55 at. %, and the at. % of “X” in the higher order alloy, based on said binary alloy, is in the range of about 1 at. % to about 15 at. %. The metals are selected according to a novel process.
    • 如在燃料电池设备的燃料处理器中那样,在氢气发生器中使用耐用的Pd基合金用于H 2 O 2选择膜。 Pd基合金包括Cu作为二元元素,并且还包括“X”,其中“X”包括至少一种B族的“M”族金属,并且用于稳定βBCC相以保持工作温度。 来自组“M”的金属选自Fe,Cr,Nb,Ta,V,Mo和W,Nb和Ta是最优选的。 “X”可以进一步包含至少一种金属,其来自非BCC(优选FCC)的组“N”,其提高膜的其它性质,例如延展性。 来自组“N”的金属选自Ag,Au,Re,Ru,Rh,Y,Ce,Ni,Ir,Pt,Co,La和In。 在。 二元Pd-Cu合金中Pd的%为约35at。 %至55华氏度。 %,和at。 基于所述二元合金的高阶合金中的“X”的%在约1at的范围内。 %至约15英寸 %。 根据新颖的方法选择金属。