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    • 4. 发明授权
    • Cellulosic fibrous structures having at least three regions
distinguished by intensive properties
    • 纤维素纤维结构具有至少三个由强度特性区分的区域
    • US5277761A
    • 1994-01-11
    • US724551
    • 1991-06-28
    • Dean Van PhanPaul D. Trokhan
    • Dean Van PhanPaul D. Trokhan
    • D21F1/44D21F11/00D21H27/00F22B37/48D21H15/02
    • D21F11/006D21F11/00F22B37/483Y10T428/24273Y10T428/24322Y10T428/24331Y10T428/24339Y10T428/24455Y10T428/24562Y10T428/24992
    • A cellulosic fibrous structure, such as paper. The fibrous structure has at least three intensively distinct regions. The regions are distinguished from one another by intensive properties such is basis weight, density and projected average pore size, or thickness. In one embodiment, the fibrous structure has regions of two basis weights, a high basis weight region and a low basis weight region. The high basis weight region is further subdivided into low and high density regions so that a fibrous structure having three regions is produced.A second embodiment is a four region fibrous structure. Two of the regions have generally equivalent relatively high basis weights and two of the regions having generally equivalent relatively low basis weights. The high basis weight regions and low basis weight regions are further subdivided according to relatively high and relatively low densities, so that when the high and low basis weight regions are permuted with the high and low density regions, four different regions result. The regions distinguished by density will have inversely proportionate projected average pore sizes.
    • 纤维素纤维结构,如纸。 纤维结构具有至少三个密集区域。 这些区域通过诸如基重,密度和预计平均孔径或厚度的强化特性而彼此区分。 在一个实施方案中,纤维结构具有两个基重,高基重区域和低基重区域的区域。 高基重区域进一步细分为低密度区域和高密度区域,从而产生具有三个区域的纤维结构。 第二实施例是四区纤维结构。 两个区域具有通常相等的相对较高的基重,并且两个区域具有通常相当的相对较低的基重。 高基重区域和低基重区域根据相对较高和相对较低的密度进一步细分,使得当高和低基重区域被高密度区域和低密度区域置换时,产生四个不同的区域。 由密度区分的区域将具有相反的预计平均孔径比例。
    • 8. 发明授权
    • Waterless self-emulsifiable chemical softening composition useful in
fibrous cellulosic materials
    • 用于纤维状纤维素材料的无水自乳化化学软化组合物
    • US5474689A
    • 1995-12-12
    • US333893
    • 1994-11-02
    • Robert G. LaughlinDean Van PhanPaul D. Trokhan
    • Robert G. LaughlinDean Van PhanPaul D. Trokhan
    • C11D1/62C11D3/00C11D3/20C11D3/37D06M13/148D06M13/17D06M13/463D06M15/53D21H17/06D21H17/07D21H17/53D21H21/24D21H21/54D21H21/22
    • C11D3/3707C11D1/62C11D3/0015C11D3/2065D06M13/148D06M13/17D06M13/463D06M15/53D21H17/06D21H17/07D21H17/53D21H21/24D21H21/54
    • Substantially waterless self-emulsifiable chemical softening compositions are provided comprising a mixture of a quaternary ammonium compound and a polyhydroxy compound. Preferred quaternary ammonium compounds include dialkyl dimethyl ammonium salts such as di(hydrogenated)tallow dimethyl ammonium chloride, di(hydrogenated)tallow dimethyl ammonium methyl sulfate. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, polyglycerols having a weight average molecular weight of from about 150 to about 800 and polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to 4000. The substantially waterless self-emulsifiable chemical softening compositions are prepared by mixing the quaternary ammonium compound with the polyhydroxy compound at a specific temperature range wherein the polyhydroxy compound is miscible with the quaternary ammonium compound. The resulting stable solid or concentrated fluid mixture can then be economically shipped to the consumer or ultimate user. The ultimate users of the chemical softening composition simply dilute the mixture with a liquid carder (e.g., water) to form an aqueous dispersion suitable for treating fibrous cellulosic materials. The substantially waterless self-emulsifiable chemical softening compositions disclosed herein are primarily intended for softening disposable paper products such as tissues and towels.
    • 提供基本上无水的可自乳化的化学软化组合物,其包含季铵化合物和多羟基化合物的混合物。 优选的季铵化合物包括二烷基二甲基铵盐如二(氢化)牛脂二甲基氯化铵,二(氢化)牛脂二甲基铵甲基硫酸盐。 优选的多羟基化合物选自甘油,重均分子量为约150至约800的聚甘油和重均分子量为约200至4000的聚氧乙烯二醇和聚氧丙烯二醇。基本上无水的可自乳化的 通过在多羟基化合物与季铵化合物混溶的特定温度范围下混合季铵化合物与多羟基化合物来制备化学软化组合物。 所得稳定的固体或浓缩流体混合物然后可以经济地运送到消费者或最终用户。 化学软化组合物的最终使用者用液体梳理器(例如水)简单地稀释混合物以形成适于处理纤维状纤维素材料的水分散体。 本文公开的基本上无水的可自乳化的化学软化组合物主要用于软化诸如纸巾和毛巾的一次性纸制品。
    • 9. 发明授权
    • Method of makig a superabsorbent polymer foam
    • 超吸收聚合物泡沫的方法
    • US5328935A
    • 1994-07-12
    • US37803
    • 1993-03-26
    • Dean Van PhanPaul D. Trokhan
    • Dean Van PhanPaul D. Trokhan
    • A61L15/42A61L15/60C08J9/14C08J9/20C08J9/28
    • A61L15/425A61L15/60C08J9/14
    • A method of making an improved superabsorbent polymer foam having a morphology to provide improved absorptive properties is disclosed. The foam preferably comprises a superabsorbent polymer formed from a substantially water-soluble, unsaturated monomer having neutralized carboxyl groups and a substantially water-soluble internal crosslinking agent. The monomer and crosslinking agent are expanded in the presence of a substantially water-insoluble blowing agent and a suitable solvent and reacted to form a superabsorbent polymer foam having substantially continuous, intercommunicating channels substantially throughout the foam and a relatively high surface area to mass ratio.Absorbent products, members and articles containing the foam are also disclosed.
    • 公开了制备具有提供改善的吸收性质的形态的改进的超吸收性聚合物泡沫体的方法。 泡沫体优选包含由具有中和的羧基和基本上水溶性的内部交联剂的基本上水溶性的不饱和单体形成的超吸收性聚合物。 单体和交联剂在基本上不溶于水的发泡剂和合适的溶剂的存在下膨胀,并反应以形成具有基本上连续的,相互连通的通道,基本上贯穿整个泡沫体和相对较高的表面积与质量比的超吸收性聚合物泡沫体。 还公开了含有泡沫的吸收产品,构件和制品。
    • 10. 发明授权
    • Multi-ply facial tissue paper product comprising biodegradable chemical
softening compositions and binder materials
    • 包含可生物降解的化学软化组合物和粘合剂材料的多层面巾纸产品
    • US5437766A
    • 1995-08-01
    • US141320
    • 1993-10-22
    • Dean Van PhanPaul D. TrokhanStephen R. KellyWard W. OstendorfBart S. Hersko
    • Dean Van PhanPaul D. TrokhanStephen R. KellyWard W. OstendorfBart S. Hersko
    • A47K7/00A47K10/16D21H17/06D21H17/07D21H17/53D21H21/24D21H27/00D21H27/30D21H27/40D21H27/38
    • D21H21/24D21H17/06D21H17/07D21H27/30
    • Multi-ply facial tissue paper products comprising biodegradable chemical softener compositions and a combination of a wet strength binder, either permanent and/or temporary, and a dry strength binder is disclosed.The multi-ply facial tissue paper products contain a biodegradable chemical softening composition comprising a mixture of a biodegradable quaternary ammonium compound and a polyhydroxy compound. The multi-ply facial tissue paper products also contain an effective amount of a wet strength binder, either permanent and/or temporary, and a dry strength binder to control linting and/or to offset the loss in tensile strength, if any, resulting from the use of the biodegradable chemical softening compositions. The use of both wet strength binder, either permanent and/or temporary, and dry strength binder also improves the retention of the chemical softening composition in the sheet. This results in improving one or more of the following properties of the multi-ply facial tissue paper product: the flexibility, the slip-stick coefficient of friction, the FFE-Index and the HTR-Texture.Preferably, the majority of the biodegradable chemical softening compositions will be disposed on the outer layers of the multi-ply facial tissue paper products where they are most effective. In other words, the biodegradable chemical softening compositions and the wet strength binder, either permanent and/or temporary, and the dry strength binder can be selectively distributed within the multi-ply facial tissue paper product to enhance the softness, absorbency, and/or lint resistance of a particular layer or ply.
    • 公开了包含可生物降解的化学软化剂组合物和永久和/或临时的湿强度粘合剂和干强度粘合剂的组合的多层面巾纸产品。 多层面巾纸产品包含可生物降解的化学软化组合物,其包含可生物降解的季铵化合物和多羟基化合物的混合物。 多层面巾纸产品还含有有效量的永久和/或暂时的湿强度粘合剂和用于控制棉绒和/或抵消拉伸强度(如果有的话)的损失的干强度粘合剂, 使用可生物降解的化学软化组合物。 使用永久和/或暂时的湿强度粘合剂和干强度粘合剂也可以改善片材中化学软化组合物的保留性。 这导致改善多层面巾纸产品的一个或多个以下性能:柔性,滑粘摩擦系数,FFE-Index和HTR纹理。 优选地,大部分可生物降解的化学软化组合物将被布置在多层面巾纸产品的外层上,其中它们是最有效的。 换句话说,可生物降解的化学软化组合物和永久性和/或临时性的湿强度粘合剂和干强度粘合剂可以选择性地分布在多层面巾纸产品中以增强柔软性,吸收性和/或 特定层或层的棉绒抗性。