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    • 2. 发明专利
    • MICROCAPSULE FORMULATIONS OF AGRICULTURAL CHEMICALS
    • CA2150920A1
    • 1994-06-23
    • CA2150920
    • 1993-12-02
    • DU PONT
    • BEESTMAN GEORGE BERNARD
    • A01N25/04A01N25/28A01N37/22B01J13/14
    • A composition comprising highly concentrated microencapsules containing pesticides having a skin or shell wall of polyurea, polyamide, polysulfonamide, polyester, polycarbonate of polyurethane suspended in an aqueous liquid containing an elmulsifier which is a random co-or terpolymer of vinylpyrroiidone that will form a stable oil-in-water emulsion under the conditions described and a process for preparing said composition by mixing a liquid phase water immiscible pesticide to be encapsulated with a first shell wall component in the aqueous liquid to form an oil-in-water emulsion and then adding a second shell wall component to the emulsion causing the first shell wall component to react with the second wall component to form a skin of polycondensate shell wall about the pesticide to be encapsulated or alternatively when the first shell wall component is an isocyanate or mixture thereof allowing the first shell component in the emulsion to hydrolyze when to form amine groups which react with residual isocyanate to generate a shell wall of polyurea which suspensions may be used directly as an aqueous suspension or dried to form water dispersible formulations of microcapsules.
    • 9. 发明专利
    • BR9610111A
    • 1999-02-23
    • BR9610111
    • 1996-08-23
    • DU PONT
    • WYSONG ROBERT DAVIDBEESTMAN GEORGE BERNARDSCHURR GEORGE ALAN
    • A01N25/26A01N25/28A01N47/36B01J2/00
    • PCT No. PCT/US96/13677 Sec. 371 Date Feb. 25, 1998 Sec. 102(e) Date Feb. 25, 1998 PCT Filed Aug. 23, 1996 PCT Pub. No. WO97/07676 PCT Pub. Date Mar. 6, 1997A composition comprising a mononucleate solid crop protection particle coated with a water-insoluble coating material has a diameter in the range of 0.5 to 50 mu . This composition is made by a process which results in substantial non-agglomeration of the coated particles. In a particular embodiment, a crop protection composition comprises a mononucleate solid crop protection particle coated with either wood rosin, rosin derivatives, waxes, fatty derivatives, sterols, long-chain sterol esters and sulfur. Alternatively, the coating material may be a water-insoluble synthetic latex polymer. The composition may be used in a mixture which also includes a crop protection chemical partner comprising a solid particle. The partner ordinarily degrades the solid crop protection particle when stored or aged together as a solid particle mixture. However, when the composition solid particle is coated, this degradation is prevented.