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    • 7. 发明申请
    • ETHYLENE TETRAFLUOROETHYLENE (METH)ACRYLATE COPOLYMERS
    • 乙烯四氟乙烯(甲基)丙烯酸酯共聚物
    • WO2009143194A1
    • 2009-11-26
    • PCT/US2009/044580
    • 2009-05-20
    • E. I. DU PONT DE NEMOURS AND COMPANYQIU, WeimingRAGHAVANPILLAI, AnilkumarMURPHY, Peter, MichaelFLATTER, Jessica, Louise, Nee Sinks
    • QIU, WeimingRAGHAVANPILLAI, AnilkumarMURPHY, Peter, MichaelFLATTER, Jessica, Louise, Nee Sinks
    • C08F220/24C08F220/56C09D133/16C09D133/26
    • C08F14/18C08F220/24C08F220/34C08F220/36C08F220/38C09D133/16C09D133/26Y10T428/2395Y10T428/23986Y10T428/3154
    • A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20 % to about 95 % of a monomer, or mixture of monomers, of formula (I): C n F 2n +1 (CH 2 ) X [(CF 2 CF 2 ) y (CH 2 CH 2 ) z ] m - L-C(O)-C(R)=CH 2 (I) wherein R is H, Cl, F or CH 3 ; L is O, S, NH, S-(CH 2 )A S-(CH 2 ) r NH, OC(O)NH-CH 2 CH 2 O, NHC(O)NHCH 2 CH 2 O, S-(CH 2 ) r OC(O)NHCH 2 CH 2 O, or S(CH 2 ) r NHC(O)NHCH 2 CH 2 O; subscript n is an integer from 1 to about 6; subscript x is an integer from 1 to about 6; subscripts y, z and m are each independently 1, 2 or 3 or a mixture thereof; and subscript r is from 1 to about 10; and wherein the total number of carbons in the fluorocarbon-hydrocarbon chain segment (formula (I) excluding L-C(O)-C(R)=CH 2 ) ranges from about 8 to about 22, and (b) from about 5 % to about 80 % of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R 2 ) 2 N-R 3 -O-C(O)-C(R)=CH 2 (II) wherein R is H, Cl, F or CH 3 ; each R 2 is independently a C 1 to C 4 alkyl; and R 3 is a divalent linear or branched C 1 to C 4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
    • 共聚物组合物,其包含按以下重量百分比共聚的单体:(a)约20%至约95%的式(I)单体或单体混合物:CnF2n + 1(CH2)X [(CF2CF2) y(CH 2 CH 2)z] m -LC(O)-C(R)= CH 2(I)其中R是H,Cl,F或CH 3; L是O,S,NH,S-(CH 2)A S-(CH 2)r NH,OC(O)NH-CH 2 CH 2 O,NHC(O)NHCH 2 CH 2 O,S-(CH 2)rOC(O)NHCH 2 CH 2 O或S )NHC(O)NHCH 2 CH 2 O; 下标n为1〜6的整数; 下标x为1〜6的整数; 下标y,z和m各自独立地为1,2或3或其混合物; 下标r为1〜10; 并且其中氟碳烃链段(不包括LC(O)-C(R)= CH 2)的式(I))中的碳总数为约8至约22,和(b)约5%至约 80%至少一种:(i)具有约6至约18个碳原子的直链,支链或环状烷基的(甲基)丙烯酸烷基酯单体; 或(II)式(II)的单体(R2)2N-R3-O-C(O)-C(R)= CH2(Ⅱ)其中R是H,Cl,F或CH3; 每个R 2独立地为C 1至C 4烷基; 并且R 3是二价直链或支链C1至C4亚烷基; 并且其中所述氮为约40%至100%盐碱化; 或(iii)其混合物。