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1. 发明申请

US20100188801A1 Method of Manufacture of an Energy Storage Device 审中-公开
标题翻译：储能装置的制造方法
公开(公告)号：US20100188801A1
公开(公告)日：2010-07-29
申请号：US12752735
申请日：2010-04-01
申请人： Alexander Lyubomirskiy , Valeriy Valentinovich Pavlov , Alexander Mikhailovich Timonov , Sergey Anatolijevich Logvinov , Dmitriy Ivanovich Pivunov , Svetlana Viktorovna Vasiljeva , Nik Shkolnik , Sam Kogan
发明人： Alexander Lyubomirskiy , Valeriy Valentinovich Pavlov , Alexander Mikhailovich Timonov , Sergey Anatolijevich Logvinov , Dmitriy Ivanovich Pivunov , Svetlana Viktorovna Vasiljeva , Nik Shkolnik , Sam Kogan
IPC分类号： H01G9/042 , C08F2/58 , B05D3/00 , H01G9/035
CPC分类号： H01M4/137 , H01G9/0032 , H01G9/0036 , H01G9/04 , H01G11/48 , H01M4/0438 , H01M4/0466 , H01M4/60 , H01M4/66 , H01M4/663 , H01M4/667 , H01M4/668 , Y02E60/13
摘要： A method of preparing an energy-storage device is disclosed, which involves deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization to prepare an electrode for use in the energy-storage device. Polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged in an electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/L within the range of potentials from −3.0 V to +1.5 V, and a metal complex polymer represented by the formula poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mol/L, wherein Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, and Salen is a residue of bis(salicylaldehyde)-ethylenediamine. Deposition of the redox polymer occurs in an electrolyte in which the cations have a diameter that is larger than the diameter of the cations of the electrolyte employed in the energy-storage device for which the electrode is manufactured.
摘要翻译：公开了一种制备储能装置的方法，其包括通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上，以制备用于储能装置的电极。聚合发生在施加在基板和对电极之间的电压上，两者都被浸没在电解液中。电解质含有有机溶剂，能够溶解在溶剂中的化合物，在-3.0V〜+1.5V的电位范围内，以不低于0.01mol / L的浓度形成电化学惰性离子的化合物，以及由以不低于5×10 -5 mol / L的浓度溶解的聚[Me（R- Salen）]式，其中Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是双（水杨醛） - 乙二胺的残基。氧化还原聚合物的沉积发生在其中阳离子的直径大于制造电极的储能装置中所用电解质的阳离子的直径的电解质中。

2. 发明授权

US07563354B2 Method for the manufacture of electrode for energy-storage devices 有权
标题翻译：用于制造储能装置的电极的方法
公开(公告)号：US07563354B2
公开(公告)日：2009-07-21
申请号：US11088509
申请日：2005-03-24
申请人： Alexander Mikhailovich Timonov , Sergey Anatolijevich Logvinov , Dmitriy Ivanovich Pivunov , Svetlana Viktorovna Vasiljeva , Nik Shkolnik , Sam Kogan
发明人： Alexander Mikhailovich Timonov , Sergey Anatolijevich Logvinov , Dmitriy Ivanovich Pivunov , Svetlana Viktorovna Vasiljeva , Nik Shkolnik , Sam Kogan
IPC分类号： C25D9/00
CPC分类号： H01M4/0438 , C08G12/06 , H01G9/0036 , H01G9/155 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/606 , Y02E60/13
摘要： Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from −3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5-10−5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.
摘要翻译：聚 - [Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，两者都被浸没在含有机溶剂的电解质中，并且能够溶解在所述溶剂。该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性的（浓度不小于0.01mol / l）的离子，并且溶解在金属络合物[Me（R-Salen）浓度不小于5-10-5mol / l（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是双 - （水杨醛）的残基，乙二胺在希夫的基地。

3. 发明授权

US07292431B2 Electrochemical capacitor and method of use 有权
标题翻译：电化学电容器及其使用方法
公开(公告)号：US07292431B2
公开(公告)日：2007-11-06
申请号：US11098698
申请日：2005-04-04
申请人： Alexander Mikhailovich Timonov , Sergey Anatolijevich Logvinov , Dmitriy Ivanovich Pivunov , Svetlana Viktorovna Vasiljeva , Nik Shkolnik , Sam Kogan
发明人： Alexander Mikhailovich Timonov , Sergey Anatolijevich Logvinov , Dmitriy Ivanovich Pivunov , Svetlana Viktorovna Vasiljeva , Nik Shkolnik , Sam Kogan
IPC分类号： H01G9/00
CPC分类号： H01M4/602 , H01G9/042 , H01G9/22 , H01G11/02 , H01G11/26 , H01G11/32 , H01G11/48 , Y02E60/13 , Y10T29/417
摘要： The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from −3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.
摘要翻译：本发明是一种电化学电容器，其电极在导电衬底上制成，其上沉积有一层聚[Me（R-Salen）]型氧化还原聚合物。 Me是过渡金属（例如Ni，Pd，Co，Cu，Fe），R是给电子取代基（例如CH 3 O，C 2， H 2 O-，HO-，-CH 3 3），Salen是席夫碱中双（水杨醛） - 乙二胺的残基。电解质包括有机溶剂，能够溶解在这样的溶剂中的化合物，所得到的浓度不低于0.01mol / l，并且在电位从-3.0V到+ 1.5V（例如，四甲基铵，四丙基铵，四丁基铵的盐）和溶解的金属络合物[Me（R-Salen）]。使用电容器的方法考虑周期性地交替电极的连接极性，导致电极的电化学特性再生。

4. 发明申请

US20050258042A1 Method of manufacture of an electrode for electrochemical devices 审中-公开
标题翻译：电化学装置用电极的制造方法
公开(公告)号：US20050258042A1
公开(公告)日：2005-11-24
申请号：US11100036
申请日：2005-04-06
申请人： Alexander Lyubomirskiy , Valeriy Pavlov , Alexander Timonov , Sergey Logvinov , Dmitriy Pivunov , Svetlana Vasiljeva , Nik Shkolnik , Sam Kogan
发明人： Alexander Lyubomirskiy , Valeriy Pavlov , Alexander Timonov , Sergey Logvinov , Dmitriy Pivunov , Svetlana Vasiljeva , Nik Shkolnik , Sam Kogan
IPC分类号： H01G9/00 , H01G9/04 , H01G9/058 , H01M4/137 , H01M4/60 , H01M4/66 , H01M4/04
CPC分类号： H01M4/137 , H01G9/0032 , H01G9/0036 , H01G9/04 , H01G11/48 , H01M4/0438 , H01M4/0466 , H01M4/60 , H01M4/66 , H01M4/663 , H01M4/667 , H01M4/668 , Y02E60/13
摘要： Deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/l within the range of potentials from −3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.
摘要翻译：公开了通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上。所述聚合发生在施加在基板和反电极之间的电压，两者都被浸没在电解质中。电解质含有有机溶剂，能够溶解在溶剂中的化合物和在-3.0V至+1.5V的电位范围内以不低于0.01mol / l的浓度形成电化学惰性离子的化合物，以及金属络合物聚[ Me（R-Salen）]以不低于5×10 -5摩尔/升的浓度溶解。 Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是Schiff碱中的双（水杨醛） - 乙二胺的残基）。在电解质中发生氧化还原的沉积，其中化合物的阳离子的直径大于含有电极的储能装置的电解质阳离子的直径。

5. 发明申请

US20050217998A1 Method for the manufacture of electrode for energy-storage devices 有权
标题翻译：用于制造储能装置的电极的方法
公开(公告)号：US20050217998A1
公开(公告)日：2005-10-06
申请号：US11088509
申请日：2005-03-24
申请人： Alexander Timonov , Sergey Logvinov , Dmitriy Pivunov , Svetlana Vasiljeva , Nik Shkolnik , Sam Kogan
发明人： Alexander Timonov , Sergey Logvinov , Dmitriy Pivunov , Svetlana Vasiljeva , Nik Shkolnik , Sam Kogan
IPC分类号： H01G9/04 , H01G9/155 , H01M4/137 , H01M4/60 , H01M4/04
CPC分类号： H01M4/0438 , C08G12/06 , H01G9/0036 , H01G9/155 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/606 , Y02E60/13
摘要： Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from −3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5·10−5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.
摘要翻译：聚 - [Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，两者都被浸没在含有机溶剂的电解质中，并且能够溶解在所述溶剂。该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性的（浓度不小于0.01mol / l）的离子，并且溶解在金属络合物[Me（R-Salen）浓度不低于5.10〜5mol / l，（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是双（水杨醛） - 乙二胺在希夫碱。

6. 发明申请

US20050225928A1 Electrochemical capacitor and method of use 有权
标题翻译：电化学电容器及其使用方法
公开(公告)号：US20050225928A1
公开(公告)日：2005-10-13
申请号：US11098698
申请日：2005-04-04
申请人： Alexander Timonov , Sergey Logvinov , Dmitriy Pivunov , Svetlana Vasiljeva , Nik Shkolnik , Sam Kogan
发明人： Alexander Timonov , Sergey Logvinov , Dmitriy Pivunov , Svetlana Vasiljeva , Nik Shkolnik , Sam Kogan
IPC分类号： H01G9/00 , H01G9/022 , H01G9/04 , H01G9/042 , H01G9/22 , H01M4/04 , H01M4/60
CPC分类号： H01M4/602 , H01G9/042 , H01G9/22 , H01G11/02 , H01G11/26 , H01G11/32 , H01G11/48 , Y02E60/13 , Y10T29/417
摘要： The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from −3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.
摘要翻译：本发明是一种电化学电容器，其电极在导电衬底上制成，其上沉积有一层聚[Me（R-Salen）]型氧化还原聚合物。 Me是过渡金属（例如Ni，Pd，Co，Cu，Fe），R是给电子取代基（例如CH 3 O，C 2， H 2 O-，HO-，-CH 3 3），Salen是席夫碱中双（水杨醛） - 乙二胺的残基。电解质包括有机溶剂，能够溶解在这样的溶剂中的化合物，所得到的浓度不低于0.01mol / l，并且在电位从-3.0V到+ 1.5V（例如四甲基铵，四丙基铵，四丁基铵的盐）和溶解的金属络合物[Me（R-Salen）]。使用电容器的方法考虑周期性地交替电极的连接极性，导致电极的电化学特性再生。

7. 发明申请

US20090026085A1 METHOD FOR PRODUCING ELECTRODE FOR ELECTROCHEMICAL ELEMETN AND METHOD FOR PRODUCING ELECTROCHEMICAL ELEMENT WITH THE ELECTRODE 审中-公开
标题翻译：用于生产电化学电极的电极的方法和用电极生产电化学元件的方法
公开(公告)号：US20090026085A1
公开(公告)日：2009-01-29
申请号：US11917002
申请日：2005-06-10
申请人： Hidenori Uchi , Kenji Tamamitsu , Shunzo Suematsu , Satoru Tsumeda , Alexander M. Timonov , Sergey A. Logvinov , Nikolay Shkolnik , Sam Kogan
发明人： Hidenori Uchi , Kenji Tamamitsu , Shunzo Suematsu , Satoru Tsumeda , Alexander M. Timonov , Sergey A. Logvinov , Nikolay Shkolnik , Sam Kogan
IPC分类号： C25B3/00
CPC分类号： H01G11/48 , H01G11/24 , H01G11/28 , H01G11/30 , H01G11/32 , H01G11/86 , H01M4/0438 , H01M4/0466 , H01M4/137 , H01M4/1399 , H01M4/60 , H01M4/602 , H01M4/606 , H01M10/052 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： A method for producing an electrode for an electrochemical element absorbs monomers for polymerization on a surface having a specific surface area of 100 to 3000 m2g−1 and having an average pore diameter in the range of 0.4 to 100 nm, performing electrolysis polymerization by applying pulse voltage, and forming a conductive polymer layer on the surface of the conductive porous material, forming a thin and uniform electrode film. In a method for producing an electrochemical element, a conductive polymer layer is formed on the conductive porous material by absorbing monomers for polymerization on a surface of a conductive porous material having a specific surface area and pore diameter as above forming a electrochemical cell by using the conductive porous material, the monomers are absorbed in the pores, putting the electrochemical cell and the electrolyte solution in an outer casing, and performing electrolysis polymerization of the monomers in the electrolyte solution.
摘要翻译：一种电化学元件用电极的制造方法，在比表面积为100〜3000m 2 / g的表面吸收聚合用单体，平均孔径为0.4〜100nm，通过施加脉冲进行电解聚合电压，并在导电性多孔材料的表面上形成导电聚合物层，形成薄而均匀的电极膜。在电化学元件的制造方法中，通过在上述形成电化学电池的比表面积和孔径以上的导电性多孔质材料的表面上吸收用于聚合的单体，在导电性多孔质材料上形成导电性聚合物层，导电多孔材料，单体被吸收在孔中，将电化学电池和电解质溶液放入外壳中，并进行电解液中单体的电解聚合。

8. 发明申请

US20080213500A1 Method for Producing Electrode Material 审中-公开
标题翻译：生产电极材料的方法
公开(公告)号：US20080213500A1
公开(公告)日：2008-09-04
申请号：US11664286
申请日：2004-09-30
申请人： Hidenori Uchi , Kenji Tamamitsu , Satori Tsumeda , Alexander M. Timonov , Sergey Nikolay Shkolnik , Sam Kogan
发明人： Hidenori Uchi , Kenji Tamamitsu , Satori Tsumeda , Alexander M. Timonov , Sergey Nikolay Shkolnik , Sam Kogan
IPC分类号： C08F2/58
CPC分类号： H01G9/155 , H01M4/0438 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/1399 , H01M4/602 , H01M10/0525 , Y02E60/13 , Y02T10/7022
摘要： To provide a method for producing an electrode material which is improved in energy density and is excellent in output characteristics. The present invention provides a manufacturing method for the electrode material comprising the steps of: 1) immersing a conductive material having a specific surface area of 200 to 3000 m2g−1 in a complex monomer solution of a transition metal having at least two different oxidation numbers, 2) performing electro polymerization by applying pulse voltage using the conductive material as an electrode to stack the complex monomer under the condition that electrolyzation time is 0.1 to 60 second and a downtime is 10 to 600 second, and 3) forming on the surface of the conductive material an energy accumulating redox polymer layer containing polymer complex compound of transition metal formed by the stacked complex monomer, thereby accumulating energy via a redox reaction: wherein a thin and uniform electrode film is formed, namely the electrode material which is excellent in output characteristics and improves energy density is manufactured according to the method.
摘要翻译：提供能够提高能量密度且输出特性优异的电极材料的制造方法。本发明提供一种电极材料的制造方法，包括以下步骤：1）将比表面积为200〜3000μm2〜在具有至少两个不同氧化数的过渡金属的复合单体溶液中，2）通过使用导电材料作为电极施加脉冲电压来进行电聚合，以在电解时间为0.1至60秒的条件下堆叠复合单体，以及停机时间为10〜600秒，3）在导电材料的表面上形成能量积聚的氧化还原聚合物层，其含有由层叠的复合单体形成的过渡金属的聚合物络合物，由此通过氧化还原反应积累能量：其中薄形成均匀的电极膜，即根据该方法制造输出特性优异，能量密度提高的电极材料。

9. 发明申请

US20080300381A1 Electrode Material and Electrochemical Device 审中-公开
标题翻译：电极材料和电化学装置
公开(公告)号：US20080300381A1
公开(公告)日：2008-12-04
申请号：US11664281
申请日：2004-09-30
申请人： Hidenori Uchi , Kenji Tamamitsu , Shunzo Suematsu , Satoru Tsumeda , Alexander M. Timonov , Sergey A. Logvinov , Nikolay Shkolnik , Sam Kogan
发明人： Hidenori Uchi , Kenji Tamamitsu , Shunzo Suematsu , Satoru Tsumeda , Alexander M. Timonov , Sergey A. Logvinov , Nikolay Shkolnik , Sam Kogan
IPC分类号： C08G79/00
CPC分类号： H01M4/60 , H01G9/155 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/602 , H01M10/0525 , H01M2004/028 , Y02E60/13
摘要： To provide an electrode material excellent in output characteristics and cycle property and an electrochemical device using the electrode material. The electrode material comprising polymer complex compound represented by the following graphical formula: and the electrochemical device using the electrode material. Even if such a large size ion is employed, enhanced output characteristics could be obtained in the present invention. Polymer complex compound is polarized due to an electron attracting substituent, or steric hindrance occurs due to a substituent having a branch structure so that interval of polymer complex compound formed on the electrode is increased and doping reaction. Therefore, even if using large size ions smooth and rapid doping and undoping reaction could take place.
摘要翻译：提供输出特性和循环特性优异的电极材料和使用电极材料的电化学装置。该电极材料包含由以下图示式表示的聚合物复合化合物：和使用电极材料的电化学装置。即使采用这样大的离子，本发明也可以得到增强的输出特性。聚合物复合化合物由于吸电子取代基而极化，或者由于具有分支结构的取代基而发生空间位阻，使得在电极上形成的聚合物络合物的间隔增加和掺杂反应。因此，即使使用大尺寸离子，也可以进行平滑，快速的掺杂和非掺杂反应。

10. 发明授权

US07888229B2 Method for manufacturing an energy storage device 有权
标题翻译：储能装置的制造方法
公开(公告)号：US07888229B2
公开(公告)日：2011-02-15
申请号：US11726985
申请日：2007-03-23
申请人： Irina Chepurnaya , Alexander Timonov , Sergey Logvinov , Sam Kogan
发明人： Irina Chepurnaya , Alexander Timonov , Sergey Logvinov , Sam Kogan
IPC分类号： H01L21/20
CPC分类号： H01G9/155 , H01G9/038 , H01G9/058 , H01G9/15 , H01G11/02 , H01G11/24 , H01G11/26 , H01G11/58 , Y02E60/13 , Y10T29/417
摘要： The present invention relates to methods of manufacturing an electrochemical energy storage device, such as a hybrid capacitor. The method comprises saturating a porous electrically conductive material in a solution comprising an organic solvent and a metal complex or a mixture of metal complexes; assembling a capacitor comprising the positive electrode made of porous electrically conductive material saturated with a metal complex, a negative electrode, and a separator in a casing; introducing the electrolyte solution into the casing; sealing the casing; and subsequent charge-discharge cycling of the capacitor. The charge-discharge cycling deposits a layer of an energy-accumulating redox polymer on the positive electrode. The electrolyte solution for filling the hybrid capacitor contains an organic solvent, a metal complex, and substances soluble to a concentration of no less than 0.01 mol/L and containing ions that are electrochemically inactive within the range of potentials between −3.0 V to +1.5 V.
摘要翻译：本发明涉及电化学储能装置如混合电容器的制造方法。该方法包括在包含有机溶剂和金属络合物或金属络合物的混合物的溶液中饱和多孔导电材料; 组装一个电容器，该电容器包括由壳体中的金属络合物，负极和隔板饱和的多孔导电材料制成的正电极; 将电解质溶液引入壳体中; 密封套管; 以及随后的电容器的充放电循环。充电 - 放电循环在正电极上沉积一层能量聚集的氧化还原聚合物。用于填充混合电容器的电解液包含有机溶剂，金属络合物和可溶于0.01mol / L浓度的物质，并且在-3.0V至+1.5之间的电势范围内含有电化学惰性的离子五

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