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1. 发明授权

US06503989B1 Polyolefin-based printable articles 失效
标题翻译：聚烯烃类可印刷制品
公开(公告)号：US06503989B1
公开(公告)日：2003-01-07
申请号：US09624163
申请日：2000-07-24
申请人： Zdenek Hruska
发明人： Zdenek Hruska
IPC分类号： C08L2330
CPC分类号： C08L23/02 , C08L79/02 , C08L2555/40 , Y10T428/31855 , Y10T428/31938 , C08L2666/20
摘要： A monolayer polyolefin-based printable article includes 0.1 to 5% by weight of at least one polyaminoalkylene, and is characterized in that it has been treated by means of an oxidative surface treatment, such as a corona treatment. A process for the manufacture of a polyolefin-based printable article, according to which at least one surface region of the article, including at least one polyolefin and from 0.1 to 5% by weight of at least one polyaminoalkylene, involves subjecting the region to an oxidative surface treatment. A printing process, according to which a polyolefin-based article, including from 0.1 to 5% by weight of at least one polyaminoalkylene and treated by means of an oxidative surface treatment, utilizes an electrophotography technique to print on the article.
摘要翻译：单层聚烯烃类可印刷制品包含0.1至5重量％的至少一种聚氨基亚烷基，其特征在于其已经通过氧化表面处理如电晕处理进行处理。一种用于制造聚烯烃基可印刷制品的方法，根据该方法，制品的至少一个表面区域包括至少一种聚烯烃和0.1至5重量％的至少一个聚氨基亚烷基，包括使该区域经受氧化表面处理。根据该方法，包含0.1至5重量％的至少一种聚氨基亚烷基并通过氧化表面处理处理的聚烯烃基制品利用电子照相技术在制品上印刷。

2. 发明授权

US5958524A Process for the surface treatment of articles comprising at least one plastic material 失效
标题翻译：用于表面处理包含至少一种塑料材料的制品的方法
公开(公告)号：US5958524A
公开(公告)日：1999-09-28
申请号：US902074
申请日：1997-07-29
申请人： Claude Dehennau , Zdenek Hruska , Frederic Menu
发明人： Claude Dehennau , Zdenek Hruska , Frederic Menu
IPC分类号： C08J7/00 , C08J7/12 , B05D3/04 , B05D3/14
CPC分类号： C08J7/126
摘要： The invention relates to a process for the surface treatment of at least one portion of an article comprising at least one plastic material, the process comprising a step of fluorination for out most 12 seconds, following a step of an energetic surface oxidation of this portion.
摘要翻译：本发明涉及一种用于表面处理包含至少一种塑料材料的制品的至少一部分的方法，所述方法包括在该部分的能量表面氧化步骤后最多12秒的氟化步骤。

3. 发明授权

US5605718A Process for the surface treatment of an article by sulphonation and neutralization 失效
标题翻译：通过磺化和中和处理物品的方法
公开(公告)号：US5605718A
公开(公告)日：1997-02-25
申请号：US458413
申请日：1995-06-02
申请人： Anne Tinant , Fr ed eric Menu , Zdenek Hruska
发明人： Anne Tinant , Fr ed eric Menu , Zdenek Hruska
IPC分类号： C08J7/00 , B05D3/10 , C08J7/12 , C08J7/14
CPC分类号： C08J7/14
摘要： Process for the surface treatment of at least a part of an article comprising at least one surface essentially composed of a plastic, the said process comprising at least one sulphonation stage and at least one neutralization stage and being characterized in that the neutralization is carried out by bringing into contact with at least one polyamine compound.
摘要翻译：用于表面处理包含至少一个基本上由塑料构成的表面的至少一部分制品的工艺，所述方法包括至少一个磺化阶段和至少一个中和阶段，其特征在于中和由与至少一种多胺化合物接触。

4. 发明授权

US6046274A Flexible composition based on vinyl chloride polymer, use of said composition for manufacturing articles and articles made of said composition 失效
标题翻译：基于氯乙烯聚合物的柔性组合物，所述组合物用于制造由所述组合物制成的制品和制品
公开(公告)号：US6046274A
公开(公告)日：2000-04-04
申请号：US973272
申请日：1998-01-28
申请人： Dominique Grandjean , Zdenek Hruska , Danny Van Hoyweghen , Henri Wautier
发明人： Dominique Grandjean , Zdenek Hruska , Danny Van Hoyweghen , Henri Wautier
IPC分类号： A61L29/00 , A61L29/04 , A61L31/00 , A61L31/04 , C08G63/664 , C08L27/06 , C08L67/04 , C08L71/02 , B32B27/30 , B65D30/02
CPC分类号： C08G63/664 , A61L29/049 , A61L31/041 , C08L27/06 , C08L67/04 , Y10T428/1341 , Y10T428/31935 , Y10T428/31942
摘要： The invention relates to a flexible composition comprising a vinyl chloride polymer and a block copolymer. The latter comprises a poly(ethylene oxide) block and a block of a polymer which is miscible with the vinyl chloride polymer, other than the latter itself. The invention also relates to a poly(ethylene oxide)/poly-.epsilon.-caprolactone diblock copolymer which can be used in this composition, as well as to the use of this composition for the manufacture of an article and to an article comprising this composition.
摘要翻译： PCT No.PCT / EP96 / 02223 Sec。 371日期1998年1月28日 102（e）1998年1月28日PCT PCT 1996年5月22日PCT公布。 WO96 / 38503 PCT出版物日期1996年12月5日本发明涉及一种包含氯乙烯聚合物和嵌段共聚物的柔性组合物。后者包括聚（环氧乙烷）嵌段和与氯乙烯聚合物可混溶的聚合物嵌段，而不是后者本身。本发明还涉及可用于该组合物中的聚（环氧乙烷）/聚ε-己内酯二嵌段共聚物，以及该组合物用于制造制品和使用该组合物的制品。

5. 发明授权

US5654378A Polyolefin-based articles printed by means of inks for PVC and processes for their manufacture 失效
标题翻译：用于PVC的油墨印刷的聚烯烃类制品及其制造方法
公开(公告)号：US5654378A
公开(公告)日：1997-08-05
申请号：US423151
申请日：1995-04-17
申请人： Claude Dehennau , Zdenek Hruska , Frederic Menu
发明人： Claude Dehennau , Zdenek Hruska , Frederic Menu
IPC分类号： B41M1/30 , C08J5/18 , C08J7/12 , C08J7/18 , C08F8/22
CPC分类号： B41M1/305
摘要： The invention relates to articles including at least one polyolefin, which are surface-treated and printed with inks for PVC, which are characterized by the surface presence of fluorine and oxygen in concentrations such that the oxygen/carbon atomic ratio (O/C), measured by ESCA spectroscopy at a depth of 1.5 nm, is at least 0.08 and that the fluorine/carbon atomic ratio (F/C) (measured in the same way) has a value of at least 90% of that of the O/C ratio and of not more than 290% of this ratio. It also relates to a process for their manufacture.
摘要翻译：本发明涉及包含至少一种聚烯烃的制品，其被表面处理并印刷有用于PVC的油墨，其特征在于氟和氧的表面存在，其浓度使得氧/碳原子比（O / C），通过ESCA光谱法在1.5nm的深度测量为至少0.08，并且氟/碳原子比（F / C）（以相同的方式测量）具有至少90％的O / C值比例不超过此比例的290％。它还涉及其制造方法。

6. 发明授权

US06335131B1 Articles printed by electrophotography 失效
标题翻译：用电子照相印刷的文章
公开(公告)号：US06335131B1
公开(公告)日：2002-01-01
申请号：US09440090
申请日：1999-11-15
申请人： Zdenek Hruska , Claude Dehennau
发明人： Zdenek Hruska , Claude Dehennau
IPC分类号： G03G1316
CPC分类号： G03G7/004 , G03G7/008
摘要： The invention relates to an article of which at least one surface zone comprises at least one polyolefin and has been printed by means of a toner by an electrophotographic technique, characterized in that the printed zone contains no toner printing primer and in that the adhesion of the toner to the article is such that it withstands a stripping force of at least 0.4 N/mm exerted by means of an adhesive tape. It also relates to a process for the manufacture thereof.
摘要翻译：本发明涉及一种制品，其中至少一个表面区域包含至少一个聚烯烃，并且通过电子照相技术通过调色剂印刷，其特征在于，印刷区域不含调色剂印刷底漆，并且其粘合性制品的调色剂使得其经受通过胶带施加的至少0.4N / mm的剥离力。它还涉及其制造方法。

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