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1. 发明专利

JP2011167688A Humidity controlling and gas adsorbing material, and method for manufacturing the same 审中-公开
标题翻译：湿度控制和气体吸附材料及其制造方法
公开(公告)号：JP2011167688A
公开(公告)日：2011-09-01
申请号：JP2011070519
申请日：2011-03-28
申请人： Hokkaido Univ , Sangi-Tuuun Co Ltd , Shizen Sozai Kenkyusho:Kk , Wakkanai Green Factory:Kk , 三岐通運株式会社 , 国立大学法人北海道大学 , 有限会社稚内グリーンファクトリー , 株式会社自然素材研究所
发明人： NAGANO KATSUNORI , YOSHIDA SHIGEO , TOGAWA JUNYA , ITO HARUJI
IPC分类号： B01J20/12 , A61L9/01 , A61L9/16 , B01D53/28 , B01J20/32 , C01B33/40
摘要： PROBLEM TO BE SOLVED: To provide a functional material usable for various purposes by adding high gas adsorbing function for different gases to siliceous shale having high humidity controlling capacity and a high adsorbability for basic gas.
SOLUTION: The humidity controlling and gas adsorbing material contains the siliceous shale as a principal component subjected to a treatment by an alkaline compound to the natural siliceous shale having a moisture absorbing capacity and moisture absorbing/releasing characteristics autonomically releasing the moisture, and also having gas adsorbing capacity for gas selected among toluene, methyl mercaptan and hydrogen sulfide besides the humidity controlling function and the gas adsorbing capacity for ammonia, derived from the natural siliceous shale. The siliceous shale subjected to the treatment by an alkaline compound has a peak of the fine hole diameter in the range of 8.5-10 nm, and an average fine hole diameter in the range of 8.5-9.5 nm. At least one kind selected among hydroxide, carbonate and silicate of an alkali metal or an alkaline earth metal is carried in at least a part in the fine holes.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：为了提供可用于各种目的的功能材料，通过将不同气体的高气体吸附功能添加到具有高湿度控制能力和对碱性气体的高吸附性的硅质页岩。解决方案：湿度控制和气体吸附材料包含硅质页岩作为经由碱性化合物处理的天然硅质页岩的主要成分，其具有吸湿能力和吸水/释放特性自发地释放水分，以及除天然硅质页岩之外，还具有选自甲苯，甲硫醇和硫化氢中的气体的气体吸附能力，除了湿度控制功能和氨的气体吸附能力。通过碱性化合物处理的硅质页岩的细孔直径的峰值在8.5-10nm的范围内，平均细孔直径在8.5-9.5nm的范围内。碱金属或碱土金属的氢氧化物，碳酸盐和硅酸盐中的至少一种在微孔中的至少一部分被承载。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2014144423A Method of manufacturing particulate siliceous shale material, and particulate siliceous shale material obtained by the method 审中-公开
标题翻译：制造颗粒状硅质材料的方法和方法获得的颗粒状硅质材料
公开(公告)号：JP2014144423A
公开(公告)日：2014-08-14
申请号：JP2013014302
申请日：2013-01-29
申请人： Hokkaido Univ , 国立大学法人北海道大学 , Wakkanai Green Factory:Kk , 有限会社稚内グリーンファクトリー
发明人： NAGANO KATSUNORI , TOGAWA JUNYA
IPC分类号： B01J20/30 , B01D53/28 , B01J20/12 , B02C13/13
摘要： PROBLEM TO BE SOLVED: To provide a Wakkanai-layer siliceous shale material with higher quality which enables utilization in a wide range, exerts higher absorption and desorption of moisture, and further enables providing a product with a new bright color tone by converting Wakkanai-layer siliceous shale to fine particles having a sharp particle distribution and a particle size of not greater than 20 μm.SOLUTION: A method of manufacturing a siliceous shale material is to directly obtain a particulate siliceous shale material having a sharp particle size distribution by a dry pulverizing method. The method of manufacturing a siliceous shale material includes pulverizing coarse particles of Wakkanai-layer siliceous shale as a raw material with a dry-type pulverizing machine having a nozzle-discharging mechanism for separating and removing hard-to-grind matter while pulverizing the raw material, and separating and removing a hard-to-grind part, which is relatively hard to be ground, composing the Wakkanai-layer siliceous shale raw material to obtain the particulate siliceous shale material having an average particle size of not greater than 20 μm, and a maximum particle size of 50 μm.
摘要翻译：要解决的问题：为了提供更高质量的稚内层硅质页岩材料，其能够在较宽范围内利用，发挥更高的吸湿和解吸作用，并且还可以通过将稚内层转化为具有新的亮色调的产品硅质页岩具有尖锐的颗粒分布和不大于20μm的颗粒尺寸的细颗粒。解决方案：制造硅质页岩材料的方法是通过干式粉碎直接获得具有尖锐粒度分布的颗粒状硅质页岩材料方法。制造硅质页岩材料的方法包括用干式粉碎机将稚内层硅质页岩粗颗粒粉碎成具有用于在粉碎原料的同时分离除去难以研磨物质的喷嘴排出机构，并分离除去相对难以研磨的难研磨部分，构成稚内层硅质页岩原料，得到平均粒径不大于20μm的颗粒状硅质页岩材料，以及最大粒径为50μm。

3. 发明专利

JP2010174415A Method of production of moisture absorbing/releasing paper and moisture absorbing/releasing paper 审中-公开
标题翻译：水分吸收/释放纸和水分吸收/释放纸的生产方法
公开(公告)号：JP2010174415A
公开(公告)日：2010-08-12
申请号：JP2009019846
申请日：2009-01-30
申请人： Hokkaido Univ , Mitsubishi Paper Mills Ltd , Shizen Sozai Kenkyusho:Kk , Wakkanai Green Factory:Kk , 三菱製紙株式会社 , 国立大学法人北海道大学 , 有限会社稚内グリーンファクトリー , 株式会社自然素材研究所
发明人： NAGANO KATSUNORI , NAKABAYASHI SAYA , YOSHIDA SHIGEO , TOGAWA JUNYA , KUROKAWA ASAMI , KOIKE NAOMASA , TAKAOKA KAZUCHIYO
IPC分类号： D21H21/14 , D21H17/67 , D21H27/00
摘要： PROBLEM TO BE SOLVED: To provide a method of production of moisture absorbing/releasing paper holding paper characteristics, suppressing swelling-caused dimensional change, material falling down and dispersal, and further capable of exerting excellent moisture absorbing/releasing performance. SOLUTION: The method of production of moisture absorbing/releasing paper includes a step of providing a paper substrate by papermaking from an aqueous slurry, which aqueous slurry contains at least pulp fiber and an inorganic porous material having characteristics: 1-10 nm average pore radius, 80 m 2 /g or more of specific surface area, and 5-80 μm average particle diameter, and contains 5-65 mass% in terms of solid content of the inorganic porous material, and a step of coating or impregnating the paper substrate with a salt solution containing at least one salt compound selected from the group consisting of lithium chloride, sodium chloride, magnesium chloride, and calcium chloride. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决问题的方法：提供吸湿释放纸张保持纸特性的方法，抑制膨胀引起的尺寸变化，材料落下和分散，并且还能够发挥优异的吸湿性能。解决方案：生产吸湿纸的方法包括通过造纸从含水浆料提供纸基底的步骤，该含水浆料至少包含纸浆纤维和具有以下特征的无机多孔材料：1-10nm 平均孔半径，比表面积80μm2 / SP / g以上，平均粒径为5-80μm，以无机多孔质体的固体成分计含有5-65质量％以及用含有选自氯化锂，氯化钠，氯化镁和氯化钙中的至少一种盐化合物的盐溶液涂布或浸渍纸基材的步骤。版权所有（C）2010，JPO＆INPIT

4. 发明专利

JP2010115643A Dehumidification filter, desiccant air-conditioner using this dehumidification filter and air-conditioning method 有权
标题翻译：除湿过滤器，使用此除湿过滤器的空气调节器和空调方法
公开(公告)号：JP2010115643A
公开(公告)日：2010-05-27
申请号：JP2009240716
申请日：2009-10-19
申请人： Fuji Slate Kk , Hokkaido Univ , Shizen Sozai Kenkyusho:Kk , Wakkanai Green Factory:Kk , 国立大学法人北海道大学 , 富士スレート株式会社 , 有限会社稚内グリーンファクトリー , 株式会社自然素材研究所
发明人： NAGANO KATSUNORI , NAKABAYASHI SAYA , YOSHIDA SHIGEO , TOGAWA JUNYA , KUROKAWA ASAMI , MABUCHI YUZO , MABUCHI ISATO
IPC分类号： B01D53/28 , B01D53/26 , B01J20/12 , F24F3/14
摘要： PROBLEM TO BE SOLVED: To provide a dehumidification filter which has high dehumidifying function and the capability to easily and certainly regenerate itself at a lower temperature than conventionally set and ideally at normal temperatures and is very useful in terms of energy saving and device miniaturization, when this filter is applied to a desiccant rotor. SOLUTION: This dehumidification filter has the characteristics: a dehumidifying material formed of siliceous shale with numerous pores having an average pore diameter of 3-18 nm and a specific surface area of not less than 80 m 2 /g, is made to deposit on or to be included in a base material to be used for a desiccant rotor of a desiccant air-conditioner. The dehumidifying material is left at rest for 24 hours under environments at a temperature of 40°C and a relative humidity of 30%, and then is left at rest for two hours under environments at a temperature of 30°C and a relative humidity of 75%. In this case, the dehumidifying material shows a mass increase of not less than 60 mg/g. In addition, the dehumidifying material shows a mass decrease of not less than 60 mg/g when it is left at rest for two hours under environments at a temperature of 40°C and at a relative humidity of 30%. Besides, a deliquescent material adheres to, at least, the interior of the pore of the siliceous shale showing the difference between the mass increase and the mass decrease of not more than 20 mg/g. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种具有高除湿功能的除湿过滤器，并且能够在比常规设定的温度更低的温度下容易且可靠地再生，并且在正常温度下理想地再生，并且在节能和装置方面非常有用当将该过滤器应用于干燥剂转子时，小型化。解决方案：该除湿过滤器具有以下特征：由硅质页岩形成的除湿材料，具有许多孔，平均孔径为3-18nm，比表面积不小于80m 2 SP SP > / g，沉积在干燥剂空调器的干燥剂转子所用的基材中或被包含在基材中。将除湿材料在温度40℃，相对湿度30％的环境下静置24小时，然后在30℃的温度和相对湿度的环境下静置2小时 75％。在这种情况下，除湿材料的质量增加量不小于60mg / g。此外，当在40℃的温度和30％的相对湿度的环境下静置2小时时，除湿材料的质量减少量不小于60mg / g。此外，潮解材料至少粘附在硅质页岩的孔内，显示质量增加与质量减少之间的差异不超过20mg / g。版权所有（C）2010，JPO＆INPIT

5. 发明专利

JP2008221126A Surface modified siliceous shale and water purifying method using the same 审中-公开
标题翻译：表面改性硅藻土和水的净化方法
公开(公告)号：JP2008221126A
公开(公告)日：2008-09-25
申请号：JP2007062850
申请日：2007-03-13
申请人： Hokkaido Univ , Sanki Tsuuun Kk , Shizen Sozai Kenkyusho:Kk , Wakkanai Green Factory:Kk , 三岐通運株式会社 , 国立大学法人北海道大学 , 有限会社稚内グリーンファクトリー , 株式会社自然素材研究所
发明人： NAGANO KATSUNORI , TOGAWA JUNYA , YOSHIDA SHIGEO , ITO HARUJI
IPC分类号： B01J20/12 , B01J20/34 , C01B33/00 , C02F1/28
摘要： PROBLEM TO BE SOLVED: To provide a surface modified siliceous shale which functions as adsorption material for an organic chlorine compound in water, and the surface modified siliceous shale which allows easy regeneration treatment, and can be used in a satisfactory state again, wherein adsorption performance for organic chlorine compound is kept even when performing the regeneration treatment repeatedly, and to provide a water purifying method capable of economically adsorbing and removing organic chlorine compound in contaminated water.
SOLUTION: This invention relates to the surface modified siliceous shale having adsorptivity for organic chlorine compound, wherein the surface of siliceous shale of which the specific surface area measured by a BET method according to nitrogen method is 100 m
2 /g or more is subjected to hydrophobic treatment with a silane coupling agent.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种表面改性硅质页岩，其作为水中的有机氯化合物的吸附材料，以及能够容易地再生处理的表面改性硅质页岩，并且可以再次以令人满意的状态使用，其中，即使重复进行再生处理，也能够保持有机氯化合物的吸附性能，能够提供能够在受污染的水中经济吸附除去有机氯化合物的水净化方法。本发明涉及对有机氯化合物具有吸附性的表面改性硅质页岩，其中通过BET法通过氮气法测量的比表面积为100μm的硅质页岩表面为100m < / SP> / g以上的硅烷偶联剂进行疏水处理。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2010174172A Coating agent 审中-公开
标题翻译：涂料代理
公开(公告)号：JP2010174172A
公开(公告)日：2010-08-12
申请号：JP2009019884
申请日：2009-01-30
申请人： Fuji Slate Kk , Hokkaido Univ , Shizen Sozai Kenkyusho:Kk , Wakkanai Green Factory:Kk , 国立大学法人北海道大学 , 富士スレート株式会社 , 有限会社稚内グリーンファクトリー , 株式会社自然素材研究所
发明人： NAGANO KATSUNORI , NAKABAYASHI SAYA , YOSHIDA SHIGEO , TOGAWA JUNYA , KUROKAWA ASAMI , MABUCHI YUZO , MABUCHI ISATO
IPC分类号： C09D201/00 , C09D5/02 , C09D7/12 , C09D133/00
摘要： PROBLEM TO BE SOLVED: To provide a coating agent forming a continuous porous film having excellent humidity control properties and satisfactory gas adsorption.
SOLUTION: The coating agent for forming the continuous porous film having humidity control/gas adsorption properties includes at least an inorganic porous material having 1 to 10 nm average pore radius, ≥80 m
2 /g specific surface area and ≤80 μm average particle diameter, a porous film forming material and at least one salt compound selected from the group consisting of lithium chloride, sodium chloride, magnesium chloride and calcium chloride.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供形成具有优异的湿度控制性能和令人满意的气体吸附的连续多孔膜的涂布剂。解决方案：用于形成具有调湿/气体吸附性能的连续多孔膜的涂布剂至少包括平均孔半径为1-10nm的无机多孔材料，≥80m2 / SP / g 比表面积和≤80μm平均粒径，多孔成膜材料和至少一种选自氯化锂，氯化钠，氯化镁和氯化钙的盐化合物。版权所有（C）2010，JPO＆INPIT

7. 发明专利

JP2010094636A Moisture absorbing and discharging material, and method of manufacturing the same 有权
标题翻译：水分吸收和排出材料及其制造方法
公开(公告)号：JP2010094636A
公开(公告)日：2010-04-30
申请号：JP2008269255
申请日：2008-10-19
申请人： Hokkaido Univ , Shizen Sozai Kenkyusho:Kk , Wakkanai Green Factory:Kk , 国立大学法人北海道大学 , 有限会社稚内グリーンファクトリー , 株式会社自然素材研究所
发明人： NAGANO KATSUNORI , NAKABAYASHI SAYA , YOSHIDA SHIGEO , TOGAWA JUNYA , KUROKAWA ASAMI
IPC分类号： B01D53/28 , B01J20/12 , F24F3/14
摘要： PROBLEM TO BE SOLVED: To provide an excellent moisture absorbing and discharging material, which increases the most moisture-absorbing amount from a middle humid zone to a high humid zone by reforming siliceous shale as compared to raw stone, and discharges the absorbed moisture in case of decreasing a relative humidity to attain a rapid discharge of the moisture without any humidity accumulation. SOLUTION: In the moisture absorbing and discharging material, a sodium chloride adheres to at least the inside of the fine pore of the siliceous shale having many pores in which an average fine pore diameter is 3-18 nm and a specific surface area is 80 m 2 /g or more. The method of manufacturing the same is provided. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供优异的吸湿排放材料，其通过与原始石头相比重新形成硅质页岩，从而从中部湿润区域到高湿度区域增加最多的吸湿量，并且将吸收在相对湿度降低的情况下的水分，以便在没有任何湿度积聚的情况下快速排出水分。解决方案：在吸湿排放材料中，氯化钠至少粘附到具有许多孔的硅质页岩的至少内部，其中平均细孔直径为3-18nm，比表面积是80m 2 / g以上。提供其制造方法。版权所有（C）2010，JPO＆INPIT

8. 发明专利

JP2008221125A Humidity conditioning and gas adsorption material and manufacturing method of the same 有权
标题翻译：湿度调节和气体吸收材料及其制造方法
公开(公告)号：JP2008221125A
公开(公告)日：2008-09-25
申请号：JP2007062849
申请日：2007-03-13
申请人： Hokkaido Univ , Sanki Tsuuun Kk , Shizen Sozai Kenkyusho:Kk , Wakkanai Green Factory:Kk , 三岐通運株式会社 , 国立大学法人北海道大学 , 有限会社稚内グリーンファクトリー , 株式会社自然素材研究所
发明人： NAGANO KATSUNORI , YOSHIDA SHIGEO , TOGAWA JUNYA , ITO HARUJI
IPC分类号： B01J20/14 , A61L9/01 , A61L9/16 , B01D53/28
摘要： PROBLEM TO BE SOLVED: To provide a functional material which uses siliceous shale, is excellent in both of humidity conditioning and gas adsorption and can be used for various purposes by further adding the high gas adsorption function for different gas, to the siliceous shale known to have high humidity conditioning ability and high adsorption ability for basic gas, and to provide a technique capable of easily and freely imparting a desired performance according to use to the siliceous shale and, thereby, capable of freely designing the functional material having the various characteristics above described.
SOLUTION: The humidity conditioning and gas adsorption material comprises the siliceous shale having a micropore diameter distribution measured according to a nitrogen adsorption method, wherein the micropore diameter has a peak in two regions of the range of 10-13 nm and 3.0 nm or less and the average micropore diameter falls into the range of 11 to 14 nm.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：为了提供使用硅质页岩的功能材料，在湿度调节和气体吸附两者都是优异的，并且可以通过进一步将不同气体的高气体吸附功能添加到硅质中而用于各种目的已知具有高的调湿能力和对碱性气体的高吸附能力的页岩，并且提供一种能够根据硅质页岩容易且自由地赋予期望性能的技术，从而能够自由地设计具有上述各种特征。解决方案：湿度调节和气体吸附材料包括根据氮吸附法测量的微孔直径分布的硅质页岩，其中微孔直径在10-13nm和3.0nm范围内的两个区域中具有峰值以下，平均微孔直径为11〜14nm的范围。版权所有（C）2008，JPO＆INPIT

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