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    • 3. 发明授权
    • Separation of chlorosilanes by liquid extraction
    • 通过液体萃取分离氯硅烷
    • US4402796A
    • 1983-09-06
    • US419855
    • 1982-09-20
    • Ollie W. MarkoStefan F. Rentsch
    • Ollie W. MarkoStefan F. Rentsch
    • C01B33/107C07F7/20
    • C07F7/20C01B33/1071
    • This invention relates to a method of separating close-boiling chlorosilanes from mixtures by employing the technique of liquid extraction with sulfolane and a hydrocarbon compound as co-solvents. The hydrocarbon compound employed is substantially immiscible in sulfolane and is present in sufficient amounts so that two liquid phases are formed, one being suloflane-rich and the other being hydrocarbon-rich. The mixture of chlorosilanes is intimately mixed with the two solvents and allowed to partition between the two phases. The preferred liquid extraction procedure is where the sulfolane and hydrocarbon solvent are in a countercurrent relationship within an extraction tower. Experimentally determined selectivity coefficients show that mixtures of (1) dimethyldichlorosilane and methyltrichlorosilane, (2) phenylmethyldichlorosilane and phenyltrichlorosilane, and (3) trimethylchlorosilane and tetrachlorosilane can be successfully separated by the techniques of this invention.
    • 本发明涉及通过采用液体萃取技术与环丁砜和烃化合物作为共溶剂分离近沸点氯硅烷的方法。 使用的烃化合物在环丁砜中基本上是不混溶的,并且以足够的量存在,从而形成两个液相,一个是富含氟烷烃,另一个是富烃的。 氯硅烷的混合物与两种溶剂紧密混合并允许在两相之间分配。 优选的液体提取方法是环丁砜和烃溶剂在萃取塔内呈逆流关系。 实验确定的选择性系数表明,通过本发明的技术可以成功地分离(1)二甲基二氯硅烷和甲基三氯硅烷,(2)苯基甲基二氯硅烷和苯基三氯硅烷和(3)三甲基氯硅烷和四氯硅烷的混合物。
    • 6. 发明授权
    • Separation of chlorosilanes by extractive distillation
    • 通过萃取蒸馏分离氯硅烷
    • US4402797A
    • 1983-09-06
    • US419856
    • 1982-09-20
    • Roland L. HalmStefan F. Rentsch
    • Roland L. HalmStefan F. Rentsch
    • C01B33/107B01D3/40C07F7/20
    • C07F7/20B01D3/40
    • An improved method for the separation of close-boiling chlorosilanes is described. The method consists of the extractive distillation of the close-boiling chlorosilanes using sulfolane as the extractive solvent and thereafter separating the higher-boiling chlorosilane and sulfolane by distilling the higher-boiling chlorosilane from the higher-boiling chlorosilane and sulfolane mixture to which is added a hydrocarbon solvent. Preferred hydrocarbon solvents include normal-heptane, normal-nonane, and 2,2,4-trimethylpentane. The sulfolane obtained from the higher-boiling chlorosilane and sulfolane mixture is suitable for recycling to the extractive distillation process as the sulfolane contains only limited amounts of dissolved chlorosilane.
    • 描述了一种用于分离近沸点氯硅烷的改进方法。 该方法采用环丁砜萃取溶剂萃取蒸馏近沸点氯硅烷,然后将高沸点氯代硅烷从高沸点氯硅烷和环丁砜混合物中分离出来,分离出高沸点氯硅烷和环丁砜, 烃溶剂。 优选的烃溶剂包括正庚烷,正壬烷和2,2,4-三甲基戊烷。 由较高沸点的氯代硅烷和环丁砜混合物得到的环丁砜适用于回收循环,因为环丁砜仅含有限量的溶解氯硅烷。