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1. 发明授权

US08741337B2 Encapsulation of oxidatively unstable compounds 有权
标题翻译：氧化不稳定化合物的包封
公开(公告)号：US08741337B2
公开(公告)日：2014-06-03
申请号：US12811479
申请日：2009-01-02
申请人： William A. Hendrickson , John M. Finney , Olaf C. Moberg , Christopher J. Rueb , Robert G. Bowman , Chetan S. Rao , Nita M. Bentley
发明人： William A. Hendrickson , John M. Finney , Olaf C. Moberg , Christopher J. Rueb , Robert G. Bowman , Chetan S. Rao , Nita M. Bentley
IPC分类号： A61K9/127 , A61J3/07 , A23L2/00 , A23L1/221
CPC分类号： A23L2/39 , A23L2/52 , A23L27/72 , A23L33/105 , A23L33/12 , A23L33/16 , A23P10/30 , A61K9/5015 , A61K9/5036 , A61K9/5063 , A61K9/5073
摘要： An encapsulated material containing an oxidation-sensitive core is covered by at least a dried phospholipid layer, and contains at least one phytosterol in the core, the phospholipid layer or in a further layer or layers. By using microencapsulation, oxidatively unstable materials may be provided with a synthetic protective barrier and rendered less susceptible to oxidative degradation.
摘要翻译：含有氧化敏感核心的包封材料至少被干燥的磷脂层覆盖，并且在芯部，磷脂层中或在另外的层中含有至少一种植物甾醇。通过使用微胶囊化，氧化不稳定的材料可以具有合成的保护屏障，并且对氧化降解的影响较小。

2. 发明授权

US08252354B2 Manufacture of seed derivative compositions 有权
标题翻译：种子衍生物组合物的制造
公开(公告)号：US08252354B2
公开(公告)日：2012-08-28
申请号：US12802337
申请日：2010-06-04
申请人： John M. Finney , Christopher J. Rueb , William A. Hendrickson , Daniel R. Roesler , Robert G. Bowman , David A. Canfield
发明人： John M. Finney , Christopher J. Rueb , William A. Hendrickson , Daniel R. Roesler , Robert G. Bowman , David A. Canfield
IPC分类号： A23L1/10
CPC分类号： A23L1/366 , A21D2/266 , A23L25/30 , A23L29/238
摘要： A method is used to separate fractions from a seed. This can be done by: a) Physically breaking down the Chia seed into smaller particles; b) Adding a liquid carrier to the broken Chia seed to form a Chia liquid carrier blend; c) Optionally providing further processing of the Chia liquid carrier blend to further reduce the particle size of the Chia particles d) Optionally centrifuging the Chia liquid carrier blend; e) Optionally forming at least three discernible layers of materials within the centrifuged Chia liquid carrier blend; f) Optionally separating the composition of at least one layer from remaining layers; and g) Optionally combining the separated layers together into a desired combination/ratios h) Drying the separated layers or combined layers into a flowable powder.
摘要翻译：一种方法用于从种子中分离级分。这可以通过以下方式完成：a）将Chia种子物理分解成更小的颗粒; b）将液体载体添加到破碎的Chia种子中以形成Chia液体载体共混物; c）任选地提供Chia液体载体共混物的进一步处理以进一步降低Chia颗粒的粒度d）任选地将Chia液体载体共混物离心; e）任选地在离心的Chia液体载体共混物内形成至少三个可辨别的材料层; f）任选地将至少一层的组合物与剩余的层分离; 和g）任选地将分离的层合在一起形成所需的组合/比例h）将分离的层或组合层干燥成可流动的粉末。

3. 发明授权

US06562986B2 Process for the direct oxidation of olefins to olefin oxides 失效
公开(公告)号：US06562986B2
公开(公告)日：2003-05-13
申请号：US10079112
申请日：2002-02-19
申请人： Robert G. Bowman , Alex Kuperman , Howard W. Clark , George E. Hartwell , Garmt R. Meima
发明人： Robert G. Bowman , Alex Kuperman , Howard W. Clark , George E. Hartwell , Garmt R. Meima
IPC分类号： C07D30110
CPC分类号： B01J23/66
摘要： A process and catalysts for the direct oxidation of an olefin having three or more carbon atoms, such as propylene, by oxygen to an olefin oxide, such as propylene oxide. The process involves contacting the olefin under reaction conditions with oxygen in the presence of hydrogen and a catalyst. The catalyst contains silver and titanium, optionally gold, and optionally, at least one promoter element selected from Group 1, Group 2, zinc, cadmium, the lanthanide rare earths, and the actinide elements. Suitable supports include titanium dioxide, titanium dioxide on silica, titanosilicates, promoter metal titanates, titanium dispersed on silica and promoter metal silicates.

4. 发明授权

US5304688A Process for the preparation of bishydroxy aromatic compounds 失效
标题翻译：二羟基芳族化合物的制备方法
公开(公告)号：US5304688A
公开(公告)日：1994-04-19
申请号：US46696
申请日：1993-04-13
申请人： Robert G. Bowman , Muthiah N. Inbasekaran
发明人： Robert G. Bowman , Muthiah N. Inbasekaran
IPC分类号： C07C37/20 , C07C39/20 , C07C39/16
CPC分类号： C07C37/20 , C07C2103/18
摘要： A process for the preparation of bishydroxy aromatic compounds, such as 9,9-bis(4-hydroxyphenyl)fluorene, involving contacting a ketone, such as fluorenone, with phenol or substituted phenol in the presence of a mercaptan cocatalyst and a solid superacid catalyst of Hammett acid strength H.sub.0 greater than about -13.0. Solid superacid catalysts include the sulfates, sulfated oxides, sulfated oxyhydroxides, and sulfated oxysilicates of aluminum, tin, and the Group IVA metals, such as zirconium, as well as mixed metal oxides, such as tungsten-zirconium oxides. Isolated yields are high for 9,9-bis(4-hydroxyphenyl)fluorene.
摘要翻译：一种制备双羟基芳族化合物如9,9-双（4-羟基苯基）芴的方法，包括使一种酮如芴酮与苯酚或取代的苯酚在硫醇助催化剂和固体超强酸催化剂存在下接触哈米特酸强度H0大于约-13.0。固体超强酸催化剂包括铝，锡和ⅣA族金属如锆的硫酸盐，硫酸化氧化物，硫酸化羟基氧化物和硫酸化硅酸盐，以及诸如钨 - 锆氧化物的混合金属氧化物。 9,9-双（4-羟基苯基）芴的分离收率高。

5. 发明授权

US5239105A Catalytic formation of diarylcarbonates 失效
标题翻译：二芳基碳酸酯的催化形成
公开(公告)号：US5239105A
公开(公告)日：1993-08-24
申请号：US828339
申请日：1992-01-30
申请人： R. Garth Pews , Robert G. Bowman
发明人： R. Garth Pews , Robert G. Bowman
IPC分类号： C07C68/02
CPC分类号： C07C68/02
摘要： Diphenylcarbonate is produced by contacting phenol with phosgene or phenylchloroformate or mixture thereof in the presence of one or more heterogeneous catalysts. The catalysts include Group VB metal oxides: silicates of Groups IIA, IIIB, IVB, VB, and the lanthanide and actinide metals: tungsten oxides: and clays. The more preferred catalysts are silicates of yttrium, titanium, or zirconium.
摘要翻译：通过在一种或多种非均相催化剂的存在下使苯酚与氯气或氯代苯甲酸苯酯或其混合物接触来制备碳酸二苯酯。催化剂包括VB族金属氧化物：IIA，IIIB，IVB，VB族的硅酸盐，以及镧系元素和锕系金属：氧化钨和粘土。更优选的催化剂是钇，钛或锆的硅酸盐。

6. 发明授权

US5118850A Catalytic reforming of alkyleneamines to linearly-extended polyalkylenepolyamines 失效
标题翻译：将亚烷基胺催化重整成线性延伸的聚亚烷基多胺
公开(公告)号：US5118850A
公开(公告)日：1992-06-02
申请号：US611244
申请日：1990-11-09
申请人： Robert G. Bowman , David C. Molzahn , George E. Hartwell
发明人： Robert G. Bowman , David C. Molzahn , George E. Hartwell
IPC分类号： C07C209/64
CPC分类号： C07C209/64
摘要： A process for reforming alkyleneamines to predominantly linearly-extended polyalkylenepolyamines comprising contacting an alkyleneamine or mixture thereof with a catalyst under conditions such that a mixture of polyalkylenepolyamines enriched in linearly-extended products is formed, said catalyst containing at least one compound selected from the group consisting of (a) Group VB metal oxides, (b) Group VB metal phosphates, (c) silicates of Groups IIA, IIIB, IVB, VB, and the lanthanide and actinide metals, and (d) tungsten oxdies, with the proviso that the silicates and tungsten oxides are essentially free of aluminum. For example, ethylenediamine is contacted with a catalyst of niobium phosphate or niobic acid under reaction conditions to yield predominantly non-cyclic polyethylenepolyamines.
摘要翻译：一种将亚烷基胺重整为线性延伸的聚亚烷基多胺的方法，包括在形成富含线性延伸产物的多亚烷基多胺的混合物的条件下使亚烷基胺或其混合物与催化剂接触，所述催化剂含有至少一种选自以下的化合物：（a）VB族金属氧化物，（b）VB族金属磷酸盐，（c）IIA，IIIB，IVB，VB族和镧系元素和锕系金属的硅酸盐，（d）钨氧化物，条件是硅酸盐和钨氧化物基本上不含铝。例如，乙二胺在反应条件下与磷酸铌或铌酸的催化剂接触，主要产生非环状聚亚乙基多胺。

7. 发明授权

US5030740A Process for preparing linearly-extended polyalkylenepolyamines 失效
标题翻译：制备线性延伸的聚亚烷基多胺的方法
公开(公告)号：US5030740A
公开(公告)日：1991-07-09
申请号：US257891
申请日：1988-10-14
申请人： Robert G. Bowman , David C. Molzahn , George E. Hartwell
发明人： Robert G. Bowman , David C. Molzahn , George E. Hartwell
IPC分类号： C07D295/08 , B01J23/30 , B01J27/24 , B01J31/02 , C07B61/00 , C07C209/16 , C07C211/14 , C07C213/02 , C07C215/14 , C07D295/023 , C07D295/12 , C08G73/02
CPC分类号： C07D295/023 , C07C209/16 , C08G73/0206 , C08G73/024 , C08G73/0273
摘要： A process for preparing linearly-extended polyalkylenepolyamines, such as linear and branched polyethylenepolyamines, comprising contacting a difunctional aliphatic alcohol, such as monoethanolamine, with a reactant amine, such as ethylenediamine, in the presence of a catalyst containing tungsten oxide essentially free of the metals of Groups VIII, IB, and IIB of the Periodic Table. Included among the linearly-extended polyalkylenepolyamines are alcohol-extended piperazines, such as N-(2-hydroxyethyl)-piperazine, and amine-extended piperazines, such as N-(2-aminoethyl)piperazine.
摘要翻译：制备线性延伸的聚亚烷基多胺如线性和支化聚亚乙基多胺的方法，包括使二官能脂肪醇如单乙醇胺与反应物胺如乙二胺在含有基本上不含金属的氧化钨的催化剂存在下接触的元素周期表VIII，IB和IIB族。在线性延伸的聚亚烷基多胺中包括醇延伸的哌嗪，例如N-（2-羟乙基） - 哌嗪和胺扩展的哌嗪，例如N-（2-氨基乙基）哌嗪。

8. 发明授权

US4973569A Preparation of group VB metal phosphate catalysts therefor 失效
标题翻译： VB族金属磷酸盐催化剂的制备
公开(公告)号：US4973569A
公开(公告)日：1990-11-27
申请号：US475581
申请日：1990-02-06
申请人： Robert G. Bowman , George E. Hartwell
发明人： Robert G. Bowman , George E. Hartwell
IPC分类号： C07D295/023 , C07D295/088 , C07D295/13
CPC分类号： C07D295/023 , C07D295/088 , C07D295/13
摘要： A process for preparing alkyl-extended, alcohol-extended or amine-extended piperazines or mixtures thereof comprising contacting a difunctional aliphatic alcohol with a reactant amine, wherein at least one of the aliphatic alcohol or the reactant amine contains a piperazine moiety, in the presence of a catalyst containing a Group VB metal oxide or a Group VB metal phosphate, or mixtures thereof. For example, monoethanolamine reacts with piperazine in the presence of a catalyst of niobic acid supported on hydrated alumina to yield predominantly N-(2-aminoethyl)piperazine. Also, N-hydroxyethylpiperazine reacts with piperazine in the presence of a catalyst of niobium phosphate to yield predominantly 1,2-bis(piperazinyl)-ethane.
摘要翻译：制备烷基延伸的，延伸醇的或胺延伸的哌嗪或其混合物的方法，包括使二官能脂族醇与反应物胺接触，其中至少一种脂族醇或反应物胺含有哌嗪部分，的含VB族金属氧化物或VB族金属磷酸盐的催化剂，或其混合物。例如，单乙醇胺在负载在水合氧化铝上的铌酸催化剂存在下与哌嗪反应，主要产生N-（2-氨基乙基）哌嗪。此外，N-羟乙基哌嗪与磷酸铌催化剂存在下与哌嗪反应，主要产生1,2-双（哌嗪基） - 乙烷。

9. 发明授权

US4891349A Catalyst for preparing amines 失效
标题翻译：用于制备胺的催化剂
公开(公告)号：US4891349A
公开(公告)日：1990-01-02
申请号：US268908
申请日：1988-11-07
申请人： Robert G. Bowman
发明人： Robert G. Bowman
IPC分类号： B01J23/75 , B01J37/03 , C07C209/16 , C07D295/023
CPC分类号： C07D295/023 , B01J23/75 , C07C209/16 , B01J37/03
摘要： A method for producing amines, the method comprising contacting at reactive conditions at least one alcohol, aldehyde or ketone, or a mixture thereof, with an aminating agent in the presence of a catalyst, is improved by employing as the catalyst a composition comprising cobalt, copper, and a third component selected from a group consisting of iron, zinc, zirconium and mixtures thereof.
摘要翻译：一种制备胺的方法，该方法包括在反应条件下使至少一种醇，醛或酮或其混合物与胺化剂在催化剂存在下接触，通过使用包含钴，铜和选自铁，锌，锆及其混合物的第三组分。

10. 发明授权

US4806690A Method of producing amines 失效
标题翻译：生产胺的方法
公开(公告)号：US4806690A
公开(公告)日：1989-02-21
申请号：US732978
申请日：1985-05-13
申请人： Robert G. Bowman
发明人： Robert G. Bowman
IPC分类号： C07D295/02 , B01J21/06 , B01J23/72 , B01J23/74 , B01J23/75 , B01J23/80 , B01J37/03 , C07C209/14 , C07C209/16 , C07C209/26 , C07C211/10 , C07C211/14 , C07C213/02 , C07C215/08 , C07C221/00 , C07C223/02 , C07C225/02 , C07D295/023 , C07C85/06
CPC分类号： C07D295/023 , B01J23/75 , C07C209/16 , B01J37/03
摘要： A method for producing amines, the method comprising contacting at reactive conditions at least one alcohol, aldehyde or ketone, or a mixture thereof, with an aminating agent in the presence of a catalyst, is improved by employing as the catalyst a composition comprising cobalt, copper, and a third component selected from a group consisting of iron, zinc, zirconium and mixtures thereof.

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