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1. 发明申请

WO1992011201A1 METHOD OF ALKALIMONOFLUOROPHOSPATE MANUFACTURE 审中-公开
标题翻译：碱性磷酸盐制造方法
公开(公告)号：WO1992011201A1
公开(公告)日：1992-07-09
申请号：PCT/EP1990002304
申请日：1990-12-24
申请人： KALI-CHEMIE AKTIENGESELLSCHAFT , SWIDERSKY, Hans-Walter , RUDOLPH, Werner , HARTMAN, Ulrich , MOEWIUS, Frank , RADONZ, Veronika , MEISEL, Manfred
发明人： KALI-CHEMIE AKTIENGESELLSCHAFT
IPC分类号： C01B25/455
CPC分类号： C01B25/455
摘要： In a method for manufacturing alkalimonofluorophosphate of general formaula M2PO3F (I), where M stands for the cation of a metal of the first main group of the periodic system, in particular potassium, a reaction mixture containing alkali metal cations M, phosphate, fluoride, particularly in the form of alkali hydroxyde, phosphoric acid and hydrofluoric acid, and water, the molar ratio of M:P:F being (2+/-0,1):(1+/-0.05):(1+/-0.1) and the molar ratio of water:P being at least 1:1, is heated to a temperature of 150 DEG C to 400 DEG C. Alkalimonofluorophosphate of general formula (I) occurs, with evaporation of water, as a reaction product, which is then isolated.
摘要翻译：在一般形式的M2PO3F（I）的碱式氟磷酸盐的制造方法中，M表示周期性系统的第一主要组分的金属的阳离子，特别是钾，含有碱金属阳离子M，磷酸盐，氟化物，特别是碱式氢氧化物，磷酸和氢氟酸以及水的形式，M：P：F的摩尔比为（2 +/- 0,1）:( 1 +/- 0.05）:( 1 +/- 0.1），水的摩尔比为至少1:1，加热至150℃至400℃。通式（I）的三氟磷酸盐，作为反应产物蒸发，然后隔离。

2. 发明申请

WO1995010494A1 PROCESS FOR PRODUCING PENTAFLUOROETHANE AND FOR PURIFYING 1,1,1,2-TETRAFLUOROETHANE 审中-公开
标题翻译：用于生产五氟乙烷和1,1,1,2-四氟乙烷的净化
公开(公告)号：WO1995010494A1
公开(公告)日：1995-04-20
申请号：PCT/EP1994003299
申请日：1994-10-06
申请人： SOLVAY FLUOR UND DERIVATE GMBH , HERKELMANN, Ralf , RUDOLPH, Werner , SANDER, Rüdiger
发明人： SOLVAY FLUOR UND DERIVATE GMBH
IPC分类号： C07C19/08
CPC分类号： C07C17/04 , C07C17/395 , C07C19/08
摘要： The invention relates to a process for producing pentafluoroethane from unsaturated compounds with two carbon atoms substituted by hydrogen and possibly fluorine, especially trifluoroethylene. The process can also be used in a process for purifying R134a of such unsaturated compounds. 1,1,1,2-tetrafluoroethane (R134a), a substitute for CFC be produced by addition reaction of hydrofluorides to trifluoroethylene (R1123). Due to the method, unsaturated CHF components, especially the initial compound, are present as traces in the product and have a toxic effect. It has been found that such unsaturated CHF components in R134a can be removed by reaction with high-valency metal fluorides, especially CoF3. Pentafluoroethane (R125) is formed which is not toxic and can, if desired, be removed from the R134a by ordinary processes like distillation and is a useful substance. Surprisingly, R125 and R134a are not fully fluorinated by high-valency metal fluorides in suitable conditions.
摘要翻译：本发明涉及一种用于从具有两个，与氢和任选氟取代的碳原子，特别是从三氟属不饱和化合物生产五氟乙烷的方法。该方法也可以在为R134a的的这类不饱和化合物的纯化方法中使用。 1,1,1,2-四氟乙烷（R134a）等一个CFC替代品，可以通过加入的氟化氢来制备，以三氟乙烯（R1123）。不饱和CHF组件，特别是原料化合物是，由于包含在产品中的痕迹的处理，并且具有毒性作用。现已发现，在R134a的这种不饱和CHF部件通过用高价金属氟化物反应，尤其是失效后果3可以被去除。它形成五氟乙烷（R125），其是无毒的，并且，如果需要，通过常规方法，例如可以从R-134a的通过蒸馏分离，并表示一个有价值的材料。令人惊讶地，没有从高价金属氟化物R125和R134a合适的条件下durchfluoriert。

3. 发明申请

WO1998024750A1 PRODUCTION OF CARBOXYLIC ACID FLUORIDES 审中-公开
标题翻译：生产碳素酰基氟
公开(公告)号：WO1998024750A1
公开(公告)日：1998-06-11
申请号：PCT/EP1997006647
申请日：1997-11-28
申请人： SOLVAY FLUOR UND DERIVATE GMBH , BRAUN, Max , EICHHOLZ, Kerstin , RUDOLPH, Werner
发明人： SOLVAY FLUOR UND DERIVATE GMBH
IPC分类号： C07C51/58
CPC分类号： C07C51/60 , B01J19/02 , B01J19/123 , B01J2219/00078 , B01J2219/0245 , B01J2219/0254 , B01J2219/0875 , C07C51/58 , C07C53/50 , C07C53/48 , C07C53/46
摘要： The invention relates to a method for the production of carboxylic acid fluorides of the formula RCFXC(O)F, wherein X designates F or Cl. Compounds of the formula RCFXCHFCl are reacted with oxygen by photochemical oxidation in the gaseous phase. This yields good quantities of highly selective carboxylic acid fluorides. It is preferable to work under sensitization with chlorine and light at a wavelength of lambda >/=280 nm. This makes it possible to work without the use of pressure. Glass apparatus may be covered with a protective coating so as to protect it against traces of hydrogen fluoride. To this end, for example, heat-shrinkable sleeves made of translucent hydrogen fluoride-resistant material may be used. Polytetrafluoroethylene, polyfluoropropylene or a mixture thereof are especially suitable for this purpose. This type of protection is also suited for other reactions, such as photo-induced fluoro-dediazonation in hydrogen fluoride/pyridine for the production of aromatic compounds fluorinated in the nucleus or the oxidation of CHCL2 groups for the production of carboxylic acid fluorides.
摘要翻译：公开的是用于制备式RCFXC（O）F，其中X是F或Cl的羧酸氟化物的方法。反应与氧气式RCFXCHFCl的化合物转化成在气相中的光化学氧化。形成以良好的收率和高选择性的羧酸氟化物。优选在敏化进行与波长为λ的氯和光> / = 280纳米。这是可能的，而不的工作压力。玻璃装置可被提供用于防止RF迹线以保护涂层。对于这一个就可以了，例如，热收缩使用耐HF，半透明材料制成。作为该材料聚四氟乙烯，Polyfluorpropylen或它们的混合物是特别合适的。这种保护也适用于其它反应，例如，光诱导氟dediazoniation在氟化氢/吡啶生产核氟化的芳族化合物的或CHCl 2的基团为羧酸氯化物的制剂的目的氧化的目的。

4. 发明申请

WO1997000847A1 DIFLUOROCHLORACETYL, DICHLORACETYL AND TRICHLORACETYL CHLORIDE PREPARATION 审中-公开
标题翻译：制造DIFLUORCHLOR-，二氯和三氯
公开(公告)号：WO1997000847A1
公开(公告)日：1997-01-09
申请号：PCT/EP1996002596
申请日：1996-06-17
申请人： SOLVAY FLUOR UND DERIVATE GMBH , BRAUN, Max , RUDOLPH, Werner , EICHHOLZ, Kerstin
发明人： SOLVAY FLUOR UND DERIVATE GMBH
IPC分类号： C07C53/48
CPC分类号： C07C51/58 , C07C53/48
摘要： A process is disclosed for preparing chlorodifluoracetyl chloride from 1,1,-difluor-2,2-dichlorethylene, dichloracetyl chloride from trichlorethylene or 1,1,2,2-tetrachlorethane and trichloracetyl chloride from tetrachlorethylene. Said starting compounds are continuously reacted in the gaseous phase with oxygen to obtain a photochemical oxidation reaction, chlorine being optionally added as a sensitiser. When chlorine is added, the reaction mixture is irradiated with light with a wavelength lambda >/= 280 nm. The reaction is preferably carried out without pressure. Particularly high yields with high selectivity are reached by using doped high-pressure mercury-vapour lamps.
摘要翻译：描述了从1,1-二氟-2,2-二氯乙烯，三氯乙烯，1,1,2,2-四氯乙烷的二氯乙酰氯和三氯乙酰氯从四氯乙烯制备的氯化chlorodifluoroacetyl的方法。它连续地转换的起始化合物光化学氧化提到以便与氧气，氯气可以添加作为增感剂，并在气相中进行操作。该反应在除了该照射波长为λ> / = 280纳米的光的氯等的情况下进行。优选进行无压力。特别强高Selektivitiät的销售使用掺杂高压汞灯时来实现。

5. 发明专利

AT325966B 未知
公开(公告)号：AT325966B
公开(公告)日：1975-11-25
申请号：AT758672
申请日：1972-09-04
申请人： MESSMER GRETA , MONNERJAHN WALTER , RUDOLPH WERNER
IPC分类号： F21S2/00 , B60Q7/00

6. 发明专利

DE2145146A1 未知
公开(公告)号：DE2145146A1
公开(公告)日：1973-03-15
申请号：DE2145146
申请日：1971-09-09
申请人： MESSMER GRETA , MONNERJAHN WALTER , RUDOLPH WERNER
发明人： MONNERJAHN WALTER , RUDOLPH WERNER
IPC分类号： F21S2/00 , B60Q7/00

7. 发明专利

DE1845877U 未知
公开(公告)号：DE1845877U
公开(公告)日：1962-02-01
申请号：DER0023322
申请日：1961-12-01
申请人： RUDOLPH WERNER
发明人： RUDOLPH WERNER

8. 发明专利

CA2087354A1 PROCESS FOR WORKING UP A HYDROGEN FLUORIDE PHASE FROM A FLUORINATION REACTION MIXTURE 未知
公开(公告)号：CA2087354A1
公开(公告)日：1993-07-16
申请号：CA2087354
申请日：1993-01-15
申请人： EICHER JOHANNES , RUDOLPH WERNER , SCHULTE BERNHARD , SOLVAY FLUOR & DERIVATE
发明人： EICHER JOHANNES , RUDOLPH WERNER , SCHULTE BERNHARD
IPC分类号： C01B7/19 , C07C17/20 , C07C17/21 , C07C17/38 , C07C19/08 , B01D53/26
摘要： A process for working up the hydrogen fluoride phase of reaction mixtures from fluorination reactions comprising contacting the hydrogen fluoride phase with oleum in order to obtain dried hydrogen fluoride, which can be recycled to the fluorination reaction.

9. 发明专利

ATA758672A 未知
公开(公告)号：ATA758672A
公开(公告)日：1975-01-15
申请号：AT758672
申请日：1972-09-04
申请人： MESSMER GRETA , MONNERJAHN WALTER , RUDOLPH WERNER
IPC分类号： F21S2/00 , B60Q7/00

10. 发明专利

DE7134384U 未知
公开(公告)号：DE7134384U
公开(公告)日：1972-03-16
申请号：DE7134384
申请日：1971-09-09
申请人： MESSMER G , MONNERJAHN W , RUDOLPH WERNER

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